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UNITED STATES ENVIRONMENTAL PROTECTION REGION 4 Science and Ecosystem Support Division Enforcement and Investigations Branch 980 College Station Road Athens, Georgia 30605-2720
4SESD-EIB
January31, 2011
FEB
SESD Final Field Investigation Report for Hercules Inc., Hattiesburg, Mississippi EPA ID No. MSD 008 182 081; SESD Project No. 10-0629
FROM:
Sharon Matthews, PG Enforcement Section
, ‘
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THRU:
Laura Ackerman, Chief Enforcement Section
TO:
Larry Lamberth, Chief South Enforcement and Compliance Section RCRA & OPA Enforcement and Compliance Branch RCRA Division Attached is the final Field Investigation Report for the sampling conducted at
Hercules Inc. in Hattiesburg, Mississippi on September 28-29, 2010. If you have any questions, please contact me at matthews.sharon(epa.gov. or at (706) 355-8608.
Attachment
Randy Jackson, RCRA w/attachment Willie McKercher, MDEQ w/attachment Jan Patton, MDEQ w/ attachment
VED —
7 2011
Dept oj Eaviro Office of Poi:JgJitY
MEMORANDUM SUBJECT:
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United States Environmental Protection Agency Region 4 Science and Ecosystem Support Division 980 College Station Road Athens, Georgia 30605-2720 S7. .
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Field Investigation Report Hercules Inc. Hattiesburg, Mississippi Date of Final Report: January 31, 2011 SESD Project Identification Number: 10-0629 Requestor: Randy Jackson South Enforcement & Compliance Section RCRA & OPA ECB, RCRA Division 61 Forsyth Street, SW Atlanta, GA 30303-8960
SESD Project Leader: Sharon Matthews SESD Enforcement Section 980 College Station Road Athens, Georgia 30605-2720
___________ ________
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Title and Approval Sheet
Title: Hercules Inc. Field Investigation Report
Approving Official:
Lau a Ackerman, Section Chief Enforcement Section Enforcement and Investigations Branch
Date
SESD Project Leader:
rj Sharon Matthews, PG Enforcement Section Enforcement and Investigations Branch
SESD PROJECT NO. 10-0629
Date
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0 FIELD INVESTIGATION REPORT Hercules Inc., Hattiesburg, Mississippi SESD Project Identification Number: 10-0629 I. INTRODUCTION On September 28-29, 2010, representatives of the Science and Ecosystem Support Division (SESD) conducted a sampling investigation at the Hercules Inc. facility in Hattiesburg, Mississippi. This field investigation was requested by the EPA South Enforcement & Compliance Section, RCRA Division and the Mississippi Department of Environmental Quality (MDEQ) as part of the EPA Surface Impoundment Initiative. In April 2008, Hercules Inc. informed the MDEQ that an onsite impoundment basin was to be closed. MDEQ requested additional information on closure operations including a request for Hercules to characterize the sludge. After three sampling events, the results indicated some areas of the sludge exhibited hazardous characteristics for benzene. A notice of violation (NOV) was issued in November 2008 to the facility. MDEQ contacted the EPA to see if they would conduct sampling and analysis of the sludge disposal area from prior surface impoundment clean-outs to determine if illegal disposal had occurred. The sludge disposal area is located on the ‘back forty” of the facility’s 170 acres, and spans an area of 6 to 7 acres. Personnel that participated in the investigation included: Randy Jackson Paula Whiting Araceli Bonilla Jan Patton Willie McKercher Gloria Tatum Rick Sumrall Charles Jordan Kipper Montgomery Kevin Simmons Art Masters Bill Simpson Marty Allen Sharon Matthews
EPA Region 4-Atlanta, GA EPA Region 4-Atlanta, GA EPA Region 4-Atlanta, GA MDEQ Jackson, MS MDEQ Jackson, MS MDEQ Jackson, MS MDEQ Jackson, MS Hercules- Hattiesburg, MS Arcadis Baton Rouge, LA EPA Region 4-Athens, GA EPA Region 4-Athens, GA EPA Region 4- Athens, GA EPA Region 4-Athens, GA EPA Region 4-Athens, GA —
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—
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(404) 562-8464 (404) 562-9277 (404) 562-9790 (601) 961-5782 (601) 961-5731 (601) 961-5011 (601) 961-5791 (601) 584-3360 (225) 292-1004 (706) 355-8730 (706) 355-8612 (706) 355-8748 (706) 355-8651 (706) 355-8608
II. SUMMARY SESD collected a total of thirteen subsurface waste samples, twelve from the “back forty” area and one from the “wetlands” area. Samples were analyzed for volatile organic compounds (VOC5), semi volatile organic compounds (SVOC5), metals and TCLP. MDEQ and EPA requested the analytical data be compared to residential levels for soil given in the Tier 1 Target Remediation Goals (TRGs) and the most recent USEPA Regional Screening levels (RSLs).
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Eighteen volatile organic compounds were detected in the thirteen samples. Benzene failed the TCLP regulatory limit of 0.5 mg/L in six of the samples and was detected in ten samples. Toluene and p-isopropyltoluene were detected in all thirteen samples. Methylcyclohexane and 1, 2, 4-trimethylbenzene were detected in eleven samples and. Cyclohexane was detected in nine samples and ethyl beuzene was detected in eight samples. The remainder of the VOCs were detected in six or less of the samples. Forty SVOCs were detected in the thirteen samples. None of the SVOCs failed TCLP for the thirteen samples. The compound 1, 1 -biphenyl was detected in twelve of the thirteen samples and petroleum product was detected in eleven of the samples. Phenol, hexahydro tetramethylmethanonaphthalene (TIC) and dimethylisopropyiphenanthrene (TIC) were detected in ten of the samples. Nine samples contained camphene, 2-methylnaphthalene, and naphthalene. Eight of the samples contained diphenyl ether (TIC), (3-and/or 4) methylphenol, methyl (methylethyl) benzene (TIC), methyl (methylethyl)cyclohexane (TIC), and trimethyl bicycloheptane (TIC). Seven of the samples contained 2-methyiphenol, fluoranthene and pinene (TIC). The remainder of the SVOCs were detected in six or less of the samples. Twenty-two metals were detected in the thirteen samples with seventeen detected in all of the samples. Arsenic was detected in samples HERCO4-B, HERCO5-A, HERC1O-B and HERC 13-B at levels that exceeded both the MDEQ and EPA regulatory levels with values ranging from 5.0 to 6.4 mg/kg. None of the samples exceeded the MDEQ and EPA regulatory levels for Chromium III; however, all of the samples exceeded the EPA regulatory level of 0.29 mg/kg for Chromium VI. Vanadium was detected in samples HERCO3-B, HERCO4-B, HERCO5A, HERCO8, HERCO9-B, HERC1O-B, HERC1 1-B, HERC12-B and HERC13-B at levels that exceeded the EPA regulatory level of 5.5 mg/kg with values ranging from 5.6 to 18 mg/kg. No other metal concentrations exceeded the MDEQ and EPA regulatory levels. None of the metals failed TCLP for the thirteen samples. III. SITE BACKGROUND The facility is located at 613 West Seventh Street in Hattiesburg, Mississippi (Figure 1). Facility operations, which began in 1923, included wood grinding, shredding extraction, fractionation, refining, distillation and processing of rosin from pine tree stumps. Some of the products that were manufactured included modified resins, polyamides, ketene dimmer, crude tall oil wax emulsions, synthetic rubber and the agricultural pesticide Delnav. Hercules also manufactured specialty organic chemicals for use in paper products. Over 250 products were produced at the facility. Hercules downsized the Hattiesburg operations and has now ceased operations. A state preliminary assessment was completed in December 1989 and indicated two source areas which included about 38 acres of contaminated soil and almost 900,000 cubic feet of surface impoundments. The contaminated soil contained cadmium, cobalt, lead, mercury, toluene, MEK, benzene, PCBs and acetone. Contaminants present in the surface impoundments included arsenic, heavy metals, toluene, MEK and benzene. In April 2008 the facility sent a letter to MDEQ to close an onsite impoundment basin. MDEQ requested additional information on closure operations including a request for Hercules to characterize the sludge. After three sampling events, the results indicated some areas of the SESD PROJECT NO. 10-0629
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sludge exhibited hazardous characteristics for benzene. A notice of violation (NOV) was issued November 2008. Prior surface impoundment clean-outs had been taken to a landfill disposal area located on the ‘back forty” of the facility’s 170 acres, spanning an area of 6 to 7 acres. According to information from MDEQ, the “back forty” had been used to dispose of process wastes, boiler ash and waste treatment sludge from plant activities. A compliance evaluation inspection conducted by MDEQ in March 2009 resulted in several violations involving the surface impoundment and closure/post-closure procedures. MDEQ then requested EPA’s assistance in sampling and testing the sludge disposal area to determine if illegal disposal had occurred. IV. IMSSCUSSION OF FIELD ACTIVITIES SESD personnel arrived at the site Tuesday, September 28, 2010 at around 7:45 am and met with EPA-Atlanta, MDEQ and facility personnel to assess the proposed sampling areas. Using an authoritative sampling design, sampling locations were determined in the field by MDEQ and EPA personnel based on access and prior knowledge of the site. Twelve borings were completed using Geoprobe direct-push technology or hand auger in the ‘back forty” disposal area. Total depth of the sludge had been estimated to be around 14 to 16 feet below land surface but was actually closer to 5 to 8 feet in depth. Two samples had been proposed from the wetlands, but only one could be collected due to the high quantity of vegetative material/roots. Two samples had been proposed from the impoundment outfall, but those sample locations were deleted and added to the samples to be collected from the “back forty”. Samples from the sludge disposal area were collected based on visual observations and screening results obtained with the Thermo Toxic Vapor Analyzer (TVA) 1000B. All samples were analyzed for VOCs, SVOCs, metals and TCLP. Table 1 gives information on the waste samples. Sampling locations are shown on Figures 3, 4 and 5. Photographs taken during the investigation are included in Appendix A. Waste Samples Under the direction of EPA-Atlanta and MDEQ personnel, sample HERCO1-A was collected from the “back forty” using Geoprobe direct-push equipment to a depth of 0 to 4 feet below land surface (BLS). The core was screened with a Thenno Toxic Vapor Analyzer (TVA) 1 000B. The sample was described as a black organic rich material with a strong odor of pine. The waste sample core was placed in a glass pan and using a stainless steel spoon, three 8-ounce glass containers were filled for the VOC, SVOC and total metals analyses. The VOC sample was collected first, and then the remainder of the sample was homogenized in the glass pan. The facility elected to split with EPA for all samples and supplied one 4-ounce amber glass container for VOCs, one 16-ounce glass container for SVOCs and one 8-ounce plastic container for metals. For sample EIERCO2-B, a stainless steel hand auger was used to auger to 5 feet BLS. The waste sample was collected from 3.5 to 5 feet BLS and was described as a tan to black sticky material. EPA and facility containers were filled for the VOC, SVOC and total metals analyses using the same procedure described above.
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Sample HERCO3-B was also collected with a stainless steel hand auger from some of the oldest part of the “back forty” sludge disposal area. The waste sample was collected from 4 to 5 feet BLS and was described as a black organic material with a strong odor, sandier at depth. Native material of sand and gravel was noted at about 6 feet BLS. EPA and facility containers were filled for the same analyses using the same procedure described above. Sample HERCO4-B was collected with a stainless steel hand auger from the older part of the “back forty” sludge disposal area. The waste sample was collected from 6 to 7 feet BLS and was described as a black organic material with some odor. EPA and facility containers were filled for the same analyses using the same procedure described previously. Sample HERCO5-A was collected with a stainless steel hand auger from the older part of the “back forty” sludge disposal area. The waste sample was collected from 5.5 to 6.5 feet BLS and was described as a dark organic sludge with a strong odor. EPA and facility containers were filled for the same analyses using the same procedure described before. Sample HERCO6-B was collected with a stainless steel hand auger from 4.5 to 5.5 feet BLS and was described as a dark gray to black sludge with a strong odor, drier material at the surface that became moister and sandier with depth. The sand that was encountered at 5.5 to 6 feet BLS is the sand layer that sits on top of the Hattiesburg clay in this area, indicating native material. EPA and facility containers were filled for the same analyses using the same procedure described previously. Sample HERCO7-B was collected with a stainless steel hand auger from 5.5 to 6 feet BLS and was described as a drier dark organic material which became moister with depth. EPA and facility containers were filled for the same analyses using the same procedure described before. Sample HERCO8 was collected with a stainless steel scoop from the “wetlands” area from a depth of about 3 to 4 inches. The material was mostly cat-tails and detritus with some stratified sludgy material with no odor. Two samples had been proposed from the wetlands, one around the influent and one from the effluent, but only the influent sample could be collected due to the high amount of vegetative material/roots around the effluent area. EPA and facility containers were filled for the same analyses using the same procedure described previously. Sample HERCO9-B was collected from the “back forty” using Geoprobe direct-push equipment. The first core was 0 to 4 feet BLS and was a black organic material. The second core was collected from 4 to 8 feet BLS and was black sludge for the first foot, then native sand. Because the core was compacting inside the core barrel, it was decided to hand auger this and subsequent samples to collect enough material io fill all the EPA and facility sample containers. The sample was collected from 5 to 6 feet BLS and described as a black sludge material. EPA and facility containers were filled for the same analyses using the same procedure described before.
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Sample HERC1O-B was collected with a stainless steel hand auger from 5 to 6 feet BLS. Native sand was encountered at 6 feet BLS. The black sludge sample was collected above the sand and some odor was noted during sampling. EPA and facility containers were filled for the same analyses using the same procedure described previously. Sample HERC11-B was collected with a stainless steel hand auger from 5 to 6 feet BLS. Native sand was encountered at 6 feet BLS. The sample was collected above the sand and was described as a black organic sludge with some odor. EPA and facility containers were filled for the same analyses using the same procedure described before. Sample HERC12-B was collected with a stainless steel hand auger from 4.5 to 5.5 feet BLS. Native sand was encountered at 5.5 feet BLS. The sample was collected above the sand and was described as a black sludge with some odor. EPA and facility containers were filled for the same analyses using the same procedure described previously. Sample HERC13-B was collected with a stainless steel hand auger from 4.5 to 5.5 feet BLS. Native sand was encountered at 5.5 feet BLS. The sample was collected above the sand and was described as a black sludge material with a strong odor and an oily sheen. EPA and facility containers were filled for the same analyses using the same procedure described before. V. RESULTS OF ANALYSES Samples were analyzed for VOCs by SW-846 Methods 8260C, for SVOCs by SW-846 Method 8270D and for total metals by SW-846 Method 6010. Analytical results for the VOC detected analytes in the waste samples are given in Table 2 and the TCLP results are given in Table 3. The MDEQ Tier 1 TRG and EPA Regional Screening Levels (RSLs) for VOCs in residential soils are listed in Table 4. Results for the SVOC-detected analytes are given in Table 5. Because no compounds failed TCLP for SVOCs, there is no TCLP table. The MDEQ Tier 1 TRG and EPA RSLs for SVOCs in residential soils are listed in Table 6. Analytical results for total metals are given in Table 7 and the MDEQ Tier 1 TRG and EPA RSLs for metals are given in Table 8. Because no compounds failed TCLP for metals, there is no TCLP table. The complete set of results generated by the SESD laboratory is included as Appendix B. The following analytes were detected in samples collected at the facility: Volatile Organic Compounds- (Tables 2,3 and 4) Eighteen volatile compounds were detected in the thirteen samples (Table 2). Toluene and p-isopropyltoluene were detected in all thirteen samples. Methylcyclohexane and 1,2,4trimethylbenzene were detected in eleven samples and benzene was detected in ten samples. Cyclohexane was detected in nine samples and ethyl benzene was detected in eight samples. The remaining VOCs were detected in six or less of the samples. Benzene failed the TCLP regulatory limit of 0.5 mg/L in six of the samples (Table 3). Analytical data was compared to the MDEQ and EPA regulatory levels referenced in Table 4. Exceedences are listed below: HERCO 1-A Analytes exceeding the reference standard or level: benzene (18 mg/kg), toluene (7100 mg/kg) -
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HERCO2-B Analytes exceeding the reference standard or level: benzene (37 mg/kg), ethyl benzene (6.5 J, 0 mg/kg), toluene (16000 mg/kg) -
HERCO3-B Analytes exceeding the reference standard or level: benzene (3.4 mg/kg) -
HERCO4-B Analytes exceeding the reference standard or level: benzene (19 mg/kg), toluene (3000 mg/kg) -
HERCO5-A Analytes exceeding the reference standard or level: benzene (14 mg/kg), toluene (5300 mg/kg) -
HERCO6-B Analytes exceeding the reference standard or level: toluene (280 mg/kg) -
HERCO7-B Analytes exceeding the reference standard or level: toluene (1400 mg/kg) -
HERCO8 Analytes exceeding the reference standard or level: none -
HERCO9-B Analytes exceeding the reference standard or level: benzene (170 mg/kg), toluene (1100 mg/kg) -
HERC 10-B Analytes exceeding the reference standard or level: benzene (140 mg/lcg), toluene (3100 mg/kg) -
HERC1 1-B Analytes exceeding the reference standard or level: benzene (77 mg/kg), toluene (2600 mg/kg) -
HERC 12-B Analytes exceeding the reference standard or level: benzene (440 mg/kg), isopropylbenzene (47 mg/kg), toluene (160 mg/kg) -
HERC 13-B Analytes exceeding the reference standard or level: benzene (390 mg/kg), toluene (3400 mg/kg) -
Semi Volatile Organic Compounds (Tables 5 and 6) Forty SVOCs were detected in the thirteen samples (Table 5). The compound 1,1 biphenyl was detected in twelve of the thirteen samples and petroleum product was detected in eleven of the samples. Phenol, dimethylisopropylphenanthrene (TIC), and hexahydro tetramethylmethanonaphthalene (TIC) were detected in ten of the samples. Nine samples contained 2-methylnaphthalene, camphene and naphthalene. Eight of the samples contained diphenyl ether (TIC), (3-and/or 4) methylphenol, methyl(methylethyl)benzene (TIC), methyl(methylethyl)cyclohexane (TIC), and trimethylbicycloheptane (TIC). Seven of the samples contained 2-methyiphenol, fluoranthene and pinene (TIC). The remainder of the SVOCs were detected in six or less of the samples. None of the SVOCs failed TCLP for the thirteen samples. Analytical data was compared to the MDEQ and EPA regulatory levels referenced in Table 6. Exceedences are listed below: -
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HERCO1-A Analytes exceeding the reference standard or level: naphthalene (6.2 mg/kg) -
HERCO2-B Analytes exceeding the reference standard or level: 1,1-biphenyl (3900 mg/kg), naphthalene (8.8 mg/kg) -
HERCO3-B Analytes exceeding the reference standard or level: none -
HERCO4-B Analytes exceeding the reference standard or level: naphthalene (7.8 mg/kg) -
HERCO5-A Analytes exceeding the reference standard or level: naphthalene (8.7 mg/kg) -
HERCO6-B Analytes exceeding the reference standard or level: none -
HERCO7-B Analytes exceeding the reference standard or level: none -
HERCO8 Analytes exceeding the reference standard or level: none -
HERCO9-B Analytes exceeding the reference standard or level: none -
HERC1O-B Analytes exceeding the reference standard or level: naphthalene (6.7 mg/kg) -
HERC 11-B Analytes exceeding the reference standard or level: none -
HERC12-B Analytes exceeding the reference standard or level: naphthalene (3.9 mg/kg) -
HERC1 3-B Analytes exceeding the reference standard or level: naphthalene (5.2 mg/kg) -
Metals (Tables 7 and 8) Twenty-two metals were detected in the thirteen samples (Table 7). Seventeen of the metals were detected in all of the samples. Arsenic was detected in samples HERCO4-B, HERCO5-A, HERC1OB and HERC13-B at levels that exceeded both the MDEQ and EPA regulatory levels with values ranging from 5.0 to 6.4 mg/kg. None of the samples exceeded the MDEQ and EPA regulatory levels for Chromium III; however, all of the samples exceeded the EPA regulatory level of 0.29 mg/kg for Chromium VI with values ranging from 7.7 to 45 mg/kg. Vanadium was detected in samples HERCO3-B, HERCO4-B, HERCO5-A, HERCO8, HERCO9-B, HERC1O-B, HERC1 1-B, HERC12-B arid HERC13-B at levels that exceeded the EPA regulatory level of 5.5 mg/kg with values ranging from 5.6 to 18 mg/kg. No other metal concentrations exceeded the MDEQ and EPA regulatory levels. None of the metals failed TCLP for the thirteen samples. Analytical data was compared to the MDEQ and EPA regulatory levels referenced in Table 8. Exceedences are listed below: HERCO1-A Analytes exceeding the reference standard or level: chromium VI (24 mg/kg) -
HERCO2-B Analytes exceeding the reference standard or level: chromium VI (11 mg/kg) -
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HERCO3-B Analytes exceeding the reference standard or level: chromium VI (7.7mg/kg), vanadium (8.7 mg/kg) -
HERCO4-B Analytes exceeding the reference standard or level: arsenic (6.4 mg/kg), chromium VI (29 mg/kg), vanadium (5.6 mg/kg) -
HERCO5-A Analytes exceeding the reference standard or level: arsenic (5.6 mg/kg), chromium VI (45 mg/kg), vaiadium (6.6 mg/kg) -
HERCO6-B Analytes exceeding the reference standard or level: chromium VI (20 J,O mg/kg) -
HERCO7-B Analytes exceeding the reference standard or level: chromium VI (32 mg/kg) -
HERCO8 Analytes exceeding the reference standard or level: chromium VI (20 mg/kg), vanadium (18 mg/kg) -
HERCO9-B Analytes exceeding the reference standard or level: chromium VI (20 mg/kg), vanadium (5.9 mg/kg) -
HERC 10-B Analytes exceeding the reference standard or level: arsenic (5.0 mg/kg), chromium VI (26 mg/kg), vanadium (7.6 mg/kg) -
HERC1 1-B Analytes exceeding the reference standard or level: chromium VI (25 mg/kg), vanadium (7.2 mg/kg) -
HERC 12-B Analytes exceeding the reference standard or level: chromium VI (18 mg/kg), vanadium (7.5 mg/kg) -
HERC13-B Analytes exceeding the reference standard or level: arsenic (5.6 mg/kg), chromium VI (36 mg/kg), vanadium (9.0 mg/kg) -
VI. RESULTS OF FIELD QUALITY CONTROL SAMPLES Field quality control samples for this investigation consisted of equipment rinse blanks collected from the liners used for the Geoprobe cores. No VOCs, SVOCs or metals were detected in the blanks. No metals were detected in the blank of the preservative used for the equipment rinse blank for metals analysis. VII. METHODOLOGY Field activities were conducted in accordance with the Region 4 SESD Field Branches Quality System and Technical Procedures. Specific field procedures applicable to this investigation included the following: Soil Sampling, SESDPROC-300-Rl Waste Sampling SESDPROC-302-Rl
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Sediment Sampling, SESDPROC-200-R2 SESD Operating Procedure for Sample and Evidence Management, SESDPROC-005-Rl Global Positioning System, SESDPROC-l l0-R2 Management of Investigation Derived Waste, SESDPROC-202-Rl Field Equipment Cleaning and Decontamination, SESDPROC-205-Rl Packing, Marking, Labeling and Shipping of Environmental & Waste Samples, SESDPROC-209-R 1 Field quality control measures were in accordance with the SESD Operating Procedure for Field Sampling Quality Control, SESDPROC-01 1-R2, and 40 CFR Part 136, Table IIRequired Containers, Preservations Techniques, and Holding Times, Revised as of July 1, 2007. All field measurement instruments and equipment were maintained in accordance with the SESD Operating Procedure for Equipment Inventory and Management, SESDPROC- 1 08-R3. Samples were analyzed at the SESD laboratory in accordance with the SESD Analytical Support Branch Laboratory Operations and Quality Assurance Manual, January 2010. The laboratory is accredited by the national Environmental Laboratory Accreditation Program (NELAP).
REFERENCES Personnel communication: Kevin Koporec to Sharon Matthews regarding RSLs, 1/19/11 “Site Inspection” for Hercules Inc. prepared by B&V Waste Science and Technology Corp. for the US EPA Region 4. April, 1993. USEPA Regional Screening Levels (11/10) Mississippi Department of Environmental Quality Tier 1 TRG Table (2/28/02)
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FIGURE 1
FACILITY LOCATION MAP HERCULES, INC. HATTIESBURG, MISSISSIPPI
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“Wetlands
FIGURE 2 —SITE LOCATION MAP HERCULES, INC., HATTIESBURG, MISSISSIPPI
•11
Approximate Hercules ;— Boundary
0
0.05
0.1
,
,‘
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SESD PROJECT NO. 10-0629
FIGURE 3- SAMPLE LOCATIONS HERCULES, INC., IIATTIESBIJRG, MISSISSIPPI Page 14 of 41
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FIGURE 4- “BACK 40” SAMPLE LOCATIONS Expanded view HERCULES, iNC., UATTIESBURG, MISSISSIPPI Page 15 of 41
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FIGURE 5- “WETLANDS” SAMPLE LOCATION Expanded view HERCULES, INC., HATTIESBURG, MISSISSIPPI Page 16 of 41
©
HERCO1-A
HERCO2-B HERCO3-B
HERCO4-B HERCO5-A HERCO6-B
HERCO7-B
HERCO8
HERCO9-B
HERC1O-B HERC11-B
HERC12-B
HERC13-B
HERCO1
HERCO2 HERCO3
HERCO4 HERCO5 HERCO6
HERCO7
HERCO8
HERCO9
HERC1O HERC11
HERCI2
HERC13
WA
WA
WA WA
WA
WA
WA
WA WA WA
WA WA
WA
Media Code
SESD PROJECT NO. 10-0629
Sample ID
Station 1D
9/29/10
9/29/10
9/29/10 9/29/10
9/29/10
9/29/10
9/28/10
9/28/10 9/28/10 9/28/10
9/28/10 9/28/10
9/28/10
Sample Date
31.34377
3 1.34354
3 1.34329 3 1.34335
31.34329
3 1.33928
31.34380
31.34425 3 1.34402 31 .343 89
31.34344 31.34417
31.34350
Latitude
89.31358 ±10’
89.31357±11’
89.3 1323 ±12’ 89.3 1285 ±12’
89.31363 ±16’
89.30500 ±12’
89.31316 ±10’
89.31284±15 89.31318 ±11’ 89.31351 ±12’
,
89.31308 ±13’ 89.31328 ±16’
89.31332±10’
Longitude
-
Hit sand at 6 feet bls; some odor Black organic sludge; some odor; into sand at 6 feet BLS Black sludge; some odor; into sand at 5.5 feet BLS Black sludge material; strong odor, oily sheen; into sand at 5.5 feet BLS
Black organic rich material; very strong odor; pine smell Tan to black sticky material Oldest material in “back 40”: black organic material; strong odor; sandier at depth Back organic material; some odor Dark organic sludge; strong odor Drier material; dark gray to black sludge; strong odor; moister & sandier w/depth Drier dark organic material; moister w/depth Only “wetland” sample; mostly cattails, some sludgy material; no odor Black sludge material into sand at 6 feet BLS
Sample Description
TABLE 1 SAMPLE DESCRIPTIONS HERCULES INC. BATTIESBURG, MISSISSIPPI
—
hand auger
—
—
hand auger
hand auger
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4.5 to 5.5 feet
—
hand auger
-
4.5 to 5.5 feet
5 to 6 feet
—
3 to 4 inches scoop 5 to 6 feet tried Geoprobe; had to handauger to get enough sample 5 to 6 feet—hand auger
5.5 to 6 feet hand auger —
4.5 to 5.5 feet
—
—
4 to 5 feet hand auger 6 to 7 feet hand auger 5.5 to 6.5 feet—hand auger
-
0 to 4 feet Geoprobe 3.5 to 5 feet—hand auger
Sample Interval (BLS)/ Sample Method
K
D
5.1 3,0 3.9J,O U 18 5.3 J,0 110 2.4 3,0 U U U 6.9 J,0 U U 1100 U 7100 U U
1{ERCO1 J{ERCO1-A WA 9/28/10 U 7.OJ,O U 37 U 190 6.5 J,O U U U 17 J,0 U U 1700 U 16000 U U
HERCO2 HERCO2-B WA 9/28/10 0.76 J,0 2.1 U 3.4 U U 0.62 J,0 U 0.72 J,0 U 8.6 1.2 0.5 3,0 420 1.4 0.82J,0 40 NJ 20 NJ
HERCO3 1{ERCO3-B WA 9/28/10 5.8 J,0 4.6 J,0 25 19 5.6 J,0 910 2.2 3,0 U U U 20 U U 3500 U 3000 U U
HERCO4 HERCO4-B WA 9/28/10 4.6 J,O 4.0 3,0 6.3 J,0 14 3.6 J,0 420 2.6 J,0 U U 4.6 J,0 22 U U 3500 U 5300 U U
HERCO5 RERCO5-A WA 9/28/10
U 0.40 J,0 U U 0.42 J,0 U U U U U 0.24 J,0 U U 38 U 280 U U
HERCO6 1{ERCO6-B WA 9/28/10
SESD PROJECT NO. 10-0629
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Numbers in BOLD exceed the USEPA Regional Screening Levels (11/10) and/or values in the MDEQ Tier 1 TRG Table (2/28/02) J= the identification of the analyte is acceptable; the reported value is an estimate NJ = Presumptive evidence that analyte is present; reported as a tentative identification (TIC) with an estimated value. 0 = other qualifiers have been assigned providing additional information and are defmed in the analytical data sheets included as Appendix B of this report U= the analyte was not detected at or above the reporting limit
Analyte (m- and/or p-)Xylene 1 ,2,4-Trimethylbenzene 1,2-Dichlorobenzene Benzene Carbon disulfide Cyclohexane Ethyl Benzene Isopropylbenzene Methyl Acetate Methyl Isobutyl Ketone Methylcyclohexane n- Butylbenzene o-Xylene p-Isopropyltoluene tert-Butylbenzene Toluene Dimethyloctane (TIC) Ethylmethylcyclohexane (TIC)
Station JD Sample ID Media Code Sample Date Units mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/lcg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg
TABLE 2 Detected Volaffle Organic Compounds Hercules Inc., Hattiesburg, Mississippi
HERCO8 HERCO8 WA 9/29/10 U U U U U U U U U U U U U 2.6 U 34 U U
I{ERCO7 HERCO7-B WA 9/28/10 2.9 1.3 J,O U U 0.78 J,0 U 0.92 J,O U U U U U 0.73 J,0 170 U 1400 U U 3.2 3.0 U 170 U 29 1.0 J,O U U U 8.2 U 1.0 J,0 610 U 1100 U U
HERCO9 HERCO9-B WA 9/29/10 U 7.OJ,0 34 140 U 1500 4.0 J,0 U U U 12 J,0 U U 3400 U 3100 U U
F{ERC1O HERCIO-B WA 9/29/10 -
U U U 77 U 100 U U U U 7.4 J,0 U U 720 U 2600 U U
-
HERC1 1 1{ERC1 1-B WA 9/29/10 U 5.OJ,O U 440 U 48 U 47 U U 11 J,0 U U 2400 U 160 U U
HERC12 HERC12-B WA 9/29/10 -
U 5.5 J,O 31 390 U 870 U U U 11 J,0 10 J,0 U U 3100 U 3400 U U
HERC13 HERC13-B WA 9/29/10
SESD PROJECT NO. 10-0629
Page 19 of 41
Numbers in BOLD exceed the USEPA Regional Screening Levels (11/10) and/or values in the MDEQ Tier 1 TRG Table (2/28/02) J= the identification of the analyte is acceptable; the reported value is an estimate NJ = Presumptive evidence that analyte is present; reported as a tentative identification (TIC) with an estimated value. 0= other qualifiers have been assigned providing additional information and are defmed in the analytical data sheets included as Appendix B of this report U= the analyte was not detected at or above the reporting limit
Station ID Sample ID Media Code SamDle Date Analyte Units (m- and/or p-)Xylene mg/kg 1 ,2,4-Trimethylbenzene mg/kg 1 ,2-Dichlorobenzene mg/kg Benzene mg/kg Carbon disulfide mg/kg Cyclohexane mg/kg Ethyl Benzene mg/kg Isopropylbenzene mg/kg Methyl Acetate mg/kg Methyl Isobutyl Ketone mg/kg Methylcyclohexane mg/kg Butylbenzen ne mg/kg o-Xylene mg/kg p-Isopropyltoluene mg/kg tert-Butylbenzene mg/kg Toluene mg/kg Dimethyloctane (TIC) mg/kg Ethylmethylcyclohexane (TIC) mg/kg
TABLE 2 (con’t) Detected Volatile Organic Compounds Hercules Inc., Hattiesburg, Mississippi
Analyte
Station ID Sample ID Media Code Sample Date Units mg/L NA-S
f{ERCO7 HERCO7-B WA 9/28/10 NA-5
HERCO8 HERCO8 WA 9/29/10
0.21
HERCO1 l{ERCO1-A WA 9/28/10
1.8
RERCO9 HERCO9-B WA 9/29/10
0.62 J,O
HERCO2 HERCO2-B WA 9/28/10
SESD PROJECT NO. 10-0629
Numbers in BOLD exceed the EPA Regulatory Level of 0.5 mg/L for benzene.
Benzene
Benzene
Analyte
Station ID Sample 1D Media Code Sample Date Units mg/L I
—
2.2
I{ERC1O HERC1O-B WA 9/29/10
NA-5
HERCO3 HERCO3-B WA 9/28/10
TABLE 3 Volatile Organic Compounds TCLP Results Hercules Inc., Hattiesburg, Mississippi
0.54 J,O
HERC11 HERC11-B WA 9/29/10
0.22
RERCO4 HERCO4-B WA 9/28/10
1.8
3.6
HERC13 HERC13-B WA 9/29/10
NA-5
HERCO6 HERCO6-B WA 9/28/10
Page 20 of 41
HERC12 HERCI2-B WA 9/29/10
0.23
HERCO5 F[ERCO5-A WA 9/28/10
Units mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg -
MDEQ Tier 1 TRG Soil Unrestricted mg/kg m 418; p 461 3910 279 0.887 7.97 NS 395 9.43 78200 6260 NS 3130 413 NS 3130 38 NS NS EPA RSLs Soil Residential 3400 62 1900 1.1 820 7000 5.4 2100 78000 5300 NS NS 3800 NS NS 5000 NS NS —
mg/kg
SESD PROJECT NO. 10-0629
Page 21 of 41
Regulatory levels are taken from the USEPA Regional Screening Levels (11/10) and the MDEQ Tier 1 TRG Table (2/28/02) NS = No Regulatory Standard/Level
Analyte (m- and/or p-)Xylene 1,2,4-Trimethylbenzene 1 ,2-Dichlorobenzene Benzene Carbon disulfide Cyclohexane Ethyl Benzene Isopropylbenzene (AKA cumene) Methyl Acetate Methyl Isobutyl Ketone Methylcyclohexane n- Butylbenzene o-Xylene p-Isopropyltoluene tert-Butylbenzene Toluene Dimethyloctane (TIC) Ethylmethylcyclohexane (TIC)
MDEQ Tier 1 TRG Soil Restricted mg/kg m 418; p 461 102000 279 1.36 7.97 NS 395 9.43 2040000 163000 NS 81800 413 NS 81800 38 NS NS
TABLE 4 EPA and MDEQ Regulatory Levels for Volaffle Organic Compounds Hercules Inc., Hattiesburg, Mississippi
0
SESD PROJECT NO. 10-0629
Station ID Sample ID Media Code Sam :ile Date Analyte Units (3-and/or 4-)Methylphenol mg/kg 1,1 -Biphenyl mg/kg 2,4-Dimethyiphenol mg/kg 2-Methylnaphthalene mg/kg 2-Methyiphenol mg/kg Acenaphthene mg/kg Dibenzofuran mg/kg Fluoranthene mg/kg Fluorene mg/kg Naphthalene mg/kg Phenanthrene mg/kg Phenol mg/kg Pyrene mg/kg (Dimethylethyl)ethoxybenzene (TIC) mg/kg (Dimethylethyl)methylphenol (TIC) mg/kg (Menthenol)terpineol (TIC) mg/kg (Methvlvropyl)benzene (TIC) ma/ku Bis(methylethyl)biphenyl (TIC) mg/kg Camphene (TIC) mg/kg Camphor (TIC) mg/kg Chiorotrimethylbicycloheptane (TIC) mg/kg Cycloisolongifolene (TIC) mg/kg Decahydroftmethyhethylenemethanoamlene mg/kg (TIC) Dimethylisopropyiphenanthrene (TIC) mg/kg Diphenyl ether (TIC) mg/kg Ethyl(methylethyl)benzene (TIC) mg/kg HERCO2 HERCO2-B WA 9/28/10 50 3900 U 5.6 4.7 J,O 2.9 4.1 9.8 3.4 8.8 5.5 J,O 5.4 J,O U 300 TN U 60 NJ U U 200 NJ U U 80 NJ U U U 70 NJ
FIERCO1 ITERCO1-A WA 9/28/10 20 J,O 1600 U 4.6 7.8 J,O U U 11 J,O 3.0 6.2 U 5.3 J,O 16 100 NJ U 90 NJ U U 200 NJ U U 80 NJ U
U 1000 NJ 60 NJ
200 NJ 800 NJ U
U 130 U U U U U U U U U 8.9 J,O U U U U U U U U U U U
HERCO3 HERCO3-B WA 9/28/10 HERCO4 HERCO4-B WA 9/28/10
200 NJ U U
53 1800 6.0 J,O 8.4 4.3 J,O 3.8 3.0 U 2.7 7.8 3.0 J,N 71 3.6 U U 300 NJ U U 300 NJ 200 NJ 100 NJ U U
TABLE 5 Detected Semi Volatile Organic Compounds Hercules Inc., Hattiesburg, 1’lississippi
100 NJ U U
100 1200 U 14 4.9 J,O 2.8 U 11 U 8.7 U 31 5.7 U U 300 NJ U U 200 NJ U 100 NJ 200 NJ 400 NJ
HERCO5 HERCO5-A WA 9/28/10
200 NJ 600 NJ U
78 330 U U 17 J,O U U U U U U U U U U U U U U U U U U
FIERCO7 FIERCO7-B WA 9/28/10
Page 22 of 41
200 NJ 200 NJ U
U 120 U U U U U U U U U U U U U U U U U U U U U
I{ERCO6 HERCO6-B WA 9/28/10
mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 1000 NJ 300 NJ 2000 NJ 800 NJ U U N U 500 NJ U U 70 J 600 NJ U 300 NJ 2000 NJ U 200 NJ U U U U 300 NJ 3000 J
U
U U U 3000 NJ 600 NJ U U N U 200 NJ 50 NJ U 900 J
HERCO3 HERCO3-B WA 9/28/10
HERCO2 HERCO2-B WA 9/28/10
1000 NJ U U U U U N U 700 NJ 200 NJ 300 NJ 2000 J
U
HERCO4 HERCO4-B WA 9/28/10
400 NJ 700 J
U U U U U U N 200 NJ 900 NJ
400 NJ
HERCO5 HERCO5-A WA 9/28/10
2000 NJ U U U U U N U U U U 6000 J
U
HERCO6 HERCO6-B WA 9/28/10
1000 NJ U U U U U N U U U U 5000J
U
HERCO7 HERCO7-B WA 9/28/10
SESD PROJECT NO. 10-0629
Page 23 of 41
Numbers in BOLD exceed one or both of the USEPA Regional Screening Levels (11/10) or the MDEQ Tier 1 TRG Table (2/28/02) J= the identification of the analyte is acceptable; the reported value is an estimate NJ = Presumptive evidence that analyte is present; reported as a tentative identification (TIC) with an estimated value. 0 = other qualifiers have been assigned providing additional information and are defmed in the analytical data sheets included as Appendix B of this report U= the analyte was not detected at or above the reporting limit TIC = Tentatively Identified Compound
Analyte Hexahydrodimethyl(methylethyl)naphthalene (TIC) Hexahydrotetramethylmethanonaphthalene (TIC) Limonene (TIC) Methyl(methylethyl)benzene (TIC) Methyl(methylethyl)cyelohexane (TIC) Methyl(methylethyl)cyclohexene (TIC) Methyl(methylethyl)phenanthrene (TIC) Petroleum Product Phenanthrenecarboxylic acid (TIC) Pinene (TIC) Propyiphenol (TIC) Trimethylbicycloheptane (TIC) Unidentified Compound(s)
Station H) HERCO1 Sample ID HERCO1-A Media Code WA Sample Date 9/28/10 Units mg/kg U
TABLE 5 (con’t) Detected Semi Volatile Organic Compounds Hercules Inc., Hattiesburg, Mississippi
ti-I
Cl)
C
p 0
.
tD
.
J)
0
CcJQ
©
; O —. Cl)
—. (M
mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 200 NJ U U U U U U N U U U U 2000 J U U U 7000 NJ 4000 NJ U U N U 2000 NJ 200 NJ 200 NJ 2000 3
U
U 2000 NJ U 600 NJ 700 NJ 1000 NJ 100 NJ U N U U U 100 NJ 1000 J
HERC1O HERCIO-B WA 9/29/10
HERCO9 HERCO9-B WA 9/29/10
1000 NJ U 100 NJ 700 NJ 2000 NJ U U N U 100 NJ U 200 NJ 2000 J
U
I{ERC11 }{ERC1 1-B WA 9/29/10
500 NJ U U 3000 NJ 2000 NJ 80 NJ U N U U 300 NJ 200 NJ 1000 J
U
HERC12 HERC12-B WA 9/29/10
1000 NJ U U 7000 NJ 4000 NJ 200 NJ U U U 2000 NJ 200 NJ 200 NJ 2000 NJ
U
KERC13 HERC13-B WA 9/29/10
SESD PROJECT NO. 10-0629
Page 25 of 41
Numbers in BOLD exceed one or both of the USEPA Regional Screening Levels (11/10) or the MDEQ Tier 1 TRG Table (2/28/02) J= the identification of the analyte is acceptable; the reported value is an estimate NJ = Presumptive evidence that analyte is present; reported as a tentative identification (TIC) with an estimated value. 0= other qualifiers have been assigned providing additional information and are defmed in the analytical data sheets included as Appendix B of this report U= the analyte was not detected at or above the reporting limit TIC = Tentatively Identified Compound
Analyte Hexahydrodimethyl(methylethyl)naphthalene (TIC’> Hexahydrotetramethylmethanonaphthalene (TIC) Limonene (TIC) Menthene (TIC) Methyl(methylethyl)benzene (TIC) Methyl(methylethyl)cyclohexane (TIC) Methyl(methylethyl)cyclohexene (TIC) Methyl(methylethyl)phenanthrene (TIC) Petroleum Product Phenanthrenecarboxylic acid (TIC) Pinene (TIC) Propylphenol (TIC) Trimethylbicycloheptane (TIC) Unidentified Compound(s)
Station U) HERCO8 Sample ID HERCO8 Media Code WA Sample Date 9/29/10 Units mg/lcg U
TABLE 5 (con’t) Detected Semi Volatile Organic Compounds Hercules Inc., Hattiesburg, Mississippi
0
SESD PROJECT NO. 10-0629
NS No Regulatory Standard/Level TIC = Tentatively Identified Compound
Analyte (3-and/or 4-)Methylphenol 1,1-Biphenyl 2,4-Dimethyiphenol 2-Methylnaphthalene 2-Methyiphenol Acenaphthene Dibenzofuran Fluoranthene Fluorene Naphthalene Phenanthrene Phenol Pyrene (Dimethylethyl)ethoxybenzene (TIC) (Dimethylethyl)methylphenol (TIC) (Menthenol)terpineol (TIC) (Methylpropyl)benzene (TIC) Bis(methylethyl)biphenyl (TIC) Camphene (TIC) Camphor (TIC) Chiorotrimethylbicycloheptane (TIC) Cycloisolongifolene (TIC) Decahydrotrimethylmethylenemethanoazulene (TIC) Dimethylisopropylphenanthrene (TIC) Diphenyl ether (TIC) Ethyl(methylethyl)beiizene (TIC) Hexahydrodimethyl(methylethyl)naphthalene (TIC) Units mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg -
MDEQ Tier 1 TRG Soil Restricted mg/kg 102000/10200 10200 40800 40900 102000 123000 8180 81700 81700 247 61300 123000 61300 NS NS NS NS NS NS NS NS NS NS NS NS NS NS -
MDEQ Tier 1 TRG Soil Unrestricted mg/kg 3910/391 3910 1560 1560 3910 4690 313 3130 3130 194 2350 46900 2350 NS NS NS NS NS NS NS NS NS NS NS NS NS NS
TABLE 6 EPA and MDEQ Regulatory Levels for Semi Volatile Organic Compounds Hercules Inc., Hattiesburg, Mississippi
-
mg/kg
Page 26 of 41
EPA RSLs Soil Residential 7500 3900 1200 310 3100 3400 78 2300 2300 3.6 NS 18000 1700 NS NS NS NS NS NS NS NS NS NS NS NS NS NS
0
SESD PROJECT NO. 10-0629
NS = No Regulatory Standard/Level TIC = Tentatively Identified Compound
Analyte Hexahydrotetramethylmethanonaphthalene (TIC) Limonene (TIC) Menthene (TIC) Methyl(methylethyl)benzene (TIC) Methyl(methylethyl)cyclohexane (TIC) Methyl(methylethyl)cyclohexene (TIC) Methyl(methylethyl)phenantbrene (TIC) Petroleum Product Phenanthrenecarboxylic acid (TIC) Pinene (TIC) Propyiphenol (TIC) Trimethylbicycloheptane (TIC) Unidentified Compound(s) Units mg/kg mg/kg mg/lcg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg NS NS NS NS NS NS NS NS NS NS NS NS NS
MDEQ Tier 1 TRG Soil NS NS NS NS NS NS NS NS NS NS NS NS NS
MDEQ Tier 1 TRG Soil
TABLE 6 (con’t) EPA and MDEQ Regulatory Levels for Semi Volatile Organic Compounds Hercules Inc., flattiesburg, Mississippi
NS NS NS NS NS NS NS NS NS NS NS NS NS
Page 27 of 41
EPA RSLs Soil
6600 U U 18 U U 75J,0 24 7.9 69 3,0 1200 3,0 23 65 4.6 8.0 71 3,0 U U U 170 3,0 2.1 U 32 4.3 0.58 270 3,0
HERCO1 HERCO1-A WA 9/28/10 4900 U U 18 U U 58 11 14 44 1600 60 45 3.8 3.1 120 U U U 150J,0 1.6 U 17 2.1 0.57 120
HERCO2 HERCO2-B WA 9/28/10
5700 U U 21 U U 210 7.7 2.9 29 4300 9.1 230 31 U 80 180 U U U 2.1 U 62 8.7 1.2 68
HERCO3 HERCO3-B WA 9/28/10
5200 U 6.4 27 U 0.46 400 29 14 100 3400 26 76 14 4.0 200 96 U U 130 3,0 6.1 U 42 5.6 0.99 510
I{ERCO4 HERCO4-B WA 9/28/10
5100 U 5.6 35 U 0.49 2000 45 17 84 4600 34 170 32 4.8 210 110 U U 460 3,0 8.9 U 51 6.6 1.1 690
HERCOS FIERCO5-A WA 9/28/10 5800 U U 100 3,0 U U 5000 20J,O 7.2 27 3,0 4000 3,0 22 440 3,0 200 3,0 21 J,0 543,0 160 U U 180 3,0 34 3,0 U 56 3,0 3.9 1.9 500J,0
HERCO6 HERCO6-B WA 9/28/10
6700 U U 23 U 0.48 710 32 9.5 26 5200 23 62 37 40 44 U U U 130 3,0 8.9 U 22 2.8 1.7 650
HERCO7 HERCO7-B WA 9/28/10
Numbers in BOLD exceed one or both of the USEPA Regional Screening Levels (11/10) or the MDEQ Tier 1 TRG Table (2/28/02) J= the identification of the analyte is acceptable; the reported value is an estimate 0= other qualifiers have been assigned providing additional information and are defmed in the analytical data sheets included as Appendix B U= the analyte was not detected at or above the reporting limit SESD PROJECT NO. 10-0629 Page 28 of 41
Analyte Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Silver Sodium Strontium Thallium Titanium Vanadium Yttrium Zinc
Station ID Sample ID Media Code Sam)le Date Units mg/kg mg/kg mg/lcg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg
TABLE 7- Metals Data Hercules Inc., Hattiesburg, Mississippi
7900 U U 61 U U 250 20 2.7 17 8300 24 240 350 37 8.2 210 U U U 2.6 U 98 18 2.7 130
HERC08 HERCO8 WA 9/29/10 7100 U U 23 U U 530 20 10 110 3500 25 160 39 13 150 160 U 1.0 150J,O 4.6 U 46 5.9 2.0 220
HERCO9 HERCO9-B WA 9/29/10 6400 U 5.0 33 U U 2800 26 14 210 3200 23 200 36 6.4 340 220 U U 210J,O 7.3 U 61 7.6 1.2 570
HERC1O HERC1O-B WA 9/29/10 7000 U U 23 U U 350 25 10 93 1900 23 170 14 4.0 140 160 U U 180J,O 4.2 U 52 7.2 1.2 270
HERC11 HERC1 1-B WA 9/29/10 6700 U U 30 U U 1200 18 13 110 4700 18 210 36 2.8 270 170 U U 240J,O 8.5 U 54 7.5 1.6 370
l{ERC12 I{ERC12-B WA 9/29/10 6800 U 5.6 45 U U 1700 36 21 210 3100 36 150 15 5.6 490 190 U U 230J,O 8.9 U 76 9.0 1.2 480
HERC13 HERC13-B WA 9/29/10
Numbers in BOLD exceed one or both of the USEPA Regional Screening Levels (11/10) or the MDEQ Tier 1 TRG Table (2/28/02) J= the identification of the analyte is acceptable; the reported value is an estimate O = other qualifiers have been assigned providing additional information and are defmed in the analytical data sheets included as Appendix B U= the analyte was not detected at or above the reporting limit SESD PROJECT NO. 10-0629 Page 29 of 41
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Silver Sodium Strontium Thallium Titanium Vanadium Yttrium Zinc
Analyte
Station ID Sample ID Media Code Sample Date Units mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg
-
TABLE 7 Metals Data (con’t) Hercules Inc., Hattiesburg, Mississippi
Units mg/kg mg/lcg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg -
MDEQ- Soil Restricted mg/kg 2040000 81.7 3.82 14300 1020 1020 NS 3070000 381 12300 8170 613000 1700 NS 4080 1020 4080 NS 1020 1020 NS 123000 143 8180000 1430 NS 61300 -
MDEQ- Soil Unrestricted mg/kg 78200 31.3 0.426. 5480 156 39.1 NS 117000 227 4690 3130 23500 400 NS 1560 391 1560 NS 391 391 NS 46900 5.48 313000 548 NS 23500 —
-
EPA RSLs Soil Residential mg/kg 77000 31 (metallic) 0.39 (inorganic) 15000 160 ( & compounds) 70 (diet) NS 120000 0.29 23 3100 55000 400 ( & compounds) NS 1800 (non-diet) 390 1500 (soluble salts) NS 390 390 NS 47000 NS NS 5.5 (metallic) NS 23000 (metallic)
SESD PROJECT NO. 10-0629
Page 30 of 41
Regulatory levels are taken from the USEPA Regional Screening Levels (11/10) or the MDEQ Tier 1 TRG Table (2/28/02) NS = No Regulatory Standard/Level
Vanadium Yttrium Zinc
Titanium
Analyte Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium III Chromium VI Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Silver Sodium Strontium (stable) Thallium
TABLE 8- EPA and MDEQ Regulatory Levels for Metals Hercules Inc., Hattiesburg, Mississippi
0
0
APPENDIX A PHOTOGRAPHS OF SAMPLING ACTIVITIES Hercules Inc., Hattiesburg, Mississippi SESD Project Identification Number: 10-0629
SESD PROJECT NO. 10-0629
Page 31 of4l
o
0
Photograph 1 Example of waste/sludge from the “Back 40”
Photograph 2 Assessing the HERCO3-B sample location
Photograph 3 Example of waste/ sludge from the “Back 40”
SESD PROJECT NO. 10-0629
Page32of4l
0
0
Photograph 4 Example of waste! sludge from the “Back 40”
Photograph 5 Collecting sample HERCO3-B
Photograph 6 Air monitoring during HERCO3-B sample collection
SESD PROJECT NO. 10-0629
Page 33 of 41
0
0
Photograph 7 Sample location HERCO5-A
Photograph 8 Sample location HERCO4-B
Photograph 9 Sample BERCO6-B
,1
SESD PROJECT NO. 10-0629
Page 34 of4l
0
C Photograph 10 Sample HERCO7-B
Photograph 11 Hand augering sample HERCO7-B
SESD PROJECT NO. 10-0629
Page 35 of 41
C
C
Photograph 12 Sampling “wetlands” to collect HERCO8
Photograph 13 Sample HERCO8 note dense root system —
SESD PROJECT NO. 10-0629
Page36of4l
0
0
Photograph 14 Sample HERCO8 note dense root system —
Photograph 15 Attempting to collect another sample from the “wetlands” dense root system prevented sample collection -
SESD PROJECT NO. W-0629
Page37of4l
0
‘I
-.
1
Sample HERCO6-B
-
-S
-:
•‘)-
•‘.4_ ,. ;-.--
-
-
-
L. -
—
:
:7
-
‘.
J_HERCO7-B
Photograph 16 Locations for samples HERCO6-B and HERCO7-B
I
Photograph 17— General area of sample HERCO5-A
SESD PROJECT NO. 10-0629
I Page 38 of 41
0
Photograph 18 General area of sample HERCO4-B
Photograph 19 Coring HERCO9-B using Geoprobe
a SESD PROJECT NO. 10-0629
: ç ;
Photograph 20 Collecting sample HERCO9-B with hand auger
Page39of4l
0
0
L
Photograph 21 Collecting sample HERC 1 1-B
Photograph 22 Collecting sample HERC11-B
Photograph 23 Collecting sample HERC 12-B
SESD PROJECT NO. 10-0629
Page 40 of 41
0
0
APPENDIX B SESD ANALYTICAL DATA SHEETS Hercules Inc., Hattiesburg, Mississippi SESD Project Identification Number: 10-0629
Semi-Volatile Organic Compounds Volatile Organic Compounds Metals
=
34 pages
SESD PROJECT NO. 10-0629
—
=
=
59 pages
60 pages
—
—
issued 11/1/10
issued 11/8/10
issued 1/4/11
Page 41 of 41
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
November 1, 2010 4SESD-ASB
MEMORANDUM SUBJECT:
FINAL Analytical Report Project: 10-0629, Hercules Inc Civil Enforcement
FROM:
Janet Muse OCS Chemist
THRU:
Sallie Hale, Chief ASB Organic Chemistry Section
TO:
Sharon Matthews
Attached are the final results for the analytical groups listed below. These analyses were performed in accordance with the Analytical Support Branch’s (ASB) Laboratory Operations and Quality Assurance Manual (ASB LOQAM) found at www.epa.gov/region4/sesdlasbsop. Any unique project data quality objectives specified in writing by the data requestor have also been incorporated into the data unless otherwise noted in the Report Narrative. Chemistry data have been verified based on the ASB LOQAM specifications and may have been qualified if the applicable quality control criteria were not met. For a listing of specific data qualifiers and explanations, please refer to the Data Qualifier Definitions included in this report. The reported results are representative only of the samples as received by the laboratory.
Analyses Included in this report:
Method Used:
Semi Volatile Organics (SVOA) Semivolatile organic compounds
EPA 8270D
TCLP SemiVolatiles (TCLPS) Semivolatile organic compounds
Page 1 of 59
E104009 SVOA TCLPS FINAL
EPA 8270D
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
Sample Disposal Policy
Because of the laboratory’s limited space for long term sample storage, our policy is to dispose of samples on a periodic schedule. Please note that within 60 days of this memo, the original samples and all sample extracts and/or sample digestates will be disposed of in accordance with applicable regulations. The 60-day sample disposal policy does not apply to criminal samples which are held until the Laboratory is notified by the criminal investigators that case development and litigation are complete. These samples may be held in the laboratory’s custody for a longer period of time if you have a special project need. If you wish for the laboratory to hold samples beyond the 60-day period, please contact our Sample Control and provide a reason for holding samples Coordinator, Debbie Colquitt, by e-mail at beyond 60 days
Page 2 of59
E104009 SVOA TCLPS FfNAL
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
SAMPLES INCLUDED IN THIS REPORT
Project: 10-0629, Hercules Inc Sample ID
Laboratory ID
Matrix
Date Collected
Date Received
ERBO1
E104009-01
EquipmentRinse Blank
9/23/10 13:30
10/1/10 8:35
HERCO1-A
E104009-03
Waste
9/28/10 10:10
10/1/10 8:35
HERCO2-B
E104009-04
Waste
9/28/10 10:55
10/1/10 8:35
IIERCO3-B
E104009-05
Waste
9/28/10 13:15
10/1/10 8:35
HERCO4-B
E104009-06
Waste
9/28/10 13:50
10/1/10 8:35
HERCO5-A
E104009-07
Waste
9/28/10 14:05
10/1/10 8:35
HERCO6-B
E104009-08
Waste
9/28/10 14:55
10/1/10 8:35
HERCO7-B
E104009-09
Waste
9/28/10 15:25
10/1/10 8:35
HERCO8
E104009-10
Waste
9/29/10 08:50
10/1/10 8:35
FIERCO9-B
E104009-11
Waste
9/29/10 14:20
10/1/10 8:35
HERCIO-B
E104009-12
Waste
9/29/10 14:15
10/1/10 8:35
HERC11-B
E104009-13
Waste
9/29/10 14:30
10/1/10 8:35
HERC12-B
E104009-14
Waste
9/29/10 14:50
10/1/10 8:35
HERC13-B
E104009-15
Waste
9/29/10 15:10
10/1/10 8:35
Page 3 of 59
E104009 SVOA TCLPS FINAL
11/1/10 16:40
0 0 Sr
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700
V
DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
DATA QUALIFIER DEFINITIONS
U H—7 j
N NA-5 NJ 0-2
The analyte was not detected at or above the reporting limit. Recommended preparation holding time exceeded The identification of the analyte is acceptable; the reported value is an estimate. There is presumptive evidence that the analyte is present; the analyte is reported as a tentative identification. Not Analyzed. Cannot exceed TCLP regulatory levels based on Total Scan analyses. Presumptive evidence that analyte is present; reported as a tentative identification with an estimated value. Result greater than MDL but less than MRL.
OL-2
Laboratory Control Spike Recovery greater than method control limits
OL-3
Laboratory Control Spike Precision outside method control limits
OM-1
Matrix Spike Recovery less than method control limits
OM-6
Matrix Spike Recovery less than 10%
R
The presence or absence of the analyte can not be determined from the data due to severe quality control problems. The data are rejected and considered unusable.
ACRONYMS AND ABBREVIATIONS
CAS
Chemical Abstracts Service Note: Analytes with no known CAS identifiers have been assigned codes beginning with “E”, the EPA 11) as assigned by the EPA Substance Registry System (www.epa.gov/srs), or beginning with “R4-”, a unique identifier assigned by the EPA
Region 4 laboratory.
IvIDL
Method Detection Limit The minimum concentration of a substance (an analyte) that can be measured and reported with a 99% confidence that the analyte concentration is greater than zero.
I\’IRL
Minimum Reporting Limit Analyte concentration that corresponds to the lowest demonstrated level of acceptable quantitation. The MRL is sample-specific and accounts for preparation weights and volumes, dilutions, and moisture content of soil/sediments.
TIC
Tentatively Identified Compound An analyte identified based on a match with the instrument software’s mass spectral library. A calibration standard has not been analyzed to confirm the compound’s identification or the
-
-
-
estimated concentration reported.
Page 4 of 59
EI04009 SVOA TCLPS FINAL
11/1/10 16:40
C
C
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc
-
Reported by Janet Muse
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: ERBOI Station ID:
E104009-01
Matrix: Equipment Rinse Blank
Date Collected: 9/23/10 13:30 C4S Niunber
.4nalyie
1319-77-3
(3-and’or 4-)Methylphenol
92-52-4
Results Qualifiers
Units
1IRL
9.8 U, J. 1-1-7
ugiL
9.8
10/13/10 7:44
EPA 82700
1,1 -Biphenyl
2.0 U, J, [-1-7
ug/L
2.0
10/13/10 17:44
EPA 8270D
95-94-3
I ,2,4,5-Tetrachlorobenzene
9.8 U, J, H-7
ug;L
9.8
1%0/l0
10.13,10 17:44
EPA 82700
95-50-1
1 ,2-Dichlorobenzene
9.8 L’,J,H-7
uWL
9.8
100)0
541-73-1
1 ,3-Dichlorobenzene
9.8 U, J, 1-1-7
ug/L
9.8
0)10
10/13/10 17:44 10/13/10
106-46-7
I ,4-Dichlorobenzene
9.8 U,J,H-7
ug/L
9.8
90-12-0
I -Methylnaphthalene
2.0 U, J, H-7
ug!L
2.0
58-90-2
2,3,4,6-Tetrachiorophenol
9.8 U, J, 1-1-7
ug/L
9.8
95-95-4
2,4,5-Trichiorophenol
9.8 U, J, H-7
ugfL
Prepured
17:44
10/13/10 17:44 10/13/10 ‘7:44 10/13/10 17:44
9.8
l0?0
10/13/10 17:44
9.8
lOflO
10/13/10 17:44 10/13/10 7:44 10/13/10 17:44 10/13/10 17:44 10/13/10 17:44 10/13/10 7:44 10/13/10 17:44 10/13/10
88-06-2
2,4,6-Trichlorophenol
9.8 U, J, H-7
120-83-2
2,4-Dichiorophenol
9.8 U, J, H-7
ug/L
9.8
I0310
105-67-9
2,4-Dimethyiphenol
9.8 U, J, H-7
ug/L
9,8
‘°°
ugfL
.4naIy.ed ,‘ileihod
51-28-5
2,4-Dinitrophenol
9.8 U. 3, 11-7
ug/L
9.8
12 1-14-2
2,4-Dinitrotoluene
9.8 U, 3, H-7
ug/L
9.8
606-20-2
2,6-Dinitrotoluene
9.8 U, J, H-7
ug!L
9.8
91-58-7
2-Chloronaphthalene
9.8 U, J, H-7
ugJL
9.8
95-57-8
2-Chlorophenol
9.8 U,J,H-7
ug/L
534-52-1
2-Methyl-4,6-dinitrophenol
9.8 U, J, F1-7
ug/L
9.8
91-57-6
2-Methylnaphthalene
2.0 U, J, H-7
ug/L
2.0
I0/7I0 l0/0
1010
lO/04/l0 6.57
17:44
10/13/10 17:44 10/13/10 17.44 10/I 3/10 17:44
95-48-7
2-Methylphenol
9.8 U,J,H-7
ugfL
9.8
88-74-4
2-Nitroaniline
9.8 U, 3, H-7
uWL
9.8
88-75-5
2-Nitrophenol
9.8 U, J. H-7
ugfL
9.8
I01i0
91-94-1
3,3’-Dichlorobenzidine
9.8 U, J, H-7
ug!L
9.8
I0/0O
99-09-2
3-Nitroaniline
9.8 U,J,H-7
ug/L
9.8
10/04/10
10,13/10 7:44 10)13/10 17.44 10/13/10 17:44 10/13/10
101-55-3
4-Bromophenyl phenyl ether
9.8 U, J, H-7
ug!L
9.8
I0/07I0
10/13/10
59-50-7
4-Chloro-3-methylphenol
9.8 U, J, H-7
ugJL
9.8
0/04/10
10/13)10
106-47-8
4-Chioroaniline
9.8 U, J, H-7
ug’L
9.8
7005-72-3
4-Chiorophenyl phenyl ether
9.8 U. J. H-7
ug/L
9.8
I0)0
100-01-6
4-Nitroaniline
9.8 U, J, H-7
ug/L
9.8
0/ 6 I0/ W 7
100-02-7
4-Niliophenol
9.8 U, J, H-7, QL-3
ugIL
9,8
10/04/10
Page 5
of 59
E104009 SVOA TCLPS F[-NAL
17:44 1744
17:44 1013/10 17:44
10/13/10 17:44 10/13/10
EPA 8270D EPA 82700 EPA 82700 EPA 8270D EPA 82700 I/PA 82701)
EPA 8270D EPA 8270D EPA
82700
EPA 82700 EPA 82700 EPA 8270D EPA 8270D EPA 82700
EPA 8270D EPA 82700 EPA
8270D
EPA 82700 EPA
8270D
EPA 8270D EPA 82700 EPA 82700 EPA 8270D EPA 8270D EPA 8270D
17:44
EPA 8270D
10/13/10 7:44
EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id; 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: ERBOI
E104009-0l
Matrix: Equipment Rinse Blank
Station ID: Date Collected: 9/23/10 13:30 C4S
Number
.4nalyte
83-32-9
Acenaphthene
Units
IIRL
2.0 U, 3, H-7
uglL
2.0
Results Qualifiers
208-96-8
Acenaphthylene
2.0 U,JH-7
ugIL
2.0
98-86-2
Acetophenone
9.8 U, J, 11-7
ug/L
9.8
120-12-7 1912-24-9 100-52-7 56-55-3 50-32-8
Anthracene Atrazine Benzaldehyde
Benzo(a)pyrene
17:44
2.0 U, J, 11-7
ug/L
2.0
9.8 U. J. H-7
ug/L
9.8
I0/0
9.8
°°
2.0 U, 3. H-7 2.0 U, J, H-7
ug/L
ugIL
2.0
ug/L
2.0 10/04/10 6:57
205-99-2
Benzo(b)tluoranlhene
2.0 U. J, 11-7
ug!L
7 0
191-24-2
Benzo(g,h,i)perylene
2.0 U, 3, H-7
ug/L
2.0
1O/600
70
0/04/10
207-08-9
Benzo(k)tluoranthene
2.0 U, J, II-?
ug/L
9.8 9.8
100-51-6
Benzyl alcohol
9.8 L, J, H-7
ug!L
85-68-7
Benzyl butyl phthalate
9.8 U, J. 1-1-7
ug/L
9.8
111-91-1
Bis(2-chloroethoxy)methane
9.8 U. J, H-7
ug/L
111-44-4
bis(2-Chloroethyl) Ether
9.8 U, 3, 11-7
ug!L
9.8
39638-32-9
Bis(2-chloroisopropyl) ether
9.8 U, J, 11-7
ug/L
9.8
117-81-7
Bis(2-ethylhexyl) phthalate
9.8 U, J, 11-7
ug/L
9.8
105-60-2
Caprolactam
9.8 U, J, H-7, QL-3
ug/L
9.8
86-74-8
Carbazole
2.0 U, 3, 11-7
ug!L
2.0
218-01-9
Chrysene
2.0 U, J, 1-1-7
ug!L
2.0
53-70-3
Dibenz(a,h)anthracene
2.0 U. J, 11-7
132-64-9
Dibenzofuran
2.0 U, 3, H-7
ugfL
2.0
9.8 U, J. H-7
ug/L
9.8
84-66-2 13 1-1 1-3
Diethyl phthalate Dimethyl phthalate
9.8 U, J, 1-1-7
ug/L
7:44
I0/l0
206-44-0
Fluoranthene
2.0 U, J, 1-1-7
ug/L
2.0
‘°°
2.0 U, J, 1-1-7
ug/L
2.0
10/710
I%0
67-72-1
Page 6 of59
Hexachloroethane
E104009 SVOA TCLPS FINAL
9.8
9.8 U. 3, 11-7
ug/L
9.8
EPA 82700 EPA 8270D EPA 82700 EPA 8270D EPA 82700
10/13/10 17:44 10/13/10
9.8 U, J, 1-1-7
9.8 U. 3,11-7
EPA 82700 EPA 8270D
10/04/10
117-84-0
Hexachlorocyclopentadiene (HCCP)
EPA 82700 EPA 82700
EPA 8270D
9.8
77-47-4
EPA 82700
EPA 82700
9.8
9.8
EPA 82701)
1013.10 17:44
ugJL
ug/L
EPA 82700
‘°°
ugfL
ug!L
0/13/10 17:44 10/13/10 17:44 10/13/10 17:44 10/13/10 17:44 10/13/10 17:44 10/13/10 17:44
9.8
9.8 U, 3,11-7
EPA 8270D
10/13/10 17:44 10/13/10 17:44 10/13/10 17:44
I0/13/l0 17:44
9.8 U, J. H-7
Hexachlorobenzene (HCB)
EPA 82700
10/13/10 17:44
17:44
Di-n-butylphtha late
118-74-I
EPA 8270D EPA 82700
°°
Di-n-octylphthalate
Fluorene
EPA 82700
7:44
10/13/10 17:44 10/13/10
io;o
EPA 82700 EPA 8270D
01/13/40 17:44
6:57
84-74-2
86-73-7
101310 17:44 10/13/10 17:44 10/13/10
10/13/tO 17:44
2.0
ugIL
.4m4rzed /tfefhod 10/13/10 17:44 10/13/to
10/04/10
9.8 U,J,F1-7
Benzo(a)anthracene
Prepared
10)0
i0)I0
10/13/10 17:44 10/13/10 17:44 10/13/10 17:44 10/13/10 17:44 loll 3/JO 17:44 I0/13/10 17:44 10/13/tO 17:44 10/13:10
17:44
EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc
-
Reported by Janet Muse
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: ERBO1 Station ID:
E104009-O1
Matrix: Equipment Rinse Blank
Date Collected: 9/23/10 13:30 C.4S Nn,nher
Results Qualifiers
.4nalyte
Units
MRL
Prepared
.lnalyed 10/13/10 17:44
lfethod
193-39-5
Indeno (1,2.3-cd) pyrene
2.0 U, J, H-7
ug/L
2.0
10/04/10 6:57
78-59-I
Isophorone
9.8 U, J, H-7
ugIL
9.8
10/04/10
10/13/10
91-20-3
Naphthalene
2.0 U, J, H-7
ug/L
2.0
10/04/10 6:57
17:44 1013/10 17.44
98-95-3
Nitrobenzene
9.8 U, J, H-7
ug/L
9.8
10/04/10 6:57
10/13/10 17:44
EPA 8270D
621-64-7
n-Nitroso di-n-Propylamine
9.8 U. J, 11-7
ug/L
9.8
1004/10 6:57
10:13110 17:44
EPA 82700
9.8
10/04/10
10/13/10
EPA 8270D
122-39-4
n-Nitrosodiphenylamine/Diphenylamine
9.8 U, J, H-7
ugJL
g74,’:
Pentachlorophenol
9.8 U, J. 11-7
ug/L
9.8
85-01-8
Phenanthrene
2.0 U. J, H-7
ug/L
2.0
108..’
Phenol
9.8 Ii. J, H-7
ug/L
9.8
129-00-0
Pyrene
2.0 U, 3, H-7
ug/L
ug/L
657
6:57 10/04/10 6:57 10/04/10 6:57
17:44 10/13)10
17:44 10/13/10 17:44
EPA 8270D
EPA 8270D EPA 82700
EPA 82700 EPA 827013
10/04/10
10/13.10
2.0
6:57 10/04/10 6:57
17:44 10/13/10 17:44
EPA 82700
10
10/04/10 657
10/13/10 1744
EPA 82700
EPA
8270D
Tentatively Identified Compounds: R4-0000
Page 7 of 59
Tentatively Identified Compounds
E104009 SVOA TCLPS FTNAL
10 U
11/1/10 16:40
0 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercu’es Inc
-
Reported by Janet Muse
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: IIERCOI-A
E104009-03
Matrix: Waste
Station ID: HERCOI Date Collected: 9/28/10 10:10 CAS Nwnber
1319-77-3 92-52-4 58-90-2 95-95-4
Results Qualifiers
4nalyte
(3-and/or 4-)Methylphenol
20 J. Q-2
1600
1,1 -Biphenyl 2,3,4,6-Tetrachlorophenol 2,4,5-Trichlorophenol
Units
mg/kg
mg/kg
MRL
Prepared
26
10/05/10 12:00
26
10/05/10 12:00
.4navzed ,Sfethod 10/09/10
23:16 10/09/10 23:16 1009/)0
mg/kg
10/05/10
2:00
23:16
26 U
mg/kg
10/05/10 12:0))
10/09/10 23:16 10/09/10 23:16 10/09/10 23:16
26 U
26
88-06-2
2,4,6-Trichiorophenol
26 U
mg/kg
120-83-2
2,4-Dichlorophenol
26 U
mg/kg
10/05/10 12:00 10/05/10 12:00
26 U
mg/kg
‘3
0/05/10 12:00
26
10/05/10 12:00
2316 10/09/10 23:16
10/05/10
10/09/10
12:00
23:16 10/09/10 23:16 0/09/10
105-67-9
2,4-Dimethylphenol
26
51-28-5
2,4-Dinitrophenol
26 U, R. QM-6
mg/kg
121-14-2
2,4-Dinitrololuene
26 U
mg/kg
., ..,
‘
606-20-2
2,6-Dinitrotoluene
26 U
mg/kg
91-58-7
2-Chloronaphthalene
26 U
mg/kg
26
10/05/10
12:00 10/05/10 12:00 10/05/10 12:00
95-57-8
2-Chiorophenol
26 U
mg/kg
.,;
534-52-1
2-Methyl-4,6-dinitrophenol
26 Li
mg/kg
26
10/05/10
2•6
10/05/1))
91-57-6 95-48-7
88-74-4 88-75-5 91-94-1
2-Methylnaphthalene
4.6 7.8 J, Q-2
2-Methyiphenol 2-Nitroaniline
2-Nitrophenol 3,3’-Dichlorobenzidine
mg/kg mg/kg
-•‘3
26 1.;
mg/kg
•,i
26 U
mg/kg
26
26 U
mg/kg
‘,
., ‘3
99-09-2
3-Nitroaniline
26 U
mg/kg
101-55-3
4-Bromophenyl phenyl ether
26 U
mg/kg
26
mg/kg
-, ‘3
59-50-7
106-47-8 7005-72-3
4-Chloro-3-methylphenol
26 U 26 U
4-Chioroaniline 4-Chiorophenyl phenyl ether
mg/kg
120-12-7 1912-24-9
Page 8 of 59
Anthracene Atrazine
E104009 SVOA TCLPS Ffl’,’AL
10/09/10 23:16
EPA 8270D EPA 82700
2:00 10/05/10
1009/10
12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 0/05/10 12:00 10/05/10 12:00 10/05/10 12:00
23:16 10/09/10 23:16 10/09/10
10/05/10
23:16
EPA 82700 EPA 82700 EPA 8270D
10/09/10 23:16 10/09/10 23:16 10/09/10 23:16
EPA 82700
1009/10 23:16
EPA 82700
10/09/TO 23:16
EPA 82700
EPA 82700
EPA 82700
mg/kg
EPA 82700
mg/kg
)0/05/10 2:00
10/09/10
23:16
EPA 82700
10/05/10
10/09/10 2316
EPA 8270D
10/09/TO 23:16
EPA 82700
2.6 U
mg/kg
26 U
EPA 82700 EPA 8270D
10/09/10 23:16
mg/kg
Acetophenone
EPA 82700 EPA 82700
10/05/10 12:00
26 -, ‘3
26 U 26 U
98-86-2
EPA 82700 EPA 82700
EPA 82700
4-Nitroaniline
2.6 U
EPA 8270D
EPA 82700
4-Nitrophenol
Acenaphthylene
EPA 82700
10/1)9/10
mg/kg
100-02-7
208-96-8
EPA 82700
10/09/10 2316
10/09/10 23.16
12:01) 10/05/10
EPA 82700
10/05/10 2:1))) 10/05/10 12:00 10/05/10 12:00
26 U
100-01-6
Acenaphthene
23:16
EPA 82700
10/09/10 2316
mg/kg
83-32-9
26
2:00
10/09/10
EPA 8270D
26
e
26
2.6 U
mg/kg
26
26 U
mg/kg
.,
12:00
12:00 10/05/10
12:00
23:16 10/09/10
23:16 10/09/10 23:16
EPA 8270D EPA 8270D
11/1/10 16:40
C)
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: IIERCOI-A Station ID: HERCOI
E104009-03
Matrix: Waste
Date Collected: 9/28/10 10:10 CAS
Number
.4nalyte
100-52-7
Benzaldehyde
26 U
56-55-3
Benzo(a)anthracene
2.6
U
Results Qualifiers
Units
MRL
Prepared
.1 nalyed
mg/kg
26
050 2 T 1
mg/kg
2.6
12:00 12:00
10:09,10 23:16 10109110 23:16 10/09/10 23:16 10/09/10 23:16 1009/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/11) 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 1009/10 23:16
50-32-8
Benzo(a)pyrene
2.6 U
mg’kg
2.6
205-99-2
Benzo(b)fluoranthene
2.6 U
mg/kg
2.6
191-24-2
Benzo(g,h.i)perylene
2.6 U
mg/kg
2.6
207-08-9
Benzo(k)fluoranthene
2.6 U
mg/kg
2.6
85-68-7
Benzyl butyl phthalate
26 U
mg/kg
26
111-91
26
12:00 1TO 1l/0
ii:io
Bis(2-chloroethoxy)methane
26 U
mg/kg
111-44-4
bis(2-Chloroethyl) Ether
26 U
mg/kg
26
°
39638-32-9
Bis(2-chloroisopropyl) ether
26 U
mg/kg
26
1//T0
117-81-7
Bis(2-cthylhexyl) phthalate
26 U
mg/kg
26
105-60-2
Caprolactam
26 U, R, QM-6
mg/kg
26
1201
86-74-8
Carbazole
2.6 U
mg/kg
2.6
U/O50
218-01-9
Chrysene
2.6 U
mg/kg
2.6
53-70-3
Dibenz(a,h)anthracene
2.6 U
mg/kg
2.6
132-64-9
Dibenzofuran
2.6 U
mg/kg
2.6
84-66-2
Diethyl phthalate
26 U
mg/kg
26
131-11-3
Dimethyl phthalate
26 U
mg/kg
26
84-74-2
Di-n-butylphthalate
26 U
mg/kg
26
117-84-0
Di-ri-octylphthalate
26 U
mg/kg
26
19/20:0
206-44-0
Fluoranthene
11 J,QM-1
mg/kg
2.6
04 1 9 °
86-73-7
Fluorene
3.0
mg/kg
2.6
H/1:5o/r0
118-74-1
Hexachlorobenzene (HCB)
26 U
mg/kg
26
-
12:00 11/0 9/20:50/T0
ll/0
12.
87-68-3
Hexachiorobutadiene
26 U
mg/kg
26
77-47-4
Hexachiorocyclopentadiene (HCCP)
26 U, J, QM-l
mg/kg
26
67-72-1
Hexachloroethane
26 U
mg/kg
26
‘9’°
193-39-5
Indeno (1,2.3-cd) pyrene
2.6 U
mg1g
2.6
1f1:5I0
78-59-1
Isophorone
26 U
mg/kg
26
91-20-3
Naphthalene
6.2
mg/kg
2.6
‘‘°
98-95-3
Nitrobenzene
26 U
mg/kg
26
19/2050
621-64-7
n-Nitroso di-n-Propylamine
26 U
mg/kg
26
20
Page 9 of 59
E104009 SVOA TCLPS FINAL
12:00 IT/305O
llethod EPA 8270D
EPA 8270D EPA 82700 EPA 8270D EPA 82700
EPA 8270D EPA 82700
EPA 8270D EPA 82700 EPA 8270D EPA 82700
EPA 8270D EPA 8270D
EPA 8270D EPA 82700 EPA 82700 EPA 82700
EPA 8270D EPA 8270D
EPA 8270D EPA 82700
EPA 8270D EPA 827/3D EPA 827/3D
EPA 82700 EPA 827/3D
EPA 82700 EPA 827/3D EPA 827/3D EPA 827/3D EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART, Id: 10-0629 Inc Reported by Janet Muse Hercules 10-0629, Project: -
Semi Volatile Organics ProjecI: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCOI-A
Matrix:
Station ID: HERCO1
E104009-03 Waste
Date Collected: 9/28/10 10:10
c4s N,unber 122-39-4
Results Qualifiers
.4nalyfr n-Nitrosodiphenylamine/Diphenylamine
26 U
Units mg/kg
MRL
Prepared
26
10/05/10 12:00 10/OS/ID 1200 10/05/10 12:00 10/05/10
87-86-5
Pentachiorophenol
26 U
mg/kg
26
85-01-8
Phenanthrene
2.6 U
mg/kg
2.6
108-95-2
Phenol
5.3 J, Q-2
mg/kg
26 2.6 26
129-00-0
Pyrene
16
mg/kg
I 10-86-1
Pyridine
26 U
mg/kg
100 NJ
mg/kg
90 NJ
mg/kg
inaly:ed Method
12:00
10/09/10 23:16 10/09/10 23:16 10/09/10 23:I6 10/09/10 23:I6
10:05/10
10/09/10
12:00 10/05/10 12:00
23:16 10/09/10 23:16
10/05/10 12:00 10/05/10 12:00
10/09/10 23:16 10/09/10 23:16
10/05/10
10/09/10
12:00 10/05/10 12:00 10/05/10
23:16 10/09/10 23:16 10/0910 23:16 10/09/10 23-6 10/09/10 2316
EPA 8270D
EPA 8270D EPA
8270D
EPA 8270D EPA 8270D EPA 8270D
Tentatively Identified Compounds: R4-8000900 R4-6552 R4-653 I
(Dimethylethyl)ethoxybenzene (TIC) (Menthenol)terpineol (TIC) Camphene (TIC)
R4-8000904
Cycloisolongifolene (TIC)
R4-8000535
Diphenyl ether (TIC)
R4-8000898
Ethyl(methylethyl)benzene (TIC)
R4-8000899
Hexahydrotetramethylmethanonaphthalene (TIC)
R4-7545
Limonene (TIC)
R4-6584
Methyl(methylethyl)benzene (TIC)
R4-8000897
MethyI(methylethyl)cyclohexane (TIC)
R4-6500
Petroleum Product:
R4-6520
Pinene (TIC)
R4-650I
[nidentified Compounds
Page 10 of59
E104009 SVOA TCLPS FfNAL
200 NJ
mg/kg
80 NJ
mg/kg
1000 NJ
mg/kg
60 NJ
mg/kg
1000 NJ
mg/kg
300 NJ
mg/kg
12:00
10/05/10 1200 10/05/10 12:00
500 NJ
mg/kg
10/05/10 12:00
0/09/10 23:16 10/09/10 23:16 10/09/I)) 23:16 10/09/10 23:16 10/09/10 23:16
70 J
mg/kg
100510 1200
1009:10 2316
2000 NJ
mg/kg
800 NJ
mg/kg
N
10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00
EPA 8270D EPA 8270D EPA 8270D
EPA 8270D EPA 8270D
EPA 8270D EPA 8270D
EPA 8270D EPA 8270D EPA 8270D
EPA 8270D EPA 8270D EPA 8270D
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
TCLP SemiVolatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCOI-A Station ID: IIERCOI
E104009-03
Matrix: Waste
Date Collected: 9/28/10 10:10 C.4S Niunber
.4nalyte
1319-77-3
(3-andlor4-)Methylphenol:
58-90-2
2,3,4,6-Tetrachlorophenol:
XA-5
0.10
95-95-4
2,4.5-Trichlorophenol:
NA-5
0.10
Results Qualifiers
NA-5
Units
bIRL
0.10
88-06-2
2,4,6-Tnchlorophenol:
NA-5
0.10
121-14-2
2,4-Dintro1o1uene:
NA-S
0.10
95-48-7
2-Methylphenol:
NA-S
0.10
118-74-1
1-lexachloroberizene (HCB):
NA-5
0.10
87-68-3
-
Hexachlorobutadiene:
NA..5
0.10
flexachioroethane
NA 5
0 10
98-95-3
Nitrobenzene:
NA-5
0.10
87-86-5
Pentachlorophenol:
NA-5
0.10
110-86-1
Pyridine:
Page 11 of59
NA-5
E104009 SVOA TCLPS FINAL
0.10
Prepared
nav:ed .‘.lethod
I0JI0
‘%°‘°
EPA 8270D
0 j 1 190
10/90I0
EPA 8270D EPA8270[) EPA 8270D
°‘°
hI’A
1%o/1o
8270D
EPA 8270D
‘°
EPA 8270D
10/05/10
EPA 8270D
1005/10
1009/10
‘°2°
10/09/ID
1O10
Il/409/0
EPA 87OD
EPA827OD EPA 8270D EPA827OD
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO2-B
E104009-04
Mairix: Waste
Station ID: HERCO2 Date Collected: 9/28/10 10:55 CAS Number
1319-77-3
Results Qualifiers
4nulyte
(3-andlor4-)Methylphenol
Units
50
mg/kg
3900
MRL
25
92-52-4
1,1-Biphenyl
mg/kg
51
58-90-2
2,3,4,6-Tetrachlorophenol
25 U
mg/kg
25
95-95-4
2,4,5-Trichlorophenol
25
U
mg/kg
25 25
88-06-2
2,4,6-Trichlorophenol
25 U
mg/kg
120-83-2
2,4-Dichlorophenol
25 U
mg/kg
25
105-67-9
2,4-Dimelhylphenol
25 U
mg/kg
25
51-28-5
2,4-Dinitrophenol
25 U
mg/kg
25
121-14-2
2,4-Dinitrotoluene
25 U
mg/kg
25
606-20-2
2,6-Dinitrotoluene
25 U
mg/kg
25
9 1-58-7
2-Chloronaphthalene
25 U
mg/kg
25
95-57-8
2-Chlorophenol
25 U
mg/kg
25
534-52-1
2-Methyl-4.6-dinitrophenol
25 U
mg/kg
25
91 -57-6
2-Methylnaphthalene
5.6
mg/kg
2.5
95-48-7
2-Methylphenol
4.7 J, Q-2
mg/kg
25
88-74-4
2-Nitroaniline
25 U
mg/kg
25
88-75-5
2-Nitrophenol
25 U
mg/kg
25
91-94-1
3,3’-Dichlorobenzidine
25 U
mg/kg
25
25
99-09-2
3-Nitroartiline
25 U
mg/kg
101-55-3
4-Bromophenyl phenyl ether
25 U
mg/kg
25 25
59-50-7
4-Chloro-3-methylphenol
25 U
mg/kg
106-47-8
4-Chloroaniline
25 U
mg/kg
25
7005-72-3
4-Chlorophenyl phenyl ether
25 U
mg/kg
25
100-01-6
4-Nitroaniline
25 U
mg/kg
25
100-02-7
4-Nitrophenol
25 U
mgkg
25 2.5
2.5
83-32-9
Acenaphthene
2.9
mg/kg
208-96-8
Acenaphthylene
2.5 U
mg/kg
98-86-2
Acetophenone
25 U
mg/kg
25
120-12-7
Anthracene
2.5 U
n/g’kg
2.5
1912-24-9
Alrazine
25 U
mg/kg
25
Page 12 of59
E104009 SVOA TCLPS FINAL
Prepared 0/05/10 12:00 10/05/10 12:00 10)05/10 1200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 100510 1200 10/05,10 12:00 10/05/10 12:00 10/05/10 1200 0/05/10 12:00 10/os/la 2:00 10/05/10 12:00 10/85/10 12:00 10/05/10 12-00 10/05/10 12:00 10/05/10 1200 10105/10 12:00 10,05/10 12:00 10/05/10 12:00 I0(05/I0 12:00 10105/10 12:00
1nuvzed ,Otethod 10/09/10 23:51 10/09/10 23:51 10.09110 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10(09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10.’09/10 23:5! 10/09/10 23:51 10/09/10 2351 10/09/10 2351 10/09/10 23:5! 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 l0’09/10 23:5! 10/09/10 23:51 10/09/10 23:5! 10/09/10 23:51 10/09/10 23:51
EPA 8270D
EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA 8270[) EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 8270D EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700
11/1/10
16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO2-B Station ID: HERC02 Date Collected:
E104009-04
Matrix: Waste
9/28/10 10:55
C4S Vgrnber
.4na!yte
100-52-7
Benzaldehyde
25 U
56-55-3
Benzo(a)anthracene
2.5
50-32-8
Benzo(a)pyrene
205-99-2
Results Qualifiers
Units
hfRL
Prepared
lnatr:ed
mg/kg
25
U
mg/kg
2.5
2.5 U
mg/kg
2.5
10/05/10 12:00 10/05/10 12:00 1005/10
Benzo(b)fluoranthene
2.5 U
mg/kg
2.5
10/05/10
191-24-2
Benzo(g,h.i)perylerse
2.5 U
mg/kg
2.5
00510 2-00
207-08-9
Benzo(k)fluoranthene
2.5 U
mg/kg
2.5
85-68-7
Benzyl butyl phthalale
25 U
mg/kg
25
10/05/ID 12:00 10/05/10
10/09,10 23:51 10/09/10 23:51 10/0910 23:51 10/09/10 23:51 1009.10 23:51 10/09/10 23:51 10/09)10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:5! 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:5! 10/09/10
111—91—1
Bis(2-chloroethoxy)methane
25 U
mg/kg
25
111-44-4
bis(2-Chloroethyl) Ether
25 U
mg/kg
25
39638-32-9
Bis(2-chloroisopropyl) ether
25 U
mg/kg
25
117-81-7
Bis(2-ethylhexyl) phthalate
25 U
mg/kg
25
105-60-2
Caprolactam
25 U
mg/kg
25
86-74-8
Carbazole
2.5 U
mg/kg
2.5
218-01-9
Chrysene
2.5 U
mg/kg
2.5
53-70-3
Dibenz(a,h)anthracene
2.5 U
mg/kg
2.5
132-64-9
Dibenzofuran
4.1
mg/kg
2.5
84-66-2
Diethyl phthalate
25 U
mg/kg
25
131-11-3
Dimethyl phthalate
25 U
mg/kg
25
84-74-2
Di-n-butylphthalate
25 U
mg/kg
25
117-84-0
Di-n-octylphthalate
25 U
mg/kg
25
206-44-0
Fluoranthenc
9.8
mg/kg
2.5
86-73-7
Fluorene
3.4
mg/kg
2.5
118-74-1
I-lexachlorobenzene (IICB)
25 U
mg/kg
25
87-68-3
Hexachlorobutadiene
25 U
mg/kg
25
77-47-4
Hexachlorocyclopentadiene (HCCP)
25 U
mg/kg
25
67-72-1
Hexachioroethane
25 U
mg/kg
25
193-39-5
Indeno (1,2.3-cd) pyrene
2.5 U
mg/kg
2.5
78-59-1
Isophorone
25 U
mg/kg
25
91-20-3
Naphthalene
8.8
98-95-3
Nitrobenzene
25 U
mg/kg
25
621-64-7
n-Nitroso di-n-Propylamine
25 U
mg/kg
25
Page 13 of59
E104009 SVOA TCLPS FINAL
2.5
1200 12:00
12:00
10/05/10 12:00 0/05/ID 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 0/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 1200 10/05/10 12:00 1005:10 12:00 10/05/10 12.00 10/05/10 12:00 10/05/10 12:00 10 05’IO 2:00
23:51
10.09/10 23:51 0/09/10 23:51
10/09/10 23:5! 10/09/10 23:51 10,09/10 23:5! 10/09/10 23:51 1009/10 23:5!
herhod
EPA 8270D EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA 02701) EPA 8270D EPA 82700 EPA 8270D EPA 8270D EPA 8270D EPA 82700 EPA 82700 EPA 8270D EPA 8270D EPA 82700 EPA 8270D EPA 8270D EPA 8270D EPA 8270D EPA 8270D EPA 8270D EPA 8270D EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Janet Muse -
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO2-B
E104009-04
Matrix: Waste
Station ID: HERCO2 Date Collected: 9/28/10 10:55 C.4S .‘,unher
Resulls Qualifiers
.4nalyte
122-39-4
n-Nitrosodiphenylamine/Diphenylamine
Units
25 U
mg/kg
MRL
Prepared
25
10/05/10 2:00 10/05/JO 1200 b/OS/lU 1200 10/05/10 12:00 10/05/10 2:00 10/05/10 12:00
10/09/10 23:51 10/09/10 235J 10/09/10 2351 10/09/10 23:51 10/0910 23:51 10/09/JO 23:51
10/05/10 12:00 10/05/10 12:00 10105/jO
10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 I0/09/I0 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 100910 235!
87-86-5
Pentachlorophenol
25 U
mg/kg
25
85-01-8
Phenanthrene
5.5 J, QL-2
mg/kg
2.5
108-95-2
Phenol
5.4 J, Q-2
mg/kg
25 2.5 25
129-00-0
Pyrene
2.5 U
mg/kg
110-86-1
Pyridine
25 U
mg/kg
300 NJ
mg/kg
60 NJ
mg/kg
Analyzed 0k/hod EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA 8270D
Tentatively Identified Compounds: R4-8000900
(Dimethylethyl)ethoxybenzcnc (TIC)
R4-6552
(Menthenol)terpineol (TIC)
R4-6531
Camphene (TIC)
200 NJ
mg/kg mg/kg
200 NJ
mg/kg
50 NJ
mg/kg mg/kg
1005.10 200
R4-8000904
Cycloisolongifolene (TIC)
80 NJ
R4-8000898
Ethyl(methylethyl)benzene (TIC)
70 NJ
mg/kg
3000 NJ
mg/kg
600 NJ
mg/kg
R4-6584
Methyl(rnethylethyl)benzene (TIC)
R4-8000897
Methyl(methylethyl)cyclohexane (TIC)
R4-6500
Peholeum Product:
R4-6520
Pinene (TIC)
R4-8000466
Propylphenol (TIC)
R4-6501
Unidentified Compounds
Page 14 of59
E104009 SVOA TCLPS FINAL
12:00
10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 I0/05/bO 2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00
N
900 J
EPA 8270D
EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 82700
EPA 8270D EPA 82700 EPA 82700
EPA 8270D
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
TCLP SemiVolatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: 1{ERCO2-B Station ID: HERCO2
E104009-04
Matrix: Waste
Date Collected: 9/28/10 10:55 (*IS .Vuuther
.4nalyte
1319-77-3
(3-and/or 4-)Methylphenol:
Results Qualifiers
NA-5
Units
jlfRL
0.10
58-90-2
2,3,4,6-Tetrachlorophenol:
NA-5
0.10
95-95-4
2,4,5-Trichlorophenol:
NA-5
0.10
88-06-2
2,4,6-Trichlorophenol:
NA-S
0.10
121-14-2
2,4-Dinitrotoluene:
NA-S
0.10
95-48-7
2-Methylphenol:
NA-S
0.10
118-74-1
I-lexachlorobenzene (11CR):
NA-5
0.10
Hexachlorobutadiene:
NA-5
0.10
NA-5
0.10
87-68-3--.
-..
67-72-1 Hexachioroethane: 98-95-3
Nitrobenzene:
NA-5
0.10
87-86-5
Pentachlorophenol:
NA-5
0.10
110-86-1
Page 15 of 59
Pyridine:
NA-5
E104009 SVOA TCLPS FINAL
0.10
Prepared
10/05/10
1naI’zed
I0’09’I0
944
41)4
10/05/10
10/09/10 14:04 0/09/10 1404 10/09/b 14:04 0/09/10
944
10,051)0 944 10/05/ID 9:44 10/05/10
10/05/10 944 10/OS/b 944 10/05/10 9:44 b/OS/b 9:44
10/05/10 944
10/09/10 14:04 10109/10 14:04 10/09/10 14:04 10/09/10 4:04 10/09/10 14:04
0:05/)0
10/09/10
944
404 10/09/10 14:04
10/05/10
944
Ofethod
EPA 8270D
EPA 8270D EPA 8270D
EPA 8270D EPA 8270D
EPA 8270D EPA 8270D
EPA
8270D
EPA 8270D
EPA 8270D EPA 8270D EPA 8270D
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id. 10-0629
/
Project: 10-0629, Hercules Inc
-
Reported by Janet Muse
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO3-B
E104009-05
Matrix: Waste
Station ID: IIERCO3 Date Collected: 9/28/10 13:15 CIS Nwnher
.4nalyte
1319-77-3
(3-and/or 4-)Methylphenol
Re.si,Il Qualifiers
24 U
MRL
Prepared
.4nalvzed
24
10/05/10
mg/kg
2.4
10/05/10
mg/kg
24
10/09/10 22:06 10/09/10 22:06 10/09/10 2206 10/09/10 22:06 10/09:10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10:09:10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/tO 22:06 10/09/10 22.06 10:091)0 22:06 10/09/10 22:06 10/09/10 22:06 10’09/10 22:06 10.09.10 22:06 10/09/10 22:06 10/09:10 22:06 10/09/10 22:06
Un/ta
mg/kg
92-52-4
1,1-Biphenyl
58-90-2
2,3,4,6-Tetrachlorophenol
24 U
95-95-4
2,4,5-Trichlorophenol
24 lj
mg/kg
24
24 U
mg/kg
24
88-06-2 120-83-2
130
2.4,6-Trichlorophenol 2,4-Dichlorophenol
24 U
mg/kg
24 24
105-67-9
2,4-Dirnethylphenol
24 U
mg/kg
51-28-5
2,4-Dinitrophenol
24 U
mg/kg
24
121-14-2
2,4-Dinitrotoloene
24 U
mg/kg
24 24
606-20-2
2,6-Dinib-otoluene
24 U
mg/kg
9 1-58-7
2-(’hloronaphthalene
24 U
mg/kg
24
95-57-8
2-Chiorophenol
24 U
mg/kg
24
534-52-1
2-Methyl-4,6-dinitrophenol
24 U
mg/kg
24
91-57-6
2-Methylnaphthalene
2.4 U
mg/kg
2.4
95-48-7
2-Methylphenol
24 U
mg/kg
24 24
88-74-4
2-Nitroaniline
24 U
mg/kg
88-75-5
2-Nitrophenol
24 U
mg/kg
24
91-94-1
3,3’-Dichlorobenzidine
24 ii
mg/kg
24 24 24
99-09-2
3-Nitroaniline
24 U
mg/kg
101-55-3
4-Bromophenyl phenyl ether
24 U
mg/kg
59-50-7
4-Chloro-3-methylphenol
24 U
mg/kg
24
106-47-8
4-Chloroaniline
24 U
mg/kg
24
7005-72-3
4-Chlorophenyl phenyl ether
24 U
mg/kg
24
100-01-6
4-Nitroaniline
24 U
mg/kg
24
100-02-7
4-Nitrophenol
24 U
mg/kg
24
83-32-9
Acenaphthene
2.4 U
mg/kg
2.4
208-96-8
Acenaphthylene
2.4 U
mg/kg
2.4
98-86-2
Acetophenone
24 U
mg/kg
24
120-12-7
Anthracene
2.4 U
mg/kg
2.4
19 12-24-9
Atrazine
24 U
mg/kg
24
Page 16of59
E104009 SVOA TCLPS FINAL
12:00 12:00 10/05/10 •0 10/05/10 12:00 10/05/10 12:00
10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 1200 10/05/10 12:00 1005/10 2:00 10/05/10 12:00 10/05/10 12:00 0/05/10 12:00 10/05/10 12:00 10/05/10 12:0)) 10/05/10 2:00 10/05/10 12:00 0/05/10 12:00 10/05/10 12:00 10/05/10 2:00 0/05/10 12:00 1005/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00
tiethod
EPA 82700
EPA 8270D EPA 8270D EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA827OD EPA 82700
EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82701) EPA
82700
EPA 82700 EPA 8270D EPA 82700 EPA
8270D
EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA
8270D
EPA 82700 EPA 82700 EPA
82700
EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercu’es Inc Reported by Janet Muse -
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO3-B
E104009-05
Matrix: Waste
Station ID: HERCO3 Date Collected: 9/28/10 13:15 C4S Number
Results Qualifiers
lna!yte
Linit9
MRL
Prepared 10/05/10 12:00 10/05/10 12:00 0/05/10 200 10/05/10 12:00 10/05/10 1200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 l2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 b/OS/b 1200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 b/OS/b 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 0/05/10 12:00 b/OS/b 12:00 10/05/10 12:00 10/05/10 12:00
100-52-7
Benzaldehyde
24 U
mg/kg
24
56-55-3
Benzo(a)anthracene
2.4 U
mg/kg
2.4
50-32-8
Benzo(a)pyrene
2.4 U
mg/kg
2.4
205-99-2
Benzo(b)fluoranthene
2.4 C
mg/lcg
2.4
191-24-2
Benzo(g,h,i)perylene
2.4 U
mg/kg
2.4
207-08-9
Benzo(k)fluoranthene
2.4 U
mg/kg
2.4
85-68-7
Benzyl butyl phthalate
24 U
mg/kg
24
111-91-1
Bis(2-chloroethoxy)methane
24 U
mg/lcg
24
111-44-4
bis(2-Chlorocthyl) Ether
24 U
mg/kg
24
39638-32-9
Bis(2-chloroisopropyl) ether
24 U
mg/kg
24
117-81-7
Bis(2-ethylhexyl) phthalate
24 U
mg/kg
24
105-60-2
Caprolactam
24 U
mg/kg
24
86-74-8
Carbazole
2.4 U
mg/kg
2.4
218-01-9
Chrysene
2.4 C
mg/kg
2.4
53-70-3
Dibenz(a,h)anthracene
2.4 U
mg/kg
2.4
132-64-9
Dibenzofuran
2.4 U
mg/kg
2.4 24
84-66-2
Diethyl phthalate
24 U
mg/kg
131-11-3
Dimethylphthalate
24 U
mg/kg
24
84-74-2
Di-n-butylphthalate
24 U
mg/kg
24
117-84-0
Di-n-octylphthalate
24 U
mg/kg
24
206-44-0
Fluoranthene
2.4 U
mg/kg
2.4
86-73-7
Fluorene
2.4 U
mg/kg
2.4
118-74-I
Hexachlorobenzene (HCB)
24 U
mg/kg
24
87-68-3
Hexachlorobutadiene
24 U
mg/kg
24
77-47-4
Hexachlorocyclopentadiene (HCCP)
24 U
mg/kg
24
67-72-1
Hexachloroethane
24 U
mg/kg
24
193-39-5
Indeno (1,2,3-cd) pyrene
2.4 U
mg/kg
2.4
78-59-1
Isophorone
24 L
mg/kg
24
91-20-3
Naphthalene
2.4 U
mg/kg
2.4
98-95-3
Nitrobenzene
24 U
mg/kg
24
62 1-64-7
n-Nitroso di-n-Propylamine
24 U
mg/kg
24
Page 17 of59
E104009 SVOA TCLPS FINAL
.inalrzed /‘Jethad 10/09/10 22:06 10/09/10 22:06 10/09/10 2206 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/I 0 22:06 10/09/lO 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 2206 10/09/10 22:06 I0/09/b0 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 b0/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/b 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06
EPA 8270D EPA 8270D EPA 8270D EPA 8270D EPA 8270D
EPA 8270D EPA 8270D
EPA 8270D EPA
8270D
EPA 8270D EPA 8270D
EPA 8270D EPA 8270D
EPA 8270D EPA 8270D
EPA 8270D EPA 8270D
EPA827OD EPA
8270D
EPA 8270D EPA 8270D EPA
8270D
EPA 8270D
EPA 8270D EPA 8270D EPA
82700
EPA 8270D EPA
8270D
EPA 8270D EPA
8270D
EPA 8270D
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 1 0-0629, Hercules Inc Reported by Janet Muse -
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: LIERCO3-B
E104009-05
Matrix: Waste
Station ID: IIERCO3 Date Collected: 9/28/10 13:15 C4S [Viunher
Resnils Qualifiers
4naly:e
Units
MRL
Prepared
lnalvzed
24
10/05/10 12:00 10/05/10 12:00
10/09/10 22:06 10,09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06
122-39-4
n-Nitrosodiphenylamine/Diphenylamine
24 U
mg/kg
87-86-5
Penlachlorophenol
24 U
mg/kg
24
85-01-8
Phenanthrene
2.4 U
mg/kg
2.4
108-95-2
Phenol
8.9 3, Q-2
mg/lcg
24 2.4 24
129-00-0
Pyrene
2.4 U
mg/kg
110-86-1
Pyridine
24 U
mg/kg
200 NJ
mg/kg
800 NJ
mg/kg
10/05110
12:00 10/05/10 2:00 10/05/10 2:00 10/05/10 12:00
‘ifethod
EPA 82700
EPA 8270D EPA 82700 EPA 8270D EPA 82700
EPA 8270D
Tentatively Identified Compounds: R4-6603 R4-8000535
Dimethylisopropyiphenanthrene (TIC) Diphenyl ether (TIC)
R4-8000899
Hexahydrotetramethylmethanonaphlhalene (TIC)
600 NJ
mg4cg
R4-6584
Methyl(methylethyl)benzene (TIC)
300 NJ
mg/kg
R4-8000897
Methyl(methylethyl)cyclohexane (TIC)
2000 NJ
mg/kg
R4-6514
Methyl(methylethyl)phenanthrene (TIC)
200 Nj
mg/kg
R4-8000901
Trimethylbicycloheptane (FEC)
300 NJ
mg/kg
R4-6501
Page 18of59
Unidentified Compounds
E104009 SVOA TCLPS FINAL
3000 3
mg/kg
10/05/10 12:00 0/05)10 12:00 10/05/10 12:00
10/05/10 12:00 10/05/10 2:00
10/05/10 12:00 10/05/10
10/09/10 22:06 10/09/10 22:06
10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10
12:00
22:06
10/05/10 12:00
10/09/10 22:06
FPA 62701) EPA
8270D
EPA 82700
EPA 8270D EPA 8270D
EPA 82700 EPA 8270D EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules mc- Reported-by Janet Muse
TCLP SemiVolatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO3-B Station ID: HERCO3
E104009-05
Matrix: Waste
Date Collected: 9/28/10 13:15 C4S Nu,a her
.4nalvte
1319-77-3
(3-andlor4-)Methylphenol:
Results Qualifiers
NA-5
Units
MRL
0.10
58-90-2
2,3,4,6-Tetrachlorophenol:
NA-5
0.10
95-95-4
2,4,5-Trichlorophenol:
NA-5
0.10
88-06-2
2,4,6-Trichlorophenol:
NA-S
0.10
121-14-2
2,4-Dinitrotoluene:
NA-S
0.10
95-48-7
2-Methylphenol:
NA-S
0.10
118-74-1
I-Iexachlorobenzene (FICB):
NA-S
0.10
87-68-3
Hexachiorobutadiene:
NA-S
0.10
67-72-1
Flexachloroethane:
NA-5
0.10
98-95-3
Nitrobenzene:
NA-5
0.10
87-86-5
Pentachlorophenol:
NA-S
0.10
110-86-1
Pyridine:
XA-5
0.10
Page 19 of59
E104009 SVOA TCLPS FINAL
Prepared 10/05/10
Analyzed Method
10105/10 944 10/05/b 944 10/05/10 944 10/05/10 9:44 10/05/10 944
10/09/10 4.04 10/09/10 14:04 10/09/10 1404 0/09/10 14:04 10/09/10 1404 10/09/10 14:04
10/05/10
0/09/10
944 10/05/10 944 10/05/10 944 10/05/10 9:44 10/05/10 944 10/05/10 9:44
4:04
EPA 82700
10/09/10 14:04 10/09/10 1404 10/09/10 1404 10/09/10 1404 10/09/10 14:04
EPA 8270D
EPA 8270D EPA 8270D EPA 82700 EPA
8270D
EPA 82700
EPA 8270D
EPA
82700
EPA 82700 EPA 82701)
EPA 8270D
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 1O-0629, Hercules Inc Reported by Janet Muse -
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: UERCO4-B Station ID: HERCO4
E104009-06
Matrix: Waste
Date Collected: 9/28/10 13:50 C4S Number
.4nalyre
1319-77-3
(3-and/or4-)Methylphenol
Results Qual,fiers
Units
MRL
53
mg/kg
25
1800
mg/kg
25 25
92-52-4
1,1-Biphenyl
58-90-2
2,3,46-Tetrachlorophenol
25
U
mg/kg
95-95-4
2,4,5-Trichlorophenol
25 U
mg/kg
25
88-06-2
2,4,6-Trichlorophenol
25 U
mg/kg
25
120-83-2
2,4-Dichlorophenol
25 U
mg/kg
25
105-67-9
2,4-Dirnethylphenol
6.0 3, Q-2
mg/kg
25
5 1-28-5
2,4-Dinitrophenol
25 U
mg/kg
25
121-14-2
2,4-Dinitrotoluene
25 U
mg/kg
25
606-20-2
2,6-Dinitrotoluene
25 U
mg/kg
25
9 1-58-7
2-Chloronaphthalene
25 U
mg/kg
25
95-57-8
2-Chlorophenol
25 U
mg/kg
25
534-52-1
2-Methyl-4,6-dinitrophenol
25 U
mg/kg
25
91-57-6
2-Methylnaphthalene
8.4
mg/kg
2.5
95-48-7
2-Methylphenol
43 J Q-2
mg/kg
25
88-74-4
2-Nitroaniline
25 U
mg/kg
25
88-75-5
2-Nitrophenol
25 U
mg/kg
25
91-94-1
3,3-Dichlorobenzidine
25 U
mg/kg
25
99-09-2
3-Nitroaniline
25 U
mg/kg
25
101-55-3
4-Bromophenyl phenyl ether
25 1.
mg/kg
25
59-50-7
4-Chloro-3-methylphenol
25 U
mg/kg
25
106-47-8
4-Chloroaniline
25 U
mg/kg
25
7005-72-3
4-Chlorophenyl phenyl ether
25 U
mg/kg
25
100-01-6
4-Nitroaniline
25 U
mg/kg
25
100-02-7
4-Nitrophenol
25 U
mg/kg
25
83-32-9
Acenaphthene
3.8
mg/kg
2.5
208-96-8
Acenaphthylene
2.5 U
mg/kg
2.5
98-86-2
Acetophenone
120-12-7
Anthracene
1912-24-9
Atrazine
Page 20 ofS9
E104009 SVOA TCLPS FINAL
25 U
mg/kg
25
2.5 U
mg/kg
2.5
25 U
mg/kg
25
Prepared
1 nutyzed
10/05/10 1201) I01 12:00 10/05/10 (2:00 0/05/10 2:00 10/05/10 2:00 10/05/10 12:00 10/05/10 (2:00 10/05/10 12:00 10/05/10 200 (0/05/10 12:00 10/05/10 12:00 (0/05/10 12:00 10/05/10 (2:00 10/05/10 200 10/05/10 1200 10/05)10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10)05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 (2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 2:0(1 (0/05/10 12:00 10/05/10 (2:00
10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10)10 0:26 10/10/10 0:26 10/10/10 0:26 10/10)10 026 10/10)10 0:26 10/10/10 0:26 10/10/10 026 (0/10/(0 0:26 0:26 10/10/10 0:26 1(1/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10)10/10 0:26 10/10/10 026 10/10/10 026
Olethod
EPA 82700 EPA
8270D
EPA 82700 EPA
8270D
EPA 8270D EPA
8270D
EPA 8270D EPA
82700
EPA 8270D EPA
82700
EPA 82701) EPA 82700 EPA
82700
EPA 82700 EPA 8270D EPA
8270D
EPA 82700 EPA
82700
EPA 8270D EPA
82700
EPA 82700 EPA
8270D
EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700
11/1/10 16:40
0
0 -
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700
LE]
DART. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Janet Muse
PRD
-
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO4-B Station ID: HERCO4
E104009-06
Matrix: Waste
Date Collected: 9/28/10 13:50 C4S Number
4nalyre
RsuIls QI4ahjiers
U,zigs
8fRL
100-52-7
Benzaldehyde
25 U
mg/kg
25
56-55-3
Benzo(a)anthracene
2.5 U
mg/kg
2.5
50-32-8
Benzo(a)pyrene
2.5 U
mg/kg
2.5
205-99-2
Benzolb)fluoranthene
2.5 U
mg/kg
2.5
19 1-24-2
Benzo(g.h.i)perylene
2.5 U
mg/kg
2.5
207-08-9
Benzo(k)fluoranthene
2.5 U
mg/kg
2.5
85-68-7
Benzyl butyl phthalate
25 U
mg/kg
25
111-91-1
Bis(2-chloroethoxy)methane
25 U
mg/kg
25
111-44-4
bis(2-Chloroethyl) Ether
25 U
mg/kg
25
39638-32-9
Bis(2-chLoroisopropyl) ether
25 U
mg/kg
25
117-81-7
Bis(2-ethylhexyl) phthalate
25 U
mg/kg
25
105-60-2
Caprolactam
25 U
mg/kg
25
86-74-8
Carbazole
2.5 U
mg/kg
2.5
218-01-9
Chrysene
2.5 U
mg/kg
2.5
53-70-3
Dibenz(a,h)anthracene
2.5 U
mg/kg
2.5
132-64-9
Dibenzofuran
3.0
mg/kg
2.5
84-66-2
Diethyl phthalate
25 U
mg/kg
25
131-11-3
Dimethyl phthalate
25 U
mg/kg
25
84-74-2
Di-n-butylphthalatc
25 U
mg/kg
25
117-84.0
Di-n-octylphthalate
25 U
mg/kg
25
206-44-0
Fluoranthene
2.5 U
mg/kg
2.5
86-73-7
Fluorene
2.7
mg/kg
2.5
118-74-1
Hexachlorobenzene (IICB)
25 U
mg/kg
25
87-68-3
Hexachlorobutadiene
25 U
mg/kg
77-47-4
Hexachlorocyclopentadiene (FICCP)
25 U
mg/kg
25 25
67-72-1
Hexachloroethane
25 U
mg/kg
25
193-39-5
Indeno (1,2.3-cd) pyrene
2.5 U
mg/kg
2.5
78-59-1
Isophorone
25 U
mg/kg
25
91-20-3
Naphthalene
7.8
mg/kg
2.5
98-95-3
Nitrobenzene
25 U
mg/kg
25
62 1-64-7
n-Nitroso di-n-Propylarnine
25 U
mg/kg
25
Page 21 of59
E104009 SVOA TCLPS FINAL
Prepared
inaly;ed Method
b/OS/b
10/10110
12:00 I0’05/lO 2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 l2:00 10/05/10 12:00 l0/05,’I0 12:00 10/05/10 12:00 10:05:10 12:00 10/05/10 12:00 10/05/10
0:26 lO/lO/lO 026 10/10/W 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/b/b 0:26 10/10/10 0:26 10/10)10 0:26 10/10/10 0:26 10/10/10 0:26 b/b/b 0:26 10)10/10 0:26 10/10/10 0:26 10/10/10 0:26 b/b/ID 0:26 b/b/b 0:26 10/10/10 0:26 b/b/b 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 1010/10 0:26 10/10/10 0:26
12:00
10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 b/OS/b 12:00 10/05/b 12:00 10/05/10 12:00 10/05/10 12:00 b/OS/b 12:00 10/05/10 I2:00 10/05/10 l2:00 10/05/10 12:00 10/05/10 12:00 10/05/10
12:00 10/05/tO
b0/l0:l0
12:00 10/05/10 2:00
0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 b/b/b 0:26 0)10/10 0:26
b/Os/b
b/b/b
12:00
0:26
I2:00
10/05/10 12:00 10/05)10 12:00 10)05/10 12:00 0/05/10
EPA 8270D EPA 8270D EPA 82700 EPA
82700
EPA 82700 EPA
8270D
EPA 82700 EPA
8270D
EPA 82700 EPA 82700 EPA 8270D EPA
8270D
EPA 82700 EPA
82700
EPA
82700
EPA
82700
EPA 8270D
EPA 8270D EPA 82700 EPA
82700
EPA 82700 EPA 8270D EPA 82700
EPA 82700 EPA 82700 El’A 82700 EPA 8270D
EPA 82700 EPA 8270D EPA 8270D EPA 82700
11/1/10 16:40
0
C
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700
4kz
k
D.A.R.T. Id. 10-0629
Project: 10-0629, Hercules Inc
-
Reported by Janet Muse
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO4-B
E104009-06
Matrix: Waste
Station ID: 1{ERCO4 Date Collected: 9/28/10 13:50 (•1S Number
122-39-4
Results Qualifiers
(nalyre
n-Nitrosodiphenylamine/Diphenylamine
Units
MRL
Prepared
.4na(v:ed
10/05/10 12:00 10/05/10 1200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00
10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26
25 U
mg/kg
25
87-86-5
Pentachlorophenol
25 U
mg/kg
25
85-01-8
Phenanthrene
3.0 J, QL-2
mg/kg
2.5
108-95-2
Phenol
71
mg/kg
25 2.5 25
129-00-0
Pyrene
3.6
mg/kg
110-86-1
Pyridine
25 U
mg/kg
lie/hod EPA 8270D
EPA 82700 EPA 82700 EPA 8270D EPA 82700
EPA 82700
Tentatively Identified Compounds: R4-6552
(Menthenol)terpineol (TIC)
300 >,‘J
mg/kg
R4-6531
Camphene (TIC)
300 NJ
mg/kg
R4-8000520
Camphor (TIC)
200 NJ
mg/kg mg/kg
R4-8000903
Chlorotrimethylbicycloheptane (TIC)
100 NJ
R4-6603
Dimethylisopropylphenanthrene (TIC)
200 NJ
mg/kg
1000 NJ
mg/kg
R4-8000899 R4-6500
Hexahydrotetramethylmethallonaphthalene (TIC) Petroleum Product:
N mg/kg
10/05/10
0/10/10
12:00 10/05/10
0:26 10/10/10
12:00 100510
EPA
10)05/10 12:00 10/05/10 12:00 10/05/10 12:00
0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26
10/05/10 12:00 10/05/10
10/10/10 0:26 10/10)10
EPA 82700
12:00 10/05/10 2:00
0:26 10,10/10
12:00
R4-6520
Pinene (TIC)
700 NJ
R4-8000466
Propylphenol (TIC)
200 NJ
mg/kg
300 NJ
mg/kg
I0/05’10
mg/kg
10/05/10 12:00
R4-800090I
Trimethylbicycloheptane (TIC)
R4-6501
Unidentified Compounds
Page 22 of59
E104009 SVOA TCLPS FINAL
2000 J
2:00
0:26 10/10110 0:26 10/10/10 0:26
EPA 82700
82700
EPA 8270D EPA 82700 EPA 82700 EPA 8270D
EPA 82700 EPA 82700
EPA 82700 EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTiON AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.AR.T. Id: 10-0629
Project: 10-0629, Hercules nc- Reported by Janet Muse
TCLP SemiVolatfies Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO4-B Station ID: HERCO4
E104009-06
Matrix: Waste
Date Collected: 9/28/10 13:50 C4S
Number
.4natyte
1319-77-3
(3-andlor4-)Methylphenol:
NA-5
58-90-2
2,3,4,6-Tetrachlorophenol:
NA-5
0.10
95-95-4
2,4,5-Trichlorophenol:
NA5
0.10
8 8-06-2
2,4,6-Trichlorophenol:
NA-5
0.10
121-14-2
2,4-Dinitrotoluene:
NA-5
0.10
95-48-7
2-Methylphenol:
NA-5
0.10
Ilexachlorobenzene (HCB):
NA-5
0.10
Il 8-74-1
87-68-3
.
--
Results Qualifiers
Hexachlorobutadiene:
67-72-t•ëxachloroethane:
Units
MRL
0.10
9:44
NA5
0.10
NA-5
0.10
bO,05/b0 9:4-I
Nitrobenzene:
NA-5
0.10
87-86-5
F’entachlorophcnol:
NA-5
0*10
110-86-1
Pyridine:
NA-5
0.10
E104009 SVOA TCLPS FINAL
10/05/10 9:44 10/05/10 9:44 10/05/10 10/05/10 9:44 0/05/10 944 10/05/10 9:44 b/OS/b 9:44 10/05/10 9:44
98-95-3
Page 23 of59
Prepared
10/05/10 9:44 005/10 944 30/05/10 9:44
Anaivzed Method 10/09/10 14:04 10/09/10 14:04 10/09/10 14:04 10/09/10 14:04 10/09/tO 404 10/09/10 14:04 10/09/10 14:04 10/09/10 14:04 100410
14:04 10/09/10 14:04 10/09/b 14:04 10/09/10 14:04
EPA 82700
EPA 8270D EPA 82700 EPA 8270D EPA 82700
EPA 82700 EP\ 82700
EPA 82700 EPA
82700
EPA 82700 EPA 82700 EPA
82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROThCTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
Semi Volatile Organics Project: 10-0629, Hercu’es Inc Lab ID:
Sample ID: HERCO5-A
E104009-07
Matrix: Waste
Station ID: HERCO5 Date Collected: 9/28/10 14:05 CIS Number
.4nalyte
1319-77-3
(3-andlor4-)Methylphenol
92-52-4
1,1-Biphenyl
Results Qualijiers
Units
MRL
Prepared
1200 10/05/10 12:00
100
mg/kg
24
1200
mg/kg
24
58-90-2
2,3,4,6-Tetrachlorophenol
24 U
mg’lg
95-95-4
2,4,5-Trichlorophenol
24 U
mg/kg
24
88-06-2
2,4,6-Trichlorophenol
24 L
mg/kg
24
120-83-2
2,4-Dichiorophenol
24 U
mg/kg
24
105-67-9
2,4-Dimethylphenol
24 U
mg/kg
24 24
24
51-28-5
2,4-Dinitrophenol
24 U
mg/kg
121-14-2
2,4-Dinitrotoluene
24 Ii
mg/kg
24 24
606-20-2
2,6-Dinitrotoluene
24 U
mg/kg
91-58-7
2-Chloronaphthalenc
24 U
mg/kg
24
95-57-8
2-h1orophenol
24 U
mg/kg
24
534-52-1
2-Methyl-4.6-dinitrophenol
24 U
mg/kg
24
91-57-6
2-Methylnapht.halene
14
mg/kg
2.4
95-48-7
2-Methylphenol
4.9 J, Q-2
mg/kg
24
88-74-4
2-Nitroaniline
24 U
mg/lcg
24 24
88-75-5
2-Nitrophenol
24 U
mg/kg
91-94-1
3,3-Dichlorobenzidine
24 U
mg/kg
24 24
99-09-2
3-Nitroaniline
24 U
mg/kg
101-55-3
4-Bromophenyl phenyl ether
24 U
mg/kg
24
59-50-7
4-Chloro-3-methylphenol
24 U
mg/kg
24
106-47-8
4-Chloroaniline
24 U
mg/kg
24
7005-72-3
4-Chtorophenyl phenyl ether
24 U
mg/kg
24 24
100-01-6
4-Nitroaniline
24 U
mg/kg
100-02-7
4-Nitrophenol
24 U
mg/kg
24 2.4 2.4
83-32-9
Acenaphthene
2.8
mg/lcg
208-96-8
Acenaphthylene
2.4 U
mg/kg
98-86-2
Acetophenone
24 U
mg/kg
24
120-12-7
Anthracene
2.4 U
mg/kg
2.4
1912-24-9
Atrazine
24 U
mg/kg
24
Page 24 of59
E104009 SVOA TCLPS FINAL
10105fl0
12:00 10/05/10 12:00 10/05/10 12:00 10/05)10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10.05,10 200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 2:00 10/05/10 12:00 0/05/10 12:00 10/05)10 12:00 10:05/10 12:00 10/05/Ill 12.00 10/05)10 12:00 10/05/10 12:00 10/05/Jo 12:00 10/05)10 12:00 10/05)10 12:00 10/05/10 1200
.lnalw;ed fethod
1:01 10/10/10 1:01 10.10.10 1:01 10/10/10 1:01 10:1010 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10110110
1:01 10/10/10 1:01 I0I0I0 1:01 10/10/10 1:01 10,10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:1)1 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1,01 10/10/10 1:01 10/10/10 1:01
EPA 8270D
EPA 82700 EPA 8270D EPA 82700 EPA 8270D EPA 8270D EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 8270D EPA
82700
EPA 8270D EPA 82700 EPA /12701) EPA 82700 EPA 8270D EPA 8270D EPA 8270D EPA
8270D
EPA 82700 EPA 8270D EPA 82700 EPA 8270D EPA 8270D EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO5-A Station ID: HERCO5
E104009-07
Matrix: Waste
Date Collected: 9/28/10 14:05 (‘AS Number
.4nalyte
100-52-7
Benzaldehyde
56-55-3
205-99-2
Benzob)fluoranthene
Results Qualifiers
Units
tIIRL
Prepared 10/05/10 2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 1200
24 U
mg/kg
24
Benzo(a)anthracene
2.4 U
mg/kg
2.4
Benzo(a)pyrene
2.4 U
mg/kg
2.4
2.4 U
mg/kg
2.4
L91-24
Benzo(g,h,i)perylene
2.4 U
mg/kg
2.4
207-08-9
Benzo(k)fluoranthene
2.4 U
mg/kg
2.4
85-68-7
Benzyl butyl phthalate
24 U
mg/kg
24
111-91-1
Bis(2-chloroethoxy)methane
24 U
mg/lcg
24
111-44-4
bis(2-Chloroethyl) Ether
24 1/
mg/kg
24
39638-32-9
Bis(2-chloroisopropyl) ether
24 U
mg/kg
24
117-81-7
Bis(2-ethyllsexy) phlhalate
24 U
mg/kg
24
105-60-2
Caprolactam
24 U
mg/kg
24
86-74-8
Carbazole
2.4 U
mg/kg
2.4
218-01-9
Chrysene
2.4 U
mg/kg
2.4
53.70.3
Dibenz(a.h)anthracene
2.4 U
mg/kg
2.4
132-64-9
Dibenzofuran
2.4 U
mgllcg
2.4
84-66-2
Diethyl phthalate
24 U
mg/kg
24
131-11-3
Dimethylphthalate
24 U
mg/kg
24
84-74-2
Di-n-butylphthalate
24 U
mg/kg
24
117-84-0
Di-n-octylphthalate
24 U
mg/kg
24
206-44-0
Fluoranthene
11
mg/kg
2.4
86-73-7
Fluorene
2.4 U
mg/kg
2.4
118-74-1
Hexachlorobenzene (HCB)
24 U
mg/kg
24
87-68-3
Hexachlorobutadiene
24 U
mg/kg
24
77-47-4
Hexachlorocyclopentadiene (HCCP)
24 U
mg/kg
24
67-72-1
Hexachloroethane
24 U
mg/kg
24
193-39-5
Indeno (1,2,3-cd) pyrene
2.4 U
mg/kg
2.4
78-59-1
Isophorone
24 U
mg/kg
24
91-20-3
Naphthalene
8.7
mg/kg
2.4
98-95-3
Nitrobenzene
24 U
mg/kg
24
621-64-7
n-Nitroso di-n-Propylamine
24 U
mg/kg
24
Page 25 of 59
E104009 SVOA TCLPS FINAL
Analyzed Method 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1.0! 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:0! 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 101
EPA 8270D EPA 8270D EI’A
8270D
EPA
8270D
EPA 8270D
EPA 82700 EPA 8270D EPA
8270D
EPA 8270D EPA 8270D EPA
82700
EPA 82700 EPA 82700 EPA
8270D
EPA 82700 EPA
8270D
EPA
8270D
EPA 82700 EPA
8270D
EPA 82700 EPA 8270D EPA 8270D EPA 8270D
EPA
8270D
EPA 8270D EPA
8270D
EPA 8270D EPA 82700 EPA 8270D EPA 8270D EPA 8270D
11/1/10 16:40
0
0
UNiTED STATES ENViRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Ed: 10-0629
Project: 10-0629, Hercules Inc
-
Reported by Janet Muse
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCOS-A
E104009-07
Matrix: Waste
Station ID: HERCO5 Date Collected: 9/28/10 14:05 C4S Nwnher
Results Qualifiers
.4nalvie
Units
MRL
Prepared
.lnaly;ed
24
10/05/10 12:00 10105110 12:00 0/05/10 12:00 10/05/10 12:00 1005/10 2:00 10/05/10 12:00
10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 I0I10I0 1:01 10/10/10 1:01
10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00
122-39-4
n-Nitrosodiphenylamine/Diphenylamine
24 U
mg/kg
87-86-5
Pentachlorophenol
24 U
mg/kg
24
2.4
85-01-8
Phenanthrene
2.4 U
mg/kg
108-95-2
Phenol
3]
mg/kg
24
5.7
mg/kg
2.4
24 U
mg/kg
24
300 NJ
mg/kg mg/kg
129-00-0
Pyrene
110-86-1
Pyridine
11cr/md EPA 82700 EPA
82700
EPA 82700 EPA 8270D EPA 82700
EPA 8270D
Tentatively Identified Compounds:
R4-8000904
Cycloisolongifolene (TIC)
200 NJ
mg/kg
R4-6506
Decahydrotrimethylmethylenemethanoazu lene (TIC)
400 NJ
mg/kg
10/05/10
12:00
10/10/10 1:01 10/10/10 1:0] 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01
R4-6603
Dimethylisopropylphenanthrene (TIC)
100 NJ
mg/kg
R4-6539
Hexahydrodimethyl(methylethyl)naphthal ene (TIC)
400 NJ
mg/kg
10/05/10 12:00 10/05/10
10/10/10 1:01 10/10/10
12:00
1:01
EPA 8270D
R4-6500
Petroleum
10/10/10 1:01
EPA 82700
R4-6519
Phenanthrenecarboxylic acid (TIC)
200 NJ
mg/kg
10/10/10
EPA 8270D
R4-6520
Pinene (TIC)
900 NJ
mg/kg
R4-800090I
Trimethylbicycloheptane (TIC)
400 NJ
mg/kg
R4-6501
Unidentified Compounds
700 J
mg/kg
10/05/10 12:00 10/05/10 12:00 10/05/10 1200 0/05/10 12:00 10/05/10 12:00
R4-6552
(Menthcnol)terpineol (TIC)
R4-6531
Camphene (TIC)
200 \J
R4-8000903
Chlorotrimethylbicycloheptane (TIC)
100 NJ
mg/kg
Page 26 of59
Product:
E104009 SVOA TCLPS FINAL
1:0] 10/10/10 1.01 10/10/10 1:01 10/10/10 1:01
EPA 8270D EPA 8270D EPA 82700
EPA 8270D EPA 82701)
EPA 8270D
EPA 8270D EPA 8270D EPA 8270D
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
TCLP SemiVolatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO5-A Station ID: HERC05
E104009-07
Matrix: Waste
Date Collected: 9/28/10 14:05 C4S Number
.4nalyte
Results Qualifiers
Units
MRL
(3-andior4-)Methylphenol:
2,3,4,6-Tetrachiorophenol:
XA-5
0.10
95-95-4
2.4,5-Trichlorophenol:
NA-5
0.10
88-06-2
2,4,6-Trichlorophenot:
NA-S
0.10
121-14-2
2,4-Dinitrotoluene:
NA-S
0.10
,
95-48-7
2-Methyiphenol:
NA-S
0.10
118-74-1
Flexachlorobenzenc (HCB):
NA-5
0.10
Hexachlorobutadiene:
NA-5
0.10
NA-S
0.10
87-68-3
-
-
—-
--
67-72-I
xachloroethane:
98-95-3
Nitrobenzene:
NA-S
0.10
87-86-5
Pentachlorophenol:
NA-5
0.10
110-86-1
Pyridine:
NA-S
0.10
Page 27 of59
E104009 SVOA TCLPS FINAL
.-lnalyzed Method
o. 10
13 19-77-3
58-90-2
NA-5
Prepared
EPA 8270D 1OE1O
EPA 82700
l%olO
‘9’
‘°°
ltJ/O
1%OO
I/O9/O
1%O1O 0,05/JO
EPA 8270D
EPA 82700 EPA827OD EPA 8270D
I009I0
EPA 8270D EPA 8270D
10/05/10 10/05/10
1O/9OO
EPA 82700 10/09/10
EPA 8270D
/O 0 It/09
EPA 8270D
I/:9/O
EPAS2700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 90 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO6-B
E104009-08
Matrix: Waste
Station ID: HERCO6 Date Collected: 9/28/10 14:55 C4S Number
.4nalyie
1319-77-3
(3-and/or 4-)Methylphenol
92-52-4
1,1-Biphenyl
Results Qualijiers
26 U 120
MRL
Prepared
mg/kg
26
mg/kg
2.6 26
10/05/10 12:00 10/05510 12:00 10/05/10 12:00 10/05/10 12:00 10.05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 2:00 10,05/10 12:00 10/05/10 12:00 10/05/10 2:00 10/05/10 12:00 10/00 2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00
Units
58-90-2
2,3,4,6-Tetrachlorophenol
26 U
mg/kg
95-95-4
2,4,5-Trichlorophenol
26 U
mg/kg
26
88-06-2
2.4,6-Trichlorophenol
26 U
mg/kg
26
120-83-2
2,4-Dichlorophenol
26 U
mg/kg
26
105-67-9
2,4-Dimethylphenol
26 U
mg/kg
26
51-28-5
2,4-Dinitrophenol
26 U
mg/kg
26
121-14-2
2,4-Dinitrotoluene
26 U
mg/kg
26
26
606-20-2
2,6-Dinitrotoluene
26 C
mg/kg
91-58-7
2-Chloronaphthalene
26 U
mg/kg
26
95-57-8
2-Chlorophenol
26 U
mg/kg
26
534-52-I
2-Methyl-4,6-dinitrophenol
26 U
mg/kg
26
91-57-6
2-Methylnaphthalene
2.6 C
mg/kg
2.6
95-48-7
2-Methylphenol
26 U
mg/kg
26
88-74-4
2-Nitroaniline
26 C
mg/kg
26
26 U
mg/kg
26
88-75-5 9 1-94-1
2-Nilrophenol 3,3’-Dichlorobenzidine
26 C
mg/kg
26 26
26
99-09-2
3-Nitroaniline
26 U
mg/kg
101-55-3
4-Bromophenyl phenyl ether
26 C
mg/kg
59-50-7
4-Chloro-3-methylphenol
26 U
mg/kg
26
106-47-8
4-Chloroaniline
26 U
mg/kg
26
7005-72-3
4-Chlorophenyl phenyl ether
26 U
mg/kg
26 26
100-01-6
4-Niti-oaniline
26 U
mg/kg
100-02-7
4-Nitrophenol
26 U
mg/kg
26
2.6 2.6
83-32-9
Acenaphthene
2.6 C
mg/kg
208-96-8
Acenaphthylene
2.6 U
mg/kg
98-86-2
Acetophenone
26 U
mg/kg
26
120-12-7
Anthracene
2.6 U
mg/kg
2.6
1912-24-9
Atrazine
26 C
mg/kg
26
Page 28 of 59
E104009 SVOA TCLPS FINAL
10/os/jo
2:00 10/05/10 2:00 10/05510 12:00 Io:o5,’Io 12:00 10/05/10 12:00 1005.10 12.000 10,05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 0/05/10 12:00 10/05/10 12:00 10/85/10 12:00
.lnalvzed ,Stcthod 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10:09,10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10,09/10 20:56 10/09/10 20:56 10/09:10 20:56 10/09/10 20:56 10/09/10 20:56 0/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20.56 10/09/10 20:56 10/09/10 20:56 1009:10 20:56 10/09/10 20:56 10:09/10 20:56 10/09/10 20:56 10/09/10 20:56 0/09/10 20:56 10/09/10 20:56 10/09/10 20.56
EPA 82700
EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA82700 EPA 82700 EPA 82700 EPA
8270D
EPA 8270D EPA 82700
EPA 82700 EPA 8270[) EPA 82700 EPA 9270D EPA 8270D
EPA 8270D EPA
8270D
EPA82700
EPA 82700 EPA 82700 EPA 82700 EPA 82700
EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENViRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 3 0605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc
-
Reported by Janet Muse
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO6-B
E104009-08
Matrix: Waste
Station ID: UERCO6 Date Collected: 9/28/10 14:55 C4S Number 100-52-7 56-55-3
Results Qualifiers
4nalyte
Benzaldehyde
26 U
Benzo(a)anthracene
2.6 U
Units mg/kg mg/kg
MRL ..,
2
50-32-8
Benzo(a )pyrene
2.6 U
mg/kg
2 •6
Benzo(b)fluoranthene
2.6 C’
mg/kg
2
191-24-2
Benzo(g,h.i)perylene
2.6 U
mg/kg
2•
•
207-08-9
Benzo(k)fluoranthene
2.6 U
85-68-7
Benzyl butyl phthalate
26 U
mg/kg
26
111—91—1
Bis(2-chloroethoxy)methane
26 U
mg/kg
-,
111-44-4
bis(2-Chloroethyl) Ether
26 U
mg/kg
.,
39638-32-9
Bis(2-chloroisopropyl) ether
26 U
mg/kg
-,
117-81-7
Bis(2-ethylhexyl) phthalate
26 U
mg/kg
26
105-60-2
Caprolactam
26 U
mg/kg
2’
86-74-8
Carbazole
2.6 U
mg/kg
2 •6 ‘
218-01-9
Chrysene
2.6 U
mg/kg
2
53-70-3
Dibenz(a.h)anlhracene
2.6 U
mg/kg
2 6
2.6 U
mg/kg
.,
84-66-2
Diethyl phthalate
26 U
mg/kg
26
13 1-11-3
Dimethyl phthalate
26 U
mg/kg
2’
84-74-2
Di-n-butylphthalate
26 U
mg/kg
26
117-84-0
Di-n-octyiphthalate
26 U
mg/kg
‘,
206-44-0
Fluoranthene
2.6 U
mg/kg
.,
.,
86-73-7
Fluorene
2.6 U
118-74-I
Hexachlorobenzene (HCB)
26 U
mg/kg
-,
•
87-68-3
Hexachlorobutadiene
26 U
mg/kg
i
77-47-4
Hexachlorocyclopentadiene (HCCP)
26 U
mg/kg
‘,
57-72-1
Hexachioroethane
26 U
mg/kg
‘,
193-39-5
Indeno (1,2,3-cd) pyrene
U
mg/kg
26
mg/kg
•,
78-59-1
26 U
Isophorone
91-20-3
Naphthalene
2.6 U
mg/kg
98-95-3
Nitrobenzene
26 U
mg/kg
521-64-7
n-Nitroso di-n-Propvlamine
26
U
mg/kg
Page 29 of 59
F 104009 SVOA TCLPS FINAL
10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 2:00
10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00
mg/kg
2.6
10/05/10 12:00 10105/10 12:00 10/05/10 12:00 005/IC 2:00
‘
mg/kg
Dibenzofuran
10/05/10 12:00
205-99-2
132-64-9
Prepared
-,
•
2’
10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00
10105/10 12:00 0/05/10 12:00 10/05/10 12:00 0 05/10 2:00
.inq1ed lie/hod 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 1009 10 20:56 10/09/ID 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 1009/l0 20:56 10/09/10 20:56 1009/10 20:56 10/09,10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/IC 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 1009 10 20:56
EPA 82700 EPA 82700 EPA
82700
EPA 8270D EPA 82700 EPA
82700
EPA 8270D EPA 82700 EPA 82700 EPA 8270D EPA %270D
EPA 82700 EPA 8270D EPA 8270D EPA 62700 EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 8270D
EPA 82700 EPA 82700 EPA 82700 EPA 82700
11/1/10 16:40
C
C
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
1
Project: 10-0629, Hercules Inc Reported by Janet Muse -
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO6-B
E104009-08
Matrix: Waste
Station ID: HERCO6 Date Collected: 9/28/10 14:55 (‘1S Vuwher
Results Qualifiers
.4nalyre
122-39-4
n-Nilrosodiphenylamine/Diphenylamine
Units
26 U
mg/kg
MRL
Prepared
.lnaty;ed
26
10/05/10 12:00 10/05/10 12:00 10/00 12:00 b/OS/b 12:00 10/05/10 12:00 10/05/10 12:00
10/09/10 20:56 10/09/1(1 20:56 10/09/10 20:56 10109/10 20:56 10/09/10 20:56 10/09/10 20:56
10/09/10 20:56 10’09/J0 20:56 10:09/10 20:56 10/09/10 2056 1009/10 2056
87-86-5
Pentachlorophenol
26 U
mg/kg
26
85-01-8
Phenanlhrene
2.6 U
mg/kg
2.6
108-95-2
Phenol
26 U
mg/kg
26
129-00-0
Pyrene
2.6 U
mg/kg
2.6
110-86-1
Pyridine
26 U
mg/kg
26
200 NJ
mg/kg
200 NJ
mg/kg
2000 NJ
mg/kg
10/05/10 12:00 10/05/10 12:00 10/05/10 12:00
mg/kg
10/05/b 1200 (0 0510 (200
lfethod EPA 82700
EPA 82700 EPA 82700
EPA 82700 EPA 8270D EPA 8270D
Tentatively Identified Compounds: R4-6603
Dimelhyllsopropylphenanthrene (TIC)
R4-8000535
Diphenyl ether (TIC)
R4-8000899
flexahydrotetramethylmethanonaphthalene (TIC)
R46500
Petroleum Product:
R4-6501
Unidentified Compounds
Page 30 of 59
E104009 SVOA TCLPS FINAL
N 6000 J
EPA 82700
EPA 82700 EPA 82700
EPA 8270D EPA 8270D
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
TCLP SemiVolatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO6-B Station ID: HERCO6
E104009-08
Matrix: Waste
Date Collected: 9/28/10 14:55 C4S Nu,nl’er
Ana!yrc
Results Qualifiers
Units
1IRL
Prepared 10/05110 9:44 10/05/10
1319-77-3
(3-andlor4-)Methylpheno[:
NA-5
010
5 8-90-2
2,3,4,6-Tetrachiorophenol:
NA-5
0.10
95-95-4
2,4,5-Trichorophenol:
NA-5
0.10
88-06-2
2,4,6-Trichlorophenol:
NAS
0.10
121-14-2
2,4-Dinitrotoluene:
NA-S
0.10
95-48-7
2-Methyiphenol:
NA5
0.10
118-74-I
Hexachlorobenzene (1-ICO):
NA-5
0.10
Hexachlorobutadiene:
NA5
87683
---
67-72-I
Hexachioroethane:
98-95-3
Nitrobenzene:
0.10
0.10 NA-S
0.10
87-86-5
Pentachlorophenol:
NA-5
0.10
110-86-1
Pyridine:
NA-5
0.10
Page 31 of59
E104009 SVOA TCLPS FINAL
9:44
10/05110 944 10/05/10 9:44 10/05/10 9:44 10/05/10 9:44 10/OSlO 9-44 10/05/10 944 10/05/10 10/05/10 9:44 lObS/b 9-44 10/05/10 9:44
.4naty:ed ,01rhod l0/09/lO l4:04 10/09/10 14:04 1009:10 14:04 10/09/10 14:04 10/09/10 404 10/09/10 14:04 10/09/10 14:04 10/09/10 14:04 10:09/10 4-04 10/09/10 14:04 10/09/10 404 10/09/10 14:04
EPA 82700 EPA 82700
EPA 82700
EPA 8270D EPA 82700 EPA 8270D
EPA 827(11) EPA
82700
EPA 82700 EPA 82700 EPA 82700 EPA 8270D
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
Semi Volatile Organics Project: 16-0629, Hercules Inc Lab ID:
Sample ID: HERCO7-B
E104009-09
Matrix: Waste
Station ID: HERCO7 Date Collected: 9/28/10 15:25 C4S
Results Qualifiers
Niunber
.4nalyte
1319-77-3
(3-andlor4-)Methylphenol
92-52-4 58-90-2
1,1-Biphenyl
mg/kg
78
mg/kg
330
2,3,4,6-Tetrachlorophenol
Units
24 U
mg/kg
Prepared
24
10/05/10 1200
2131
24
10/05/10 1200 10/05/10
10/09/10
2131
EPA 82700
oO9l0 21:31 10/09/10 21:31 10/09/10 21:3! 10/09/10 21:31 10/09/10 273! 10/09/10 21:31 10/09/10 213! 10/09/10 21:3! 10/09/10 213! 10/09/10 21:31 10/09/10 21:31 10/09/10 2137 10.09/10 2131 10/09/10 27:31 10/09/10 21:31 0/09/10 21:3! 10/09/10 2131 10/09/10 27:31 0/09/70 21:31 10/09/10 21:31 10/09/10 2131 10/09/10 21:31 10/09/10 21:31 0/09/lU 2:3! 10,09/10 27:31 10i09/10 27:3! 10/09/10 21:31 10/09/10 21:37
EPA 82700
24
2,4,5-Trichlorophenol
24 ij
88-06-2
2,4,6:rrichlorophenol
24 U
mg/kg
24
120-83-2
24-Dichlorophenol
24 U
mg/kg
24
105-67-9
2,4-Dimethylphenol
24
U
mg/kg
24 24
95-95-4
mg/kg
MRL
24
51-28-5
2,4-Dinitrophenol
24 U
mg/kg
12 1-14-2
2,4-Dinitrotoluene
24 U
mg/kg
24
606-20-2
2,6-Dinitrotoluene
24
U
mg/kg
24
91-58-7
2-Chloronaphthalene
24 U
mg/kg
24
95-57-8
2-Chlorophenol
24 U
mg/kg
24
534-52-1
2-Methyl-4.6-dinitrophenol
24 U
mg/kg
24
91-57-6
2-Methylnaphthalene
2.4 U
mg/kg
2.4
95-48-7
2-Methylphenol
17 J. Q-2
mglg
24
88-74-4
2-Nitroaniline
24 U
mg/kg
24
24 U
mg/kg
24
88-75-5
2-Nitrophenol
92-94-1
3,3’-I)ichlorobenzidine
24 U’
mg/kg
24
99-09-2
3-Nitroaniline
24 U
mg/kg
24
101-55-3
4-Bromophenyl phenyl ether
24 1.,
mg/kg
24
59-50-7
4-Chloro-3-methylphenol
24 U
mg/kg
24
106-47-8
4-Chloroaniline
24 U
mg/kg
24
7005-72-3
4-Chlorophenyl phenyl ether
24 U
mg/kg
24 24 24
100-01-6
4-Nitroaniline
24 LI
mg/kg
100-02-7
4-Nitrophenol
24 U
mg.”kg
83-32-9
Acenaphthene
2.4 U
mg/kg
2.4
208-96-8
Acenaphthylene
2.4 U
mg/kg
2.4
98-86-2
Acetophenone
120-12-7
Anthracene
1912-24-9
Alrazine
Page 32 of59
E104009 SVOA TCLPS FINAL
24 U
mg/kg
24
2.4 U
mg/kg
2.4
24 U
nlg/kg
24
12:00
10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 1005/10 200 10/05/10 12:00 10/05/10 2.00 10/05/10 12:00 10/05/10 1200
10/05/10 12:00 10/05/10 12:00 10/05/70 200 10/05/10 12:00 10/05/10 12:00 I005/l0 1200
10/05/10 1200 0/05/10 1200 10/05/10 1200 10/05/10 72:00
10/05/10 12:00 10/05/10 1200 10/05/10 209 10/05/10 12:00 0/05/70
7200 lOiOs/IO 12:00
10/05/70 1209 10/05/10 7200
10/05/10 12.013
lnalyzed ?fethod
10/09/10
EPA 82700
EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA
8270D
EPA 82700 EPA
82700
EPA 8270D
EPA 82700 EPA 82700 EPA 82700 EPA 82700
EPA 82700 EPA 82700 EPA 82700
EPA 82700 EPA 82700 EPA 82700 EPA
8270D
EPA
82700
EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA
82700
EPA 82700 EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART, Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Janet Muse -
Semi Volatile Organics Project: 10-0629, hercules Inc Lab TD:
Sample ID: HERCO7-B
E104009-09
Matrix: Waste
Station ID: HERCO7 Date Collected: 9/28/10 15:25 C4S Number
.4nulyte
100-52-7
Benzaldehyde
24 U
mg/kg
24
56-55-3
Benzo(a)anthracene
2.4 U
mg/kg
2.4
50-32-8
Benzo(a)pyrene
2.4 U
mg;kg
2.4
205-99-2
Benzo(b)fluoranthene
2.4 U
mg/kg
2.4
2.4
Results Quahjiers
Units
MRL
191-24-2
Benzo(g,h,i)perylene
2.4 U
mg/kg
207-08-9
Benzo(k)fluoranthene
2.4 U
mg/kg
2.4 24
85-68-7
Benzyl butyl phthalale
24 U
mg/kg
111-91-1
Bis(2-chloroethoxy)methane
24 U
mg/kg
24
111-44-4
bis(2-Chloroethyl) Ether
24 U
mg/kg
24
39638-32-9
Bis(2-chloroisopropyl) ether
24 U
mg/kg
24
117-81-7
Bis(2-cthylhexyl) phthalate
24 U
mg/kg
24 24 2.4
105-60-2
Caprolactam
24 U
mg/lcg
86-74-8
Carbazole
2.4 U
mg/kg
2.4
218-01-9
Chrysene
2.4 L
mg/kg
53-70-3
Dibenz(a.h)anthracene
2.4 U
mg/kg
2.4
132-64-9
Dibenzofuran
2.4 U
mg/kg
2.4
84-66-2
Diethyl phthalate
24 U
mg/kg
24
131-11-3
Dimethylphthalate
24 U
mg/kg
24
24
84-74-2
Di-n-butylphthalate
24 U
mg/kg
117-84-0
Di-n-octylphthalate
24 L
mg/kg
24 2.4
206-44-0
Fluoranthene
2.4 U
mg/kg
86-73-7
Fluorene
2.4 U
mg/kg
2.4
Hexachlorobenzene (I-ICB)
24 U
mg/kg
24
87-68-3
ilexachlorobutadiene
24 U
mg/kg
24
77-47-4
Hexachiorocyclopentadiene (IICCP)
24 U
mg/kg
24 24
118-74-1
67-72-1
Ilexachloroethane
24 U
mg/kg
193-39-5
Indeno (1,2,3-cd) pyrene
2.4 U
mg/kg
2.4 24 2.4
78-59-1
Isophorone
24 U
mg/kg
91-20-3
Naphthalene
2.4 U
mg/kg
98-95-3
Nitrobenzene
24 U
mg/kg
24
62 1-64-7
n-Nitroso di-n-Propylamine
24 U
mg/kg
24
Page 33 of 59
E104009 SVOA TCLPS FINAL
Prepared 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 l0.05l0 12.00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 1200 10/05/10 12:00 lU/OS/b 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05110 12:00 10/05/JO 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10:05/10 2:00 10,05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10
2:00
10/05/10 12:00 10/05/10 1200 10/05/10 12:00 10/05/10 12:08 10/05/10 12:00
.lnulv:ed ltethod 10/09/10 21:31 10/09/10 2131 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21 31 10/09/10 21:31 1009/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 1009/10 21:31 10/09/10 21.31 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21 31 10.!09/10 21:31 10/09/10 2131 10/09/10
EPA 82700 EPA 82700 EPA
82700
EPA
82700
EPA 82700
EPA 8270D EPA 8270D EPA 8270D EPA 82700
EPA 82700 EPA 82700
EPA 8270D EPA 8270D EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA
82700
EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 82700
EPA 8270D EPA 02700
EPA 82700 EPA 8270D EPA
82700
21:31
EPA 8270D
10/09/10 21:31 100910 21:31
EPA 82700 EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc
-
Reported by Janet Muse
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO7-B
E104009-09
Matrix: Waste
Station 1D: HERCO7 Date Collected: 9/28/10 15:25 CAS Nwnber
122-39-4
Resalts Qualifiers
4na!yte
n-Nitrosodiphenylamine/Diphenylamine
24 U
Units
mg/kg
MRL
Prepared
24
10/05/10 12:00 10/05/10
87-86-5
Pentachlorophenol
24 U
mg/kg
24
85-01-8
Phenanthrene
2.4 U
mg/kg
2.4
108-95-2
Phenol
24 U
mg/kg
24
129-00-0
Pyrene
2.4 U
mg/kg
2.4
110-86-1
Pyridine
24 U
mg/kg
24
12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00
lnalyzed Method 10/09/10 21:31 10/09)10 21:31 10/09/10 21:31 10/09/10 2131 10/09/10 2131 10/09/10 21:31
EPA 8270D EPA 8270D EPA 8270D EPA 82700 EPA 8270D EPA 82700
Tentatively Identified Compounds: R4-6603
Dimethylisopropylphenanthrene (TIC)
200 NJ
mgrkg
R4-8000535
Diphenyl ether (TIC)
600 NJ
mg/kg
1000 NJ
rng:kg
R4-8000899
Hexahydrotetrarnethylmethanonaphthalene
10/05/10 12:90 10/05/10 2:00 10/05/10 12:00
10/09/10 21:31 21:3 I 10/09/10 21:31
10/05/10 12:00 10/05/10 12:00
10/09/10 21:31 10/09/10 21:31
EPA 8270D
EPA 8270D EPA 8270D
(TIC)
R4-6500
Petroleum Product:
R4-6501
Unidenlilied Compounds
Page 34 of59
E104009 SVOA TCLPS FINAL
N 5000 .1
mg/kg
EPA 8270D EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules mc- Reported by Janet Muse
TCLP SemiVolatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO7-R Station ID: HERCO7
E104009-09
Matrix: Waste
Date Collected: 9/28/10 15:25 C.4S Number
.4naiyre
1319-77-3
(3-and/or 4-)Methylphenol:
58-90-2
2,3,4,6-Tetrachlorophenol:
NA-5
0.10
95-95-4
2,4,5-Trichlorophenol:
NA-5
0. 10
8 8-06-2
2,4,6-Trichlorophenol:
NA-S
0.10
121-14-2
2,4-Dinitrotoluene:
NA-5
0.10
95-48-7
2-Methyiphenol:
NA-S
0.10
118-74-I
Hexachlorobenzcne (1 ICB):
NA-S
0.10
87-68-3
Hexachiorobutadiene:
NA-S
0.10
Hexachioroethane:
NA-5
0.10
67-72-I
Results Qualifiers
‘-
NA-5
Units
MRL
Prepared
0.10
1005/10 9:44
10/09/10
10/05/10
1005/10
10/09/10 1404 10/09/10 14:04 10/09/10 14:04 10,09/10 1404 10/09/10 14:04 10/0910 404
EPA 8270D
10/05/10
10/09/10
9:44 10/05/10
14:04 10/09/10
EPA 82700
10/05/10
10/09/10
10/05/10 9:44
10/05/10 9:44 1005:10 10/05/10
.4natyzed Method
1404
EPA 8270D
EPA 8270D EPA 8270D EPA 82700 EPA 8270D EPA
82700
EPA 8270D
98-95-3
Nitrobenzene:
NA-S
0.10
9:44
14:04
EPA 82700
87-86-5
Pentachlorophenol:
NA-S
0.10
10/05/10 944
10/0910 404
EPA 8270D
110-86-1
Pyridine:
NA-S
0.10
10/05/10 9:44
10/09/10 14:04
EPA 82700
Page 35 of 59
E104009 SVOA TCLPS FINAL
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART, Id: 10-0629
Project: 10-0629, Hercules Inc
-
Reported by Janet Muse
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO8
El 04009-10
Matrix: Waste
Station ID: HERCO8 Date Collected: 9/29/10 8:50 (Z4S Number
1319-77-3 92-52-4
Results Qualijiers
I nu1te
(3-and!or4-)Methylphenoi 1,1-Biphenyl
24 U
Units
mg/kg
MRL
Prepared
.1 natvzed
24
10/05/10 12:00
10/09/10 22:41
10/05/10
10/09/10
1200 10/05/10 200 10/05/10 12:00 10/05/10 (2:00 10/05/10 2:00 10/05/10 12:00 10/05/10 2:0(1 10/05/10 200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 (2:00 10/05/10 12:00 10/05/10 (2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 005/10 12:00 10/05/10 12:00 10/05/10 (2:00 10/05/10 (2:00 10/05/10 1200 10/05/10 12:00 10/05/10 12:00
22:4 I 1009/lU 224 10/09/10 22:41 10/09/10 22:41 10/09/10 22:41 10/09/10 22:41 10/09/10 22:41 10/09/10 224 10/09/10 22:41 10/09/10 22:41 10/09/10 22:4! 10/09/10 22:41 10/09/1(1 22:41 10/09/10 22:41 (0/09/10 22:41 10/09/10 22:41 10/09/10 2241 0/0910 2241 10/09/10 22:41 10,09/10 22:4! 10/09/10 22:4! 10/09/10 22:41 0/09/10 22:4! 1009/10 22:41
EPA 8270D
005)10
10/09/10
EPA 82700
2.4 U
mg/kg
2.4 24
58-90-2
2,3,4,6-Tetrachlorophenol
24 U
mg/kg
95-95-4
2,4,5-Trichlorophenol
24 U
mg/kg
24 24 24
88-06-2
2,4,6-Trichlorophenol
24 U
mg/kg
120-83-2
2,4-Dichlorophenol
24 U
mg/kg
24 U
mg/kg
24
mg/kg
24 24
105-67-9
2,4-Dimethylphenol
5 1-28-5
2,4-Dinitrophenol
24 U
12 1-14-2
2,4-Dinitrololuene
24 U
mg/kg
24
606-20-2
2,6-Dinitrotoluene
24 U
mg/kg
9 1-58-7
2-Chloronaphthalcne
24 U
mg/kg
24
95-57-8
2-Chlorophenol
24 U
mg/kg
24
534-52-1
2-MeIhyl-4,6-dinitrophenol
24 U
mg/kg
24
2.4 U
mg/kg
2.4 24
9 1-57-6
2-Methylnaphthalene
95-48-7
2-Methylphenol
24 U
mg/kg
88-74-4
2-Nitroaniline
24 U
mg/kg
24 24
88-75-5
2-Nitrophenol
24 U
mg/kg
91-94-1
3,3’-Dichlorobenzidine
24 U
mg/kg
24 24
99-09-2
3-Nitroaniline
24 U
mg/kg
101-55-3
4-Bromophenyl phenyl ether
24 U
mg/kg
24
59-50-7
4-Chloro-3-methylphenol
24 U
mg/kg
24
106-47-8
4-Chloroaniline
24 U
mg/kg
24
7005-72-3
4-Chlorophenyl phenyl ether
24 U
mg/kg
24
mg/kg
24 24
100-01-6
4-Nitroaniline
24 U’
100-02-7
4.Nitrophenol
24 U
mg/kg
2.4 2.4
83-32-9
Acenaphthene
2.4 U
mg/kg
208-96-8
Acenaphthylene
2.4 U
mg/kg
98-86-2 120-12-7
1912-24-9
Page 36 of 59
Acetophenone
24 U
mg/kg
24
Anthracene
2.4 U
mg/kg
2.4
24 U’
Alrazine
E104009 SVOA TCLPS FINAL
mg/kg
24
2:00 10/05/10 (2:00 10/05/10 2:00
10/05/10 (2:00 10/05/10
12:00
2241 10/09/10 22:4! 10/09/10 22:4! 10/09/10 22:41
0/09/10 22:4!
:1t4’tIlud
EPA 8270D
EPA 8270D EPA 8270D EPA 82700 EPA
8270D
EPA 8270D EPA
82700
EPA 8270D EPA
82700
EPA 82700 EPA
8270D
EPA 92701) E1’A 82700 EPA 92701) EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700
EPA 82700 EPA
8270D
EPA 8270D
EPA 8270D
EPA 82701) EPA 82700
EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700
,
\o
00•1
D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Janet Muse -
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO8 Station ID: HERCO8
E104009-10
Matrix: Waste
Date Collected: 9/29/10 8:50 CAS Number
.lnalyte
100-52-7
Bcnzaldehyde
24 U
56-55-3
Benzo(a)anthracene
50-32-8
Benzo(a)pyrcne
205-99-2
Results Qualifiers
Units
MRL
Prepared
mg/kg
24
2.4 U
mg/kg
2.4
2.4 U
mg/kg
2.4
Benzo(b)fluoranthene
2.4 U
mg/kg
2.4
191-24-2
Benzo(g,h,i)perylene
2.4 U
mg/kg
2.4
207-08-9
Benzo(k)fluoranthene
2.4 U
mg/kg
2.4
100510 12:00 10/05110 12:00 10/05/10 12:00 10/05/10 12:00 1010510 12:00 10/05/10 12:00
85-68-7
Benzyl butyl phlhalalc
24 U
mg/kg
24
10/05/10
2:00
22:41
11 1-91-1
Bis(2-chloroethoxy)methane
24 U
mg/kg
24
10/05/10
24 U
mg/kg
24
10/09/10 22:41 10/09/10
111-44-4
‘‘bis(2-Chloroethyl) Ether
39638-32-9
Bis(2-chloroisopropyl) ether
24 U
mg/kg
1 17-81-7
Bis(2-ethylhexyl) phthalate
24 U
mg/kg
24
105-60-2
Caprolactam
24 U
mg/kg
24
86-74-8
Carbazole
2.4 U
mg/kg
2.4
218-01-9
Chrysene
2.4 U
mg/kg
2.4
24
53-70-3
Dibenz(a,h)anthracene
2.4 U
mg/kg
2.4
132-64-9
Dibenzofuran
2.4 U
mg/kg
2.4
84-66-2
Diethyl phthalate
24 U
mg/kg
24
131-11-3
Dimethylphthalate
24 U
mg/kg
24
84-74-2
Di-n-butylphthalate
24 U
mg/kg
24
117-84-0
Di-n-octylphthalate
24 U
mg/kg
24
206-44-0
Fluoranthene
2.4 U
mg/kg
2.4
86-73-7
Fluorene
2.4 U
mg/Icg
2.4
I 18-74-I
Hexachlorobenzene ([1(B)
24 U
mg/kg
24
87-68-3
Hexachlorobutadiene
24 U
mg/kg
77-47-4
1-lexachlorocyclopentadiene (IICCP)
24 U
mg/kg
24
67-72-1
Hexachloroethane
24 U
mg/kg
24
193-39-5
Indeno (1,2.3-cd) pyrene
2.4 U
mg/kg
2.4
78-59-1
Isophorone
24 U
mg/kg
24
24
91-20-3
Naphthalene
2.4 U
mg/kg
2.4
98-95-3
Nitrobenzene
24 U
mg/kg
24
621-64-7
n-Nitroso di-n-Propylamine
24 U
mg/kg
24
Page 37 of 59
E104009 SVOA TCLPS FINAL
12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/00/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10
.1 nalv:ed ,llethod 10/09/10 22:41 10/09/10 22:41 10/09/10 2241 10/09/10 22:41 1009.10 22:4 I 10/09/10 22:41 10/09/10
22:41
10/09/10 22:41 10/09/10 22:41 10/09/10 22:41 10/09/10 22:41 10/09/10 22:41 0/09/10 22:41 10/09/10 22:41 10/09/10 22:41 0/09/10 22:41 10/09/10 22:41
10/09/10 22:41 10/09/10
EPA82700 EPA 8270D EPA 8270D
EPA 82700 EPA 82700 EPA
82700
EPA 82700 EPA 82700 EPA 82700
EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA
82700
EPA 82700 EPA 82700 EPA 82700 EPA
82700
EPA 8270D EPA
8270D
22:41
EPA 8270D
10/09/10 22:41 10/09/10
EPA 82700
12:00
22:41
10/05/10 12:00 10:’OS/lO 12:00 10/05/10 12:00 10/05/10
10/09/10 22:41 10/09/10 22:41 10/09/10 22:41 1009/10
12:00
22:41
10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 0 0510 12:00
0/09/10 22:41 100910 22.41 10/09/10 22:41 00910 22:41
EPA 82700 EPA
82700
EPA 82700
EPA
82700
EPA 8270D EPA
8270D
EPA 82700 EPA 82701) EPA 8270D
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 0-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO8
E104009-10
Matrix: Waste
Station ID: HERCO8 Date Collected: 9/29/10 8:50
cis Niunber
Re,sulls Qualifiers
.dnalt’te
Units
MRL
Prepared 10/05/10 12:00 10)05/10
10/09/10 22:41 10/09(10
10/05/10 12:00 10/05/ID 12:00 10)05/10
10/09/lO 22:41 10/09/10 22:41 10/09/10
122-39-4
n-Nitrosodiphenylamine/Diphenylamine
24 U
mg/kg
24
87-86-5
Pentachlorophenol
24 U
mg/kg
24
85-01-8
Phenanthrene
2.4 U
mg/kg
2.4
108-95-2
Phenol
24 C
mg/kg
24
2.4 U
mg/kg
2.4
129-00-0
110-86-I
Pyrene
Pyridine
24 U
mg/kg
70 NJ
mg/kg
400 NJ
mg/kg
200 NJ
mg/kg
24
12:00
.1naled Method
22:41
EPA 82700
EPA 8270D EPA 82700 EPA 8270D
12:00
22:41
EPA 8270D
10/05/10 12:00
10/09/10 22:41
EPA 8270D
10/05/10
0/09/10
12:00 10/05/10 12:00 10/05/10
22:41 10/09/10 22:41 10:09/10
12:00
22:41
10/05/ID
10/09/10
22:41
EPA 82700
1005 10 200
0/09/10 2241
EPA 82700
Tentatively Identified Compounds: R4-6558
Bis(methylethyl)biphenyl
(TIC) (TIC)
R4-6603
Dimethylisopropylphenanthrene
R4-8000899
Hexahydrotetramethylmethanonaphthalene (TIC)
R4-6500
Petroleum Product:
R4-6501
Page 38 of59
Unidentified Compounds
E104009 SVOA TCLPS FINAL
2:00
2000 J
mg/kg
EPA 82700 EPA 82700 EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse
PRO’
-
TCLP SemiVolatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO8 Station ID: IIERCO8
E104009-10
Matrix: Waste
Date Collected: 9/29/10 8:50 C4S Number
.4na!yre
1319-77-3
(3-and/or4-)Methylphenol:
Results Qualifiers
NA-S
Units
MRL
0.10
58-90-2
2,3,4,6-Tetrachlorophenol:
NA-5
0.10
95-95-4
2,4,5-Trichlowphenol:
NA-S
0.10
88-06-2
2,4,6-Trichlorophenol:
NA-5
0.10
121-14-2
2,4-Dinitrotoluene:
NA-5
0.10
95-48-7
2-Methyiphenol:
NA-S
0.10
118-74-1
Flexachlorobenzene (HCB):
NA-5
0.10
87-68-3
-HexachIorobutadiene:
NA-S
0.10
NA 5
0 10
98-95-3
Nitrobenzene:
NA-5
0.10
87-86-5
Pentachlorophenol:
NA-5
0.10
110-86-1
Pyridine:
Page 39 of59
NA-5
E104009 SVOA TCLPS FINAL
0.10
Prepared
•lnalv:ed Method
1010
EPA827OD
1%0Io
9l09/0
IO)0
l9:09/O
EPA 8270D
‘°2°
‘?°
EPA 8270D
I0J/O
EPA 8270D
EPA 8270D EPA 8270D
10/05/10
0/09/10
EPA 8270D
10/05/10
10/09/10
EPA 8270D
10/05/10
10/09/10
‘°° °° ‘°°
EPA 8270D EPA 8270D
/09 9 I / 0 0
EPA 8270D EPA827OD
11/1/10 16:40
0
C
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse
PRD
-
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO9-B
E104009-11
Matrix: Waste
Station ID: HERCO9 Date Collected: 9/29/10 14:20 C4S :V,unber
.4nalyte
13 19-77-3
(3-and/or 4-)Methylphenol
Results Qualifiers
25 U
MRL
Prepared
mg/kg
25
mg/kg
2.5
25
10/05/10 12:00 10/05/]0 zoo 10105/Io 2:00 0/00/10 12:00 10/05/10 12:00 10/05/10 12:110 10.05/10 1200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 2:00 10/05/10 12:00 10/05/10 12:00 10/05/10
Units
92-52-4
1,1-Biphenyl
58-90-2
2,3,4,6-Tetrachlorophenol
25 U
mg/kg
95-95-4
2,4,5-Trichiorophenol
25 15
mg/kg
25 25
290
88-06-2
2,4,6-Trichlorophenol
25 IJ
mg/kg
120-83-2
2,4-Dichlorophenol
25 15
mg/kg
25
105-67-9
2.4-Dirnclhylphenol
25 U
mg/kg
25
51-28-5
2,4-Dinitrophenol
25 U
mg/kg
25
121-14-2
2,4-Dinitrotoluene
25 U
mg/kg
25
606-20-2
2,6-Dinitrotoluene
25 15
mg/kg
25
9 1-58-7
2-Chloronaphthalene
25 U
mg/kg
25
95-57-8
2-Chlorophenol
25 15
mg/kg
25
534-52-1
2-Methyl-4.6-dinitrophenol
25 U
mg/kg
25
91-57-6
2-Methylnaphihalene
mg/kg
2.5
95-48-7
2-Methylphenol
25 U
mg 1g
25
88-74-4
2-Nitroanjljne
25 15
mg/kg
25
88-75-5
2-Nitrophenol
25 U
mg’kg
25
91-94-1
3,3’-Dichlorobenzidine
25 1.
mg/kg
25
99-09-2
3-Nitroaniline
25 U
mg/kg
25
101-55-3
4-Bromophenyl phenyl ether
25 15
mg/kg
25 25
2.6
59-50-7
4-Chloro-3-methylphenol
25 U
mg/kg
106-47-8
4-Chloroaniline
25 15
nig/kg
25
7005-72-3
4-Chlorophenyl phenyl ether
25 U
mg/kg
25
100-01-6
4-Nitroaniline
25 15
mg/kg
25
100-02-7
4-Nitrophenol
25 U
mg/kg
25 2.5
2.5
83-32-9
Acenaphthene
2.5 15
ing/kg
208-96-8
Acenaphthylene
2.5 U
mg/kg
98-86-2
Acetophenone
120-12-7
Anthracene
1912-24-9
Atrazine
Page 40 of59
13104009 SVOA TCLPS FINAL
25 15
mg/kg
25
2.5 U
mg/kg
2.5
25 15
mg/kg
25
12:00
10/05/10 12:00 10/05/10 12:00 10/05/10 12.00 10/05/ID 1200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10,05/10 12:00 10/05/b 12:00 10/05/10 1200 10.05/10 12:00 10/05/10 1200 10)05/H) 12:00 10/05/Ill 12011 10/05/10 12:00 10/05/10 12:00
lna(vzed Method 10/10/10 1:37 10/10/ID 1:37 10110! 10 1:37 10/10/10 1:37 10/10/10 1:37 10/10/10 137 10/lO/lO 37 10/10/10 1:37 10/10/10 1:37 10/10/10 1:37 10/10/10 1:37 10/10/10 1:37 10/10/10 1:37 10/10)10 1:37 1010/10 1:37 10/10/10 1:37 10/10/10 1:37
10/10/10 1:37 10.1010 1:37 10/10/10 1:37 10/10110 1:37
10/10/10 1:37 10/10/10 1:37 10/10/10 1:37 lO/lO/lO 1:37 10/10110 137 10/10/10
EPA 8270D
EPA 82700 EPA 82700
EPA 82700 EPA 8270D EPA 8270D EPA 82701) EPA 8270D EPA 82700 EPA
8270D
EPA 8270D EPA 8270D EPA 8270D EPA 8270D EPA 8270D EPA
82700
EPA 8270D EPA 8270D EPA 82700 EPA
82700
EPA 82700 EPA 8270D EPA 82700 EPA 82700
EPA 82700 EPA 8270D
1:37
EPA 8270D
1000/10 1:37
EPA 82700
1:37 10/10/10 1:37
EPA 82700 EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc Repoed by Janet Muse -
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO9-B
E104009-11
Matrix: Waste
Station ID: HERCO9 Date Collected: 9/29/10 14:20 CAS
MRL
Prepared
mg/kg
25
2.5 U
mg/kg
2.5
2.5 U
mg/kg
2.5
2.5 U
mg/kg
2.5
10/05/10 12:00 10/05)10 12:00 10/05/tO 12.00 10/05/10 12:00 10/05/10 12:00 10)05/10 2:00 10/05110 12:00 10)05/10 12:00
Re,suIIy Qual/fiers
Number
.4milyre
100-52-7
Benzaldehyde
25 U
56-55-3
Benzo(a)anthracene
50-32-8
Benzo(a)pyrene
205-99-2
Benzo(b)fluoranthene Bcnzo(g,h.)perylene
19 1-24-2
Units
2.5 U
mg/kg
2.5 25
207-08-9
Benzo(k)fluoranthene
2.5 U
mg/kg
85-68-7
Benzyl butyl phthalate
25 U
mg/kg
111-91-1 111-44-4
.
2.5
Bis(2-chloroethoxy)methane
25 U
mg/kg
25
bis(2-Chloroethyl) Ether
25 U
mg/kg
25
39638-32-9
Bis(2-chloroisopropyl) ether
117-81-7
Bis(2-ethylhexyl) phthalate
105-60-2
Caprolactam
25 U
mg/kg
25 U
mg/kg
25 U
25 25
mg/kg
25
86-74-8
Carbazole
2.5 U
mg/kg
2.5
218-01 -9
Chrysene
2.5 U
mg/kg
2.5
53-70-3
Dibenz(a,h)an0hracene
2.5 U
mg/lcg
2.5
Analyzed ,lfethod 1:37 10/10/10 1:37 10/10/10 1:37 10/10/10 1:37 10/10)10 1:37
10/10/10 1:37 10/10/10 1:37 10/10/10
EPA 82700
12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/tO 12:00
10:10:10 1:37
EPA 82700
10/10/10 1:37 10/10/10 1:37 10/10/tO 1:37
EPA 82700
10/10/10
0/0510
to/I 0/10
1:37
2.5
12:00
1:37
84-66-2
Diethyl phthalate
25 U
mg/kg
25
10/05/tO
10/10/10
12:00
1:37
25 U
mg/kg
25
10/05/to
10/10/10
2:00
25
10/05/10
1:37 10/10/10
mg/kg
25 2.5
117-84-0
Di-n-octylphthalate
25 U
mg/kg
206-44-0
Fluoranthene
6.8
mg/kg
86-73-7
Fluorene
2.5 U
mg/kg
2.5
118-74-I
I-lexachlorobenzene (FICB)
25 U
mg/kg
25
87-68-3
Hexachlorobutadiene
25 U
mg/kg
25
77-47-4
Hexachlorocyclopentadiene (FICCP)
25 U
mg/kg
25
67-72-1
Ilexachloroethane
25 U
mg/kg
25 2.5
193-39-5
Indeno (1,2,3-cd) pyrene
2.5 U
mg/kg
78-59-1
Isophorone
25 U
mg/kg
25
91-20-3
Naphthalene
3.1
mg/kg
2.5
98-95-3
Nitrobenzene
25 U
mg/kg
25
621-64-7
n-Nitroso di-n-Propylarnine
25 U
mg/kg
25
Page 41 of 59
E1O4009SVOATCLPSFINAL
EPA 82700
EPA 82700
mg/lcg
25 U
EPA 82700
10/10/10 1:37
12:00 10/05/10 12:00
2.5 U
Di-n-butylphthalate
EPA 82700
EPA 82700
Dibenzofuran
84-74-2
EPA 82700
1:37
132-64-9
Dimethylphthalate
EPA 82700
10/10/10 1:37
10/05/10
10/05/10
131-11-3
EPA 82700 EPA 82700
12:00 10/05/10 12:00
10/05/tO 12:00
10/05/to
12:00 10/05/10 12:00 10/05/10 2:00 10/05/tO 12:00 10/05/10 12:00
10:05/10
1:37
10/10/10 1:37
EPA 82700
EPA 82700 EPA 8270D EPA 8270D EPA 82700 EPA827OD EPA 82700 EPA 82700
10/10/10 1:37
EPA
10/10/10 1:37
EPA 82700
10/10/10
EPA 82700
1:37 10/10/1 0 :37 tO/I 0t0 1:37
EPA
82700
82700
EPA 82700
10/10/10 1:37
EPA 82700
10/10/10 1:37
EPA 82700
12:00 10/05/10 12:00 10/05/tO 12:00 10/05/10 12:00 10/05/tO
10/10/10 :37 10/10/10
2:00
1:37
10/10/10 1:37 10/10/tO 1:37
EPA 82700
EPA 82700
EPA 82700 EPA 82700
11/1/10 16:40
0 S r
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700
/
I.
0
5t
DART. Id: 10-0629 Inc Reported by Janet Muse Hercules Project: 10-0629,
\ZY
-
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
SampIelD:HERCO9-B
E104009-11
Matrix: Waste
Station ID: HERCO9 Date Collected: 9/29/10 14:20 C4S Nmnhpr
Resulls Qnalrjlers
.4naiyte
122-39-4
n-Nitrosodiphenylamine/Diphenylaxnine
Units
25 U
mg/kg
MRL
Prepared
.lna(vzed
25
10105/10 12:00 10105/10 2:00 10/05/10 12:00 10/05/10 12:00
10/10/10 1:37 10/10/10 1:37 10/10/10 1:37 10/10:10 :37
10/05/10
10/10/10
2:00 10/05/10 12.00
1:37 10/10/10 1:37
87-86-S
Pentachlorophenol
25 U
mg/kg
25
85-01-8
Phcnanthrene
3.1 J, QL-2
mg/kg
2.5
108-95-2
Phenol
7.2 J, Q-2
mg/kg
25
129-00-0
Pyrene
3.5
mg/kg
2.5
110-86-1
Pyridine
25 U
mg/kg
25
100 NJ
mg/kg
Ifethad EPA 82700 EPA 8270D EPA 82700 EPA 8270D EPA 82700
EPA
8270D
Tentatively Identified Compounds: R4-8000682
(Dimethylethyl)methylphenol (TIC)
1005.10
2:00 10/05/10 12:00
10/10/10 1:37
10/10/10 1:37 10/10:10
EPA 8270D
EPA 8270D
R4-653 I
Camphene (TIC)
100 NJ
mg/kg
R4-6506
Decahydrotrimethylmethylenemethanoazu
300 NJ
mg/kg
biOS/b
12:00
1:37
EPA 82700
400 Xi
mg/kg
10/05/10 12:00
10/10/10 1:37
EPA 8270D
1000 NJ
mg/kg
10/05/10 12:00
10/10/10 1:37
EPA 82700
2000 NJ
mg/kg
10/05/10 12:00
10/10/10 1:37
EPA 8270D
600 NJ
mg/kg
10/05/10 12:00 10/05/10 12:00 10/05/10 12:00
0/10/10
EPA 82701)
Ienc (TIC)
R4-6603 R4-8000535
Dimethylisopropylphenanthrene (TIC) Diphenyl ether (TIC)
R4-8000899
Hexahydrotetramethylmethanonaphthalene (TIC)
R4-8000907
Menthene (TIC)
R4-6584
Methyl(methylethyl)benzene (TIC)
R4-8000897
Methyl(methylethyl)cyclohexane (TIC)
R4-8000906
Methyl(methylethyl)cyclohexene (TIC)
R4-6500
Petroleum Product:
R4-800090I
Trimethylbicycloheptane (TIC)
R4-6501
Unidentified Compounds
Page 42 of 59
E104009 SVOA TCLPS FINAL
700 NJ
mg/kg
1000 NJ
mg/kg
100 N.I
mg/kg
N 100 NJ
1000 J
mg/kg mg/kg
10/05/10
2:00 10/05/10 1200 10/05/10 12:00 10/05/10 12:00
1:37
10/10/10 1:37
10/10/10 1:37 10/10/10 1:37 10/10/10 137
10/10/10 1:37 10/10/10 1:37
EPA 8270D EPA 8270D EPA
8270D
EPA 82700 EPA 8270D EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc - Reported by Janet Muse
TCLP SemiVolatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO9-B Station ID: HERCO9
E104009-11
Matrix: Waste
Date Collected: 9/29/10 14:20 C.4S Number
.4nalyte
1319-77-3
(3-andior 4-)Methylphenol:
58-90-2
2,3,4,6-Tetrachlorophenol:
NA-S
0.10
95-95-4
2.4.5-Trichlorophenol:
NA-S
0.10
88-06-2
2,4,6-Trichlorophenol:
\A-5
0.10
121-14-2
2,4-Dinilrotolucne:
NA-5
0.10
95-48-7
2-Methylphenol:
118-74-1
Resulty Qualifiers
::.HexachIorobenzene (IICB):
NA-5
Units
1IRL
Prepared
0. 10
I%OIO
NA-S
0.10
NA-5
0.10
87-683
Hexach1orobutadiene:
NA-5
0.10
6772 1
exachloroethane
NA 5
0 10
98-95-3
Nitrobenzene:
NA-5
0.10
87-86-5
Pentachlorophcnol:
NA-5
0.10
110-86-1
Pyridine:
Page 43
of 59
NA-5
E104009 SVOA TCLPS FINAL
0.10
4nal:ed llethod l00
EPA 8270D
1t/190
EPA 8270D
I0JI0 14:04
1%oo
EPA 8270D
EPA 8270D
1005/10
EPA 8270D
1%010
EPA 8270D
10/05/10
10/09/10
10/05/10
10/09/10
I0’05/10
009/0
944 10/05/10
1404
105/l0 1010
EPA 8270D EPA 8270D EPA8 70D
EPA 8270D
0 j 1
EPA 8270D
1/409f0
EPA 8270D
11/1/10 16:40
0
0
UNITEI) STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCIO-B
E104009-12
Matrix: Waste
Station ID: HERC1O Date Collected: 9/29/10 14:15 CAS
Niunher
.4nalyte
1319-77-3
(3-and/or 4-)Methylphenol
92-52-4
1,1 -Biphenyl
Results Qualifiers
25 U
1600
MRL
Prepared
mg/kg
2S
mg/kg
25
10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/TO 2:00 10)05/10 1200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 1005/10 2:00 10/05/TO 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10)05/10 12:00 1005/10 12:00 10/05/10 12:00 10/05/10 12:00 10,05/10 12:00 10)05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10)05/10 12:00
Units
58-90-2
2,3,4,6-Tetrachlorophenol
25 U
mg/kg
95-95-4
2,4,5-Trichiorophenol
25 U
mg/kg
88-06-2
2.4,6-Trichiorophenol
25 U
mg/kg
120-83-2
2,4-Dichlorophenol
25 U
mg/kg
25
105-67-9
2,4-Dimethylphenol
25 U
mg/kg
2S 2S 25
51-28-5
2,4-Dinitrophenol
25 U
mg/kg
121-14-2
2,4-Dinitrotoluene
25 U
mg/kg
25
2S
606-20-2
2,6-Dinitrotoluene
25 U
mg/kg
25
91-58-7
2-Chloronaphthalene
25 U
mg/kg
-
95-57-8
2-Chiorophenol
25 U
mg/kg
2—
534-52-1
2-Methyl-4,6-dinitrophenol
25 U
mg/kg
25
91-57-6
2-Methylnaphthalene
4.6
mg/kg
-,
-,
-‘
95-48-7
2-Methylphenol
25 U
mg/kg
88-74-4
2-Nitroaniline
25 U
mg/kg
2S 2S
25
88-75-5
2-Nitrophenol
25 U
mg/kg
91-94-I
3,3’-Dichlorobenzidine
25 U
mg/kg
25
99-09-2
3-Nitroanihne
25 U
mg/kg
2S
101-55-3
4-Bromophenyl phenyl ether
25 U
mg/kg
59-50-7
4-Chloro-3-rnethylphenol
25 U
mg/kg
—-‘
2S
106-47-8
4-Chioroaniline
25 U
mg/kg
7005-72-3
4-Chiorophenyl phenyl ether
25 U
mg/kg
2S 25
100-01-6
4-Nitroaniline
25 U
mg/kg
100-02-7
4-Nitrophenol
25 U
mg/kg
2S
83-32-9
Acenaphthene
2.5 U
mg/kg
•
208-96-8
Acenaphthylene
2.5 U
mg/kg
25
98-86-2
Acetuphenone
25 U
mg/kg
2.5 U
mg/kg
25 U
mg/kg
120-12-7
Anthracene
1912-24-9
Atrazine
Page 44 of59
E104009 SVOA TCLPS FINAL
2—:2 0
•-‘
2S
.lnatyzed Method 10/10/10 2:12 10/10)10 2:12
EPA 8270D
1010/10
EPA 8270D
2:12 10/10/10 2:12 1010/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10 10:10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2 12 10/10/10 2:12 10/10/10 2:12 10/10:10 2:12 10/10/10 2:12 10/10/10 2:12 10/10)10 2:12 10/10)10 2:12 10/10/TO 2:12 10/10/10 2:12 10/10/10 2:12
EPA 8270[)
EPA 82700 EPAO27OD EPA
82700
EPA 82700 EPA 82700 EPA R270D
EPA 82700 EPA 82701) EPA 82700 EPA 8270D EPA 82700 EPA 8270D
EPA 82700 EPA 8270D EPA 8270D EPA 8270D EPA 82700 EPA 827012 EPA 8270D EPA 82700 EPA 8270D
EPA 8270D EPA 82700 EPA 82700 EPA 827012
EPA 8270D EPA 827012
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 10-0629, Hercules nc Reported by Janet Muse -
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERC1O-B
E104009-12
Matrix: Waste
Station ID: HERCIO Date Collected: 9/29/10 14:15 C.4S
Vu,nber
Results Qualifiers
4nulyte
Units
MRL
25 U
mg/kg
25
Benzo(a)anthracene
2.5 U
mg/kg
2.5
50-32-8
Benzo(a)pyrene
2.5 U
mg/kg
2.5
205-99-2
Benzo(b)fluoranthene
2.5 U
mg/kg
2.5
191-24-2
Benzo(gh.i)perylene
2.5 U
mg/kg
2.5
207-08-9
Benzo(k)fluoranthene
2.5 U
mg/kg
2.5
85-68-7
Benzyl butyl phthalale
25 U
mg/kg
25
100-52-7
Benzaldehyde
56-55-3
111-91-1
Bis(2-chloroethoxy)methane
25 U
mg/kg
25
111-44-4
bis(2-Chloroethyl) Ether
25 1
mg/kg
25
39638-32-9
Bis(2-chloroisopropyl) ether
25 U
mg/kg
25
117-81-7
Bis(2-ethylhexyl) phthalate
25 U
mg/kg
25
105-60-2
Caprolactam
25 U
mg/kg
25
2.5
86-74-8
Carbazole
2.5 U
mg/kg
218-01-9
Chrysene
2.5 U
mg/kg
2.5
53-70-3
Dibenz(a,h)anthracene
2.5 U
mg/kg
2.5
132-64-9
Dibenzofuran
2.5 U
mg/kg
2.5
84-66-2
Diethyl phthalate
25 U
mg/kg
25
131-1 1-3
Dimethyl phthalate
25 U
mg/kg
25
84-74-2
Di-n-butylphthalate
25 U
mg/kg
25 25
117-84-0
Di-n-octylphthalate
25 U
mg/kg
206-44-0
Fluoranthene
2.5 U
mg/kg
2.5
86-73-7
Fluorene
2.5 U
mg/kg
2.5
118-74-I
Hexachlorobenzene (HCB)
25 U
mg/kg
25
87-68-3
Hexachlorobutadiene
25 U
mg/kg
25
77-47-4
Hexachlorocyclopentadiene (HCCP)
25 U
mg/kg
25
67-72-1
Hexachloroethane
25 U
mg/kg
25
193-39-5
Indeno (1,2.3-cd) pyrene
2.5 U
mg/kg
2.5
78-59-1
Isophorone
25 U
mg/kg
25
91-20-3
Naphthalene
6.7
mg/kg
2.5
98-95-3
Nitrobenzene
25 U
mg/kg
25
62 1-64-7
n-Nitroso di-rb-Propylamine
25 U
mg/kg
25
Page 45 of 59
E104009 SVOA TCLPS FINAL
Prepared 10105/10 2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 b/OS/b 12:00 10/05/10 12:00 10/05/10 12:00 10/0510 12:00 10/05/10 12:00 10/00/10 12:00 b/oS/b 12:00 l005/I0 12:00 10/05/10 12:00 10/05/10 12:00 b/OS/b 12:00 10/05/10 12:00 10/05/10 12:00 10:05/10 12:00 bO/05/10 12:00
b/OS/b 12:00 10/05/10 12:00 10/05/10 12:00
10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 2:00 bO/05/bo 12:00 l0/05/I0 12:00 10/05/10 12:00 10/05/10
2:00
.4naly;ed Method 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/lO 2:12 10/10/10 2:12 10/b/b 2:12
10/10/10 2:12 I0/10/b0 2:12 10/10/10 2:12 l010l0 2:12 10/10/10 2:12 010:10 2:12 10/10/10 2:12 10/1010 2:12 10/10/10 2:12 b/b/b 2:12 10/10/10 2:12 l0:IOilO 2:12 10/10/10 2:12 10/10:10 2:12 10/b/b 2:12 101010 2:12 b/b/b 2:12 IO/b0/l0 2:12 10/10/10 2:12 lO/lO/lO 2:l2 10/10/10 2:12 b/b/b 2:12 b/b/b 2:12 10/10/10 2:12
EPA 82700
EPA 82700 EPA 82700 EPA
8270D
EPA 8270D
EPA 8270D EPA 82700 EPA 8270D EPA 82700
EPA 82700 EPA 82700 EPA 8270D EPA 82700
EPA 82700 EPA 82700
EPA 82700 EPA 82700 EPA
8270D
EPA 82700 EPA 8270D
EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 8270D
EPA 8270D EPA 82700 EPA 82700 EPA
82700
11/1/10 16:40
C
C
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project 10 0629 Hercules Inc Reported by Janet Muse -
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ED:
Sample ID: HERCIO-B
E104009-12
Matrix: Waste
Station ID: HERCIO Date Collected: 9/29/10 14:15 C4S Number
122-39-4
Results Qualifiers
.4nal’te
n-Nitrosodiphenylamine/Diphenylamine
25 U
Units mg/kg
IIRL
Prepared
25
10/05/10 12:00
0/05/10
87-86-5
Pentachlorophenol
25 U
mg/kg
25
85-01-8
Phenanthrene
2.5 U
mg/kg
2.5
108-95-2
Phenol
129-00-0
Pyrene
110-86-1
Pyridine
mg/kg
25
3.4
mg/kg
2.5
25 L
mg/kg
25
200 NJ
mg/kg
90 NJ
mg/kg
18 .1, Q-2
.4nulyzed herhod
12:00 10/05/10 2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00
10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 0/10/10 2:12 1010/l0 2:12
10/05/10 2:00 10/05/10 12:00 10/05/10 2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00
10/10/10 2:12 10/10/10 2:12 010/10 2:12 10/I W10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12
EPA 82700
EPA 82700 EPA 8270D EPA 8270D EPA 82700 EPA 82700
Tentatively Identified Compounds: R4-6552
(Menthenol)terpineol (TIC)
R4-6583
(Methylpropyl)benzene (TIC)
R4-653l
Camphene (TIC)
R4-8000535
Diphenyl ether (TIC)
R4-6584
Methyl(methylethyl)benzene (TIC)
R4-8000897
Methyl(methylethyl)cyclohexane (TIC)
R4-6500
Petroleum Product:
1000 NJ
mg/kg
200 NJ
mg/kg
7000 NJ
mg/kg
4000 NJ
mg/kg
N
2000 NJ
mg/kg
R4-6520
Pinene (TIC)
R4-8000466
Propyiphenol (TIC)
200 NJ
mg/kg
R4-8000901
Trimethylbicycloheptane (TIC)
200 NJ
mg/kg
R4-6501
Unidentified Compounds
Page 46 of 59
E104009 SVOA TCLPS FINAL
2000 J
mg/kg
EPA 8270D
EPA 82700 EPA 82701) EPA
82700
EPA 8270D EPA 8270D
EPA 8270D EPA 82700 EPA 82700 EPA
82700
EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Janet Muse -
TCLP SemiVolatfies Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERC1O-B Station ID: HERC1O
E104009-12
Matrix: Waste
Date Collected: 9/29/10 14:15 CAS Number
.4nalvte
13 19-77-3
(3-andior4-)Methylphenol:
Resulls Qualifiers
NA-5
Uuits
iIRL
0.10
58-90-2
2,3,4,6-Tetrachiorophenol:
NA-5
0.10
95-95-4
2.4.5-Trichlorophenol:
NA-5
0.10
88-06-2
2,4,6-Trichlorophenol:
NA-5
0.10
121-14-2
2,4-DinitrotoIucn:
95-48-7
2-Methylphenol:
NA-S
0.10
118-74-1
Flexachlorobenzene (FICB):
NA-5
0.10
87-68-3
Hexachlorobutadiene:
NA-S
0.10
67-72-1
Hexachloroethane:
NA-5
0.10
98-95-3
Nitrobenzene:
NA-5
0.10
87-86-5
Pentachlorophenol:
NA-5
0.10
110-86-1
Pyridine:
Page 47 of 59
NA-5
NA-S
E104009 SVOA TCLPS FINAL
0.10
0.10
Prepared
10/05/10
Analyzed Ole/hod
10/05/10
10/09/10 4:04 10/09/10 14:04 10/09/10 404 10/09/10 14:04 10/09/10 14-04 10/09/10 14:04 10/09/10 1404 10/09/10 14:04 10/09/10 14:04 10/09/10 14:04 10/09/10 404 10/09/10
9-44
14:04
9:44
10/05/10 9:44 10/05/10 9-44
10/05/10 10/05/10 10/05/10 9:44 10/05/10 944 10/05/10 9:44 1005/10 944 10/05110 10:05/10 944
EPA 8270D EPA 8270D EPA 82700 EPA
8270D
EPA 82700
EPA 8270D EPA 82701)
EPA 8270D EPA 82700 EPA 8270D EPA 8270D EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 [).A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERC1I-B
E104009-13
Matrix: Waste
Station ID: HERC1I Date Collected: 9/29/10 14:30 C4S Nuin her
.dna!yte
13 19-77-3
(3-andlor4-)Methylphenol
Resnils Qualijiers
MRL
Prepared
.4nuivzed
mg/kg
25
mg/kg
25
10/10/10 2:48 10/10/10 2:48
mg/kg
25
10/10/10
Units
95-95-4
2,4,5-Trichlorophenol
25 U
mg/kg
25
88-06-2
2,4,6-Trichlorophenol
25 U
mg/kg
25
120-83-2
2,4-Dichloropheno!
25 U
mg/kg
25 25 25
0105/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/tO 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:1)0 10/05/10 12:00
92-52-4
1,1-Biphenyl
58-90-2
2,3,4,6-letrachlorophenol
13 J. Q-2 480 25 U
105-67-9
2,4-Dimethylphenol
25 U
mg/kg
51-28-5
2,4-Dinitrophenol
25 U
mg/kg
121-14-2
2,4-Dinitrotoluene
25 U
mg/kg
25
606-20-2
2,6-Dinitrotoluene
25 U
mg/kg
25
91-58-7
2-Chloronaphthalene
25 U
mg/kg
25
95-57-8
2-Chlorophenol
25 U
mg/kg
25
534-52-1
2-Methyl-4.6-dinitrophenol
25 U
mg/kg
25
2.5 25
10/05/10 12:00 10/05/10 12:00
10/05/10 12:00 10/05/10 1200 10/05/10 12:08 10/05/tO
10/10/10
EPA 82700 EPA 8270D
2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/tO 2:48
mg/kg
25
25 U
mg/kg
25
12:00
9 1-94-1
3,3’-Dichlorobenzidine
25 U
mg/kg
25
10/05/10
10/10/10
25
10,05/10 12:00
2:48
10/05/10 12:00 10/05/10
10/10/10 2:48 1010/10 2:48 10,10/10 2:48 10/10/10 2:48 Ia/to/to 2:48 10/10/10 2:48 to/jo/la 2:48 10/10/10
3.8 J, Q-2
mg/kg
99-09-2
3-Nitroaniline
25 U
10 1-55-3
4-Bromophenyl phenyl ether
59-50-7
4-Chloro-3-methylphenol
106-47-8
4-Chloroaniline
7005-72-3
4-Chlorophenyl phenyl ether
mg/kg
25 U
mg/kg
25
25 U
mg/kg
25
25 U
mg/kg
25
25 U
mg’kg
25
25 U
mg/kg
25
4-Nitrophenol
25 U
mg/kg
25
Acenaphthene
2.5 U
mg/kg
2.5
208-96-S
Acenaphthylene
2.5 U
mg/kg
2.5
98-86-2
Acetophenone
25 U
mg/kg
25
120-12-7
Anthracene
2.5 U
mg/kg
2.5
25 U
mg/kg
100-01-6
4-Nitroaniline
100-02-7
83-32-9
19 12-24-9
Page 48 of59
Atrazine
E104009 SVOA TCLPS FINAL
25
12:00
to/os/to 12:00 10/05/10 12:00
12:00
10/05/10 12:00 10/05/10 12:00
10/05/10 12.00 10/05/10 12:00 10/05/10 1200 10/05/10
EPA 8270D EPA 82700
EPA 8270D
25 U
2-Methylphenol
EPA 82701)
2:48 10/10)10 2:48
2-Nitrophenol
95-48-7
EPA 8270D
EPA 82700
2-Nitroaniline
2.6
EPA 82700
2:48 10/10/10 2:48
88-75-5
2-Methylnaphthalene
EPA 82700
2:48
88-74-4
91-57-6
EPA 8270D
ooo
248 10/10/10 2:48 l0/lOilO 2:48 10/10/to 2:48 10/10/10 2:48
mg/kg
lie/hod
2.48 10/10:10
12:00
2:48
10/05)10 12:00 0/05/10
10/10/10 2:48 10/10/10
EPA 8270D
EPA 8270D EPA 8270D EPA 8270D EPA 8270D EPA 8270D
EPA 8270D EPA
8270D
EPA 8270D EPA 8270D EPA 8270D t’P\ 82700
EPA827OD EPA 82700 EPA 82700 EPA 82700
EPA 82700
t2:00
2:48
EPA 8270D
10/05/10 12:08
10/10/10 2:48
EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Janet Muse
L 4
cDs:.
-
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERC11-B Station ID: ITERC1I
E104009-13
Matrix: Waste
Date Collected: 9/29/10 14:30 C.4S Number
.tnalvre
100-52-7
Benzaldehyde
Results Qualifiers 25 U
Units mg/kg
MRL 25
56-55-3
Benzo(a)anthracene
2.5 U
mg/kg
2.5
50-32-8
Benzo(a)pyrene
2.5 U
mg/kg
2.5
205-99-2
Benzo(b)fluoranthene
2.5 U
mg/kg
2.5
191-24-2
Benzo(g,h.i)perylene
2.5 U
mg/kg
2.5
207-08-9
Benzo(k)fluoranthene
2.5 U
mg/kg
2.5
85-68-7
Benzyl butyl phthalate
25 U
mg/kg
25
Bis(2-chloroethoxy)methane
25 U
mg/kg
25
bis(2-Chloroethyl) Ether
25 U
mg/kg
25
111-91-I 111-44-4
-
39638-32-9
Bis(2-chloroisopropyl)
25 U
mg/kg
25
117-81-7
Bis(2-ethylhexyl) phthalate
25 U
mg/kg
25
ether
105-60-2
Caprolactam
25 U
mg/kg
25
86-74-8
Carbazole
2.5 U
mg/kg
2.5
218-01-9
Chiysene
2.5 U
mg/kg
2.5
53-70-3
Dibenz(a,h)anthracene
2.5 U
mg/kg
2.5
132-64-9
Dibenzofuran
2.5 U
mg/kg
2.5
84-66-2
Diethyl phthalate
25 U
mg/kg
25
131-11-3
Dimethylphthalate
25 U
mg/kg
25
84-74-2
Di-n-butylphthalate
25 U
mg/kg
25
117-84-0
Di-n-octylphthalate
25 U
mg/kg
25
206-44-0
Fluoranthene
10
mg/kg
2.5
86-73-7
Fluorene
2.5 U
mg/kg
2.5
118-74-I
Hexachlorobenzene (I-ICB)
25 U
mg/kg
25
87-68-3
Hexachlorobutadiene
25 U
mg/lcg
25
77-47-4
flexachlorocyclopentadiene
25 U
mg/kg
25
67-72-1
Hexachloroethane
25 U
mg/kg
25
193-39-5
Indeno
2.5 U
mg/kg
2.5
78-59-1
Isophorone
25 U
mg/kg
25
91-20-3
Xaphthalene
33
mg/kg
2.5
98-95-3
Nitrobenzene
25 U
mg/kg
25
621-64-7
n-Nitroso di-n-Propylamine
25 U
mg/kg
25
Page 49 of 59
(HCCP)
(1.2.3-cd) pyrene
E104009 SVOA TCLPS FINAL
Prepared
Analyzed ltethod 10.1010
12:00
2-48
10/05/10
10/10/10
12:00 (00510 (200 10/05/10 12:00 (2:00 10/05/10 12:00 0/05/10 12.00 10/05/10 12:00 10/05/10 12:00
10/05/10 1200 10/05/10 12:00 10/05/10 12:00 I0/05’lo (200
10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00
10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 2.00
2:48
10.10.10 2:48
10/10/10 2:48 10/1010 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 248 10/10/10 2.415
10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:40 10/10/10 2:48 10/10/10 2:48 0/10/10 2:40 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48
EPA827OD EPA 8270D EPA 8270D
EPA 82700 EPA82700
EPA 82700 EPA 82700
EPA 82700 EPA 82700
EPA 82700 EPA 0270!) EPA
8270D
EPA 82700 EPA
8270D
EPA 82700
EPA 8270D EPA 8270D EPA
82700
EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 8270D EPA 8270D EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERC11-B
E104009-13
Matrix: Waste
Station ID: IIERC1I Date Collected: 9/29/10 14:30 C.4S ;Viginber
Results Qualifiers
4nalyie
Units
MRL
Prepared
25
10/05/10 12:00 10/05/10 12:00 10/05/10 1200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00
10/10/10 2:40 10/10110 2:48 10/10/10 2:48 1010/10 2:48 10/10/10 2:48 10/10/10 2:48
111/05/10 2.00 10/05/10 2:00 10/05.10 12:00 10/05/10 12:00
10/10/10 2:40 1W10/10 2:48 10/10110 2:48 10/10/10 248
10/05/10 12:00 10/05/10 12:00 biOS/b 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 200 10/05/10 12:00
10/10/10 2:48 10/10/10 2:40 0/10/10 2:48 111/10/10 2:48 10/10/10 2:48 10/10/10 248 10/10/10 2:40
25 U
mg/kg
Pentachlorophenol
25 U
mg/kg
25
Phenanthrene
5.0 J, QL-2
mg/kg
2.5
Phenol
6.2 J, Q-2
mg/kg
25
Pyrene
4.8
mg/kg
2.5
Pyridine
25 U
mg/kg
25
122-39-4
n-Nilrosodiphenylamine/Diphenylamine
87-86-5 85-01-8 108-95-2 129-00-0 110-86-1
.lnalyzed Method EPA 82700 EPA 82700 EPA 82700 EPA
8270D
EPA 82700 EPA
82700
Tentatively Identified Compounds: R4-8000682
(Dmethylethyl)methy1phcno1 (TIC)
200 NJ
mg/kg
R4-6531
Camphene (TIC)
100 NJ
mg/kg
R4-6603
Dimethylisopropylphenanthrene (TIC)
R4-8000899
Hexahydrotetramethylmethanonaphthalene (TIC)
R4-8000907
Menthene (TIC)
R4-6584
Methyl(methylethyl)benzene (TIC)
R4-8000897
MethyI(methylethyl)cyclohexane (TIC)
R4-6500
Petroleum Product:
R4-6520
Pinenc (TIC)
R4-800090l
Trimethylbicycloheptane (TIC)
R4-6501
Unidentified Compounds
Page 50 of59
E104009 SVOA TCLPS FINAL
200 NJ
mg/kg
1000 NJ
mg/kg
100 NJ
mg/kg
700 NJ
mg/kg
2000 NJ
mg kg
100 NJ
mg/kg
200 NJ
mg/kg
2000 J
mg/kg
EPA 82700 EPA
82700
EPA 8270D EPA 8270D
EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
TCLP SemiVolatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERC11-B
E104009-13
Matrix: Waste
Station 1D: HERC1I Date Collected: 9/29/10 14:30 C1S
Results Qualifiers
Nu,szh’r
.4na!yte
1319-77-3
(3-andlor4-)Methylphenol:
NA-5
Units
MRL
0.10
58-90-2
2,3,4,6-Tetrachlorophenol:
NA-S
0.10
95-95-4
2,4,5-Trichlorophenol:
NA-5
0.10
88-06-2
2,4,6-Trichlorophenol:
\A.5
0.10
121-14-2
2,4-Dinitrotoluene:
NA-S
0.10
95-48-7
2-Methylphenol:
NA-S
0.10
118-74-I
l4exachlorobenzene (HCB):
NA-5
0.10
87-683
Hexachlorobutadiene:
NA-S
0.10
67 721
1-lexachloroethane
98-95-3
Nitrobenzene:
NA-5
0.10
87-86-5
Pentachlorophenol:
NA-S
0.10
110-86-1
Page 5! of59
Pyridine:
NA
NA-5
E104009 SVOA TCLPS FINAL
0 10
0.10
Prepared
.laqlw;ed Method
l0I0
l/0
10/10
lIO
I0I0
l/11/4i0
1O11O
EPA 8270D
EPA 8270D EPA 8270D
EPA 8270D
I0M5l0
1009,10
EPA827OD
1%01o
Il14090I20
EPA82700
°oo
I009.i0
EPA 0270D
10/05/10
EPA 8270D
10/05/10
100910
10/05/10
10/09/10
ooo ‘%°°
EPA W’70D EPA827OD
lt090
EPA 8270D
1/J0
EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Ed: 10-0629 Project: 1 0-0629, Hercules Inc
-
Reported by Janet Muse
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCI2-B Station ID: HERCI2
E104009-14
Matrix: Waste
Date Collected: 9/29/10 14:50 Number
.4nalvre
MRL
Prepared
1319-77-3
(3-and/or 4-)Methylphenol
3.1 J,Q-2
mg/kg
26
mg/kg
26
26 U
mg/kg
26
2,4,5-Trichlorophenol
2615
mg/kg
26
88-06-2
2,4,6:l’richlorophenol
26 U
mg/kg
26
220-83-2
2,4-Dichiorophenol
26 U
mg/kg
26
105-67-9
2,4-Dimethylphenol
26 U
mg/kg
26
51-28-5
2,4-Dinitrophenol
26 U
mg/kg
.,
121-14-2
2,4-Dinitrotoluene
26 U
mg/kg
26
606-20-2
2,6-Dinitrotoluene
26 15
mg/kg
26
91-58-7
2-Chloronaphthalenc
26 U
mg/kg
26
95-57-8
2-Chlorophenol
26 15
mg/kg
26
534-52-1
2-Methyl-4,6-dinitrophenol
26 U
mg/kg
26
91-57-6
2-Methylnaphthalene
35
mg/kg
2 6
95-48-7
2-Methyiphenol
26 U
mg/kg
26
88-74-4
2-Nitroaniline
26 U
mg/kg
26
88-75-5
2-Nitrophenol
26 U
mg/kg
26
91-94-1
3,3-Dichlorobenzidine
26 U
mg/kg
26 26
26
10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 (2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12-00 10/05/10 12:00 10/05/10 12:00 10/05/10 (2:00 10/05/10 (2:00 10/(15/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 (2:00 10/05/10 12:00 10/05/10 (2:00 10/05/10 12:00 10/05/10 (2:00 10/1(5/10 12:1(11 10/05/10 12:00 10/05/1(1 12:00
92-52-4
1,1 -Biphenyl
500
58-90-2
2,3,4,6-Tetrachlorophenol
95-95-4
Results Quali/lers
Units
99-09-2
3-Nitroaniline
26 U
mg/kg
101-55-3
4-Bromophenyl phenyl ether
26 U
mg/kg
59-50-7
4-Chloro-3-methylphenol
26 U
mg/kg
26
106-47-8
4-Chioroaniline
26 U
mg/kg
26
7005-72-3
4-Chlorophenyl phenyl ether
26 U
mg/kg
26
100-01-6
4-Nitroaniline
26 1]
mg/kg
26
100-02-7
4-Nitrophenol
26 U
mg/kg
26
83-32-9
Acenaphihene
2.6 U
mg/kg
26
208-96-8
Acenaphthylene
2.6 U
mg/kg
2•6
98-86-2
Acetophenone
26 U
mg/kg
26
120-12-7
Anthracene
2.6 U
mg/kg
2•6
1912-24-9
Atrazine
26 U
mg/kg
.,
Page 52 of59
E104009 SVOA TCLPS FINAL
.•tnal;ed ,lfeghod 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 (0/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/I 0/10 3:24 (0/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 0/1010 3:24 10/10/10 324 3:24 10/1(1/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 (0/(0/10 3:24
EPA 8270D EPA 8270D EPA 82700 EPA
82700
EPA 82700 EPA
8270D
EPA 82700 EPA
82700
EPA 8270D
EPA 8270D EPA 82700 EPA
8270D
EPA 8270D EPA
82700
EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA 8270D EPA 82700 EPA 82700 EPA 8270D EPA 8270D EPA 8270D EPA 82700 EPA 8270D EPA 8270D
11/1/10 16:40
0
0
UMTED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc
-
Reported by Janet Muse
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERC12-B
Matrix: Waste
Station ID: HERCI2 Date Collected: CAS Number
9/29/10 14:50 Results Qualijiers
inalyte
Benzaldehyde
100-52-7
E104009-14
26 U
MRL
Prepared
mg/kg
26
mg/kg
2
‘
10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00
Units
Benzo(a)anthracene
2.6 U
50-32-8
Benzo(a)pyrene
2.6 U
mg/kg
26
205-99-2
Benzo(b)fluoranthene
2.6 U
mg/kg
‘,
191-24-2
Benzo(g.h,i)perylene
2.6 U
mg/kg
.,
2
56-55-3
e .0 .0
207-08-9
Benzo(k)fluoranthene
2.6 U
mg/kg
85-68-7
Benzyl butyl phthalate
26 U
mg/kg
26
Bis(2-chloroethoxy)methane
26 U
mg/kg
2’
26 U
mg/kg
.,
26 U
mg/kg
.,i O
111-91-1 111-44-4
.-bis(2-C’hIoroethyI) Ether
1 .0
39638-32-9
Bis(2-chloroisopropyl) ether
117-81-7
Bis(2-ethylhexyl) phthalate
26 U
mg
105-60-2
Caprolactam
26 U
mg/kg
-,
2
1 .0 1
-u
86-74-8
Carbazole
2.6 U
mg/kg
218-01-9
Chrysene
2.6 U
mg/kg
2
53-70-3
Dibenz(a,h)anthracene
2.6 U
mg/kg
26
132-64-9
Dibenzofuran
2.6 U
mg/kg
1 1
84-66-2
Diethyl phthalate
26 U
mg/kg
26
13 1-11-3
Dimethyl phthalate
26 U
mg/kg
84-74-2
Di-n-butylphthalate
26 U
mg/kg
-,
117-84-0
Di-n-octylphthalate
26 U
mg/kg
71
mg/kg
i
1
206-44-0
Fluoranthene
9.5
86-73-7
Fluorene
2.6 U
mg/kg
118-74-I
Hexachlorobenzene (HUB)
26 U
mg/kg
2
.,
87-68-3
Hexachiorobutadjene
26 U
mg/kg
‘)l
77-47-4
Hexachlorocyclopentadiene (HCCP)
26 U
mg/kg
26
67-72-1
Hexachioroethane
26 U
mg/kg
193-39-5
Indeno (1,2,3-cd) pyrene
2.6 U
mg/kg
26
78-59-1
Isophorone
26 U
mg/kg
‘-‘
91-20-3
Naphthalene
3.9
mg/kg
26
98-95-3
Nitrobenzene
26 U
mg/kg
11
621-64-7
n-Nitroso di-n-Propylamine
26 U
mg/kg
26
Page 53 of 59
E104009 SVOA TCLPS FINAL
.4nazed Method 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10.1010 324 10/10/10 3:24 10:10:10 3:24
10/10/10 3:24 10/10/10 3:24 10/10/10 324 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 324 10 10:10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24
EPA 8270D EPA 82700 EPA 82700
EPA 8270D EPA 82700 EPA
8270D
EPA 82700 EPA
82700
EPA 82700
EPA 82700 EPA 82700 EPA
82700
EPA 82700 EPA
8270D
EPA 82700 EPA
82700
EPA 82700 EPA
82700
EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 8270D EPA
82700
EPA 8270D
EPA 82700 EPA 82700 EPA
82700
EPA 8270D EPA 82700 EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTiON AGENCY Region 4 Science and Ecosystem Support Division 98() College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc
-
Reported by Janet Muse
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERC12-B
E104009-14
Matrix: Waste
Station ID: HERCI2 Date Collected: 9/29/10 14:50 C4S Number 122-39-4
Results Qualifiers
4nalyte n-Nitrosodiphenylamine/Diphenylamine
26 U
Units
mg/kg
MRL
Prepared
Analyzed
26
10/05/10
10/10/10
10/05/10 12:00 10/05/10 2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00
87-86-5
Pentachlorophenol
26 U
mg/kg
26
85-01-8
Phenanthrene
2.6 U
mg/kg
2.6
108-95-2
Phenol
mg/kg
26 2.6
26
15 J, Q-2
12:00
129-00-0
Pyrene
2.6 U
mg/kg
110-86-1
Pyridine
26 U
mg/kg
200 NJ
mg/kg
1005/10
mg/kg
10/05/10 12:00 10/05/10
3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 1010:10 3:24 10/10/10 3:24
t!ethod EPA 82700
EPA
82700
EPA 82700 EPA 82700
EPA 82700 EPA 82700
Tentatively Identified Compounds: R4-653 I
Camphene (TIC)
R4-6603
Dimethylisopropylphenanthrene (TIC)
R4-8000535
Diphenyl ether (TIC)
R4-8000899
Hexahydrotetramethylmelhanonaphlhalene (TIC)
R4-6584
Methyl(methylethyl)benzene (TIC)
300 \J 2000 NJ
mg/kg
500 >J
mg/kg
10/05/10 200
3000 NJ
mg/kg
10/05/10 12:00 10/05/10
R4-8000897
Methyl(methylethyl)cyclohexane (TIC)
2000 NJ
mg/kg
R4-8000906
Methyl(methylethyl)cyclohexene (TIC)
80 NJ
mg/kg
R4-6500
Petroleum Product:
R4-8000466
Propylphenol (TIC)
R4-8000901
Trimethylbicycloheptane (TIC)
R4-650I
Unidentified Compounds
Page 54 of59
E104009 SVOA TCLPS FINAL
2:00
300 NJ
mg/kg
200 NJ
mg/kg
1000 J
mg/kg
2:00
2:0)) 10/05/10 12:00 (1/05/10 12:0)) (0/05/10 12:00 10/05/10 12:00 10/05/10 (2:00
3:24 10/10/10 3:24 10:1010 3:24 10/10/10 3:24
10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24
EPA 82700 EPA 82700 1PA 8270D EPA 8270D
EPA 8270D EPA
82700
EPA 8270D EPA 82700
EPA 8270D EPA 8270D
EPA 8270D
11/1/10 16:40
0 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
TCLP SemiVolatiles Project: 10-0629, Hercules Inc E104009-14
Lab ID:
Sample ID: HERC12-B
Matrix: Waste
Station ID: HERC12 Date Collected: 9/29/10 14:50 C IS Vugzb’r
Results Qualifiers
4na!yie
(3-andlor4-)Methylphenol:
13 19-77-3
Units
MRL
0.10
NA-5
2,3,4,6-Tetrachiorophenol:
NA-5
95-95-4
2,4,5-Trichlorophenol:
NA-5
88-06-2
2,4,6-Trichlorophenol:
NA-5
0.10
121-14-2
2,4-Dinitrotoluene:
NA-5
0.10
58-90-2
-
0.10
2-Methylphenol:
\A5
0.10
118-74-1
Hexachlorobenzene (IICB):
NA-5
0.10
67 72 I
—
r
Hexachiorobutadiene:
Nexachloroethane
NA-5
0.10
NA 5
0 10
98-95-3
Nitrobenzene:
NA-5
0.10
87-86-5
Pentachlorophenol:
NA-5
0.10
110-86-1
Page 55 of 59
Pyridine:
NA-5
E104009 SVOA TCLPS FINAL
-lnalyzed
I%0I0
I1/409/0
10110
1/,09/0
1010
11/09/0
I0I0
919/0
0.10
Otethod
EPA 8270D EPA 8270D
EPA 8270D
0.10
95-48-7
87-68-3
Prepared
10/90 10/05/10
EPA 8270D
EPA 8270D 10/09/10
10/05/10
EPA 82701)
EPA 8270D 10/09/10
10/05/10
EPA 8270D
10/09/10
EPA 8270D EPA827OD
I00I0
9/400
EPA 8270D
1%0I0
1f/0
EPA 8270D
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Janet Muse
li PR -
-
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERC13-B
E104009-15
Matrix: Waste
Station ID: HERC13 Date Collected: 9/29/10 15:10 C4S Niunber
.4nalvte
13 19-77-3
(3-and/or 4-)Methylphenol
Results QualifIers
18 J. Q-2
Units
MRL
Prepared
mg/kg
24
mg/kg
24 24
10/05/10 1200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 0/05/10 2:00 10/05/10 12:00 10/05)10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10)05/10 12:00 10/05/10 12:00 0/05)10 12:00 10/05/10 12:00 10/05/1)) 12:00 10/05/10 12:00 10/05/10 12:00
92-52-4
1,1-Biphenyl
58-90-2
2,3,4,6-Tetrachlorophenol
24 U
mg/kg
95-95-4
2,4,5-Trichlorophenol
24 U
mg/kg
24
88-06-2
2.4,6-Trichlorophenol
24 U
mg/kg
24
120-83-2
2,4-Dichlorophenol
24 IS
mg/kg
24
105-67-9
2,4-Ditnethylphenol
24 U
mg/kg
24
5 1-28-5
2,4-Dinitrophenol
24 U
mg/kg
24
121-14-2
2,4-Dinitrotoluene
24 U
mg/kg
24
1500
606-20-2
2,6-Dinitrotoluene
24 15
mg/kg
24
9 1-58-7
2-Chloronaphthalene
24 U
mg/kg
24
95-57-8
2-C’hlorophenol
24 UJ
mg/kg
24
534-52-1
2-Methyl-4,6-dinitrophenol
24 U
mg/kg
24
9 1-57-6
2-Methylnaphthalene
4.1
mg/kg
2.4
95-48-7
2-Methylphenol
4.0 J, Q-2
mg/kg
24
88-74-4
2-Nitroaniline
24 U
mg/kg
24
88-75-5
2-Nitrophenol
24 U
mg/kg
24
91-94-1
3,3’-Dichlorobenzidine
24 U
mg/kg
24
99-09-2
3-Nitroaniline
24
U
mg/kg
24
101-55-3
4-Bromophenyl phenyl ether
24 U
mg/kg
24
59-50-7
4-Chloro-3-methylphenol
24 U
mg/kg
24
106-47-8
4-Chloroaniline
24 U
mg/kg
24
7005-72-3
4-Chlorophenyl phenyl ether
24 U
mg/kg
24
100-01-6
4-Nitroaniline
24 U
mg/kg
24
100-02-7
4-Nitrophenol
24 U
mg/kg
24
83-32-9
Acenaphthene
2.4 U
mg/kg
2.4
208-96-8
Acenaphthylene
2.4 U
mg/kg
2.4
98-86-2
Acetophenone
120-12-7
Anthracene
1912-24-9
Atrazine
Page 56 of 59
E104009 SVOA TCLPS FINAL
24 U
mg/kg
24
2.4 U
mg/kg
2.4
24 U
mg/kg
24
.•lnav;ed lfethod 10/10/10 4:00 10/10/10 4:1)0 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10)10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10)10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 1010/10 4:00 10/10/10 4:00 10)10/10 4:00 10/10/10 4:00 10)10/10 4:00 10/10/10 4:00 10/10/10 4:00
EPA 8270D EPA 82700 EPA 8270D EPA 8270D EPA 82700 EPA
82700
EPA 8270D EPA 82700 EPA 8270D EPA 8270D EPA 8270D EPA 8270D EPA 82700 EPA
82700
EPA 82700 EPA 8270D EPA 8270D EPA 8270D
EPA 82700 EPA
82700
EPA 8270D EPA 8270D EPA 82700 EPA 82701) EPA 8270D EPA 82700 EPA 8270D EPA
82700
EPA 82700 EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc
-
Reported by Janet Muse
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERC13-B Station ID: HERC13
E104009-15
Matrix: Waste
Date Collected: 9/29/10 15:10 (IS Niunber
.4nalyte
100-52-7
Benzaldehyde
56-55-3
Results Qualifiers
Units
MRL
24 U
mg/kg
24
Benzo(a)anthracene
2.4 U
mg/kg
A
50-32-8
Benzo(a)pyrene
2.4 U
mg/kg
24
205-99-2
Benzo(b)fluoranthene
2.4 U
mg/kg
) A
191-24-2
Benzo(g,h,i)perylene
2.4 U
mg/kg
A
207-08-9
Benzo(k)fluoranthene
2.4 U
mg/kg
8 5-68-7
Benzyl butyl phthalate
24 U
mg/kg
24
111-91-1
I3is(2-chloroethoxy)methane
‘‘
‘
A
24 U
mg/kg
‘A
bis(2-Chloroethyl) Ether
24 U
mg/kg
2A
39638-32-9
Bis(2-chloroisopropyl) ether
24 U
mg/kg
2A
117-81-7
Bis(2-ethylhexyl) phthalate
24 U
mg/kg
24
105-60-2
Caprolactam
24 U
mg/kg
‘A
111-44-4
.
86-74-8
Earbazole
2.4 U
mg/kg
24
218-01-9
Chrysene
2.4 U
mg/kg
) A
53-70-3
Dibenz(a,h)anthracene
2.4 U
mg/kg
24
132-64-9
Dibenzofuran
2.4 U
mg/kg
24
84-66-2
Diethyl phthalate
24 U
mg/kg
24
131-11-3
Dimethyl phthalate
24 U
mg/kg
24
84-74-2
Di-n-butylphthalate
24 U
mg/kg
24
117-84-0
Di-n-oclylphthalate
24 U
mg/kg
206-44-0
Fluoranthene
7.0
mg/kg
-)
86-73-7
Fluorene
2.4 U
mg/kg
24
118-74-1
Hexachlorobenzene (HCB)
24 U
mg/kg
24 24
2A
87-68-3
Hexachiorobutadiene
24 U
mg/kg
77-47-4
Hexachlorocyclopentadiene (HCCP)
24 U
mg/kg
24
67-72-1
Hexachioroethane
24 U
mg/kg
24
193-39-5
Indeno (1,2,3-cd) pyrene
2.4 U
mg/kg
24
78-59-1
Isophorone
24 U
mg/kg
)A
91-20-3
Naphthalene
5.2
mg/kg
24
98-95-3
Nitrobenzene
24 U
mg/kg
24
621-64-7
n-Nitroso di-n-Propylamine
24 U
mg/kg
24
Page 57 of59
E104009 SVOA TCLPS FINAl..
Prepared 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 2:00 10/05/10 12:00 10/05/10 12:00 10/05,10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 2:00 10/05/10 12:00 10/05/10 2:00 10/05/10 12:00
tna4zed Method 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 0/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00
EPA 82701)
EPA 8270D ‘EPA 8270D
EPA 82700 EPA 82700 EPA 8270D EPA 82700
EPA 8270D EPA 82700 EPA 8270D
EPA 82700 EPA 8270D EPA 82700
EPA 8270D EPA 8270D
EPA 82700 EPA 82700
EPA 8270D EPA 82700 EPA 8270D EPA 82700 EPA 8270D EPA 8270D
EPA 82700 EPA 82701) EPA 82700 EPA 8270D
EPA 82700 EPA 82700 EPA 82700 EPA 82700
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project; 10-0629, Hercules Inc Reported by Janet Muse -
Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCI3-B
E104009-15
Matrix: Waste
Station ID: HERCI3 Date Collected: 9/29/JO 15:10 (‘IS .‘Vuuzher
Results Qualifiers
.4rndrte
Linli
MRL
Prepared
24
°‘°° 12:00 10/05/jO 2:00 10/05/10 12:00 10/05/10 2:00 10/05!I0 12:00 10/05/10 12:00
122-39-4
n-Nitrosodiphenylamine/Diphenylamine
24 U
mg/kg
87-86-5
Pentachlorophenol
24 U
mg/kg
24
85-01-8
Phenanthrene
2.4 U
mg/kg
2.4
108-95-2
Phenol
28
mg/kg
24 2.4 24
129-00-0
Pyrene
3.1
mg/kg
110-86-1
Pyridine
24 U
mg/kg
400 NJ
mg/kg
1000 NJ
mg/kg
4navzed Mcfhad 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 4:00 10/10/10 4:00 10/10/10 4:00
EPA 82701)
EPA 8270D EPA 82701) EPA 82700 EPA 82700
EPA 82700
Tentatively Identified Compounds: R4-6552
(Menthenol)terpineol (TIC)
R4-6531
Camphene (TIC)
R4-6603
Dirnethylisopropylphenanthrene (TIC)
200 N.J
mg/kg
10/05/10 12:00 10/05/10 12:00 10/05/10 12:00
10/10/10 4:00 10/10/10 4:00 10/10/10 400 10/10/10 4:00 10/10/10 4:00
R4-8000535
Diphenyl ether (TIC)
5000 NJ
mg/kg
R4-8000899
Ilexahydrotetramethylmethanonaphthalene (TIC)
1000 NJ
mg/kg
12:00 10/05/10 12:00
R4-6584
Methyl(methylethyl)benzene (TIC)
7000 NJ
mg/kg
10/05/10 12:00
10/10/10 4:00 10:10/10
EPA 8270D
EPA 8270D EPA 8270[)
EPA 82700 EPA 82700
EPA
8270D
R4-8000897
Methyl(methylethyl)cyclohexane (TIC)
4000 NJ
mg/kg
10/05/10
12:00
4:00
EPA 8270D
R4-8000906
Methyl(methylethyl)cyclohexene (TIC)
200 NJ
mg/kg
10/05,10 12.00
10/10,10 4:00
EPA 82700
2000 NJ
mg/kg
10/05/10 12:00 0)05)10
10/10/10 4:00 10/10/10
R4-6520
Pinene (TIC)
R4-8000466
Propylphenol (TIC)
200 NJ
mg/kg
R4-800090I
Trimethylbicycloheptane (TIC)
200 NJ
mg/kg
R4-6501
Page 58 of59
Unidentified Compounds
El 04009 SVOA TCLPS FINAL
2000 J
mg/kg
EPA 02701)
1200
400
EPA 82700
10/05/10 12:00 10/05/10 12:00
I0;IO/10 4:00 10/10)10 4:00
EPA 82700
EPA 82700
11/1/10 16:40
-
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Janet Muse -
TCLP SemiVolatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERC13-B Station ID: HERC13
E104009-15
Matrix: Waste
Date Collected: 9/29/10 15:10 C’S N,unher
.dnatyte
1319-77-3
(3-andlor4-)Methylphenol:
58-90-2
2,3,4,6-Tetrachlorophenol:
NA..5
0.10
95-95-4
2.4.5-Trichlorophenol:
NA-5
0.10
88-06-2
2,4,6-Trichiorophenol:
NA-5
0.10
121-14-2
2.4-Dinitrotoluenc:
NA-5
0.10
95-48-7
2-Methylphenol:
NA5
0.10
118-74-1
Hexachlorobenzene (HCB):
NA-5
0.10
87-68-3 67-72-1
-
.
Results Qualifiers
NA-5
Units
MRL
0.10
Hexachlorobutadiene:
\A5
0.10
[lexachloroethane:
NA-S
010
98-95-3
Nitrobenzene:
NA-5
0.10
87-86-5
Pentachlorophenol:
NA-5
0.10
110-86-I
Pyridine:
Page 59 of 59
NA-S
El 04009 SVOA TCLPS FINAL
0.10
Prepared 10/05/10 9:44
10/05/10 944
10.05:10 9:44 10/05/10 9:44 005 0
9:44 10/05/10 9:44
1005/10 9:44
10/05/10 9:44
10.0510
.4na(ed llethad 10/09/10 14:04 10/09/10 14:04 10/09/10 14:04 10/09/10 14:04
EPA 8270D
10/09/10 14:04
EP 8270D
10/09/ID
14:04 10/09/10 14:04 10/09/10 14:04 10/09/10
9:4-I
14:04
10/05/10 9:44 111/05/10
10/09/ID 14:04 10091/)
10/05/10 9:44
10/09/10 14:04
[I’A 8270D
EPA 8270D EPA 82701)
EPA 8270D
EPA 8270D EPA 8270D EPA 270D EPA 8270D EPA 8270D
EPA 8270D
11/1/10 16:40
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
November 8, 2010 4SESD-ASB
MEMORANDUM SUBJECT:
FINAL Analytical Report Project: 10-0629, Hercules Inc Civil Enforcement
FROM:
Kristin Trapp OCS Chemist
THRU:
Sallie Hale, Chief ASB Organic Chemistry Section
TO:
Sharon Matthews
Attached are the final results for the analytical groups listed below. These analyses were performed in accordance with the Analytical Support Branch’s (ASB) Laboratory Operations and Quality Assurance Manual (ASB LOQAM) found at www.epa.gov/region4/sesdlasbsop. Any unique project data quality objectives specified in writing by the data requestor have also been incorporated into the data unless otherwise noted in the Report Narrative. Chemistry data have been verified based on the ASB LOQAM specifications and may have been qualified if the applicable quality control criteria were not met. For a listing of specific data qualifiers and explanations, please refer to the Data Qualifier Definitions included in this report. The reported results are representative only of the samples as received by the laboratory.
Analyses Included in this report:
Method Used:
TCLP Volatiles (TCLPV) Toxicity Characteristic Leaching Procedure Volatile organic compounds
EPA 1311 EPA 8260C
Volatile Organics (VOA) Volatile organic compounds
Page 1 of 60
E104009 TCLPV VOA FINAL
EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Sample Disposal Policy Because of the laboratory’s limited space for long term sample storage, our policy is to dispose of samples on a periodic schedule. Please note that within 60 days of this memo, the original samples and all sample extracts and/or sample digestates will be disposed of in accordance with applicable regulations. The 60-day sample disposal policy does not apply to criminal samples which are held until the laboratory is notified by the criminal investigators that case development and litigation are complete.
These samples may be held in the laboratory’s custody for a longer period of time if you have a special project need. If you wish for the laboratory to hold samples beyond the 60-day period, please contact our Sample Control and provide a reason for holding samples Coordinator, Debbie Colquitt, by e-mail at beyond 60 days
Page 2 of6O
E104009 TCLPV VOA FINAL
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
SAMPLES INCLUDED IN TIllS REPORT
Project: 10-0629, Hercules Inc Sample ID
Laboratory ID
Matrix
Date Collected
ERBO1
E104009-01
Equipment Rinse Blank
9/23/10 13:30
10/1/10 8:35
HERCO1-A
E104009-03
Waste
9/28/10 10:10
10/1/10 8:35 10/1/10 8:35
Date Received
HERCO2-B
E104009-04
Waste
9/28/10 10:55
HERCO3-B
E104009-0S
Waste
9/28/10 13:15
10/1/10 8:35
HERCO4-B
E104009-06
Waste
9/28/10 13:50
10/1/10 8:35
HERCO5-A
E104009-07
Waste
9/28/10 14:05
10/1/10 8:35
HERCO6-B
E104009-08
Waste
9/28/10 14:55
10/1/10 8:35 10/1/10 8:35
HERCO7-B
E104009-09
Waste
9/28/10 15:25
HERCO8
E104009-10
Waste
9/29/10 08:50
10/1/10 8:35
HERCO9-B
E104009-11
Waste
9/29/10 14:20
10/1/10 8:35
HERCIO-B
E104009-12
Waste
9/29/10 14:15
10/1/10 8:35
HERC11-B
E104009-13
Waste
9/29/10 14:30
10/1/10 8:35
HERC12-B
E104009-14
Waste
9/29/10 14:50
10/1/10 8:35
HERC13-B
E104009-15
Waste
9/29/10 15:10
10/1/10 8:35
Page 3 of 60
El 04009 TCLPV VOA FINAL
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
DATA QUALIFIER DEFINITIONS
U D—4 H-S J NA-5
The analyte was not detected at or above the reporting limit.
NJ
Presumptive evidence that analyte is present; reported as a tentative identification with an estimated value.
0-2
Result greater than MDL but less than MRL.
0 C-i OL-1 OL-3 OR-I
Analyte concentration low in continuing calibration verification standard Laboratory Control Spike Recovery less than method control limits Laboratory Control Spike Precision outside method control limits MRL verification recovery less than lower control limits.
MRL elevated due to interferences. Recommended analytical holding time exceeded The identification of the analyte is acceptable; the reported value is an estimate. Not Analyzed. Cannot exceed TCLP regulatory levels based on Total Scan analyses,
ACRONYMS AND ABBREVIATIONS
CAS
Chemical Abstracts Service Note: Anal ytes with no known CAS identifiers have been assigned codes beginning with “E”, the EPA ID as assigned by the EPA Substance Registry System (www.epa.gov/srs), or beginning with “R4-”, a unique identifier assigned by the EPA Region 4 laboratory.
IvIDL
Method Detection Limit The minimum concentration of a substance (an analyte) that can be measured and reported with a 99% confidence that the analyte concentration is greater than zero.
MRL
Minimum Reporting Limit Analyte concentration that corresponds to the lowest demonstrated level of acceptable quantitation. The MRL is sample-specific and accounts for preparation weights and volumes, dilutions, and moisture content of soil/sediments.
TIC
Tentatively Identified Compound An analyte identified based on a match with the instrument software’s mass spectral library. A calibration standard has not been analyzed to confinn the compound’s identification or the estimated concentration reported.
-
-
Page 4 of 60
-
El04009 TCLPV VOA FINAL
Il/S/lO 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: ERBO1 Station ID:
E104009-01
Matrix: Equipment Rinse Blank
Date Collected: 9/23/10 13:30 C4S Niunher
4nalyte
Results Quali/ier.c
Units
MRL
1.0 U
ug/L
1.0 0.50 0.50
R4-7156
(m- andior p-)Xylene
630-20-6
1,1,1,2-Tetrachloroethane
0.50 U
ugIL
71-55-6
1,1,1 -Trichloroethane
0.50 U
ug/L
79-34-5
1,1,2,2-Tetrachioroethane
0.50 U
ug/L
0.50
76-13-1
I,1,2-Irichloro-1,2,2-Trifluoroethane
0.50 U
ug/L
0.50
(Freon 113) 79-00-5
1,1,2-Trichloroethane
0.50 U
ug/L
0.50
734-3
I,1-Dichloroethane
0.50 U
ugfL
0.50
75-35-4
1,1-Dichloroethene (1 ,1-Dichloroethylene)
0.50 U
ug/L
0.50
563-58-6
LI-Dichloropropene
0.50 U
ug/L
0.50
0.50 U
ug/L
0.50
87-61-6
1 ,2,3-Trichlorobenzene
96-18-4
1,2,3-Trichloropropane
0.50 U
ug/L
0.50
120-82-1
1 ,2,4-Trichlorobenzene
0.50 U
ug/L
0.50
95-63-6
1,2,4-Trimethylbenzene
0.50 U
ug/L
0.50
96-12-8
1,2-Dibromo-3-Chloropropane (DBCP)
1.0 U
ug/L
1.0
106-93-4
1,2-Dibromoethane (EDB)
0.50 U
ug/L
0.50
95-50-1
1,2-Dichlorobenzene
0.50 U
ug[L
0.50
107-06-2
1,2-Dichloroethane
0.50 U
ug/L
0.50
78-87-5
1,2-Dichioropropane
0.50 U
ugiL
0.50
108-67-8
1,3,5-Trinlethylbenzene
0.50 U
ugIL
0.50
541-73-1
1,3-Dichlorobenzene
0.50 U
ug/L
0.50
142-28-9
1,3-Dichloropropane
0.50 U
ug/L
0.50
106-46-7
1,4-Dichlorobenzene
0.50 U
ug/L
0.50
594-20-7
2,2-Dichloropropane
0.50 U
ug/L
0.50
67-64-1
Acetone
4.0 U
ugfL
4.0
71-43-2
Benzene
0.50 U
ugJL
0.50
108-86-1
Bromobenzene
0.50 U
ugfL
0.50
74-97-5
Bromochlorornethane
0.50 U
ug/L
0.50
75-27-4
Bromodichloromethane
0.50 U
ugfL
0.50
75-25-2
Bromoform
1.0 LI
ug/L
1.0
PageS of 60
E104009 TCLPV VOA FINAL
Prepared
.4nu(v:ed lkthad
0/04/10
10:0410
9:32 10/04/10 9:32
12:10 10/04/10 12:10
10/04110
10/04/10
9:32 10/04/10 9:32 10/04/10 9:32
12:10 10/04/10 12:10 10/04/10 12:10
10/04/10 9:32 10/04/10 9:32 10/04/10 9:32
10/04/10 12:10 10/04/10 12:10 10/04/10 12:10
10/04/10 9:32 10/04/10 9:32 10/04/10 9:32 10/04/10 9:32 10/04/10 9:32
10/04/10 9:32 10/04/10 9:32 10/04/10 9:32 1004/10 9:32 10/04/10 9:32 I004/10 9:32 10/04/10 9:32 10/04/10 9:32 10/04/10 9:32 10/04/10 9:32 10/04/10 9:32
10/04/jo 9:32 10/04/10 9:32 10/04/10 9:32 0/04/10 9:32 1004/10 932
EPA
8260C
EPA 8260C
EPA 8260C EPA
8260C
EPA 8260C
EPA 8260C EPA 8260C EPA 8260C
1004/10 EPA 8260C 2:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 9260U 12:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 1004/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 I0/04’IO EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 0/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: ERBO1
E104009-01
Matrix: Equipment Rinse Blank
Station ID: Date Collected:
9/23/10 13:30
(Z IS .Vu,nher
.4nalyte
74-83-9
Bromomethane
Res,,IIy Qualifiers
Units
MRL
Prepared
ug/L
2.0
10/04/10
0.50 U
ug/L
0.50
10/04/It 9:32 0/04/10 9:32 10/04/10 9:32 10/04110 9:32
0.50 U
ug’L
0.50
10,04/10 9:32
10/04/10 12:10
EPA 8260C
0.50
10/04/10 9:32
10/04/10 12:10
EPA 8260C
0.50
10/04/I 0 9:32
10/04/10 12:10
EPA 9260C
10/04/10 9:32 10/04/10 9:32
10/04/10 1210
EPA 8260C
1004/10 12:10
EPA 8260C
0.50
10/04/10
10/04/10 12:10
EPA 8260C
1004/10
2.0 U
75-15-0
Carbon disulfide
0.50 U
ug/L
0.50
56-23.5
Carbon Tetrachioride
0.50 U
ug/L
0.50
108-90-7 75..1J{).3
67-66-3 74-87-3
156-59-2 10061-01-5 110-82-7 124-48-1
Chlorobenzene Chioroethane Chloroform Chioromethane cis-1 ,2-Dichloroethene cis- I ,3-Dichloropropene
0.50 U
ugfL
0.50 U, J. QC-l
ug!L
0.50 U 0.50 U 0.50 U
Cyclohexane Dibromochloromethane
lnavzed Method
ug/L ug!L oWL
0.50 0.50
0.50 U
ugL
0.50 0.50 0.50
74-95-3
Dibromomethane
0.50 U
ugIL
75-71-8
Dichlorodifluoromethane (Freon 12)
0.50 U, J, QC-1
ug/L
9:32 9:32 10/04/10 9:32 10/04/10
12:10
EPA 8260C
10/04/10 12:10
EPA 8260C
1004.10 12:10
EPA 8260C
0/04/10 12:10
EPA 8260C
10/04/10 12:10
EPA 8260C
10/04/10 12:10
EPA 8260C
10/04/10 12:10
EPA t26OC
10/04/10
100-41-4
Ethyl Benzene
0.50 U
uWL
0.50
9:32 10/04/10 9:32
12:10
EPA 8260C
87-68.3
Hexachiorobutadierie
0.50 U
ug/L
0.50
1004/10 9:32
10/04/10 12:10
EPA 8260C
0.50 U
ugIL
0.50
10/04/10
10/04/10 12:10
EPA 8260C
98-82-8 79-20-9
Isopropylbenzene Methyl Acetate
1.0 U
ug/L
1.0
591-78-6
Methyl Butyl Ketone
1.0 U
ug/L
1.0
78-93-3
Methyl Ethyl Kclone
1.0 U
ug/L
1.0
108-10-1 1634-04-4 108-87-2 75-09-2 104-51-8 103-65-1 95-49-8 95-47-6
Methyl Isobutyl Ketone Methyl T-Butyl Ether (MTBE) Methylcyclohexane Methylene Chloride
1.0 U
ug/L
1.0
0.50 U
ug/L
0.50
10/04/10
0.50
10/04/10
0.50
10/04/10
0.50 U
ug/L
0.50 U
ug/L ugJL
n-Propylbenzene
0.50 U
ugJL
0.50
o-Chlorotoluene
0.50 U
ug/L
0.50
o-Xylene
0.50 U
ug/L
0.50 0,50 0.50
106-43-4
p.Chlorotoluene
0.50 U
ugIL
99-87-6
p-lsopropyltoluene
0.50 U
ug/L
0.50 U
ug/L
135-98-8 100-42-5
Page 6 of6O
0.50
0.50 U
n.Bulylbenzene
sec-Butylbenzene
2.0 U
Styrene
El04009 TCLPV VOA FINAL
9:32 10/04/10 9:32 10/04/10 9:32 10/04/10 9:32 0/04/It 9:32
ug/L
0.50 2.0
9:32 9:32 9:32 10/04/10 9 32 10/04/10 9:32 10/04/10 9:32 10/04/10 9:32 10/04/10 9:32 10/04/10 9:32 10/04/10 932 10 0410
932
10/04/10 12:10
EPA 8260C
10/04/It 12:10
EPA 8260C
10/04/10 12:10
EPA 8260C’
10/04/10 I2:10
EPA 8260C
1004/10 12:10
EPA 8260C
10/04/10 12:10
EPA 8260C
0/04/tO 12:10
EPA 8260C
10/04/10 12:10 10/04/10 12:10
10/04/10 12:10
10/04/10 12:10 0104110 I2:10 10/04/10 12:10 10/04/10
12:10 10.04/10 12:10
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: ERBO1 Station ID:
E104009-01
Matrix: Equipment Rinse Blank
Date Collected: 9/23/10 13:30
c.1s Number
.dntilyte
Results Qualifiers
98-06-6
tert-Butylbenzene
127-18-4
Units
MRL
Prepared
0.50
10/04/10 932 10/04/10 9:32
10/04/10 1210 10/04/10 12:10
0/04/10
10104/10
932 10/04/10 9:32
10/04/10
10.04/10
1004/10
12:10 10/04/10 12:10
toofred Method
0.50 U
ug/L
Tetrachloroethene (Teti-achloroethylene)
0.50 U
ugfL
0.50
108-88-3
Toluene
0.50 U
ug!L
0.50
156-60-5
tmns-1,2-Dichloroethene
0.50 U, J, QL-1
UgfL
050
10061-02-6
trans-l.3-Dichloropropene
0.50 U
ug/L
0.50
79-01-6
Trichioroethene (Trichloroethylene)
0.50 U
ug/L
0.50
9:32 10/04/10 9:32
75’-69-4
Trichiorofluoromethane (Freon II)
0.50 U
ugIL
0.50
10,04/10 9:32
1004/10 12:10
EPA 8260C
75-01-4
Vinyl chloride
0.50 U
ug/L
0.50
10/04/10 9:32
10/04/10 12:10
EPA 8260C
10 U
ug/L
10
10/04/10 932
10.0310
12:10 12:10
EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C
Tentatively Identified Compounds: R4-0000
Page 7 of 60
Tentatively Identified Compounds
E104009 TCLPV VOA FINAL
210
El’A 9260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules mc- Reported by Kristin Trapp
TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: ERBOI
E104009-01
Matrix: Equipment Rinse Blank
Station ID: Date Collected: 9/23/10 13:30 (‘AS
Resulis Qualifiers
Vu,nher
.4nalyte
75-35-4
Il-Dichloroethene (l.l-Dichloroethylene):
107-06-2
1,2-Dicbloroethane:
106-46-7
l.4-Dichlorohcnzcnc:
NA-5
Unigs
t1fRL
Prepared
0.00050
10/13/10 15:00 10/13/10
\A5
0.00050
NA-5
0.00050
1500
87-68-3
Hexachiorobutadiene:
\A5
0.00050
10/13/10 15:00 10113/10 1500 10/13/10 5:00 10/13/10 15:00 10/13/10 15:00 10/13/10 15:00
78-93-3
Methyl Ethyl Ketone:
NA-S
0.00 10
10/13/10 15:00
127-18-4
Tetrachloroethene (Tetrachloroethylene):
NA-5
0.00050
71-43-2
Benzene:
NA-5
0.00050
56-23-5
Carbon Telrachioride:
NA-S
0.00050
108-90-7
Chlorobenzene:
NA-S
0.00050
67-66-3
Chloroform:
NA-5
0.00050
79-01-6 75-01-4
Page 8 of 60
Trichloroethene (Trichioroethylene): Vinyl chloride:
NA-S NA-5
E104009 TCLPV VOA FINAL
0.00050 0.00050
10/13/11) 151)0
10/13/10
.1 nat rzed lie/hod 10/13/10 15:00 10/13/10 15:00 10/13/10 15:00 10/13/10 151)0 10/13/10 15:00 0/13/10 15:00 10/13/10 15:00 10/13/10 15.00 10/13/10 15:00
10/13/10 1500 10/13/10
15:00
1500
10/13/10 15:00
10/13/10 15:00
EPA 826CC EPA 826CC EPA 8260C EPA
826CC
EPA 826CC EPA
826CC
EPA
826CC
EPA
8260C
EPA 8260C EPA 826CC EPA 826CC EPA 826CC
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO1-A Station ID: HERCO1
E104009-03
Matrix: Waste
Date Collected: 9/28/10 10:10 C4S Number
.4nalyie
Res uii Quai/iers
Units
MRL
R4-7156
(m- and/or p-)Xylene
5.1 J,Q-2
mg/kg
98
630-20-6
1,1,1 ,2-Tetrachloroethane
9.8 U
mg/kg
7.0
7 1-55=6
1,1 ,1-Trichloroethane
9.8 U
mg/kg
(1 Q
79=34-5
1,1 ,2,2-Tetrachloroethane
9.8 U
mg/kg
A 0
76-13-I
1,1 ,2-Trichloro- 1 ,2,2-Trifluoroethane
9.8 U
mg/kg
98
9.8 U
mg/kg
n
Prepared
12:10 10/06/10 12:10 10/06/10 1210 10106/10 12:10 10/06/10 12:10
10/07/10 15:00 10/07/10 15:08 l007 0 15:08 10/07/10 15:08 10/07/10 15:08
10/06/10 12:10 10/06/10 12:10 10/06/10 12:10
10/07/10 15:08 10/07/10 1508 10/07/10 15:08
10/06/10 12:10 10/06/10 12:10 18/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 I0’06’10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10)06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 I2:I0
10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 10/07/10 15-08 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 1007/10 15:08 10/07/10 15:08 I0’07/I0 15:08 10/07/10 15:08 1007/10 15:08 10/07/10 15:08 10/07/10 15:08
10/06110
(Freon 113) 79-00-5
1 ,1,2-Trichloroethane
Q
1,1 -Dichloroethane
9.8 U,J.QL-1
mg/kg
9 8
75-35-4
1 ,l-Dichloroethene (1 ,1-Dichloroethylene)
9.8 U
mg/kg
A 0
563-58-6
1,1 -Dichloropropene
9.8
U
mg/kg
87-61-6
I ,2,3-Trichlorobenzene
9.8
L
mg/kg
96-18-4
I ,2,3-Trichloropropane
9.8 U
mg/kg
9 8
120-82-1
1,2,4-Trichlorobenzene
9.8 U
mg/kg
o o
95-63-6
1 ,2,4-Trimethylbenzene
3.9 J, Q-2, QR-l
mg/kg
9 8
96-12-8
1 ,2-Dibromo-3-Chloropropane (DBCP)
20 U
mg/kg
‘)A
106-93-4
1 ,2-Dibromoethane (EDB)
9.8 U
mg/kg
9 8
95-50-1
1 ,2-Dichlorobenzene
9.8 U
mg/kg
A 0 7.0
107-06-2
1 ,2-Dichloroethane
9.8 U
mg/kg
98
78-87-5
1 ,2-Dichloropropane
9.8 U
mg/kg
A 0
108-67-8
1 ,3,5-Trimethylbenzene
9.8 U
mg/kg
c,
541-73-1
1 ,3-Dichlorobenzene
9.8 U
mg/kg
A 0
142-28-9
1 ,3-Dichloropropane
9.8 U
mg/kg
106-46-7
I ,4-Dichlorobenzene
9.8 U
mg/kg
594-20-7
2,2-Dichloropropane
9.8 U
mg/kg
98
67-64-1
Acetone
78 U
mg/kg
‘,o
mg/kg
o
mg/kg
A 0
mg/kg
9 8
A 0
0
‘°
7 1-43-2
Benzene
108-86-1
Bromobenzene
9.8 U
74-97-5
Bromochioromethane
9.8 U, J,
75-27-4
Bromodichioromethane
9.8 U
mg/kg
A 0
75-25-2
Bromoform
20 U
mg/kg
2O
Page 9 of 60
18
E104009 TCLPV VOA FINAL
QL-1
.4nalv:ed ,8lethod
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA
8260C
EPA 8260C EPA
8260C
EPA 8260C EPA 8260C EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCOI-A
E104009-03
Matrix: Waste
Station ID: HERCOI Date Collected: 9/28/10 10:10 cds Nwnher
.4nalyte
74-83-9
Bromomethane
Results Qualifiers
39 U
Units
mg/kg
75-15-0
Carbon disulfide
5.3 J, Q-2
mg/kg
56-23-5
Carbon Tetrachioride
9.8 U
mg/kg
MRL
Prepared
39
10/06/10 12:10
o
9 8
Q
108-90-7
Chlorobenzene
9.8 U
mg/kg
98
75-00-3
Chloroetharie
9.8 U
mg/kg
9 8
67-66-3
C:hlorofo
9.8 U
mg/kg
9 8 9 8
74-87-3
(‘hioromethanc
9.8 U
mg/kg
156-59-2
cis-1 ,2-Dichloroethene
9.8 U
mg/kg
9 8 9 8
10061-01-5
cis- I ,3-Dichloropropene
9.8 U
mg/kg
110-82-7
Cyclohexane
110
mg/kg
9 8
124-48-1
Dibromochioromethane
9.8 U
mg.’lg
o
74-95-3
Dibromomethane
9.8 U, J, QL-1
mg/kg
98
75-71-8
Dichiorodifluoromethane (Freon 12)
9.8 U
mg/kg
9 8
mg/kg
9 8
mg/kg
9 8
100-41-4
Ethyl Benzene
2.4 J, Q-2
87-68-3
Hexachlorobutadiene
9.8 U
98-82-8
Isopropylbenzene
16 U, D-4
mg/kg
79-20-9
Methyl Acetate
20 U
mg/kg
591-78-6
Methyl Butyl Ketone
20 U
mg/kg
78-93-3
Methyl Ethyl Ketone
20 U
mg/kg
0
I6 2n
2O
108-10-1
Methyl Isobutyl Ketone
20 U
mg/kg
2O
1634-04-4
Methyl T-Butyl Ether (MTBE)
9.8 U
mg/kg
98
108-87-2
Methylcyclohexane
6.9 J, Q-2
mg/kg
9 8 9 8 o
75-09-2
Methylene Chloride
9.8 U
mg/kg
104-51-8
n-Butylbenzene
9.8 U
mg/kg
9
8
9
8
103-65-1
n-Prop lbenzene
9.8 U
mg/kg
95-49-8
o-Chlorotolucne
9.8 U
mg/kg
9.8 U
mg/kg
9 8
9.8 U
mg/kg
9 8
95-47-6
o-Xylene
106-43-4
p-Chlorotoluene
99-87-6
p-lsopropyllolucne
135-98-8
sec-Butylbenzene
100-42-5
Styrene
Page lOof6O
E104009 TCLPV VOA FINAL
mg/kg
98
9.8 U
mg/kg
9 8
39 U
nig’lg
39
1100
10/06/lU 12:10
10:06/10 12:10 10/06/111 12:10 10/06/10 12:10 10/06/10 12,18 10/06/10 12:10 10/06/10 12:10 10:06.10 12:10 10/06/10 12:10 10/06110 12:10 10/06/10 12:10 (0/06/10 12:10 10/06/10 (2:10 10/06/10 12:10 10/061(0 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:1(1 10/06/10 12:10 10/I16/10 12:10 2:10 10/06/10 2:10 10/06/10 12:10 10/06/10 (210 10/06/10 12:10 0/06/10 12(0 10/06/10 12:10
.4nulyzed ,ttethod 10/07/10 15:00 10’07/l0 15:08 10/07/10 15:08 10/07/lU 15:08 10/07/10 15:08 10/07/10 15:08 (0/07/10 (5:08 l007/10 15:08 10.07/10 15:08 10/07/10 15:08 10/07,10 15:00 10/07/10 15:08 10/07/tO 15:00 10/07/10 15:08 10/07/10 15:00 15:08 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 0/07/10 15:08 10/07/10 (5:08 0/07/10 15.08 10/07/10 15:08 0/07/Ia 15:08 10/07/10 15:08 0/07/ID 15:08 10/07/10 15:08 10/07/10 1508 10,07:10 5:08
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA
8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA
8260C
EPA 8260C EPA 8260C EPA 8260C EPA
8260C
EPA
8260C
EPA 8260C EPA
8260C
EPA
8260C
EPA
8260C
EPA 8260C EPA
8260C
EPA
8260C
EPA 8260C EPA
8260C
EPA 8260C EPA 8260C EPA 8260C
11/8/10
9:52
0
0
UNiTED STATES ENWRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO1-A Station JD: HERCO1
E104009-03
Matrix: Waste
Date Collected: 9/28/10 10:10 CAS Number
.4nuiyre
Results Qualifiers
Units
4IRL
Prepared
98-06-6
tert-Butylbenzene
127-18-4
Tetrachloroethene (Tetrachloroethylene)
108-88-3
Toluene
156-60-5
trans-l,2-Dichloroethene
9.8 U
mg/kg
9.8
10061-02-6
trans-1.3-Dichloropropenc
9.8 U
mg/kg
9.8
79-01-6
Trichloroethene (Tnchloroethylene)
9.8 U
mg/kg
9.8
75-69-4
Trichlorofluoromethane (Freon II)
9.8 U
mg/kg
9.8
75-01-4
Vinyl chloride
9.8 U
mg/kg
9.8
10/06110 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10,06/10 12:10 10/06)10 12:10 1006,10 2:10 10/06/10 12:10
200 U
mg/kg
200
10/06/10 12:10
9.8 U
mg/kg
9.8
9.8 U
mg/kg
9.8
7100
mg/kg
.4na!:ed tfethod 10/07/10 15:08 10/07/10 15:08 1008/10 13:10 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 10/07110 15:08 10/07/10 15:08
EPA 826CC
10/07/10 508
EPA 826CC
EPA 8260C
EPA 826CC EPA 8260C
EPA 826CC
EPA 826CC
EPA 826CC EPA 826CC
Tentatively Identified Compounds: R4-0000
Page 11 of6O
Tentatively Idenlitied Compounds
E104009 TCLPV VOA FINAL
11/8/10
9:52
0 \‘D
_x
0
UN ITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-270() t
DART. Id. 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:
Saniple ID: IIERCO1-A
E104009-03
Matrix: Waste
Station ID: HERCOI Date Collected: 9/28/10 10:10 C4S Niunber
Results Quakfiers
.inulyte
Units
IRL
Prepared
.4navzed Ole/hod
0.10 U
mg/L
0.10
10/13/10 15:00
10/13/b 15:23
107-06-2
1,! -Dichloroethene (1,1 -Dichloroethylene) 1 ,2-Dichloroethane
0.10 U
mgIL
0.10
10/13/10
106-46-7
1,4-Dichlorobenzene
0.10 U
mg/L
0.10
10/13/10 15:00 10/13/10
75-35-4
71-43-2
Benzene
56-23-5
Carbon Tetrachloride
108-90-7 67-66-3 87-68-3
Chlorobenzene Chloroform Hexachlorobutadiene
15-00
15:23
10/13/10
0.21
mg/L
0.10
10/13/Ia 15.00
15:23
0.10 U
mgL
0.10
10(13.10
0.10
10/13/10
0 1310 15:23 10/13/10 1523
0.10 U
mg/L
0.10 U
mg/L
0.10 C
mgJL
0.10 0.10
15:00 15:00 10:13/10
15:00 10/13/10
15:23
Methyl Ethyl Kelone
0.20 U
mg/L
0.20
127-18-4
Tetrachloroethene (Tetrachloroethylene)
0.10 U
mgfL
0.10
10/13,10
79-01-6
Trichloroethcne (Trichloroethylene)
0.10 U
mg/L
0.10
0.10 U
mg/L
0.10
10/13/10 5:00 10/13/la 15:00
Page 12 of6O
E104009 TCLPV VOA FINAL
10/13/10 101310 5:23 10/13/10 15:23 10/13/10 5:23 10/13/10 15:23
78-93-3
Vinyl chloride
l0/13il0 15:23
15:00
0/13-10
75-01-4
15:23
10/13/10
15:00 15:00
EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO2-B
E104009-04
Matrix: Waste
Station ID: HERCO2 Date Collected: 9/28/10 10:55 CAS Number
.dnalyte
R4-71 56
(m- andlor p-)Xylene
630-20-6 71-55-6
Results Qualifiers
Units
MRL
25 U
mg/kg
2S
1,1,1 ,2-Tetrachloroethane
25 U
mg/kg
2S
I ,1,1-Trichloroethane
25 U
mg/kg
25 • ‘S
79-34-5
1,1 ,2,2-Tetrachloroethane
25 U
mg/kg
76-13-1
1,1 ,2-Trichloro- 1 ,2,2-Trifluoroethane (Freon 113)
25 U
mg/kg
25
79-00-5
1,1 ,2-Trichloroethane
25 U
mg/kg
-‘5
1,1-Dichioroethane
25 U,J,QL-1
mg/kg
25
75-35-4
1,1 -Dichloroethene (1,1 -Dichloroethylene)
25 U
mg/kg
2e
563-58-6
1,1 -Dichloropropene
25
mg/kg
25
87-61-6
1 ,2,3-Trichlorobenzene
25 U
mg/kg
-‘5
25
96-18-4
1 ,2,3-Trichloropropane
25 U
mg/kg
120-82-1
I ,2,4-Trichlorobenzerie
25 U
mg/kg
‘S
95-63-6
1 ,2,4-Tnmethylbenzene
7.0 J, Q-2, QR-l
mg/kg
2S
96-12-8
1 ,2-Dibromo-3-Chloropropane (DBCP)
50 U
mg/kg
S”
106-93-4
1,2-Dibromoethane (EDB)
25 U
mg/kg
25
95-50-1
I ,2-Dichloroben.zene
25 U
mg/kg
2S
107-06-2
1 ,2-Dichloroethane
25 U
mg/kg
-,
78-87-5
1 ,2-Dichloropropane
25 1
mg/kg
-‘S
108-67-8
I ,3,5-Trimethylbenzene
25 U
mg/kg
2S 25
541-73-1
I ,3-Dichlorobenzene
25 U
mg/kg
142-28-9
I .3-Dichioropropane
25 U
mg/kg
—,
‘,
106-46-7
1 4-Dich1orobenzene
25 U
mg/kg
594-20-7
2,2-Dichloropropane
25 U
mg/kg
-‘5
mg/kg
-,n
67-64-i
Acetone
71-43-2
Benzene
108-86-1
Bromobenzene
200 U
25
37
mg/kg
25
25 U
mg/kg
-‘5
74-97-5
Bromochioromethane
25 U,J.QL-1
mg/kg
25
75-27-4
Brotnodichioromethane
25 U
mg/kg
25
75-25-2
Bromoform
50 U
mg/kg
5O
Page 13 of6O
E104009 TCLPV VOA FINAL
Prepared
.4naly.ed Method
10/06110 12:10 10/06/10 12:10 1006/10 12:10 10/06/10 12:10 10/06/10 12:10
10/07/10 15:34 10/07/10 15:34 10/07/10 15:34 10/07/10 15:34 10/07/10 15:34
10/06/10 12:10 10/06110 12:10 10/06/10 12:10
10/07/10 15:34 10/07/10 15:34 10/07/10 15:34
EPA 8260C
10/06110 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10i06/l0 12-10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10:06110 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10
100710 15:34 10/07/10 15:34 1007.10 15:34 10/07/10 15:34 10/07/10 15:34 10/07/10 15:34 10i07/I0 15:34 10/07/10 15:34 10/07/10 15:34 10/07/10 15:34 00710 15:34 10/07/10 15:34 1007/10 15:34 10/07/10 15:34 10/07/10 15:34 10/07/10 15:34 10/07/10 15:34 10/07/10 15:34 10/07/10 15:34 10/07/10 15:34 10/07/10 15:34
EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id. 10-0629
Project: 10-0629, Hercules Inc
-
Reported by Kristin Trapp
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO2-B
Matrix: Waste
Station ID: HERCO2 Date Collected: CAS Number
74-83-9
E104009-04
9/28/10 10:55 Results Qiiali/iers
4nu4vte
Bromomethane
UniL6
MRL
Prepared
.4nav:ed Method
100
10/07/10 15:34
EPA 8260C
mg/kg
25
EPA 8260C
25
10/07/10 15:34 10/07/10
100 U
mg/kg
75-15-0
Carbon disulfide
25 U
56-23-5
Carbon Tetrachioride
25 U
mg/kg
25
I/20/c0
15:34
EPA 8260C
25
ICk/0
10/07/10 15:34
EPA 8260C EPA 8260C
108-90-7
Chlorobenzene
25 U
mg/kg
75-00-3
Chloroethane
25 U
mg/kg
67-66-3
Chloroform
74-87-3
Chiorornethane
156-59-2 10061-01-5
110-82-7 124-48-1
cis- I ,2-Dichloroethene cis- I ,3-Dichloropropene Cyclohexane
EPA 8260C
25 U
mg/kg
25
19//0
10,07/10
25 U
mg/kg
25
I9//0
10/07,10
15:34
EPA 8260C
10,06/b
10/07/I 0 15:34
EPA 8260C
9/0
1007/10
EPA 8260C
25 U
mg/kg
25 U
mg/kg
190
Dibromochloromethane
l5:34
10/07/10
25 U
mg/kg mglcg
25 25
15:34 10/07/10
25 25
I5:34
10/06/10
12:10
15:34
EPA 8260C
10/07/I 0 15:34
EPA 0260C
10/137/10 15:34 10/07/10 15:34
EPA 8260C
Dibromomethane
25 L,JQL-l
mg/kg
25
75-71-8
Dichlorodifluoromethane (Freon 12)
25 U
mg/kg
25
100-41-4
Ethyl Benzene
65 I. Q-2
mg/kg
25 1 9’d°
10/07/10 15:34
EPA 8260C
87-68-3
Hexachlorobutadiene
25 U
mg/kg
25
10/07/10 I5:34
EPA 8260C
25 U
mg/kg
25
10/07/10
EPA 8260C
74-95-3
98-82-8 79-20-9
Isopropylbenzene Methyl Acetate
mg/kg 50 50
591-78-6
Methyl Butyl Ketone
50 U
78-93-3
Methyl Ethyl Ketone
50 U
mg/kg
108-10-1 1634-04-4
Methyl lsobutyl Ketone Methyl T-Butyl Ether (MTBE)
108-87-2
Methylcyclohexane
75-09-2
Methylene Chloride
104-51-8 103-65-I
95-49-8
n-Butylbenzene n-Propylbenzene o-Chlorotoluene
50 U 25 U
mg/kg mg/kg
15:34
I 0/07)10
50 U
mg/kg
11/05/10
25
12:10 I9//0
15:34
10/07/10 121
5:34
EPA 8260C
‘9,°
10/07/10 15:34
EPA 8260C
25
I0
25 U
mglcg
25
I/20/0
25
25 U
mg/kg
25
25 U
mg/kg
l9/1/0
25 U
mg/kg
25
25 U
mg/kg
25
10/26/It
mILk e
25
135-98-8 100-42-5
Styrene
Page 14of60
El 04009 TCLPV VOA FINAL
25 U 100 U
mg/kg
EPA 8260C
15:34
o-Xylene
mg/kg
EPA 8260C
10/07/1 0 5:34 10/07/10 I5:34
10/07/10
p-Chlorotoluene
1700
EPA 8260C
2:10
106-43-4
p-Isopropyltoluene
15:34 10.07/10 15:34
25
95-47-6
sec-E3utylbenzene
0/07/10
10/07/10 9/0
99-87-6
—
15:34 I0/07/l0 I 5:34 I0:07,I0 15:34
10/06/b
100
EPA 8260C
2:10
mg/kg
mg/kg
I5:34
EPA 8260C EPA 8260C
10/07/10
17 J, Q-2
25 U
15:34
10/07/10
EPA 0260C
1210
I(//0
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
I0/07/I0 15:34
EPA 8260C
10/07/10 15:34
EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules nc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: IIERCO2-B Station ID: HERCO2
E104009-04
Matrix: Waste
Date Collected: 9/28/10 10:55 CAS Number
.4nalyte
98-06-6
tert-Butylbenzene
25 U
mg/kg
127-18-4
Tetrachloroethene (Tetrachloroethylene)
25 U
mg/kg
25
108-88-3
Toluene
mg/kg
120
156-60-5
Uans-1,2-Dichloroethene
10061-02-6
trans-1.3-Dichloropropene
79-01-6
Resuli Qualifiers
Units
MRL
25
Prepared
25 U
mg/kg
25
25 U
mg/kg
25
Trichloroethene (Trichloroethylene)
25 U
mg/kg
25
75694
Trichlorofluoromethane (Freon II)
25 U
mg/kg
25
75-01-4
Vinyl chloride
25 U
mg/kg
25
12:10 10/06/10 12:10 °°“° 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10
500 U
mg/kg
500
10/06/10 210
16000
lnalyed 10/07/10 15:34 10/07/10 10/08)10 3:36
10/07/10 15:34 10/07/tO 15:34 10/07/10 15:34 10)07/10 15:34 10/07/10 15:34
Itethod EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C
Tentatively Identified Compounds: R4-0000
Page 15 of6O
Ten1atieIy Identified Compounds
E104009 TCLPV VOA FINAL
10/07/10
EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 1 0-0629, Hercules Inc Reported by Kristin Trapp -
TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO2-B
E1040094J4
Matrix: Waste
Station ID: HERCO2
Date Collected: 9/28/10 10:55 C.4S Results Quahflers
AVU,aber
.4nalyte
75-35-4
l,l-Dichloroethene
Units
MRL
Prepared
0.12 U, J, H-8
mg/L
0.12
10/21/10
10/21/10 15:00 10/21/10
15:00
.4naiy:ed ,lfethod 10/21/10 18:30
EPA 8260C
10/21/10 18:30 10/21/10 18:30 10/21/10 18:30 10/21/10 18:30 10/21/10 18:30 10/21/10 1830 10/21/10 830 10/21/10 18:30 1021/10 1830 10/21/10
EPA 8260C
(1,1 -Dichloroethylene) 107-06-2
1,2-Dichloroethane
0.12 U, J, 14-8
mgfL
0.12
106-46-7
1.4-Dichlorobenzene
0.12 U, J, H-S
mg!L
0.12
71-43-2
Benzene
0.62 J, 1-1-8
mg/L
0.12
56-23-5
Carbon Tetrachloride
0.12 Ii, J, 1-1-8, QL-3
mg/L
0.12
108-90-7
Chlorobenzene
0.12 U, J, H-S
mg/L
0.12 0.12
5:00
10/21/10 15:1)0 10,21/10 1500
10/21/10 1508 10,21/10 1500 10/21/10 15:00 10,21/10
67-66-3
Chloroform
0.12 U, J, H-8
mg/L
87-68-3
Hexachlorobutadiene
0.12 U. J, Fl-S
mgJL
0.12
78-93-3
Methyl Ethyl Ketone
0.25 U, J, H-8
mg/L
0.25
127-18-4
Tetrachloroethene (Tefrachloroethylene)
0.12 U, J, H-S
mg/L
0.12
0/21/10
5.00 15:00
79-01-6
Trichloroethene (Trichloroet.hylene)
0.12 U, J, H-8
mg/L
0. 12
10/21/10 1500
830
75-01-4
Vinyl chloride
0.12 U, J. 11-8
mg/L
0.12
10/21/10 1500
10/21/10 18:30
Page 16of60
E104009 TCLPV VOA FINAL
EPA 8260C EPA
8260C
EPA 8260C
EPA 8260C EPA 8260C EPA
8260C
EPA 8260C EPA
8260C
EPA 8260C EPA
8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc
-
Reported by Kristin Trapp
Volatile Organics Project: 10-0629, Hercules Inc Lab iD:
Sample ID: HERCO3-B
Station ID: HERCO3
E104009-05
Matrix: Waste
Date Collected: 9/28/10 13:15 C4S Number
.4naly:e
R4-7 156
(m- and/or p-)Xylene
630-20-6
Recalls Qualifiers
Unils
MRL
Prepared
.lna(vzed
0.76 J, Q-2
mg/kg
0.97
1,1,1 ,2-Tetrachloroethane
0.97 U
mg/kg
0.97
71-55-6
1,1,1 -Trichloroethane
0.97 U
mg/kg
0.97
79-34-5
1,1 ,2,2-Tetrachloroethane
0.97 U
mg/kg
0.97
10/08/10 16:38 10/08/10 16:38 10/08.10 16:38 10/08/10 16:38
EPA 8260C
76-13-1
1.1 ,2-Trichloro- I ,2,2-Trifluoroethane (Freon 113)
0.97 U
mg/kg
0.97
10/06/10 12:10 10/06/10 12:10 10.06/10 12:10 10/06/10 12:10 10.06/10 12:10
10.08.10 16:38
EPA 8260C
79-00-5
1,1 ,2-Trichloroethane
0.97 U
mg/kg
0.97
10/08/10 16:38
EPA 8260C
75.33
1,1 -Dichloroethane
0.97 U, J, QL-l
mg/kg
0.97
75-35-4
1 ,1-Dichloroethene (1 ,1-Dichloroethylene)
0.97 U
mg/kg
0.97
10/06/10 12:10 10/06/10 12:10 10/06/10 12:10
563-58-6
1,1-Dichioropropene
0.97 U
mg/kg
0.97
87-61-6
1 ,2,3-Trichlorobenzene
0.97 U
mg/kg
0.97
10/08.10 12:10 10/06/10 12:10
96-18-4
1 ,2,3-Trichloropropane
0.97 U
mg/kg
0.97
10.06/10 12:10
120-82-1
1 ,2,4-Trichlorobenzene
0.97 U
mg/kg
0.97
95-63-6
1 ,2,4-Trimethylbenzene
2.1
mg/kg
0.97
10/06/ID 12:10 10/06/10
96-12-8
1 ,2-Dibromo-3-Chloropropane (DBCP)
1.9 U
mg/kg
1.9
106-93-4
I 2-Dibromoethane (EDB)
0.97 U
mg/kg
0.97
95-50-1
1 ,2-Dichlorobenzene
0.97 U
mg/kg
0.97
10/06/10 12:10
107-06-2
1 ,2-Dichloroethane
0.97 U
mg/kg
0.97
10/06/10 12:10
78-87-5
1 ,2-Dichloropropane
0.97 U
mg/kg
0.97
108-67-8
I ,3,5-Irimethylbenzene
0.97 U
mg/kg
0.97
541-73-1
I ,3-Dichlorobenzene
0.97 U
mg/kg
0.97
142-28-9
I ,3-Dichloropropane
0.97 U
mg/kg
0.97
106-46-7
I ,4-Dichlorobenzene
0.97 U
mg/kg
0.97
594-20-7
2,2-Dichioroproparie
0.97 U
mg/kg
0.97
67-64-1
Acetone
7.8 C
mg/kg
7.8
71-43-2
Benzene
108-86-1
Bromobenzene
74-97-5
Bromochioromethane
10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 1006/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 2:10 10/06/10
75-27-4
Bromodichloromethane
75-25-2
Bromoform
1.9 U
Page 17 of6O
12:10
mg/kg
0.97
mg/kg
0.97
0.97 U, J, QL-1
mg/kg
0.97
0.97 U
mg/kg
0.97
10/06/10 12:10
mg/kg
1.9
10/06/10
3.4
0.97 U
E104009 TCLPV VOA F1i’4AL
12:10
10/06/10 12:10 10/06/10
2:10
12:10
10/00/10
16:38 10/08/10 16:38
Ofethod
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
10,08/10 16:38 10/08/10 16:38 10/08110 6:38 10/08/10 16:38 10/08/10 16:38 10/08/10 16:38 10/08/10 16:38 10/08/10 16:38 1008/10 16:38 10/08.’lO 16:38 10/08/10 16:38 10/08/10 16:38 10/08/10 16:38 10/08/10 16:38 10,08/10 16:38 10/08/10 16:38 10/08/10 16:38 10/08/10 16:38 10/08/10 16:38 10/08/10 16:38
EPA 8260C
10/08/10 16:38
EPA 8260C
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EI’A
8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 1 0-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO3-B
E104009-05
Matrix: Waste
Station ID: HERCO3 Date Collected: 9/28/10 13:15 ( I.S .Vituiher
.lnalyte
74-83-9
Bromomethane
Results Qualifiers
Units
MRL
39 U
mg/kg
0.97
75-15-0
Carbon disulfide
0.97 C
mg/kg
56-23-5
Carbon Tetrachloride
0.97 U
mg/kg
0.97
108-90-7
Chlorobenzene
0.97 C
mg/kg
0.97
75-00-3
Chloroethane
0.97 U
mg/kg
0.97
67-66-3
Chloroform
0.97 U
mg/kg
0.97 0.97
0.97
74-87-3
Chloromethane
0.97 U
mg/kg
156-59-2
cis-1,2-Dichloroethene
0.97 C
mg/kg
0.97
0.97
10061-01-5
cis-1,3-Dichloropropene
0.97 U
mg/kg
110-82-7
Cyclohexane
0.97 U
mg/kg
124-48-I
Dibromochloromethane
0.97 U
mg/kg
0.97
mg/kg
0.97 0.97
74-95-3
Dibromomethane
0.97 C
75-71-8
Dichlorodifluoromethane (Freon 12)
0.97 U
mg/kg
0.62 .1, Q-2
mg/kg
0.97
0.97 U
mg/kg
0.97
100-41-4
Ethyl
87-68-3
Flexachlorobutadiene
Benzene
3.9 C, D-4
98-82-8
lsopropylbenzene
79-20-9
Methyl Acetate
59 1-78-6
Methyl Butyl Ketone
78-93-3
mg/kg mg/kg
1.9
1.9 U
mg/kg
1.9
Methyl Ethyl Ketone
1.9 U
mg/kg
1.9
108-10-1
Methyl Isobutyl Ketone
1.9 C
mg/kg
1.9
1634-04-4
Methyl T-Butvl Ether (MTBE)
0.97 U
mg/kg
0.97
108-87-2
Methylcyclohexane
mg/kg
0.97
0.97 U
mg/kg
0.97
1.2
mg/kg
0.97 0.97
0.72 J, Q-2
75-09-2
Methylene Chloride
104-51-8
n-Butylbenzene
8.6
103-65-1
n-Propylbenzene
0.97 U
mg/kg
95-49-8
o-Chlorotoluene
0,97 C
mg/kg
0.97
95-47-6
o-Xylene
0.50 J, Q-2
mg/kg
0.97
106-43-4
p-Chlorotoluene
0.97 t
mg/kg
0.97
99-87-6
p-Isopropyltoluene
135-98-8
sec-l3utylbenzene
100-42-5
Styrene
Page 18 of6O
El 04009 TCLPV VOA FINAL
420
mg/kg
0.97 C
mg/kg
39 C
mg/kg
0.97
Prepurrd
.inuvzed
10j06/l0 12:10 10/06)10 12:10 10.06/10 12:10 10/06/10 12:10 10/06/10 12:10 I0/06/10 12:10
10/08/10 16:38 10/08/10 6:38 10.08/10 16:38 10/08/10 16:38 0/08:10 16:30 10/00/10 16:30
10/06/10
10/08/10
2:10 10/06/10 12:10 10/06)10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10:06/10 12:10 0/06/10 12:10 10/06/10 1210 10/06/10 12:10 6/06/jO 12:10 10/06/10 12:10 10/06/10 12:10 10/06/ID 12:10 10/06/10 12:10 10/06/10 12:10 10/06/ID 12:10 10/06/10 12.10 10/06/10 1210 10/06/tO 12111 10/06/10 12:10 10/06/10 12:10 10/06/10
16:38 1(1/08/10 16:38 10.08/10 16:38 10/08/10 16:38 10/08/10 6:38 10/08/10 16:38 10/08/10 6:38 (0/08/10 16.30 10/08/10 6:38 10/08/10 (6:38 10/08/10 16:38 10/08/10 16:38 10/08/10 16:38 10/00/10 16:38 10/08/10 (6:38 10/88/10 16:38 10/08/10 16:38 (0/08/10 6:38 10/08/10 16:38 10/08/10 16:38 10/08/tO 16:38 10/08/10 16:38 10/07/tO (4:42 (0/08/10 16:38 0:00/10 16:30
12:10
tfethod EPA 8260C EPA 8260C EPA
8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA
8260C
EPA 8260C EPA
8260C
EPA 8260C EPA
8260C
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA
8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA
8260C
EPA 8260C
EPA 0260C
11/8/10 9:52
0
0
UN ITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Td: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules inc Lab ID:
Sample ID: HERCO3-B Station ID: IIERCO3
E104009-05
Matrix: Waste
Date Collected: 9/28/10 13:15
Cis .Vumbcr
Results Qualifiers
.4nalvte
98-06-6
tert-Butylbenzene
127-18-4
Tetrachloroethene (Tetrachloroethylene)
108-88-3
Toluene
156-60-5 10061-02-6
Units
MRL
mg/kg
0.97
0.97 U
mg/kg
0.97
0.82 J, Q-2
mg/kg
0.97
trans-1,2-Dichloroethene
0.97 U
mg/kg
0.97
trans-1.3-Dichloropropene
0.97 U
mg/kg
0.97
79-01-6
Trichloroethene (Trichloroethylene)
0.97 U
mg/kg
0.97
75-69-4
TrichIorofluorome1hane (Freon II)
0.97 U
mg/kg
0.97
0.97 U
mg/kg
0.97
75-01-4
Vinyl chloride
1.4
Prepared
.-lnalyzed .ItetIwd
10/06/10 12:10 10106/10 12:10 10/06/10 12:10 10/06/10 12:10 10/0610 12:10 10/06/10 12:10 10/06/10 120 10/06/10 12:10
10:08/10 638 16:38 10/08/10 16:38 10/08/10 16:38 1008/10 16:38 10/08/10 16:38 10/08/10 638 10/08/10 16.38
EPA 8260C
0/06/10 12:10 10/06/10 12:10
10/08/10 16:38 10/08/10 16:38
EPA 8260C
EPA 8260C EPA 8260C
EP\826OC
EPA 8260C EPA826OC
EPA 8260C EPA 8260C
Tentatively Identified Compounds: R4-8000739
Dimethyloctane (TIC)
40 NJ
R4-8000896
Ethylmethylcyclohexane (TIC)
20 NJ
Page 19 of6O
E104009 TCLPV VOA FINAL
-
mg/kg mg/kg
EPA
8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 90 College Station Road, Athens, Georgia 30605-2700 D.A RT. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO3-B
E104009-05
Matrix: Waste
Station ID: HERCO3 Date Collected: 9/28/10 13:15 C4S Number
,4nalfr
75-35-4
1.1-Dichloroethene (1,1-Dichloroethylene):
107-06-2
1,2-Dichloroethane:
\A5
0.00050
106-46-7
1.4-Dichlorohenienc:
NA-S
0.00050
71-43-2
Benzene:
NA-5
0,00050
56-23-5
Carbon Tetrachioride:
NA-5
0.00050
Results Qualifiers
NA-5
Units
:bIRL
0.00050
108-90-7
Chlorobenz,ene:
NA-S
0.00050
67-66-3
Chloroform:
NA-5
0.00050
87-68-3
flexachlorobutadiene:
78-93-3
Methyl Ethyl Ketone:
127-18-4
Tetrachloroethene (Tetrachloroethylene):
‘çA5
0.00050
79-01-6
Trichloroethene (Trichloroethylene):
NA-S
0.00050
75-01-4
Page 20 of 60
Vinyl chloride:
0.00050 NA-5
NA-S
E104009 TCLPV VOA F[NAL
0.0010
0.00050
Prepared
.na&zed ,lfethod
10113/10 15:00 10/13/10 15:00 10/13/10 15:00 10/13)10 15:00 10/13/10 15:00 I0113/10 15:00 10/13/10 5.00 10/13/10 15.00 10/13/10 500 10/13/10
10/13/10 15:00 10/13/10 15:00 10/13/tO 15:00 10/13/l0 15:0(1 10/13/tO 5:00 10/13/10 15:00 10/13/10 15:00 10/13/10 15:00 I0/I3/10 15:00 I0/13/10
15:00
15:00
10/13/10
10/13/10
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C 1/PA 3260C EPA 8260C EPA 8260C EPA
8260C
EPA 8260C
EPA 8260C
15:00
1500
EPA 8260C
10/13/10 15:00
10/13/10 15:00
EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO4-B Station ID: HERCO4
E104009-06
Matrix: Waste
Date Collected: 9/28/10 13:50 (Is .uuzher
Resith’s Qualifiers
4nalvte
Units
mg/kg
R4-7 156
(m- and/or p-)Xylene
630-20-6
1,1,1 ,2-Tetrachloroethane
10 U
mg/kg
71-55-6
1,1, 1-Trichloroethane
IOU
mg/lg
79-34-5
1,1 ,2,2-Tetrachloroethane
10 U
76-13-I
1,1 ,2-Trichloro- I ,2.2-Trifluoroethane (Freon 113)
10 1;
79-00-5
1,1 ,2-Trichloroethane
344 y?g
1,1 -Dichloroethanc
75-35-4
563-58-6
1,1 -Dichioroethene (1 ,1-Dichloroethylene) 1,1 -Die hioropropene
5.8 J, Q-2
/IIRL
O in ‘
Prepared 10)06110
12:10 10/06/10
lnulyzed llethod 10/07/10 16:26
EPA 8260C EPA 8260C
12:10
10/07/10 16:26
10)06/10 12-10
10 (17-10 6:26
EPA 8260C
mg/kg
I0 in
10/06/10
10/07/la
12:10
16:26
EPA 8260C
mgg
I0
10/06/10 12:10
1007/10 16:26
EPA 8260C
IOU
mg/kg
in
10/06/ID 12:10
10/07/10 16:26
EPA 8260C
10 U,J,QI—I
mg/kg
I0 in
10/06/10 ]2:l0
10/07/10
lOU
mg/kg
lOU
mg/kg
I0 in ‘
87-61-6
1 ,2,3-Trichlorobenzene
96-18-4
1,2,3-Trichioropropane
lOU
mg/kg
120-82-1
I ,2,4-Trichlorobenzene
lOU
mg/kg
I0 in iv
95-63-6
1 ,2,4-Trimethylbenzene
mg/kg
I0
lOU
mg/kg
4.6 J, Q-2, QR-1
10/06/10 12:10
EPA 8260C
16:26 10/07/10 16:26
EPA 8260C
10/06/10 12:10
10/07/10 16:26
EPA 8260C
10/06/10 12:10
10/07/10
EPA 8260C
10’0610
111/07/10 6:26
EPA 8260C
10/07/10 16:26
EPA 8260C
12:10 10/06/10 12:10 10/06/10
16:26
12:10
10/07/10 16:26
EPA 8260C EPA 8260C
96-12-8
I ,2-Dibromo-3-Chloropropane (DBCP)
20 U
mg/kg
2n
10/06/10 12:10
10/07/10 16:26
106-93-4
I ,2-Dibromoethane (EDB)
lOU
mg/kg
I0
10/06/10 12:10
10/07/10 6:26
EPA 8260C
95-50-1
1,2-Dichlorobenzene
25
mg/kg
in
iv
10/06/10 12:10
10/07/10 16:26
EPA 8260C
107-06-2
1 ,2-Dichloroethane
IOU
mg/kg
10/06/10
10/07/10
78-87-5
I ,2-Dichloropropane
IOU
mg/kg
1O in
12:10 10/06/10 12:10
16:26 10/07/10 16:26
EPA 8260C
108-67-8
I ,3,5-Trimethylbenzene
IOU
mg/kg
10/06/10 12:10
10/07/10 6:26
EPA 8260C
541-73-1
I ,3-Dichlorobenzene
lOU
mg/kg
In in
10/06/10
10/07)10 16:26
EPA 8260C
142-28-9
1 ,3-Dichloropropane
IOU
mg/kg
in
10/06/10 12:10
10/07/10
10/06/10 12:10
16:26 10/07)10 16:26
EPA 8260C
in iv I0 on cv
10-06/10
10/07/10
12:10 10/06/10 12:10
16:26 10/07/10 16:26
10/0610 2:10
0/07/10
12:10
106-46-7
I ,4-Dichlorobenzene
lOU
mg/kg
594-20-7
2,2-Dichloropropane
IOU
mg/kg
67-64-1
Acetone
80 U
mg/kg
7 1-43-2
Benzene
19
mg/kg
108-86-1
Bromobenzene
IOU
mg/kg
74-97-5
Bromochloromethane
10 U,J.QL-1
mg/kg
75-27-4
Bromodichioromethane
lOU
mg/kg
in
10/06/10
75-25-2
Bromoform
20 U
mg/kg
2O
12-10
Page 21 of6O
E104009 TCLPV VOA FINAL
-
I0 in in
10/06/10 12:10 10/06/10 12:10 12:10
16:26 10/07/10 16:26 10/07/la
16:26 10/07/10 16:26 100710 16:26
EPA 8260C
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
11/8/10 9:52
0
0
UNiTED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 1 0-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO4-B
E104009-06
Matrix: Waste
Station ID: HERCO4 Date Collected: 9/28/10 13:50 ( .Vnmher
.4nalyte
74-83-9
Bromomethane
75-15-0
Carbon disullide
56-23-5
Carbon Tetrauhloride
Results Qualifiers
Units
tIIRL
Prepared
40 U
mg/kg
4O
10/06/10 12:10
5.6 J, Q-2
mg/kg
I0
10/06/10 12:10
IOU
mg/kg
10
10/0610 1210
i
r
10/06/10 1210 10/06/10 12:10
108-90-7
Chlorobenzene
10 U
mg/kg
75-00-3
Chloroethane
IOU
mg/kg
67-66-3
Chloroform
IOU
mg/kg
IO
10/06/10 12:10
74-87-3
Chioromethanc
IOU
mg/kg
‘
10/06/10 12:10
156-59-2
cis- I ,2-Dichloroethene
10061-01-5
cis- I ,3-Dichloropropene
110-82-7
Cyclohexane
10 U
mg/kg
,O
IOU
mg/kg
i
mg/kg
I0 IO
1O
910
124-48-1
Dibromochioromethane
10 U
mg/kg
74-95-3
Dibromomethane
10 L,J,QL-I
mg/kg
75-71-8
Dichiorodifluoromethane (Freon 12)
100-41-4
Ethyl Benzene
IOU 2.2 J, Q-2
mg/kg
I°
mg/kg
I0
10/06/10 210
1006/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10
12:10 10/06/10 12:10 10/06/10 12:10 10/06/10
87-68-3
[lexachiorobutadiene
IOU
mg/kg
98-82-8
Isopropylbenzene
44 L, D-4
mg/kg
44
20 U
mg/kg
‘I1
2O 2n
10/06110 12:10
79-20-9
Methyl Acetate
591-78-6
Methyl Butyl Ketone
20 U
mg/kg
78-93-3
Methyl Ethyl Ketone
20 U
mg/kg
12:10 10/06/10 12:10 10/06/10
12:10
108-10-I
Methyl Isobutyl Ketone
20 U
mg/kg
2O
10/06/10 12:10
1634-04-4
Methyl T-Butyl Ether (MTBE)
IOU
mg/kg
in
10/06/10
108-87-2
Methylcyclohexane
20
mg/kg
1O
75-09-2
Methylene Chloride
10 U
mg/kg
10
104-51-8
n-ButyIbenzene
10 U
mg/kg
103-65-1
n-Propylbenzene
IOU
mg/kg
I0 n
95-49-8
o-Chlorotoluene
IOU
mg/kg
IO
12:10 10/06/10 2:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12.10 10/06/10
95-47-6
o-Xylene
10 U
mg/kg
I0
106-43-4
p-Chlorotol uene
10 U
mg/kg
1O
99-87-6
p-Isopropyltoluene
mg/kg
50
135-98-8
sec-Butylbenzene
mg/kg
I0
12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10
40
100610 1210
100-42-5
Page 22 of 60
Styrene
3500 10 U 40 U
EIO4009 TCLPV VOA FINAL
mg/kg
.4nalvzed .0k/hod 10/07/10 16:26 10/07/10 16:26
10/07/I 0 16:26 10/07/10 16:26 1007110 16:26 10/07/10 16:26 10.07/10 16:26 10/07/10 16:26 10/07/10 16:26 10/07/10 16:26 10/07/10 16:26 10/07/10 16:26 10/07/10 16:26 10/07/10 16:26 0/07/lU 6:26 10/07/10 16:26 10/07/10 16:26 10/07/10 1626 1007 10 16:26 10/07)10 16:26 10/07/10 16:26 10/07/10 16:26 10/07/10 16:26 10/07/10 16:26 10/07/10 16:26 10/07/10 16:26 1007:10 16:26 10/07/10 16:26 10/08/10 14:28 I 0/67’ 10 1626 I 007: U 16:26
EPA 82€/OC EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 826oc EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 10-0629, Hercu’es Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules inc Lab ID:
Sample ID: HERC04-B Station ID: HERCO4
E104009-06
Matrix: Waste
Date Collected: 9/28/10 13:50 ( IS :Vumher
4nalyte
Results Qualifiers
Units
1IRL
Prepared
inalved 10/07/10 16:26 10/07/10 16:26 10/08/10 14:28 10/07/10 16:26 10:0710 16:26 10/07/10 16:26 100710 16:26 10/07/10 16:26
EPA 8260C
10/07/10 16:26
EPA 8260C
mg/kg
50
10 U
mg/kg
10
10 U
mg/kg
10
Trichloroethene (Trichioroethylene)
10 U
mg/kg
10
75-69-4
Trichlorofluoromethane (Freon Ii)
10 U
mg/kg
10
75-01-4
Vinyl chloride
10 U
mg/kg
10
10/06/10 12:10 10106/10 12:10 tO’06110 2:10 10/06/10 12:10 100610 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10
200 U
mg/kg
200
10/06/10 1210
98-06-6
tert-Butylbenzene
10 U
mg/kg
10
127-18-4
Tetrachloroethene (Tetrachloroethylene)
10 U
mg/kg
10
108-88-3
Toluene
156-60-5
trans-1,2-Dichloroethene
10061-02-6
trans-1,3-Dichloropropene
79-01-6
3000
8k/hod EPA
8260C
EPA
8260C
EPA 8260C EPA
8260C
EPA 8260C
EPA 8260C EPA 6260C
Tentatively Identified Compounds: R4-0000
Page 23 of 60
Tentatively Identified Compounds
E104009 TCLPV VOA FINAL
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-270() DART. Id: 10-0629
Project: 10-0629, Hercules Inc
-
Reported by Kristin Trapp
TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO4-B
E104009-06
Matrix: Waste
Station ID: HERCO4 Date Collected: 9/28/10 13:50 CAS :V,unber
.4nalyte
75-35-4
1,1-Dichloroethene
Resitlis Quabjiers
Unijo
MRL
Prepared
0.10
0/13/10 1500
10/13/10 1619 10/13/10 16:19 10/13/10 16:19 10/13/10 16:19 10:13/10 16:19
0.10 U
mg/L
0.10 U
mg/L
10/13/10
mg/L
0.10
10/1310 15:00
10/13/10 1500 10/13/10 15:00 10/13)10
.4nalw:ed Ofethod
EPA 8260C
(1 ,1-Dichloroethylene) 107-06-2 106-46-7
1,2-Dichloroethane 1,4-Dichlorobenzene
0.10 U
15:01)
71-43-2
Ben2ene
0.22
mgIL
0.10
56-23-5
Carbon Tetrachloride
0.10 U
mg/L
0.10
108-90-7
Chlorobenzene
67-66-3
Chloroform Flexachiorobutadiene
87-68-3
Methyl Ethyl Kelone
78-93-3 127-18-4
Tetrachloroethene (Tetrachloroethylene)
EPA
8260C
0.10
0.10 U
mg/L
0.10
15:011 10/13)10 15:00
6:19 10/13/10 16:19
EPA 8260C
0.10
10/13/10 15.00
10113110 16:19
EPA 8260C
0.20
10:13,10 500
10/13:10 16:19
EPA 9260C
0.10
10/13/10 15:00
10/13/10 1500 111/13/10 15.00
10/13/10 16:19 10/13/10 16:19 10/13/10 16:19
0.10 U
mg/L
0.20 U
mgfL
0.10 U
mg/L
Trichloroethene (Trichloroethylene)
0.10 U
mg/L
0.10
Vinyl chloride
0.10 U
mg/L
0.10
EI04009 TCLPV VOA FINAL
EPA 8260C
mg/i..
79-01-6
24 of 60
EPA 8260C
0.10 U
75-01-4
Page
10/13/10
EPA 8260C
EPA 8260C
EPA 8260C EPA 8260C EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO5-A
E104009-07
Matrix: Waste
Station ID: I{ERCO5 Date Collected: 9/28/10 14:05 CIS .u,nher
.4nalyte
R4-7156
(m- and/or p-)Xylene
4.6 J, Q-2
mg/kg
99
630-20-6
1,1,1 ,2-Tetrachloroethane
9.9 U
mg/kg
n n
71-55-6
1,1,1 -Trichloroethane
9.9 U
mg/kg
99
1,1 ,2,2-Tetrachloroethane
9.9 U
mg/kg
n n
1,1 ,2-Trichloro- 1,2,2-Trifluoroethane (Freon 113)
9.9 U
mg/kg
n n
79-00-5
1,1 ,2-Trichloroethane
9.9 U
mg/kg
n n
75-34-3
1,1 -Dichloroethane
9.9 U, 3, QL-1
mg/kg
99
9.9 U
mg/kg
o o
9.9 U
ing/kg
99
79-34-5 -13-1
75-35-4 563-58.6
Results Qualifiers
1,1 -Dichloroethene (1 ,1-Dichloroethylene) 1,1 -Dichloropropene
Units
MRL
‘
‘‘
87-61-6
I ,2,3-Trichlorobenzene
9.9 U
mg/kg
o o
96-18-4
1 ,2,3-l’richloropropanc
9.9 U
mg/kg
99
120-82-I
1 ,2,4-Trichlorobenzene
9.9 U
mg/kg
o n
95-63-6
I ,2,4-Trimethylbenzene
4.0 J, Q-2. QR-l
mg/kg
99
96-12-8
I ,2-Dibromo-3-Chloropropane (DBCP)
20 U
mg/kg
2°
106-93-4
1 ,2-Dibromoethane (EDB)
9.9 U
mg/kg
99
95-50-I
1 ,2-Dichlorobenzene
6.3 J, Q-2
mg/kg
o o ‘‘
107-06-2
1 ,2-Dichloroethane
9.9 U
mg/kg
99
78-87-5
I ,2-Dichloropropane
9.9 U
mg/kg
o n ‘‘
108-67-8
I ,3,5-Trimethylbenzene
9.9 U
mg/kg
99
U
mg/kg
0 o ‘‘
U
mg/kg
0
mg/kg
o o
mg/kg
9
mg/kg
-o
mg/kg
99
541-73-1
1 ,3-Dichlorobenzene
142-28-9
I ,3-Dichloropropane
9.9 9.9 9.9 9.9 79
U U U
9
106-46-7
1,4-Dichlorobenzene
594-20-7
2,2-Dichloropropane
67-64-I
Acetone
71-43-2
Benzene
108-86-1
Bromobenzene
9.9 U
mg/kg
o o
74-97-5
Bromochioromethane
9.9 U, 3. QL-1
mg/kg
O 0
75-27-4
Bromodichloromethane
9.9 U
mg/kg
o n
75-25-2
Bromoform
20 U
mg/kg
2O
Page 25 of 60
14
El 04009 TCLPV VOA FINAL
0
‘‘
‘‘
Prepared
1 nalyzed
10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10
10/07/10 16:52
EPA 8260C
10/07/10 16:52 10/07/10 16:52 10/07/10 16:52 0/07/TO 16:52
EPA 8260C
10/06/10 12:10 10/06/10 12:10 10/06/10 12:10
10/07/10 16:52 10/07/10 16:52 10/07/10 16:52
EPA 8260C
EPA 8260C
10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10
10/07/10 16:52 10/07/10 16:52
EPA 8260C
12:10 0/06/It 12:10
10/07/10
16:52 10/07/10 16:52 10/07/10
16:52 10/07/TO 16:52
Method
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C
EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C
10/07/10 6:52
EPA 8260C
10/07/10 16:52
EPA 8260C
10/07/tO
EPA 8260C
16:52 10/07/10 16:52
EPA 8260C
10/07/10 16:52
EPA 8260C
10/07/10 16:52
EPA 8260C
10/07/10
EPA 8260C
16:52 10/07/10 16:52 10/07/10 16:52 10/07/10 16:52 10/07/10 16:52 10/07/10 16:52
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
10/07/10 16:52
EPA 8260C
10/07/10
EPA 8260C
16:52 10/07/10 16:52
EPA 8260C
11/8/10 9:52
0 S
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 CoLlege Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
/
Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO5-A
E104009-07
Matrix: Waste
Station ID: I-IERCO5 Date Collected: 9/28/10 14:05
c-is Vu,nher
.4 an!vie
74-83-9
Bromomethane
75-15-0
Results Qualifiers
Carbon disulfide
Units
40 U
mg’kg
3.6 3, Q-2
mg/kg
56-23-5
Carbon Tetrachloride
9.9 U
mg/kg
108-90-7
Chlorobenzene
9.9 U
mg/kg
75-00-3
Chloroethane
9.9 U
mg/kg
67-66-3
Chlorofonn
9.9 U
mg/kg
74-87-3
Chloromethane
9.9 U
mg/kg
156-59-2
cis-1,2-Dichloroethene
9.9 U
mg/kg
9.9 U
mg/kg
10061-01-5
cis-1,3-Dichloropropene
110-82-7
Cyclohexane
420
MRL
Prepared
.ina(vzed
40
10/06/10 12:10 1(1/06/10
9.9
10/06/10 1210 10/06/10 12:10 10/06/10 1210 10/06/10 iio 10/06/10 12:10 (0/06/(0 2:10 0:06/10 1210 10/06/10
10/07/10 6:52 10/07/10 1652 10/07/10 16:52 10/07/10 6:52 10/07/10 16:52 10/07/10 16:52 10/07/10 1652 10/07/10 16:52 10/0710 16:52 10/07/10 (6:52 10/07/10 1652 10/07/10 16:52 10/07/10 1652 10/07/10 16:52 10/07/10 16:52 10/07/10 1652 10/07/10 6:52 0/07/10 16:52 10/07/10 (6:52 10/07/10 6:52 10/07/10 16:52 10/07/10
99
99
mg/kg
124-48-1
Dibromochloromethane
9.9 U
mg/kg
74-95-3
Dibromomethane
9.9 U, I. QL-1
mg/kg
75-71-8
Dichlorodifluoromethane (Freon 12)
9.9 U
mg/kg
100-41-4
Ethyl Benzene
2.6 J, Q-2
mg/kg
87-68-3
Flexachlorobutadiene
9.9 U
mg/kg 28 20
98-82-8
lsopropylbenzene
28 U, D-4
mg/kg
79-20-9
Methyl Acetate
20 U
mg/kg
99
59 1-78-6
Methyl Butyl Ketone
20 U
mg/kg
20
78-93-3
Methyl Ethyl Ketone
20 U
mg/kg
20
108-10-1
Methyl Isobutyl Ketone
4.6 3, Q-2
mg/kg
20
1634-04-4
Methyl T-Butyl Ether (MTBE)
9.9 U
mg/kg
108-87-2
Methylcyclohexane
22
mg/kg
75-09-2
Methylene Chloride
9.9 U
mg/kg
104-51-8
n-Butylbenzene
9.9 U
mg/kg
103-65-1
n-Propylbenzene
9.9 U
mg/kg
95-49-8
o-Chlorotoluene
9.9 U
mg/kg
95-47-6
o-Xylene
9.9 U
mg/kg
106-43-4
p-Chlorotoluene
9.9 U
mg/kg
99-87-6
p-lsopropyltoluene
135-98-8
sec-Butylbenznne
100-42-5
Styrene
Page 26 of6O
E104009 TCLPV VOA FfNAL
3500
1W06/l0 12:10 10/00/10 1210 10/06/10 12(0 10/06/10 12:10 0/06/10 12:10 (0/06/10 2:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 (210 10/06/10 1210 10/06/10 10/06/10 1210 0/06/10
99
mg/kg
9.9 U
mg/kg
9
40 U
mg/kg
40
0/06/10 12:10 10/06/It 2:10 (0/06/10 12:10 0/06/10 1210 (0/06/10 120 10/06/10 (2 0 10/06/10 20
10/07/10 6:52 10/07/10 6:52 (0:07/10 1652 10/07/JO 1652 10107/10 16:52 10/07/10 6:52 10/00/10 1454 0/07/10 652 10/07/10 16:52
,lfetkod
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA
8260C
EPA 8260C EPA
826CC
EPA 8260C EPA 826CC EPA 8260C EPA 8260C
EPA 8260C
EPA 826CC EPA 8260C EPA
826CC
EPA 826CC EPA
826CC
EPA 8260C
EPA 826CC EPA 8260C EPA 826CC EPA 826CC EPA 826CC EPA 8260C EPA 826CC EPA 8260C
11/8/10
9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO5-A Station ID: HERCO5
E104009-07
Matrix: Waste
Date Collected: 9/28/10 14:05 CAS .Vu,nber
4nalyte
Resulls Qualifiers
Unâs
MRL
Prepared
mg/kg
10/06110
mg/kg
.lnalyzed Method
10/06/ID 12:10
10/07/10 16:52 10/07/10 16:52
EPA 8260C
10/06/10 12:10
10/08/10 4:54
EPA 8260C
mg/lcg
10/06/10 12:10
10/07/10 16:52
EPA 8260C
mg/kg
10/06/10 12:10
10/07/10 6:52
EPA 8260C
9.9 U
mg/kg
10/06/10 12:10
10/07/10
EPA 8260C
Trichlorofluoromethane (Freon 11)
9.9 U
mg/kg
10/06/10
10/07/10
Vinyl chloride
9.9 U
mg/kg
12:10 10/06/10 12:10
16:52 10/07/10 16:52
200 U
mg/kg
10/06/10
100710
20
652
98-06-6
tert-Butylbenzene
127-18-4
Tetrachloroethene (Tetrachloroethylene)
108-88-3
Toluene
156-60-5
trans-1,2-Dichloroethene
9.9 C
10061-02-6
trans-1,3-Dichloropropene
9.9 U
79-01-6
Trichloroethene (Trichloroethylene)
75-69-4 75-01-4
9.9 U
9.9 U 5300
mg/kg
1210
50
16:52
EPA 8260C
EPA
8260C
EPAS26OC
Tentatively Identified Compounds: R4-0000
Page 27 of 60
Tentatively Identified Compounds
El 04009 TCLPV VOA FINAL
200
EPA 8260C
11/8/10 9:52
0 ST
,7
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700
\ ‘
DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO5-A
E104009-07
Matrix: Waste
Station ID: HERCO5 Date Collected: 9/28/10 14:05 ( IS
MRL
Prepared
mg/’..
0.10
I0/I3/l0
010 U
mg/L
0.10
1,4-Dichlorobenzene
0.10 U
mg/L
0.10
Benzene
0.23
mg/L
0.10
0.10 U
mgIL
0.10
Results Qualifiers
Vu,nher
.4nolyte
75-35-4
0.10 U
107-06-2
1,1-Dichloroethene (1,1 -Dichloroethylene) 1,2-Dichloroethane
106-46-7 71-43-2 56-23-5 108-90-7
Carbon Tetrachloride Chlorohenzene
Units
‘ng/’
0.10
1500 10/13/10 15:00
0.10
10/13/10 1500
67-66-3
Chloroform
0.10 U
87-68-3
Hexachlorobutadiene
0.10 U
nlg/L
0.10
78-93-3
Methyl Ethyl Ketone
0.20 U
mg/L
0.20
127-18-4
Tetrachloroethene (Tetrachloroethylene)
0.10 U
mg/L
0.10
75-01-4
Page 28 ot’60
Trichloroethene (Trichloroe[hylenel Vinyl chloride
E104009 TCLPV VOA FINAL
10/13/Ill
0.10 U
mg/L
79-01-6
10/13/10 15:00 10/13/tO 1500 10/13/10 15:00 10/13/10 15:00
I0/l3/I0 1500 10/13/10 15:00
.Inalyzed Method l0/l3/I0
1645
EPA 8260C
10/13/10 16:45 10/13/10 1645 10/13/10 1645 10/13/10 645 10/13/Ill 1645 10/13/10 16:45
EPA826OC
Ill/li/Ill
1645 10/IllS 1645 10/13/10 16.45 10/13/10 645
0.10 U
mg/L
0.10
IO/13.’IO
0.10 U
mgJL
0.10
10/13/10
10/13/10
15:00
16:45
EPA 8260C EPA 8260C EPA 8260C EPA
8260C
EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 0260C
EPA 8260C
11/8/10 9:52
C UNiTED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 10-0629, Hercules Inc
-
Reported by Kristin Trapp
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO6-B
E104009-08
Matrix: Waste
Station ID: HERCO6 Date Collected: 9/28/10 14:55 C4S Number
.4nalyfr
Resulls Qualifiers
R4-7156
(m- and/or p-)Xylenc
630-20-6
1,1,1 ,2-Tetrachloroethane
LJnit
MRL
Prepared
,4aated
10/06/10 12:10 10/06/10 12:10
12:10
16/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12
10/06/10 12:10
10/08/10 16:12
EPA 8260C
1006/10
10/08/10 16:12
EPA 8260C
10/08/10 16:12
EPA 8260C
1.0 U
mg/kg
1•
U
mg/kg
n
1.0
‘•‘‘
71-55-6
1,1,1 -Trichloroethane
1.0 U
mg/kg
I 0
79-34-5
1,1 ,2,2-Tetrachloroethane
1.0 U
mg/kg
1 A
76-13-1
1,1 ,2-Trichloro- 1 ,2,2-Trifluoroethane (Freon 113)
1.0 U
mg/kg
O
79-00-5
1,1 ,2-Trichloroethane
1.0 U
mg/kg
75-34—3
1,1 -Dichloroethane
75-35-4 563-58-6
1 ,1-Dichloroethene (1 ,1-Dichloroethylene) 1,1 -Dichloropropene
•
1
A
mg/kg
I 0
1.0 U
mg/kg
1 A
1.0 U
mg/kg
1 0
1.0 U, 3, QL- I
7-61-6
1 ,2,3-Trichlorobenzene
1.0 U
mg/kg
1 A
96-18-4
1 ,2,3-Trichloropropane
1.0 U
mg/kg
1 0
120-82-1
1 ,2,4-Trichlorobenzene
1.0 U
mg/kg
1 A
0.40 J, Q-2
mg/kg
i n
U
mg/kg
‘I A
95-63-6
I ,2,4-Trimethylbenzcne
96-12-8
I ,2-Dibromo-3-Chloropropane (DBCP)
2.0
106-93-4
1,2-Dibromoethane (EDB)
1.0 U
mg/kg
1 0
95-50-1
1 ,2-Dichlorobenzene
1.0 U
mg/kg
‘•‘-‘
1
107-06-2
1 ,2-Dichloroethane
1.0 U
mg/kg
1 0
78-87-5
I ,2-Dichloropropane
1.0 U
mg/kg
1 A
108-67-8
I ,3,5-Tnmethylbenzene
1.0 U
mg/kg
1 0
541-73-1
I ,3-Dichlorobenzene
1.0 U
mg/kg
I A
142-28-9
1 ,3-Dichloropropane
1.0 U
mg/kg
1 0
106-46-7
1 ,4-Dichtorobenzene
1.0 U
mg/kg
1 A
594-20-7
2,2-Dichioropropane
1.0 U
mg/kg
1 A
67-64-1
Acetone
8.0 U
mg/kg
O A °‘
71-43-2
Benzene
1.0 U
mg/kg
1 0 I A
108-86-1
Bromobenzene
1.0 U
mg/kg
74-97-5
Bromochioromethane
1.0 U, 3, QL-1
mg/kg
O
75-27-4
Bromodichloromethane
1.0 U
mg/kg
1 A
75-25-2
Bromoform
2.0 U
mg/kg
20
Page 29 of 60
El 04009 TCLPV VOA FINAL
10/06/10
12:10 10/06/10 12:10 10/06/10
12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10
10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10
10/08/10 16:12 10/08/10 16:12 10/08/ 10 16:12 10/08/10 16:12 10/08/10 16:12
10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12
10/06/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10
16:12
tfeihod
EPA 8260C
EPA
8260C
EPA 8260C
EPA 8260C EPA
8260C
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D ART. Id: 10-0629 Reported by Kristin Trapp
Project: 10-0629, Hercules Inc
-
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO6-B
E104009-08
Matrix: Waste
Station ID: HERCO6 Date Collected: 9/28/10 14:55 C4S Number
.4nalyie
74-83-9
Bromomethane
75-15-0
Carbon disulfide
Results Qualifiers 40 U
0.42 J, Q-2
Units
MRL
Prepared
mg/kg
40
mg/kg
1.0
10106/10 12:10 10/06/10 12:0 10/06/10 12:10 10/06/10 12:10
56-23-5
Carbon Tetrachloride
1.0 U
mg/kg
1.0
108-90-7
Chlorobenzene
1.0 U
mg/kg
1.0
75-00-3
Chloroethane
1.0 U
mg/kg
1.0
67-66-3
Chloroform
1.0 U
mg/kg
1.0
74-87-3
Chloromethane
1.0 U
mg/kg
1.0
156-59-2
cis-1,2-Dichloroethene
1.0 U
mg/kg
1.0
10061-01-5
cis-I,3-Dichloropropene
1.0 U
mg/kg
1.0
110-82-7
Cyclohexane
1.0 U
mg/kg
1.0
124-48-1
Dibromochloromethane
1.0 U
mg/kg
74-95-3
Dibromomethane
1.0 U
mg/kg
1.0
1.0
75-71-8
Dichlorodifluoromethanc (Freon 12)
1.0 U
mg/kg
1.0
100-41-4
Ethyl Benzene
1.0 U
mg/kg
1.0
87-68-3
1-lexachlorobutadiene
1.0 U
mg/kg
1.0
98-82-8
Isopropylbenzene
1.0 U
mg/kg
1.0
79-20-9
Methyl Acetate
2.0 U
mg/kg
2.0
591 -78-6
Methyl Butyl Ketone
2.0 U
mg/kg
2.0
78-93-3
Methyl Ethyl Ketone
2.0 U
mg/kg
2.0 2.0 1.0
108-10-1
Methyl Jsobutyl Ketone
2.0 U
mg/kg
1634-04-4
Methyl T-Butyl Ether (MTBE)
1.0 U
mg/kg
108-87-2
Methylcyclohexane
mg/kg
1.0
75-09-2
Methylene Chloride
1.0 U
mg/kg
1.0
104-51-8
n-Butylbenzene
1.0 U
mg/kg
1.0
103-65-I
n-Propylbenzene
1.0 U
mg/kg
1.0
95-49-8
o-Chlorotoluene
1 .0 U
mg/lcg
1.0
95-47-6
o-Xylene
1.0 U
mg/kg
1.0
106-43-4
p-Chlorotoluene
1.0 U
mg/kg
1.0
99-87-6
p-lsopropyltoluene
38
mg/kg
1.0
135-98-8
sec-Butylbenzene
1.0 U
mg/kg
1.0
100-42-5
Page 30 of6O
Styrene
0.24 J, Q-2
40 U
E104009 TCLPV VOA FINAL
mg/kg
40
10/06/10
12:10 10/06/10 12:10 10/06/10 12:10 10/06,10 12:10 10/06/10
12:10 10/06/10 12:10 10/06/10 (2:10
10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10
.•lnalyzed ,Ofethod 10/08/10 16:12 0/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 (6:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12
10/08/10 6:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10
12:10
16:12
10/06/10 12:10 10/06/10 12:10 10/06/1(1 12.10 10/06/10 12:10 10/06/10 12:10
10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08110 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 (0/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12
10/06/10 12:10 (0/06/10 12:10 10/06/10 12:10 10/06/10 2:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 0/06/10 12:10 10/06/10 12:10 10/06/10 (2:10
10/06/10 12:10
EPA 8260C
EPA 8260C EPA 8260C
EPA826OC EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA
8260C
EPA 8260C EPA
8260C
EPA 8260C
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C
EPA826OC EPA
8260C
EPA 8260C EPA
8260C
EPA 8260C
EPA 8260C EPA
8260C
EPA 8260C
11/8/10
9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO6-B Station ID: HERC06
E104009-08
Matrix: Waste
Date Collected: 9/28/10 14:55 C.4S Niunber
.4nalyte
Results Qualifiers
98-06-6
tert-Butylbenzene
127-18-4
Tetrachloroethene (Tetrachloroethylene)
108-88-3
Toluene
156-60-5
trans-i ,2-Dichloroethene
1.0
10061-02-6
trans-I.3-Dichloropropene
79-01-6
Trichloroethene (Trichloroethylene) 11)
75-01-4
Vinyl chloride
:IIRL
Prepared 10/OMIt 12:10 10/06/10 12:10
10,08/10 16:12 10/08/10 16:12
10/06/10
100710
12:10 10/06/10 12:10
14:16 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12
EPA 8260C
10/08/10 1612
EPA 8260C
1.0 U
mg/kg
1.0
1.0 U
mg/kg
1.0
mg/kg
10
U
mg/kg
1 .0
1.0 U
mg/kg
1.0
1.0 U
mg/kg
1.0
1.0 U
mg/kg
1.0 U
mg/kg
1.0
12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10
20 U
mg/kg
20
10/06/10 1210
280
(Freon
Units
10/06/10
.lnalvzed ,lIethod EPA 8260C EPA 8260C EPA 826gC EPA 8260C EPA 8260C EPA 8260C EPA 8260C
Tentatively Identified Compounds: R4-0000
Page 31 of6O
Tentatively Identified Compounds
E104009 TCLPV VOA FINAL
11/8/10 9:52
0
C
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Inc Reported by Kristin Trapp Hercules 10-0629, Project: -
TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO6-B
E104009-08
Matrix: Waste
Station ID: HERCO6 Date Collected: 9/28/10 14:55 C4S Vuinhcr
.4naiyte
75-35-4
1,1-Dichloroethenc (1,1-Dichloroethylene):
107-06-2 106-46-7
Results Quail/lees
1,2-Dichloroethane: l,4-Dichlorobenzene:
71-43-2
Benzene:
56-23-5
Carbon Tetrachioride:
NA-S \A-5 NA5
Linus
MRL
0.00050 000050 0.00050
NA-5
0.00050
NA-5
0.00050
108-90-7
Chlorobenzene:
NA-5
0.00050
67-66-3
Chloroform:
NA-5
0.00050
87-68-3
Hexachlorobutadiene:
78-93-3
Methyl Ethyl Ketone:
10/13/10
10/13/10
EPA 8260C
10/13/10
10/13/10 5:00
EPA 8260C
15:01) 10/13/10
15:00 10/13/10 500
1013/10
15:00 10/13/10
10/13/10
500 10/13/10
15:00 10/13/10 15:00
15:00 0/13/10 15:00
10/13/10
10/13/10
EPA 8260C
EPA 8260C
NA-5
10/13/10 15:00
1500 10/13/10 15:00
1013/10
10/13/10
500 10/13/10 15:00
1500 10/13/10 15:00
0.00050
79-01-6
NA-S
0.00050
75-01-4
Vinyl chloride:
NA-5
0.00050
EPA 8260C
EPA 8260C
15:00
0.00 10
NA-5
8260C
10/13/10
0.00050
Trichloroethene(Trichloroethylene):
EPA
EPA 8260C
5:00
NA-S
Tetrachloroethene (Tetrachioroethylene):
El04009 TCLPV VOA FINAL
..tnuly;ed .lfethod
0/13/10 15011 1013/10 15:01)
127-18-4
Page 32 of 60
Prepared
1500 10/13/10
EPA 8260C
EPA 8260C EPA 8260C EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science arid Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO7-B Station ID: HERCO7
E104009-09
Matrix: Waste
Date Collected: 9/28/10 15:25 C4S Vuinber
.4nalvre
Results Qualifiers
R4-7156
(m- and/or p-)Xylene
63 0-20-6
1,1 I ,2-Tetrachloroethane
71-55-6
,
1,1 -Trichloroethane
Units
IJRL
2.9
mg/kg
2.4 U
mg/kg
24
2.4 U
mg/kg
24
79-34-5
I ,I,2,2-Tetrachloroethane
2.4 U
mg/kg
A
76-13-1
1,1 ,2-Trichloro- I ,2,2-Trifluoroethane (Freon 113)
2.4 U
mg/kg
) A
79-00-5
1,1 ,2-Trichloroethane
2.4 U
mg/kg
2•A
75-34-3
1,1 -Dichloroethane
2.4 U,J,QL-l
mg/kg
2 •4
75-35-4
1,1 -Dichloroethene (1 ,1-Dichloroethylene)
2.4 U
mg/kg
2
563-58-6
1,1 -Die hioropropene
2.4 LT
mg/kg
24
87-61-6
I ,2,3-Trichlorobenzene
2.4 U
mg/kg
‘1 A
96-18-4
1 .2,3-Trichloropropane
2.4 U
mg/kg
24
120-82-1
1,2,4-Trichlorobenzene
2.4 U
mg/kg
24
95-63-6
1 ,2,4-Trimethylbenzene
1.3 J,Q-2
mg/kg
2 •4
96-12-8
I ,2-Dibromo-3-Chloropropane (DBCP)
4.9 U
mg/kg
A
106-93-4
I ,2-Dibromoethane (EDB)
2.4 U
mg/kg
i A
95-50-1
1 ,2-Dichlorobenzene
2.4 U
mg/kg
1 A
107-06-2
I ,2-Dichloroethane
2.4 U
mg/kg
24
78-87-5
I ,2-Dichloropropane
2.4 U
mg/kg
A
108-67-8
I ,3,5-Trimethylbenzene
2.4 U
mg/kg
24
541-73-1
1 ,3-Dichlorobenzene
2.4 U
mg/kg
) A
142-28-9
1 ,3-Dichloropropane
2.4 U
mg/kg
1 A
106-46-7
1 ,4-Dichlorobenzene
2.4 U
mg/kg
‘I A
594-20-7
2,2-Dichloropropane
2.4 U
mg/kg
2•4
67-64-1
Acetone
19 U
mg/kg
in ‘
71-43-2
Benzene
2.4 U
mg/kg
24
108-86-1
Bromobenzene
2.4 U
mg/kg
‘) A
74-97-5
Bromochioromethane
2.4 U, J, QL-1
mg/kg
24
75-27-4
Bromodichloromethane
2,4 U
mg/kg
‘1 A
75-25-2
Bromoform
4.9 U
mg/kg
0
Page 33 of 60
E104009 TCLPV VOA FINAL
A
•
•
•
4
Prepared
.1navzed Method 10/08/10 17:04 10/08/10
l0106/l0 12:10 0/06/10 12:10 10/06/jO 12:10 IO/06/lO 12:10 0/06/jO 12:10
10/08/10 17:04 10/08/10 17:04
10/06/ID 12:10 I0/06/I0 12:10 10/06/10 12:10
104)8/10 17:04 0/08/10 17:04 10/08/10 17:04
I0!06/l0 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/b 12:10 10/06/10 12.10 10/06/10 12:10 10/06/10 I2bO 0/06/10 12:10 0/06/10 12:10 10/06/10 I2:10 10/06/10 12:10
10/08/10 7:04 0/08/10 17:04 0/06/0 7:04 10/08/10 17:04 10/08/10 17:04 10/08/10 17:04 10/08/10 7:04 10/08/10 17:04 10/00/10 17:04 10/08/10 17:04 800/b 7:04 l0/08)10 17:04 0/08/IC 7.04 10/08/10 17:04 0/08/10 7:04 I0/08/l0 17.04 10/06/10 7:04 0/08/10 17:04 lO/OS/lO 17:04 I 0/08/10 17:04 10.08/10
17:04
l0/08/lO
7:04
17:04
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 6260C
EPA 8260C
EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
11/8/10
9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO7-B
E104009-09
Matrix: Waste
Station ID: IIERCO7 Date Collected: 9/28/10 15:25
C,ts Vu,nber
74-83-9
Residis Quah:fiers
.4 no!vie
Bromomethane
Units
1fRL
mg/kg
97 U
mg/kg
2.4
75-15-0
Carbon disulfide
56-23-5
Carbon Tetraehloride
2.4 U
mg/kg
2.4
108-90-7
Chlorobenzene
2.4 C
mg/kg
2.4
75-00-3
Chloroethane
2.4 U
mg/kg
2.4
67-66-3
Chloroform
2.4 U
mg/kg
2.4
74-87-3
C’hloromethane
2.4 U
mg/kg
2.4
156-59-2
0.78 J, Q-2
cis-1,2-Dichloroethene
2.4 U
mg/kg
2.4 2.4
10061-01-5
cis-1,3-Dichloropropene
2.4 U
mg/kg
110-82-7
Cyclohexane
2.4
U
mg/kg
2.4
124-48-I
Dibromochloromethane
2.4 U
mg/kg
2.4
74-95-3
Dibromomethane
2.4 U
mg/kg
2.4
75-71-8
Dichlorodifluoromethane (Freon 12)
2.4 U
100-41-4
Ethyl Benzene
87-68-3
Ilexachlorobutadiene
mg/kg
2.4
mg/kg
2.4
2.4 U
mg/kg
2.4
mg/kg
2.4
0.92 J, Q-2
98-82-8
lsopropylbenzene
2.4 U
79-20-9
Methyl Acetate
4.9 U
mg/kg
591-78-6
Methyl Butyl Ketone
4,9 U
mg/kg
78-93-3
Methyl Ethyl Ketone
4.9 U
mg/kg
108-10-I
Methyl lsobutyl Ketone
4.9 U
mg/kg
1634-04-4
Methyl T-Butyl Ether (MTRE)
2.4 U
mg/kg
2.4
108-87-2
Methylcyclohexane
2.4 U
mg/kg
2.4
75-09-2
Methylene Chloride
2.4 U
mg kg
2.4
104-51-8
n.Butylbenzene
2.4 U
mg/kg
2.4 2.4 2.4
.
103-65-1
n-Propylbenzene
2.4 U
mgkg
95-49-8
o-Chlorotoluene
2.4 U
mg/kg mg/kg
2.4
mg/kg
2.4
95-47-6
o-Xylene
106-43-4
p-Chlorotoluene
2.4 1/
99-87-6
p-lsopropylloluene
170
mg kg
2.4
2.4 V
mg/kg
2.4
97 U
mg/kg
13 5-98-8
sec-Butylbenzene
100-42-5
Styrene
Page 34 of 60
0.73 J, Q-2
El04009 TCLPV VOA FINAL
Prepared
.lna!w;ed ,llethod
10/06/10 12:10 0/06/10 12:10 ‘°‘°°° 12:10 10/06/10 12:])) 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 lO;06’IO 12:10 10/06/10 12:10 10.06110 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 (2:10 10/06/10 12:10 (0/06/10 12:10 10/06/10 12:18 10/06/10 12:10 (0/06/10 12:10 10/06/10 12:10 (0/06/10 2.10
10/08/10 17:04 10/08/10 17:04 (0/08/JO 17:04 10/08/10 7:04 10/08/10 17:04 1(1/08,10 17:04 10:08.10
0/06/10
18.08.10 (7:04
EPA 8260C
10,08/10
EPA 8260C
12:10 (1,06/10 12:10 10/06/10 12:10 10/06’lO 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/lU 2:10 10/06/10 12:10
(7:04
1(1/00/10 17.04 1006/10 17:04 10/08/10 17:04 10:08/10 17.03 10/0810 17:04 10,00/10 (7:04 10/08/10 17:04 10/08/10 (7:04 10/08/10 17:04 10/08/10 7:04 (0/08/10 (7:04 10/08/10 17:04 10/08/10 17:04 10/08/10 17:04 10/08/11> 17:04
17:04
(0:08/10 17:04 (0,08/10 17:04 10/081(0 17:04
10/08110 (704 10.08.10 17.04
10/08/10 17:04 10/08/10 (7:04
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C’ EPA
8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C
EPA
8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C
11/8/10 9:52
0
0 is.’
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700
41. fr//
DART. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO7-B
Matrix: Waste
Station ID: HERCO7 Date Collected:
E104009-09
9/28/10 15:25
C4S Nu,nher
.4nalyte
98-06-6
tert-Butylbenzene
2.4 U
127-18-4
Tetrachioroethene (Tetrachloroethylene)
2.4
Results Qualifiers
Units
MRL
Prepared
mg/kg
2.4
U
mg/kg
2.4 2.4
10/08/10 704 10/08/10 17:04 10/07/b 13:51 10/08/10 17:04 l0/08/l0 I7•04 10/08/10 17:04 0/08/10 I7:04 10/08/10 17:04
10/08/tO 17:04
108-88-3
Toluene
156-60-5
trans-1,2-Dichloroethene
2.4 U
mg/kg
10061-02-6
trans-1,3-Dichloropropene
2.4 U
mg/kg
2.4
79-01-6
Trichloroethene (Trichloroethylene)
2.4 U
mg/kg
2.4
75-69-4
Trichlorofluoromethane (Freon Ii)
2.4 U
mg/kg
2.4
75-01-4
Vinyl chloride
2.4 U
mg/kg
2.4
10/06/10 12•l0 10/06/10 12:10 l0/06/1O 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10
50 U
mg/kg
50
l0/06/10 12:10
1400
mg/kg
.
lnalrzed ,lfethod EPA 8260C EPA
8260C
EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
Tentatively Identified Compounds: R4-0000
Page 35 of6O
Tentatively Identified Compounds
E104009 TCLPV VOA FINAL
EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project. 10-0629, Hercules Inc Reported by Kristin Trapp -
TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO7-B
E104009-09
Matrix: Waste
Station ID: HERCO7 Date Collected: 9/28/10 15:25 C4S Nina her
.4nalye
75-35-4
1,1-Dichloroethene (1,1-Dichioroethylene):
Retails Qualifiers
NA5
Linus
MRL
0.00050
107-06-2
1,2-Dichloroethane:
NA-5
0.00050
106-46-7
l,4-Dichlorobenzene:
NA-S
0.00050
71-43-2
Benzene:
NA-S
0.00050
56-23-5
Carbon Tetrachloride:
NA-5
0.00050
108-90-7
Chlorobenzene:
NA-S
000050
67-66-3
Chloroform:
NA-S
0.00050
87-68-3
Hexachlorobutadiene:
NA-S
0,00050
78-93-3
Methyl Ethyl Ketone:
NA-5
0.0010
127-18-4
Tetrachloroethene (Tetrachioroethylene):
\A-5
0.00050
79-01-6
Trichloroethene (Trichloroethylene):
NA-5
0.00050
75-01-4
Vinyl chloride:
Page 36 of6O
NA-S
E104009 TCLPV VOA FINAL
0.00050
Prepared
laalvzed Method
10/13/10 15:00 10/13/10 15:01) 10/13/10 1500 0/13/10 15:00 10/13/10 15:00
10/13/10
15:00
EPA 8260C
10/13/10 15:00 10/13/10 15:00 10/13/10 15:00 10/13/10 15:00
EPA 8260C
10/13/10
10/13/10
15:00 10/13/10 15:00 10/13/10 15:00 10/13/10 15:00 10/13/It 15:01) 10/13/10 5:00 10/13/10 15:00
1500 10/13/10 15:00 10/13/10 15:00 10/13/10 15:00
10/13/10 15:00 10/13/10 15:00 10/13/10 15:00
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 0260C
EPA 8260C
11/8/10 9:52
0
C)
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO8
E104009-10
Matrix: Waste
Station ID: HERCO8 Date Collected: 9/29/10 8:50 C/IS Vu,nher
.dnalyte
R4-7156
(m- and/or p-)Xylene
630-20-6
Results Qualifiers
Units
1fRL
1.0 U
mg/kg
1 0
1,1,1 ,2-Tetrachloroethane
1.0 U
mg/kg
1 A ‘•°
71-55-6
1,1,1 -Trichloroethane
1.0 U
mg/kg
1 0
79-34-5
1,1 ,2,2-Tetrachloroethane
1.0 U
mg/kg
i n 1.
76-13-1
1 I ,2-Trichloro- I ,2,2-Trifluoroethane (Freon 113)
1.0 U
mg/kg
I
79-00-5
1,1 ,2-Trichloroethane
1.0 U
mg/kg
1
75-
1,1 -Dichloroethane
1.0 U, J, QL-1
mg/kg
I n
75-35-4
1,1 -Dichloroethene (1,1-Dichioroethylene)
1.0 (S
mg/kg
‘•
563-58-6
1,1 -Dichloropropene
1.0 U
mg/kg
1 0
87-61-6
1 ,2,3-Trichlorobenzene
1.0 U
mg/kg
A
96-18-4
1 ,2,3-Trichloropropane
1.0 U
mg/kg
I 0
120-82-1
1 ,2,4-Trichlorobenzene
1.0 (5
mg/kg
i
n
95-63-6
I ,2,4-Trimethylbenzene
1.0 U
mg/kg
1
A
96-12-8
1 ,2-Dibromo-3-Chloropropane (DBCP)
2.0 U
mg/kg
n
106-93-4
1,2-Dibromoethane (EDB)
1.0 U
mg/kg
n
95-50-1
I ,2-Dichlorobenzene
1.0 (5
mg/kg
1 A 1.1)
107-06-2
1 ,2-Dichloroethane
1.0 U
mg/kg
I 0
78-87-5
1 ,2-Dichloropropane
1.0 U
mg/kg
1
108-67-8
I ,3,5-Trimethylbenzene
1.0 U
mg/kg
1 0
541-73-I
1 ,3-Dichlorobenzene
1.0 U
mg/kg
1
142-28-9
1 ,3-Dichloropropane
1.0 U
mg/kg
1 0 1 0
A
A
106-46-7
1 ,4-Dichlorobenzene
1.0 U
mg/kg
594-20-7
2,2-Dichloropropane
1.0 U
mg/kg
O
67-64-1
Acetone
8.0 U
mg/kg
0 A
71-43-2
Benzene
1.0 U
mg/kg
i
n
108-86-1
Bromobenzene
1.0 U
mg/kg
1 0
74-97-5
Bromochioromethane
1.0 U, J. QL-1
mg/kg
1
75-27-4
Bromodichloromethane
1.0 U
mg/kg
1 0
75-25-2
Bromoform
2.0 U
mg/kg
2 0
Page 37 of 60
E104009 TCLPV VOA FINAL
A
Prepured
.Inuly.ed Method
10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10
10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20
10/06/10 12:10 10/06/10 12:10 10/06/10 12:10
10/08/10 15:20 10/08/10 15:20 10/08/10 15:20
EPA 8260C
10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10106/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10
10/08/10 15:20 10/08/10 15:20 10/08/10 5:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/00/10 15:20
EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
11/8/10 9:52
0
0
UN ITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 104)629, Hercules Inc Lab ID:
Sample ID: HERCO8
E104009-1O
Matrix: Waste
Station ID: HERCO8 Date Collected: 9/29/10 8:50 U IS .Vuinher
.4nalyte
74-83-9
Bromomethane
75-15-0 56-23-5
Results Qualifiers
Units
MRL
Prepared 10/06/10
10/06/10
12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12.10 10/06/10
15:20 10/08)10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 1520 10/08/10
40 U
mg/kg
40
C’arbon disulfide
1.0 U
mg/kg
1.0
Carbon
1.0 U
mg/kg
Tetrachloride
108-90-7
Chlorobcnzene
1.0 U
mg/kg
1.0
75-00-3
Chloroethane
1.0 U
mg/kg
1.0
67-66-3
Chloroform
1.0 U
mg/kg
1.0 1.0 1.0
74-87-3
Chloromethane
1.0 U
mg/kg
156-59-2
cis-1,2-Dichloroethene
1.0 U
mg/kg
10061-01-5
cis-1,3-Dichloropropene
1.0 U
mg/kg
10
110-82-7
Cyclohexane
1.0 C
mg/kg
1.0
1.0 U
mg/kg
1.0
1.0 L
mg/kg
1.0
1.0 U
mg/kg
1.0 1.0
124-48-1
Dibromochloromethane
74-95-3
Dibromomethane
75-71-8
Dichlorodifluoromethane (Freon
12)
100-41-4
Ethyl Benzene
1.0 U
mg/kg
87-68-3
1-lexachlorobutadiene
1.0 U
mg/kg
1.0 1.0 2.0
98-82-8
lsopropylbenzene
1.0 U
mg/kg
79-20-9
Methyl
2.0 U
mg/kg
Acetate
591-78-6
Methyl Butyl Ketone
2.0 U
mg/kg
2.0
78-93-3
Methyl Ethyl Ketone
2.0 U
mg/kg
2.0
108-10-I
Methyl Isobutyl Ketone
2.0 U
mg/kg
2.0
1634-04-4
Methyl T-ButyI Ether (M3
1.0 U
mg/kg
1.0
108-87-2 75-09-2
BE)
Methylcyclohexane Methylene Chloride
1.0 C
mg/kg
1.0
1.0 U
mg/kg
1.0
12:10
15:20
10/06)10 12:10 10/06)10 12:10 10/06/10 12:10 0/06/10
10/08)10 15:20 1008.10 15:20 10/08/10 15:20 1008/10
12:10
15:20
10/06/10 12:10 10/06/10 12:10 10/06111) 12:10 10/06/10
10/08/10 5:20 10/08/10 15:20 11800/10 15.20 1008/10
12:10
15:20
18/06)10 12:10 10/06/10 12:10 10/06/10 12.10 18.06110 12:10 10/06)10 12:10 10/06/10
10)08/10 15:20 10/08/10 15:20 l0/08i10 15:20 100810
5:20
10)08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 1520 10/08/10 5:20
103-65-1
n-Propylbenzene
1.0 U
mg/kg
1.0
95-49-8
o-Chlorotoluerie
1.0 U
mg/kg
1.0
95-47-6
o-Xylene
1.0 U
mg/kg
1.0
106-43-4
p-Chlorotoluene
1.0 Ii
mg/kg
1.0
99-87-6
p-lsopropyltoluene
2.6
mg/kg
1.0
sec-Butylbenzene
1.0 U
mg/kg
1.0 40
10:06/10 12:10
135-98-8 100-42-5
Page 38 of6O
n-Butylbenzene
1.0 U
mg/kg
1.0
40 U
Styrene
E104009 TCLPV VOA FINAL
mg/kg
15.20
10/08/10 15:20 1008/10
12.10
10/06/10 12:1(1 10/06/10 1210 0/06/IS 12:10 10/06/10 12:10 10/06/10 12:111 10/06/10 12:10 10/06/10 12:10
104-51-8
.lnulvzed Method EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA
8260C
EPA 8260C EPA
8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C I/PA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
11/8/10 9:52
0
0 6
UNTTED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700
f1
D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO8 Station ID: HERCO8
E104009-10
Matrix: Waste
Date Collected: 9/29/10 8:50 C4S Number
4nalye
Results Qualifiers
98-06-6
tert-Butylbenzene
127-18-4
Un its
MRL
Prepared
1.0
10/06/10 12:10
15:20
10/06/10
10/08/10 15:20 10/08/10 15:20 10108/10 15:20 1008 0
1.0 U
mg/kg
Tetrachloroethene (Tetrachloroethylene)
1.0 U
mg/kg
1.0
108-88-3
Toluene
34
mg/kg
1.0
156-60-5
trans-1,2-Dichloroethene
1.0 U
mg/kg
1.0
10061-02-6
trans-1.3-Dichloropropene
1.0 U
mg/kg
1.0
79-01-6
Trichloroethene (Trichloroethylene)
1.0 U
mg/kg
75-69-4
Triehlorofluoromethane (Freon 11)
1.0 U
mg/kg
1.0
75-01 -4
Vinyl chloride
1.0 U
mg/kg
1.0
20 U
mg/kg
20
1.0
12:10 10/06/10 1210 10/06/10 12:10 I0,’06.’l0 12:10
.4nav;ed Method 10/08/10
5:20
10/06/10 12:10 10:06/10 12:10 10/08/10 12:10
10/08/10 15:20 10/08/10 15:20 10/08/10 15:20
10/06/10
10/08/10
210
520
EPAN26OC
EPA 8260C EPA
8260C
EPA 8260C EPA
8260C
EPA 8260C EPA 8260C EPA 8260C
Tentatively Identified Compounds: R4-0000
Page 39 of 60
Tentatively Identified Compounds
E104009 TCLPV VOA FINAL
8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 1 0-0629, Hercules Inc Reported by Kristin Trapp -
TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO8
E104009-10
Matrix: Waste
Station ID: HERCO8 Date Collected: 9/29/10 8:50
c4s Results Qualifiers
Units
4IRL
Nwnher
.4nalyte
75-35-4
1,1 -Dichloroethene (11 -Dichloroethylene):
NA-5
0.00050
107-06-2
1,2-Dichloroethane:
NA-5
0,00050
106-46-7
l,4-Diclilorobcnzcne:
NA-5
0.00050
71-43-2
Benzene:
\A-5
0.00050
56-23-5
Carbon Tetrachioride:
NA-5
0.00050
108-90-7
Chlnrobenzene:
NA-S
0.00050
67-66-3
Chloroform:
NA-S
0.00050
87-68-3
Flexachlorobutadiene:
NA-s
0.00050
78-93-3
Methyl Ethyl Ketone:
NA-5
0.0010
127-18-4
Tetrachloroethene (Tetrachloroethylene):
NA-S
0.00050
79-01-6
Trichloroethene (Trichioroethylene):
NA-5
0.00050
75-01-4
Page 40 of6O
Vinyl chloride:
NA-5
E104009 TCLPV VOA FINAL
0.00050
Prepared 10/13/10 1500 10/13/Il) 1500 1011310 5:00 10/13/10 5.00 10/13/10 1500 10/13/10 15:00 10/13/JO 1500 10/13/10 15:00 10/13/10 15:00 10/13/10 15:00 10/13/10 500 10/13/10 15:00
.lnaiv:ed Method 10/13/10 1500 10/13/10 15:00 10/13/10 15:00 10/13/JO 15:00 10/13/10 500 10/13/JO 15:00 10/13/10 15:00 10/13/10 15:00 10/13/10 15:00 10/13/10 1500 10/1 3/JO 10/13/10 15:00
EPA 8260C EPA 8260C EPA 8260C EPA
8260C
EPA 8260C EPA
8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
11/8/10 9:52
0
0
UNiTED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO9-B Station ID: HERC09 Date Collected: CIS N,unher
E104009-11
Matrix: Waste
9/29/10 14:20
.4nalyre
Results Qualifiers
R4-7 156
(m- and/or p-)Xylcne
63 0-20-6
Units
MRL
Prepared 10/06110
3.2
mg/kg
25
1,1,1 ,2-Tetrachloroethane
2.5 U
mg/kg
“
71-55-6
I ,1,1-Trichloroethane
2.5 U
mg/kg
c
79-34-5
1,1 ,2,2-Tetrachloroethane
2.5 U
mg/kg
2 5
12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10
1,1 .2-Trichloro-1 ,22-Trifluoroethane (Freon 113)
2.5 U
mg/kg
25
12:10
1,1 ,2-Trichloroethane
2.5 U
mg/kg
‘
1,1 Dichioroethane
2.5 U,J,QL-1
mg/kg
79-00-5
-
S
S
75-35-4
1,1-Dichloroethene (1 ,l-Dichloroethylene)
2.5 U
mg/kg
5
563-58-6
1,1 -Dichloropropene
2.5 U
mg/kg
2 5
87-61-6
1 ,2,3-Trichlorobenzene
96-18-4
1 ,2,3-Trichloropropane
120-82-1
1 ,2,4-Trichlorobenzene
95-63-6
1 ,2,4-Trimethylbenzene
96-12-8
I ,2-Dibromo-3-Chloropropane (DBCP)
mg/kg
2
2.5 U
mg/kg
2 5
2.5 U
mg/kg
.,
3.0
mg/kg
2 5
5.0 U
mg/kg
5 •n 2 5
2.5 U
e
-
106-93-4
1 ,2-Dibromoethane (EDI3)
2.5 U
mg/kg
95-50-1
I ,2-Dichlorobenzene
2.5 U
mg/kg
2 5
107-06-2
I ,2-Dichloroethane
2.5 U
mg/kg
2 5
78-87-5
1 ,2-Dichloropropane
2.5 U
mg/kg
2
108-67-8
I .3,5-Trimelhylbenzene
2.5 U
mg/kg
2 5
541-73-1
1 ,3-Dichlorobenzene
2.5 U
mg/kg
.,
142-28-9
1 ,3-Dichloropropane
2.5 U:
mg/kg
2 5
106-46-7
I ,4-Dichlorobenzene
2.5 U
mg/kg
2 5
594-20-7
2.2-Dichloropropane
2.5 U
mg/kg
.,
67-64-1
Acetone
20 U
mg/kg
‘A °
7 1-43-2
Benzene
170
mg/kg
)
108-86-1
Bromobenzene
2.5 U
mg/kg
74-97-5
Bromochioromethane
2.5 U, J, QL-1
mg/kg
2 5
75-27-4
Bromodichloromethane
2.5 U
mg/kg
2 5
75-25-2
Bromoform
5.0 U
mg/kg
5 0
Page 41 of6O
El 04009 TCLPV VOA FINAL
-
e
-
-
2 5
-
10/06/10 12:10 10/06/TO 12:10 10/06/10
12:10 10:1/6/TO 12:10
10/06/10 12:10 10/06/TO I2:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/TO 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/TO 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:l0 10/06/10 12:10 10/06/10 12:10 0/06/TO 12:10
Analyzed Method 10/OS/TO 17:30 10/08/10 17:30 008. TO 7:30 10/08/10 17:30 1008/TO 7:30
EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C
10/08/10 17:30
EPA 8260C
10,08:10 17:30
EPA 8260C
10/08/10 17:30
EPA 8260C
0/08/10 7:30 10/08/10 17:30 0/08/TO 17:30 10/08/10 17:30 10/08/TO 17:30 10/08/10 17:30 10/08/10 17:30 10/08/10 17:30 10/08/TO 7:30 10/08/10 17:30 10.00/10 l7:30 10/08/10 17:30 10/08/TO 17:30 10/08/10 17:30 10/08/lO 17:30 10/08/10 17:30 10/08/10 17:30 10/08/10 17:30 b/Os/b 17:30 10/08/10 17:30 10/08/TO 17:30
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: NERCO9-B
Matrix: Waste
Station ID: l-IERCO9 Date Collected:
E104009-11
9/29/10 14:20
U IS ResuII Qualijiers
N,,,,ther
.tnalyre
74-83-9
Bromomethane
100 U
elfRL
Prepared
mg/kg
100
10/06110 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:l0 10/06/10 12:10 10O6/I0 12:10 10106/10 1210 6/06/10 12:10 10/06/10 12:10 10/06/tO 12:10 10/06/10 12:10 10/06/10 12 10 10/06/10 1210 10/06/10 12:18 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 I0’O&IO 12:10 18/06/10 12:10 10/06/10 12:10 10)06)10 12:10 10/06/tO 12:10 b0/06’IO 12:10 10/06/10 12:10 10/06)18 12:18 10/06/10 12:10 10)06/10 12:10 10/06/10 12:10 10/06/JIb 12:111 006 10
Units
75-15-0
Carbon disulfide
2.5 15
mg/kg
2,5
56-23-5
Carbon Tetrachloride
2.5 U
mg/kg
2.5
108-90-7
Chlorobenzene
2.5
15
mg/kg
2.5 2.5
75-00-3
Chloroethane
2.5 U
mg/kg
67-66-3
Chlorofonn
2.5 15
mg/kg
2.5
Chloromethane
2.5 U
mg/kg
2.5
cis-1,2-Dichloroethene
2.5 15
mg/kg
2.5
74-87-3 56.59-2 10061-01-5
cis-1,3-Dichloropropene
2.5 U
rug/kg
2.5
110-82-7
Cyclohexane
29
mg/kg
2.5
124-48-1
Dibromochloromethane
2.5 U
mg/kg
2.5
2.5
74-95-3
Dibromoinethane
2.5 U
mg/kg
75-71-8
Dichlorodifluoromethane (Freon l2
2.5 U
mg’kg
2.5 2.5
100-41-4
Ethyl Benzene
1.0 J, Q-2
mg/kg
87-68-3
Elexachlorobutadiene
2.5 U
mg/kg
2.5
98-82-8
Isopropylbenzene
6.0 15, D-4
mg/kg
6.0
79-20-9
Methyl Acetate
5.0 U
mg/kg
5.0
591 -78-6
Methyl Butyl Ketone
5.0 15
mg/kg
5.0
78-93-3
Mcth1 Ethyl Ketone
5.0 U
mg.’kg
5.0
108-10-1
Methyl Isobutyl Ketone
5.0 L’
mg/kg
5.0 2.5
2.5
1634-04-4
Methyl T-Butyl Ether (MTBE)
2.5 U
mg/kg
108-87-2
Methylcyclohexane
8.2
mg/kg
75-09-2
Methylene Chloride
2.5 U
mg/kg
2.5
104-51-8
n-Butylbenzene
2.5 15
mg/kg
2.5
103-65-1
n-Propylhenzene
2.5 U
mg/kg
2.5
95-49-8
o-Chlorotoluene
2.5 15
mg/kg
2.5
95-47-6
o-Xylene
1.0 J, Q-2
mg/kg
2.5
2.5 15
mg/kg
2.5
mg/kg
25
106-43-4
p-Chlorotoluene
99-87-6
p-lsopropyltoluene
610
135-98-8
sec-Butylbeozene
2.5 15
mg/kg
2.5
100-42-5
Styrene
100 U
mg/kg
100
Page 42 of6O
El04009 TCLPV VOA FINAL
2:10
.4nalyzed ,lh’thod 10/08/10 17:30 10/08/10 17:30 10/08/10 17:30 10/08110 17:30 10:08,10 I7:30 10/08/10 17.30 l0:06,I0 7:30 b/OS/b 17:30 10/08/b 17:30 10/08/10 17:30 10/08/10 17:30 10/08/10 17:30 10/08/10 17:30 10/08/10 17:30 10/08/10 17:30 10)08/10 17:30 l008/l0 17:30 10/08/10 17:30 10/08/10
17:30 10/08/10 17:30 10/08/10 7:30 10/08/tO 17:30 10/08/10 17:30 10/08/10 17:30 10/08/10 17:30 10/08/10 17:30 10/08/10 17:30 10/08110 17:30 10/07/10 17:17 10)08/10 730 1008.10 7:30
EPA 8260C EPA
8260C
EPA 8260C EPA 8260C EPA 8260C EPA
8260C
EPA 8260C EPA
8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA
8260C
EPA %260C EPA 8260C EPA 8260C EPA
8260C
EPA
8260C
EPA 8260C EPA 8260C EPA
8260C
EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO9-B Station ID: I{ERCO9
E104009-11
Matrix: Waste
Date Collected: 9/29/10 14:20 C.4S .V,unber
4nalyte
Results Qualifiers
98-06-6
tert-Butylbenzene
2.5 U
127-18-4
Tetrachloroethene (Tetrachloroethylene)
2.5 U
108-88-3
Toluene
156-60-5
trans-1,2-Dichloroethene
Units
MRL
mg/kg
2.5
mg/kg
2.5
Prepured 0/06/jO
trans-1,3-Dichloropropene
2.5 U
mg/kg
2.5
79-01-6
Trichloroethene (Trichloroethylene)
2.5 U
mg/kg
2.5
Trichiorofluoromethane (Freon 11)
2.5 U
mg/kg
2.5
75-01-4
Vinyl chloride
2.5 U
mg/kg
2.5
12:10 10/06/10 12:10 0/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10
50 U
mg/kg
50
10/06/10 1IO
1100
2.5 U
mg/kg
25
mg/kg
2.5
.inulyzed ‘Jethod 0/08110 7:30 10/08/10 17:30 10/07/10 17:17 10/08/10 17:30 10/08/10 7:30 10/08/jo 17:30 1008/10 7:30 10/08/10 17:30
EPA
8260C
EPA
8260C
10/08/10 1730
EPA 8260C
EPA 8200C EPA 8260C EPA
8260C
EPA 8260C EPA 8260C
EPA 8260C
Tentatively Identified Compounds: R4-0000
Page 43 of 60
Tentatie1y ldentilicd Compounds
E104009 TCLPV VOA FINAL
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO9-B
E104009-11
Matrix: Waste
Station ID: IIERCO9 Date Collected: 9/29/10 14:20 C4S
IIRL
Prepared
mg/L
0.25
0)13/10
10/13/10
1500
1711
0.25 U
mgfL
0.25
0.25 U
mg!L
0.25
10/13/Il) 15.00 l0’13;I0
mgfL
0.25
10/13/10 17:1! 10/13/10 1711 1(1/13/10 17:11 10/1310
Results Qualijiers
Nnrnber
.4nalyte
75-35-4
1,1-Dichloroethene (1,1 -Dichloroethylene)
0.25 U
107-06-2
1,2-Dichioroethane
1/nits
106-46-7
1,4-Dichlorobenzene
71-43-2
Benzene
56-23-5
Carbon Tetrachloride
0.25 U
mg.’L
0.25
108-90-7
Chlorobenzene
0.25 U
mg/L
0.25
67-66-3
Chloroform
0,25 U
mg/L
0.25
025 0.50
1.8
87-68-3
Hexachlorobutadiene
0.25 U
mgfL
78-93-3
Methyl Ethyl Ketone
0.50 U
mg/L
127-18-4
retrachloroethene (Tetrachloroethylene)
025 U
mgIL
0.25
79-01-6
Trichloroethene (Trichloroethylene)
0.25 U
mg/L
0.25
75-01-4
Vinyl chloride
0.25 U
mg/L
0.25
Page 44 of6O
E104009 TCLPV VOA FINAL
10)13/10 15:00 l0;13.l0
.1nalyzed ,lfethod
1500
17:11
(0)13/10 1500 10/13/10 5:00 10/13/10 500 10/13/10
10/13/10 1711 10/13/It 17:11 10/13/10 17:11 10/13/10
1500
1711
(0/13/10 15:00 10)13/10 (5:00 10/13/10 15:00
10/13/10 17:11 10/13/10 17:11 10/13/10 17:11
EPA 0260C’
EPA
8260C
EPA 8260c EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA
8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: I 00629
Project: 10-0629, Hercules Inc Reported by Kristin Trapp
LpRo
-
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERC1O-B Station ID: HERCIO
E104009-12
Matrix: Waste
Date Collected: 9/29/10 14:15 C IS .‘V,,mher
.4nu4’te
R4-7156
(m- and/or p-)Xylene
25 U
mg/kg
25
630-20-6
1,1,1 ,2-Tetrachloroethane
25 U
mg/kg
25
71-55-6
1,1,1-Trichloroethane
25 U
mg/kg
25
10/06/10 12:10
17:43
EPA 8260C
79-34-5
1,1,2,2-Tetrachloroethane
25 U
mg/kg
25
25 U
mg/kg
25
10/07/10 17:43 10)07/10 17:43
EPA 8260C
1,1,2-Trichloro-1,2,2-Trifluoroethane
10/06/10 12:10 10/06/10 12:10
25 U
mg/kg
25
10/07/10 17:43
El’A 8260C
25 U, J, QL-1
mg/kg
25
10/06/10 12:10 10/06/10 12:10 10/06/10
10/07/10
EPA 8260C
76-13-1
Results Qualifiers
Units
MRL
Prepared
.1 nat vzed
10/06/10
10/07/10
12:10 10/06/10
17:43 10/07/10 17:43 10/07/10
12:10
Method
EPA 8260C EPA 8260C
EPA 8260C
(Freon 113) 1,1,2-Trichloroethane
79-00-5 75-34-3 i/
/ 1,1-Dichloroethane
75-35-4
1,1-Dichloroethene
25 U
mg/kg
25
563-58-6
(1 ,1-Dichloroethylene) 1,1-Dichloropropene
25 U
mg/kg
25
87-61-6
1,2,3-Trichlorobenzene
25 U
mg/kg
25
96-18-4
1,2,3-Trichloropropane
25 U
mg/kg
25
120-82-1
1,2,4-Trichlorobenzene
25 U
mg/kg
25
95-63-6
l,2,4-Trimethylbenzene
7.0 J, Q-2, QR-l
mg/kg
25
96-12-8
1,2-Dibromo-3-Chloropropane (DBCP)
50 U
mg/kg
50
106-93-4
1,2-Dibromoethane (EDB)
25 U
mg/kg
25
95-50-1
l,2-Dichlorobenzene
34
mg/kg
25 25
107-06-2
1,2-Dichloroethane
25 U
mg/kg
78-87-5
1 ,2-Dichloropropane
25 U
mg/kg
25
108-67-8
1,3,5-Trimethylbenzene
25 U
mg/kg
25
541-73-1
1,3-Dichlorobenzene
25 U
mg/kg
25
142-28-9
1,3-Dichloropropane
25 U
mg/kg
25
106-46-7
1 ,4-Dichlorobenzene
25 U
mg/lcg
25
594-20-7
2,2-Dichloropropane
25 U
mg/kg
25
67-64-1
Acetone
U
mg/kg
200
71-43-2
Benzene
108-86-1
Bromobenzene
74-97-5
200
mg/kg
25
25 U
mg/kg
25
Bromochloromethane
25 U, J. QL-1
mg/kg
25
75-27-4
Broniodichloromethane
25 U
mg/lcg
25
75-25-2
Bromoform
50 U
mg/kg
50
Page 45 of 60
140
E104009 TCLPV VOA FINAL
12:10
10/06/10 12:10 10/06/10 12:10 10/06/10 2:10 10/06/10 12:10 10)06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10)06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10
12:10
10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10
17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10)07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07)10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43 0/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43
EPA 8260C EPA
8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA S260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA
8260C
EPA
8260C
11/8/10 9:52
0
0
UNiTED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc
-
Reported by Kristin Trapp
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCIO-B
E104009-12
Matrix: Waste
Station ID: HERC1O Date Collected: 9/29/10 14:15 U i.c .Vu,nher
.4rndrte
74-83-9
Bromomethane
Results Qualifiers
Units
MRL
Prepared 10/06/10 12:10 10/06/10 12:10 10/06/10 72:10 10/06/JO 12:10 70/06/70 12:10 0/06/JO 12:10 10/06/10 12:10 10/06/It 12:70 10/0610 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:70 10/06/10 12:10 10/06/10 12:10 10/06/JO 12:10 10/06/70 12:10 10/06/10 12:10 10/06/JO 12:10 10/06/10 12:10 10/06/10 12:71) 10/06/10 12:10 0/06/10 72:10 10/06/10 12:10 10/06/11) 12:10 10/06/10 12:10 10/tO/ID 12:10 10/06/10 12:10 10/06/Ill 1210 0/06/10 12:10 10/06/It 12:70 1006/10 1210
100 U
mg/kg
I°°
2S
75-15-0
Carbon disulfide
25 U
mg/kg
56-23-5
Carbon Tetrachioride
25 U
mg/kg
.,
108-90-7
Chlorobenzene
25 U
mg/kg
2S
75-00-3
Chioroethane
25 U
mg/kg
2S
25 U
mg/kg
7C
67-66-3
Chloroform
74-87-3
Chiorornethane
25 U
mg/kg
156-59-2
cis-1 ,2-Dichloroethene
25 U
mg/kg
2S
25 U
mgkg
-
10061-01-5
cis- 1,3-Dichloropropene
110-82-7
Cyclohexane
1500
mg/kg
.,
124-48-1
Dibromochioromethane
25 U
mg/kg
25
74-95-3
Dibromomethane
25 U,J,QL-l
mg/kg
2S
75-71-8
Dichlorodifluoromethane (Freon 12)
25 U
mg/kg
2S
mg/kg
2S
4.0 J, Q-2
100-41-4
Ethyl I3enzene
87-68-3
Flexachiorobutadiene
25 U
mg/kg
-,
98-82-8
lsopropylbenzene
70 U, D-4
mg/kg
7O
79-20-9
Methyl Acetate
50 U
mg/kg
S0
59 1-78-6
Methyl Butyl Ketone
50 U
mg/kg
78-93-3
Methyl Ethyl Ketone
50 U
mg/kg
108-10-1
Methyl Isobutyl Ketone
50 U
mg/kg
So
1634-04-4
Methyl T-Butyl Ether (MTBE)
25 U
mg/kg
2S
108-87-2
Methylcyclohexane
12 J. Q-2
mg/kg
2S 2S
75-09-2
Methylene Chloride
25 U
mgkg
104-51-8
n-Butylbenzene
25 U
mg/kg
So
=
103-65-I
n-Propylbenzene
25 U
mgkg
2S
95-49-8
o-Chlorotoluene
25 U
mg/kg
2S
95-47-6
o-Xylene
25 U
me kg
‘,
106-43-4
p-Chlorotoluene
25 U
mg/kg
2S
99-87-6
p-lsopropylloluene
mg kg
2S
135-98-S 100-42-5
Page 46 of6O
sec-Butylbenzene
3400 25 U
100 U
Styrene
E104009 TCLPV VOA F[NAL
mg/kg
2S
mg/kg
inn
.ina(vzed 11 fethod 10/07/10 17:43 10/07/10 17:43 10/07/JO 17:43 10/07/10 17:43 I 0/0710 17:43 10.07/10 77:43 10/07/10 ‘7:43 b/Ohio 17:43 1t507.’lO 17:43 111/07/10 17:43 1007.10 17:43 10/07/10 17:43 10/07/10 17:43 10/07)10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 77:43 10/07)70 17:43 70/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 ‘7:43 10/07/10 17.43 10/07/10 17:43 10/07/10 7:43 10/07/10 17:43 10,07)10 7.43 1007.10 17:43 10/07/10 17:43 10/07/10 17:43
EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 8260C EPA 826CC EPA 8260C EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 8260C EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 8260C EPA 826CC
11/8/10 9:52
0
C) \D s:e
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Suppofl Division 980 College Station Road, Athens, Georgia 30605-2700
Mt •1
D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Kristin Trapp
PR
-
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCIO-B Station ID: HERC1O
E104009-12
Matrix: Waste
Date Collected: 9/29/10 14:15 CAS Number
4nalyre
Recoils Quahjiers
Unils
IIRL
Prepared
Analyzed lfeckod
98-06-6
tert-Butylbenzene
127-18-4
Tetrachloroethene (Tetrachloroethylene)
108-88-3
Toluene
156-60-5
trans-1,2-Dichloroethene
25 U
mg/kg
10061-02-6
trans-1,3-Dichloropropene
25 U
mg/kg
25
79-01-6
Trichloroethene (Trichloroethylene)
25 U
mg/kg
25
Trichiorofluoromethane (Freon Ill
25 U
mg/kg
25
10/06/tO
10/07/10
75-01-4
25 U 25 U 3100
Vinyl chloride
25
10/06/10 12:10
10/07/10 7:43
EPA 8260C
mg/kg
25
10/06/ID 12:10
10/07/10 17:43
EPA 8260C
mg/kg
25
10/06/tO 12:10
10/07110 17:43
EPA826OC
10/06/10 12:10 10/06/10
10/07/10 17:43
EPA 8260C
mg/kg
25
1210
10/07/10 7:43
EPA 8260C
10/06/10 12:10
10/07/10 17:43
EPA 8260C
20
10/0710
743
25 U
mg/kg
25
10/06/10
12:10
17:43
500 U
mg/kg
500
100610 20
l007 10 743
EPA
8260C
EPA 8260C
Tentatively Identified Compounds: R4-0000
Page 47 of 60
Tentatively Identitieci Compounds
E104009 TCLPV VOA FINAL
EPA
8260C
11/8/10 9:52
0
0
IJNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERC1O—B
E104009-12
Matrix: Waste
Station ID: HERCIO Date Collected: 9/29/10 14:15 C4S Number
Results Qualifiers
.4na!yte
Units
MRL
Prepared
.1nuIzed ,tiethod
75-35-4
1,1-Dichloroethene (1.1 -Dichloroethylene)
025 U
mg/L
0.25
10/13/10 15:00
10/13/10 17:37
EPA 8260C
107-06-2
1,2-Dichloroethane
0.25 C
mg/L
0.25
0.25 U
0.25
10,13/10 17:37 10/13/10 17:37 1o/13.’Io 17:37 10/13/10 17:37 10/13/10 17:37 10/13/10
EPA 8260C
mg/L
10)13/10 5:00 10/13/jo 15.00 10/13/10 15:00 10/13/10 15:00 10/13/10 15:00 10/13/10
106-46-7
1,4-Dichlorobenzene
71-43-2
Benzene
2.2
mgfL
0.25
0.25
EPA
8260C
EPA
8260C
EPA
8260C
EPA
8260C
56-23-5
Carbon Tetrachloride
0.25 U
mg/L
108-90-7
Chlorobenzene
0.25 U
mg/L
0.25
67-66-3
Chloroform
0.25 U
mgfL
0.25
15:00
17:37
EPA 8260C
0.25
0/13/10 15:00
10/13/10 17:37
EPA 8260C
0.50
10/13/10
10/13/10
EPA 8260C EPA 8260C
87-68-3
Hexachlorobutadiene
0.25 C
mg/L
78-93-3
Methyl Ethyl Ketone
0.50 U
mg/L
127-18-4
Tetrachloroethene (Tetrachloroethylene)
0.25 C
mg/L
79-01-6
Trichloroethene (Trichloroethylene)
0.25 U
mgrL
0.25 U
mg/L
75-01-4
Page 48 of6O
Vinyl chloride
E104009 TCLPV VOA FINAL
0.25
10/I 3/la
15:00
10/13/10 17:37
0.25
l0/13’IO
10/13/10
1500 10/13/10 1500
17:37 10/13/10 17:37
0.25
EPA
8260C
EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCII-B Station ID: HERC1I
E104009-13
Matrix: Waste
Date Collected: 9/29/10 14:30
(. IS Nunzhcr
.4nalyre
R4-7156
(m- and/or p-)Xylene
630-20-6
Results Qualifiers
Units
1IRL
Prepared
25
10/06/10 12:10
0/07/10 009
EPA 8260C
10/06/10
10/07/10 18:09
EPA 8260C
25 U
mg/kg
1,1,1 ,2-Tetrachloroethane
25 U
mg/kg
25
71-55-6
1,1,1 -Trichloroethane
25 U
mg/kg
-,
79-34-5
1,1 ,2,2-Tetrachloroethane
25 U
mg/kg
2S
76-13-I
I 1 2 Trichloro 1 2 2 Tnfluoroethane (Freon 113)
25 L
mg/kg
2S
79-00-5
1,1 ,2-Trichloroethane
25 U
mg/kg
2S
25 U,J,QL-1
mg/kg
,1-Dichloroethane
25
12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06110 12:10 10:06/10
10)07/10 18:09
EPA 8260C
12:10
18:09 10/07/10 18:09
EPA 8260C
18/07/10 18:09 10/07/10 18:09
EPA 8260C
25 U
mg/kg
)5
1,1 -Dichloropropene
25 U
mg/kg
25
87-61-6
1 ,2,3-Trichlorobenzene
25 U
mg/kg
25
10/06/10 12:10 10/06/10 12:10
96-18-4
1 ,2,3-Trichloropropane
25 U
mg/kg
25
120-82-1
1 ,2,4-Trichlorobenzene
25 U
mg/kg
25
95-63-6
1 ,2,4-Trimethylbenzene
25 U,J,QR-1
mg/kg
25
96-12-8
1,2-Dibromo-3-Chloropropane (DBCP)
49 U
mg/kg
49
106-93-4
1 ,2-Dibromoethane (EDB)
25 U
mg/kg
25
1 ,2-Dichlorobenzene
25 U
mg/kg
25
107-06-2
I ,2-Djehloroethane
25 U
mg/kg
25
78-87-5
1 ,2-Dichloropropane
25 U
mg/kg
108-67-8
I ,3,5-Trimethylbenzene
25 U
mg/kg
541-73-1
1 ,3-Dichlorobenzene
25 U
142-28-9
I .3-Dichloropropane
25 U
10/06/10
10/07/10
18:09 10/07/10 18:09
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
EPA 8260C
25
1006/10 12:10
10(17 0 16:09
EPA 8260C
mg/kg
25
10/06/10 12:10
10/07/10 18:09
EPA 8260C
mg/kg
25
10/06/10
l0;07/l0
EPA 8260C
25
(8:09 10/07/10 18:09 10/07/10 18:09 10/07/10
0:09 10/07/10 18:09 007/10 1809
1 ,4-Dichlorobenzene
25
U
mg/kg
25 U
mg/kg
25
67-64-1
Acetone
200 U
mg/kg
200
71-43-2
Benzene
77
mg/kg
25
108-86-1
Bromobenzene
25 U
mg/kg
25
74-97-5
Bromochioromethane
25 U,J.QL-1
mg/kg
25
75-27-4
Bromodichioromethane
25 U
mg/kg
25 49
00610 1210
E104009 TCLPV VOA FINAL
10/07/10
EPA 8260C
25
2,2-Dichioropropane
Page 49 of 60
18:09 10/07/10 18:09 10/07/10 8:09 10/07/10 18:09
EPA 8260C
(8.09 10/07/10 18:09
12:10
594-20-7
49 U
10/07/10
EPA 8260C
10/06/10 12:10
12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 2:10 10/06/10 12:10 10/06/10 12:10
Bromoform
1007/10
12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10
106-46-7
75-25-2
EPA 8260C EPA 8260C
1 ,1-Dichloroethene (1,1 -Dichloroethylene)
95-50-1
10/07/10
18:09 10/07/10 18:09 10/07/10 8:09
10/06/10 12:10
75-35-4
.lnatvzed Ofetlwd
mg/kg
18:09
(0/07/10 18:09 10/07/10 18:09 10/07/10
EPA 8260C EPA
8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA
8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athejis, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc - Reported by Kristin Trapp
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCI1-B
E104009-13
Matrix: Waste
Station ID: HERC11 Date Collected: 9/29/10 14:30
c.1,s .Vuwher
74-83-9
Results Qualiliers
.4nalyfr
98
Bromomethane
U
Units
mg/kg
MRL
Prepared
.lnalyzed ,lfetlwd
00
10/06/10 12:10
10/07/10
8:09
EPA 8260C
10/06)10 12.10 10/06/10 12:10
10/07/10 (8:09
EPA 8260C
75-15-0
Carbon disulfide
25 U
mg/kg
2S
56-23-5
Carbon Tetrachioride
25 U
mg/kg
2S
108-90-7
Chlorobenzene
25 U
mg/kg
2S 2S
10/07/10
18:09 10/07/10 18:09
EPA 8260C
EPA 8260C
75-00-3
Chioroethane
25 U
mg/kg
67-66-3
Chloroform
25 U
mg/kg
2S
74-87-3
Chlororncthane
25 U
mg/kg
25
12:10 10/06/10 12:10 0/06/10 12:10 10/06/10 12:10
2S
0/06/10 12:10
10/06/10 12:10
10/07/10
18:09
EPA 8260C
10/07/10
EPA 8260C
156-59-2
cis-l ,2-Dichloroethene
10061-01-5
cis- 1 .3-Dichloropropene
110-82-7
Cyclohexane
124-48-1
Dibromochloromethane
25 U
mg/kg
12:10
18:09
25 U
mg/kg
25
10/06110
b0OTIO l8:09
EPA 8260C
25
(0/07/lU 18:09
EPA 8260C
25
25 U,J,QL-l
Dichiorodifluoromethane (Freon 12)
25 U
mg/kg
100-41-4
Ethyl Benzene
25 U
mg/kg
87-68-3
Flexachlorobutadiene
25 U
mg/kg
12:10 10/06/10 12-10 10/06/10 12:10 0/06/ID 2:10
18:09
b/OS/b (2:10
(0/07/10 18:09
EPA 8260C
26
10/06/10 12:I0
10/07/10 18:09
EPA 8260C
10/06/10
10/07/10 18:09 1(1/07/ID
Isopropylbenzene
26 U, D-4
mg/kg
Methyl Acetate
49 U
mg/kg
591-78-6
Methyl Butyl Ketone
49 U
mg/kg
49
12:10 10/06/10 2:10
78-93-3
Methyl Ethyl Ketone
49 U
mg/kg
49
10/06/10 12:10
108-10-I
Methyl Isobutyl Ketone
49 U
mg/kg
1634-04-4
Methyl T-Butyl Ether (MTBE)
25 U
mg/kg
25
108-87-2
Methylcyclohexane
7.4 J, Q-2
mg/kg
2S
75-09-2
Methylene Chloride
25 U
mg/kg
25
mg/kg
49
2S
10/06/16 1210 10/06/10 12:10 10/01)/JO 12:10 10/06/10 (2:10 0/06/10 12 (0 10/06/10
103-65-I
n-Propylbenzene
25 U
mg/kg
2S
95-49-8
o-Chlorotoluene
25 U
mg/kg
25
95-47-6
o-Xylene
25 U
mg/kg
25
10/06/10 12:10
25 1/
mg/kg
2S
10’86/b0 1210
-‘
0/06/10 12:10
2S
10/06/10 (2:10
98
0/06/10 1210
135-98-8 100-42-5
Page 50 of6O
sec-Butylbenzene
720 25 U
Styrene
98 U
E104009 TCLPV VOA FINAL
mg/kg
mg/kg mg/kg
EPA 8260C
10/07/lU
25
79-20-9
25 U
10/07/10 (8:09
EPA 8260C
98-82-8
p-lsopropyltoluene
EPA 8260C
10/06)10
Dibromomethane
99-87-6
EPA 8260C
2S
75-71-8
p-Chlorotoluene
EPA 8260C
25
74-95-3
106-43-4
EPA 8260C
mg/kg
100
n-Bulylbenzene
18:09 10/07/10 18:09 10/07/10 (8:09 10/07/10 18:09
mg/kg
25 U
mg/kg
104-51-8
007(0
(2:10 10)06/10 12:10
18.09 10/07/10 10:89
EPA 8260C
EPA 8260C EPA 8260C
10/07/lU (8:09
EPA
l0/07/10
EPA 8260C
18:09 (0/07/ID
18:09 (007/10 8:09
10/07/10 1809
10/07/10 18:09 (0/07110 8:09 10’07/10 18:09 (0,87/ID 18.09 10. 0710 18:09 10/07/IC
(8:09 0/07/It (8:09
8260C
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA
8260C.
EPA 8260C EPA 8260C EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules inc Lab ID:
Sample ID: HERCI1-B
E104009-13
Matrix: Waste
Station 1D: HERC11 Date Collected: 9/29/10 14:30 C4S Niun her
Results Qualijiers
4nulyte
Units
MRL
Prepared
.4nalyzed 10/07/10 18:09 10/07/10 18:09 10/07/10 18:09 10/07/10 18:09 10/07/10 809 10/07/10 18:09 10/07/10 18:09 10/07/jo 18:09
EPA 8260C
10/07/10 809
EPA
25 U
mg/kg
25
25 U
mgllcg
25
mg/kg
25
25 U
mg/kg
25
25 U
mg/kg
25
Trichloroethene (Trichloroethylene)
25 U
mg/kg
25
Trichlorofluoromethane (Freon 11)
25 U
mg/kg
25
Vinyl chloride
25 U
mg/kg
25
10/06110 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 1210 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10
500 U
mg/kg
500
10/06/10 1210
98-06-6
tert-Butylbenzene
127-18-4
Tetrachioroethene (Tetrachloroethylene)
108-88-3
Toluene
156-60-5
trans-1,2-Dichloroethene
10061-02-6
trans-1,3-Dichloropropene
79-01-6 75-69-4 75-014
2600
lkthod EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
Tentatively Identified Compounds: R4-0000
Page 51 of6O
Tentatively IdentiEed Compounds
E104009 TCLPV VOA F[NAL
8260C
11/8/10 9:52
0 DSTA,,
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc Repoed by Kristin Trapp -
TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: FIERCII-B Station ID: HERC1J Date Collected: C4S :Vn,nbar
E104009-13
Matrix: Waste
9/29/10 14:30
.4nalyte
Results Qualifiers
Units
MRL
Prepu red
.1 nut ved
10/21/10 00
1021/10 054
FP.\
EPA 8260C
75-35-4
1,1-Dichloroethene (1,1 -Dichloroethylene)
0025 U, J, H-8
mg’L
0.025
107-06-2
1,2-Dichloroethane
0.025 U, J. H-8
mg/L
0.025
10,21/10
10/21/10
106-46-7
1.4-Dichlorobenzene
0.025 U, J, H-8
mg/L
0.025
71-43-2
Benzene
mgfL
0.025
56-23-5
Carbon Tetrachloride
0.025 U, J, H-X, QL-3
mg/L
0.025
10/21/10 5:00 10/21/10 15:00 10/21/10
108-90-7
Chlorobenzene
0.025 C, J. 11-8
mg/L
0.025
67-66-3
Chloroform
0.025 U, J, 11-8
mg/L
0.025
87-68-3
Hexachlorobutadiene
0.025 C. J, }l-8
mg/L
0.025
78-93-3
Methyl Ethyl Ketone
0.050 U. J, Il-s
mg/L
0.050
127-18-4
Tetrachloroethene (Tetrachloroethylene)
0.025 C, J, H-S
rng/L
0.025
79-01-6
Trichloroethene (Trichloroethylene)
0.025 U, J. H-8
mg!L
0.025
10.21:10 0:54 10/21/10 18:54 10/21/10 054 10/21/10 18:54 10/21/10 18:54 10/21/10 18:54 10/21/10 18:54 10/21/18 18:54 10/21/10
75-01-4
Page 52
0.54 3, H-S
0.025 U, J, F1-8
Vinyl chloride
of
60
E104009 TCLPV VOA FINAL
mg/L
0.025
15:00
1500
10/21/10 15:00 10/21/10 15:00 0/21/10 15:00 10/21/10 15:00 10/21/10 15:00 10/21/10 15.00 10/21/10 15:00
18:54
,lfethod
8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
10.54
EPA 8260C
10/21/10 18:54
EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERC12-B
Matrix: Waste
Station ID: HERC12 Date Collected: (‘AS Number
9/29/10 14:50 Results Qualifiers
4nalyte
(m- andlor p-)Xylene
R4-7156
E104009-14
25 U
Units
mg/kg
8IRL
Prepared
4naly;ed
25
10/06110 12:10 10/06/Jo 12:10 10/06/10 12:10 10/06/JO 12:10 10/06/10 12:10
10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 1007/10 18:35
10/06/10 12:10 10/06110 12:10 10/06/10 12:10
10/07/10 18:35 10/07.10 18:35 10/07/10 18:35
18/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/JO 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/JO 12:10 1006/10 12:10 10/06/10 12:10 10)06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 1006/10 12:10
10/07/10 18:35 10/07/10 18:35 10/07/ 10 18:35 10/07)10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 0/07/10 18:35 10)07/JO 18:35 10,07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 1007:10 18:35 10/07/10 18:35 10/07/JO 18:35
63 0-20-6
1,1,1 ,2-Tetrachloroethane
25 U
mg/kg
“S
71-55-6
1,I,1-irichlorocthane
25 U
mg/kg
2S
79-34-S
1,1 ,2,2-Tetrachloroethane
25
U
mg/kg
—‘5
76-13-I
1.1 ,2-Trichloro- 1 2,2-Trifluoroethane (Freon 113)
25 U
mg/kg
25
79-00-5
1,1 ,2-Trichloroethane
25 U
mg/kg
-‘S 25
1,1-Dichioroethane
25 U,J,QL-l
mg/kg
75-35-4
I ,1-Dichloroethene (1 ,1-Dichloroethylene)
25 U
mg/kg
,‘S
563-58-6
1,1 -Dichloropropene
25 U
mg/kg
25
87-61-6
1 ,2,3-Trichlorobenzene
25 U
mg/kg
25
96-18-4
1 ,2,3-Trichloropropane
25 U
mg/kg
25
120-82-1
1 ,2,4-Trichlorobenzene
25 U
mg/kg
25
95-63-6
I ,2,4-Trimethylbenzenc
5.0 J, Q-2, QR-1
mg/kg
25
96-12-8
1 ,2-Dibromo-3-Chloropropane (DBCP)
50 U
mg/kg
50
106-93-4
I .2-Dibromoethane (EDB)
25 U
mg/kg
25 25
75-34-3
.
95-50-1
1 ,2-Dichlorobenzene
25 U
mg/kg
107-06-2
1 ,2-Dichloroethane
25 U
mg/kg
25
78-87-5
1 ,2-Dichloropropane
25 U
mg/kg
25
108-67-8
I ,3,5-Tnmethylbenzene
25 U
mg/kg
25
541-73-1
1 ,3-Dichlorobenzene
25 U
mg/kg
25
142-28-9
1 ,3-Dichloropropane
25 1.
mg/kg
25
106-46-7
1 ,4-Dichlorobenzene
25 U
mg/kg
25
U
mgkg
25
mg/kg
200
594-20-7
2,2-Dichioropropane
67-64-1
Acetone
200 U
71-43-2
Benzene
440
108-86-1
Bromobenzene
25 U
74-97-5
Bromochioromethane
75-27-4
Bromodichloromethane
75-25-2
Bromo form
Page 53 of 60
E104009 TCLPV VOA FTNAL
25
mg/kg
25
mg/kg
25
25 U, J. QL-1
mg/kg
25
25 U
mg/kg
25
50 U
mg/kg
50
lfethod
EPA
8260C
EPA 826CC EPA 826CC EPA
826CC
EPA
8260C
EPA
826CC
EPA 8260C EPA
826CC
EPA
826CC
EPA
826CC
EPA 8260C
EPA 826CC EPA 8260C
EPA 826CC EPA 8260C
EPA 8260C EPA 8260C
EPA 826CC EPA 826CC
EPA 826CC EPA 8260C EPA 826CC EPA 8260C
EPA 826CC EPA 826CC EPA
826CC
EPA 826CC
EPA 826CC EPA 826CC
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTiON AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project; 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: IIERC12-B
Matrix: Waste
Station ID: HERC12 Date Collected: C4S Number
74-83-9
E104009-14
9/29/10 14:50 Results Qualifiers
4nai5’te
Bromomethane
100 U
Units
mg/kg
MRL
100
75-15-0
Carbon disulfide
25 U
mg/kg
25
56-23-5
Carbon Tetrachioride
25 U
mg/kg
25
108-90-7
Chlorobenzene
25 U
mg/kg
25
75-00-3
Chioroethane
25 U
mg/kg
25
67-66-3
Chloroform
25 U
mg/kg
25
74-87-3
Chloromethane
25 U
mg/kg
25
156-59-2
cis- I ,2-Dichloroethene
25 U
mg/kg
25
10061-01-S
cis- I ,3-Dichloropropene
25 U
mg/kg
25
110-82-7
Cyclohexane
48
mg/kg
25
124-48-i
Dibromochioromethane
25 U
mg/kg
25 25
74-95-3
Dibromomethane
25 U, 3, QL-l
mg/kg
75-71-8
Dichlorodjfluoromethane (Freon 12)
25 U
mg/kg
25
100-41-4
Ethyl Benzene
25 U
mg/kg
25
87-68-3
I lexachlorobutadiene
25 U
mg/kg
25
98-82-8
lsopropyibenzene
47
mg/kg
25
79-20-9
Methyl Acetate
50 U
mg/kg
50
591-78-6
Methyl Butyl Ketone
50 U
mg/kg
50
78-93-3
Methyl Ethyl Ketone
50 U
mg/kg
50
108-10-1
Methyl Isobutyl Ketone
50 U
mg/kg
50 25 25
1634-04-4
Methyl T-Butyl Ether (MTBE)
25 U
mg/kg
108-87-2
Methylcyclohexane
lii, Q-2
mg/kg
75-09-2
Methylene Chloride
25 U
mgkg
25
104-51-8
n-Butylbenzene
25 U
mg/kg
25
103-65-I
n-Propylbenzene
25 U
mg/kg
25
95-49-8
o-Chlorotoluene
25 U
mg/kg
25
95-47-6
o-Xylene
25 U
mg/kg
25
25 U
mg/kg
25
mg/kg
25
106-43-4
p-Chlorololuene
99-87-6
p-lsopropyltoluene
135-98-8
sec-Btttylbenzene
100-42-5
Styrene
Page 54 of6O
E104009 TCLPV VOA FINAL
2400 25 U
tug/kg
25
100 U
mg/kg
100
Prepared 10/06/10
12:10
10/06/10 12:10 10/06/10 12:10 10/06/10 2:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/116/10 12:10 10/06/10 12:10 10/06/10 12:10 1006:10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 1006/10 12:10 10/06/10 12:10 1006.10 12:10 0/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06)10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 1006/10 12:10
..lnaly;ed ltethod 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 1835 150710 18:35 10/07/10 18:35 10 07/10 18:35 10/07/10 18:35 1007/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10:07,10 18:35 10/07/10 18:35 1007,10 18:35 10/07/10 18:35 10:07/10 18:35 10/07/18 18:35 10/07/18 18:35 10/07/10 8:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/Il) 111:35
10/07/10
18:35
EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA S260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERC12-B Station ID: HERCI2
E104009-14
Matrix: Waste
Date Collected: 9/29/10 14:50 C IS Vuather
.4nalyte
Results Qualifiers
98-06-6
tert-Butylbenzene
127-18-4
Tetrachloroethene (Tetrachloroethylene)
108-88-3
Toluene
156-60-5
trans-1,2-Dichloroethene
10061-02-6
trans-1,3-Dichloropropene
79-01-6
Trichloroethene (Trichloroethylene)
75-69-4 75-01-4
Units
‘OIRL
25 U
mg/kg
25 U
mg/kg
25
mg/kg
25
25 U
mg/kg
25
25 U
mg/kg
25
25 U
mg/kg
25
Trichlorofluoromethane (Freon 11)
25 U
mg/kg
25
Vinyl chloride
25 U
mg/kg
25
500 U
mg/kg
500
160
25
Prepared
4natyed
10)06110 12:10 10/06/10 12:10 10,06/10 12:10 10/06/10 12:10 10/06/10 II0 10/06/10 12:10 10/06110 210 10/06/10 12:10
10/07)10 3:35 10/07/10 18:35 1807:10 18:35 10/07/10 18:35 10/07)10 035
i!ethud EPA
8260C
EPA 8260C EPA 8260C EPA
8260C
EPA 8260C
10/07/10 18:35 10/07/ 10 835 10/07/10 18:35
EPA 8260C
1007:10 035
EPA 8260C
EPA 8260C EP 8260C
Tentatively Identified Compounds: R4-0000
Page 55 of 60
Tentatively Identified Compounds
E104009 TCLPV VOA FINAL
1006/10 20
11/8/10 9:52
0
C
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. 1(1: 10-0629 Inc Reported by Kristin Trapp Hercules 10-0629, Project: -
TC1P Volatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: IIERCI2-B
E104009-14
Matrix: Waste
Station ID: IIERC12 Date Collected: 9/29/10 14:50 C IS :v,g,nhei75e,
107-06-2 106-46-7 71-43-2 56-23-5 108-90-7 67-66-3 87-68-3 78-93-3 127-18-4 79-01-6 75-01-4
Page 56 of 60
Re.s,,Ils QualifIers
lrndyre
Unit.’j
MRL
Prepared
11 Dichloroethene (1.1 -Dichloroethylene)
0 25 U
mg/L
0 25
Ii/3O
1,2-Dichloroethane
0.25 U
mg/L
0.25
19/O
l,4-Dichtorobenzene Benzene Carbon Ictrachloride Chlorobenzene Chloroform Hexachlorobutadiene Methyl Ethyl Ketone Tetrachloroethene (Tetrachloroethylene) Trichloroethene (Tricl-iloroethylene)
E104009 TCLPV VOA FINAL
EPA 8260C
i9//O
EPA 8260C
EPA 8260C EPA 8260C
mg/L
0.25
1.8
mgfL
0.25
3 j 1 9 1 0
1t/32/O
0.25 U
mg/L
0.25
‘°
1/O
0.25 U
mg/L
0.25
ll/3fO
0.25 U
rng/L
0.25
°
0.25 U
mg/L
0.50 U
mg!L
0.25 L 0.25 U
mg/I.. mg/L mg/I..
EPA 8260C
9//O
0.25 U
0.25 U
Vinyl chloride
nu1v..ed 1fethod
EPA 8260C EPA 8260C 1//O
EPA 8260C
0.50
i9/3O
O Itf3 / 2
EPA 8260C
0.25
H/3O
l/32/O
EPA 8260C
0.25
‘°
0.25
0.25
EPA 8260C 1/3O
‘‘°
EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERC13-B Station ID: HERC13
E104009-15
Matrix: Waste
Date Collected: 9/29/10 15:10 C4S
Nurn her
.4nalytc
R4-7156
(m- and/or p-)Xylene
25 U
mg/kg
25
630-20-6
1,1,1 ,2-Tetrachloroethane
25 U
mg/kg
L
71-55-6
1,1,1 -Trichloroethane
25 U
mg/kg
25
Re,s,,IIs Qualifiers
Units
MR1.
-‘S
79-34-5
1,1 ,2,2-Tetrachloroethane
25 U
mg/kg
-‘5
76-13-1
1,1 ,2-Trichloro- 1 ,2,2-Trifluoroelhane (Freon 113)
25 U
mg/kg
25
79-00-5
1,1 ,2-Trichloroethane
25 U
mg/kg
e
75-4-3
1,1-Dichloroethane
25 U,J,QL-1
mg/kg
25
75-35-4
1 ,1-Dichloroethene (1 ,1-Dichloroethylene)
25 U
mg/kg
-‘5
563-58-6
1,1 -Dichloropropene
25 U
mg/kg
25
87-61-6
1 ,2,3-Trichlorobenzene
2515
mg/kg
25
96-18-4
1 ,2,3-Trichloropropane
25 U
mg/kg
25
120-82-1
1 ,2,4-Trichlorobenzene
25 U
mg/kg
25
95-63-6
1 ,2,4-Trimethylbenzene
5.5 J, Q-2, QR-1
mg/kg
25
96-12-8
1 ,2-Dibromo-3-Chloropropane (DBCP)
50 U
mg/kg
50
106-93-4
1 ,2-Dibromoethane (EDB)
25 U
mg/kg
25
95-50-1
1 ,2-Dichlorobenzene
31
mg/kg
25
107-06-2
I ,2-Dichloroethane
25 U
mg/kg
25
78-87-5
I ,2-Dichloropropane
25 U
mg/kg
25
108-67-8
1 ,3,5-Trimethylbcnzene
25 U
mg/kg
25
541-73-1
1 ,3-Dichlorobenzene
25 U
mg/kg
25
142-28-9
1 ,3-Dichloropropane
25 U
mg/kg
25
25 U
mg/kg
25 25 200
106-46-7
I ,4-Dichlorobenzene
594-20-7
2,2-Dichloropropane
25 U
mg/kg
67-64-1
Acetone
200 U
mg/kg
7 1-43-2
Benzene
390
108-86-1
Bromobenzene
25 U
mg/kg
25
mg/kg
25
74-97-5
Bromochloromethane
25 U,J,QL-1
mg/kg
25
75-27-4
Bromodichioromethane
25 U
mg/kg
25
75-25-2
Bromoform
50 U
mg/kg
50
Page 57 of 60
El 04009 TCLPV VOA FINAL
Prepared
Analyzed Method
10106/10 12:10 10/06/10 12:10 10/06110 12:10 10/06/10 12:10 10/06/10 12:10
1007/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01
10/06/10 12:10 10/06/10 12:10 10/06/10 12:10
10/07/10 19:01 10/07/10 19:01 10/07/10 19:01
10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06)10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06110 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 2:10 10/06/10 12:10
10/07/10 19:01 10/07/10 19:01 10/07/It 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01
EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: IIERC13-B
E104009-15
Matrix: Waste
Station ID: HERC13 Date Collected: 9/29/10 15:10
C: IS Viun her
Re.cidis Qualifiers
.lnalyte
Units
MRL
mg/kg
74-83-9
Bromomethane
100 U
75-15-0
Carbon disulfide
25 U
mg/kg
2S
56-23-5
Carbon Tetrachioride
25 U
mg/kg
25
108-90-7
(‘hlorobenzene
25 U
mg/kg
2S ‘)C
2S
75-00-3
Chioroethane
25 U
mg/kg
67-66-3
Chloroform
25 U
mg/kg
Prepured 10/06/10 12:10 10/06/10
10/07/10 19:01 10/07/10 19:01 10 07. 10 19:01 10/07/10 19:0) 10/07/10 19:01 10/07/10
EPA 8260C
12:10
19:)))
EPA 8260C
10/07/10 19:0) 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 1007/10 19:0) 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:0) 10/07/10 19:0) 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:0) 0/07/10 19:01 I 0.07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:0) 10/07/10 19:01 10/07/10 19:0) 1007.10 19:01
EPA 8260C
2:70 10/06/10 12:10 10/06/10
2:10 10/06/10 12:10 l0/1J6/I0
74-95-3
Dibromomethane
25 U,J,QL-1
mg/kg
75-71-8
Dichiorodifluoromethane (Freon 12)
25 U
mg/kg
100-41-4
Ethyl Benzene
25 U
mg/kg
25
87-68-3
Flexachiorobutadiene
25 U
mg/kg
25
mg/kg
33O
10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 2:10
mg/kg
S”°
10/06/10 12:10
74-87-3
Chioromethane
25 U
mg/kg
2S
156-59-2
cis- I ,2-Dichloroethene
25 U
mg/kg
25
10061-01-5
cis- I ,3-Dichloropropene
25 U
mg/kg
2S
mg/kg
‘,
870
110-82-7
Cyclohexane
124-48-1
Dibromochioromethane
98-82-8
lsopropylbenzene
79-20-9
Methyl Acetate
591-78-6
mg’kg
,
-
2S
330 U, D-4 50 U
Methyl Butyl Ketone
—,
25 U
-)
50 U
mg/kg
SO
SO SO
78-93-3
Methyl Ethyl Ketone
50 U
mg/kg
108-10-1
Methyl Isobulyl Ketone
11 J, Q-2
mg/kg
1634-04-4
Methyl T-Butyl Ether (MTBE)
25 U
108-87-2
Methylcyclohexane
10 J, Q-2
mg/kg
2S
75-09-2
Methylene Chloride
25 U
mg/kg
-,
104-51-8
n-Bulylbenzene
25 U
mg/kg
2S
103-65-I
n-Propylbenzene
25 U
mg/kg
2S 25 2S
-,
•-‘
95-49-8
o-Chlorotoluene
25 U
mg/kg
95-47-6
o-Xylene
25 U
mg/kg
25 U
106-43-4
p-Chlorotoluene
99-87-6
p-lsopropyltoluene
135-98-8
sec-Butylbenzene
100-42-5
Styrene
Page 58 ofóO
El 04009 TCLPV VOA FINAL
3100
mg/kg
25
mg/kg
2S
25 U
mg/kg
100 U
mg/kg
—
inn
.•lnafr:ed Method
10/06/10 2:10 10/06/10 12:10 10/06/10 2:10 10/06/10 12:10 10/06/10 12:10 10/06110 12:10
10/06/jo 12:10 10/06/to 12:10
10/06/10 12.10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
EPA 8260C EPA 8260C EPA 8260C EPA 8260C
11/8/10 9:52
o
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.ART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
Volatile Organics Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERC13-B Station ID: HERC13
E104009-15
Matrix: Waste
Date Collected: 9/29/10 15:10 C4S Number
4na!yte
Results Qualifiers
98-06-6
tert-Butylbenzene
127-18-4
Tetrachloroethene (Tetrachloroethylene)
108-88-3
Toluene
156-60-5
trans-1,2-Dichloroethene
10061-02-6
trans-1,3-Dichloropropene
Units
MRL
25 U
mg/kg
25
25 U
mg/kg
25
mg/kg
25
25 U
mg/kg
25
25 U
mg/kg
25 25
3400
Prepared
.lnalyzed
10/06110
1007/10 19:01 10/07/10 19:01 1007:10 1901 10/07/10 19:01 I007J0 19:01 10/07/10 19:01 100710 l9-0l 10/07/10 19:01
EPA 8260C
10/07/10 1901
EPA 8260C
12:l0 10/06/10 12:10 10106/10
79-01-6
Tricliloroethene (Trichloroethylene)
25 U
mg/kg
75-69-4
Trichlorofluoromethane (Freon 11)
25 U
mg/kg
25
75-01-4
Vinyl chloride
25 U
mg/kg
25
I2:10 10/06/10 12:10 1006:10 12:10 10/06/10 12:10 0:06.10 12:10 10/06/10 12:10
500 U
mg/kg
500
10/06/10 1210
:tfethod EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C
Tentatively Identified Compounds: R4-0000
Page 59 of 60
Tentatively Identified Compounds
E104009 TCLPV VOA FINAL
11/8/10 9:52
0
0
UNiTED STATES ENVIRONMENTAL PROTECTION AGENCY Regioll 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-270() DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Kristin Trapp -
TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCI3-B
E104009-15
Matrix: Waste
Station ID: HERC13 Date Collected: 9/29/10 15:10 C4S Number
75-35-4
Resulls Qualifiers
4nalyie
1,1-Dichloroethene
Units
MRL
Prepared
bialyzed ,ltethod
0.25 U
mg/[.
0.25
10/13/10 1500
10/13/10
EPA 8260C
0.25 U
mgJL
0.25
10/13/10
10/13/10
1500
1854 10/13/10
EPA
0/13/10
5:00 10/13/10
18:54
EPA 8260C
10/13/10
18:54
(1,1 -Dichloroethylene) 107-06-2
1,2-Dichloroethane
106-46-7
l,4-Dichlorobenzene
71-43-2
Benzene
56-23-5
Carbon Tetrachloride
108-90-7
Chlorobenzene
67-66-3
mg!L
0.25
mg/L
0.25
0.25 U
mg/L
0.25
0.25 U
mg/L
0.25
10/13/10
10/13/10 10/13/10 18:54 10/13/10 18:54
EPA 8260C
EPA 8260C EPA 8260C
0.25 U
3.6
Chloroform
1500
1854
EPA 8260C
10/1310
10/13/10 1854
EPA 8260C
10/13/10 1854
EPA 8260C
1500
15:00
0.25 U
mg/L
0.25
10/13/10 1500
0.25
10/13/10 1500
0.50
10/13/10 1500
87-68-3
Hexachiorobutadiene
0.25 U
mgfL
78-93-3
Methyl Ethyl Ketone
0.50 U
L 1 mg
18:54
127-18-4
Teachloroethene (Tetrachloroethylene)
0.25 U
mg/L
0.25
10/13/10 1500
10/13/10 18:54
79-01-6
Trichloroethene (Trichloroethylene)
0.25 U
mg/L
0.25
10/13/10 1500
10/13/10 854
0.25
10/13/10
10/13/10
15:00
18:54
75-01-4
Page 60 of 60
0.25 U
Vinyl chloride
E104009 TCLPV VOA FINAL
8260C
mg/L
EPA 8260C
EPA 8260C
EPA 8260C
11/8/10 9:52
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY’
Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
January 4, 2011
4SESD-ASB MEMORANDUM SUBJECT:
FiNAL Analytical Report Project: 10-0629, Hercules Inc Civil Enforcement
FROM:
Jenny Scifres ASB Inorganic Chemistry Section Chief
THRU:
Gary Bennett, Chief Analytical Support Branch
TO:
Sharon Matthews
Attached are the final results for the analytical groups listed below. These analyses were performed in
accordance with the Analytical Support Branch’s (ASB) Laboratory Operations and Quality Assurance Manual (ASB LOQAM) found at www.epa.gov/region4/sesdlasbsop. Any unique project data quality objectives specified in writing by the data requestor have also been incorporated into the data unless otherwise noted in the Report Narrative. Chemistry data have been verified based on the ASB LOQAM specifications and may have been qualified if the applicable quality control criteria were not met. For a listing of specific data qualifiers and explanations, please refer to the Data Qualifier Definitions included in this report. The reported results are representative only of the samples as received by the laboratory.
Analyses Included in this report:
Method Used:
TCLP Metals (TCLPM) TCLPMeLaIs
EPA6OIO
Total Metals (TMTL) Total Metals
Page 1 of34
EPA 6010
E104009 TCLPM TMTL FINAL
1/4/11 10:55
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700
/\ ‘
,
DART. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
Report Narrative
for Work Order E104009, Project: 10-0629
Tin not reported per Project Leader. There is tin in reagents used for digesting the samples. Sample Disposal Policy
Because of the laboratory’s limited space for long term sample storage, our policy is to dispose of samples on a periodic schedule. Please note that within 60 days of this memo, the original samples and all sample extracts and/or sample digestates will be disposed of in accordance with applicable regulations. The 60-day sample disposal policy does not apply to criminal samples which are held until the laboratory is notified by the criminal investigators that case development and litigation are complete. These samples may be held in the laboratory’s custody for a longer period of time if you have a special project need. If you wish for the laboratory to hold samples beyond the 60-day period, please contact our Sample Control and provide a reason for holding samples Coordinator, Debbie Colquitt, by e-mail at beyond 60 days
Page 2 of 34
EIO4009TCLPMTMTLFINAL
1/4/11 10:55
0
0
UNITED STAThS ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
SAMPLES INCLUDED IN TifiS REPORT
Project: 10-0629, Hercuks Inc Sample ID
Laboratory ID
Matrix
ERBO1
E104009-01
PB01
Date Collected
Date Received
EquipmentRinseBlank
9/23/10 13:30
10/1/10 8:35
E104009-02
Preservative Blank
9/23/10 13:30
10/1/10 8:35
HERCOI-A
E104009-03
Waste
9/28/10 10:10
10/1/10 8:35
HERCO2-B
E104009-04
Waste
9/28/10 10:55
10/1/10 8:35
HERCO3-B
E104009-05
Waste
9/28/10 13:15
10/1/10 8:35
HERCO4-B
E104009-06
Waste
9/28/10 13:50
10/1/10 8:35
HERCO5-A
E104009-07
Waste
9/28/10 14:05
10/1/10 8:35
HERCO6-B
E104009-08
Waste
9/28/10 14:55
10/1/10 8:35
HERCO7-B
E104009-09
Waste
9/28/10 15:25
10/1/10 8:35
HERCO8
E104009-10
Waste
9/29/10 08:50
10/1/10 8:35
HERCO9-B
E104009-11
Waste
9/29/10 14:20
10/1/10 8:35
1-IERCIO-B
E104009-12
Waste
9/29/10 14:15
10/1/10 8:35
HERCII-B
E104009-13
Waste
9/29/10 14:30
10/1/10 8:35
HERC12-B
E104009-14
Waste
9/29/10 14:50
10/1/10 8:35
HERCI3-B
E104009-15
Waste
9/29/10 15:10
10/1/10 8:35
Page 3 of 34
E104009 TCLPM TMTL FINAL
1/4/11 10:55
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
DATA QUALIFIER DEFINITIONS
U J
The analyte was not detected at or above the reporting limit.
NA-5
Not Analyzed. Cannot exceed TCLP regulatory levels based on Total Scan analyses.
OM-1 OM-2 OM-3 OR-2
Matrix Spike Recovery less than method control limits
The identification of the analyte is acceptable; the reported value is an estimate.
Matrix Spike Recovery greater than method control limits Matrix Spike Precision outside method control limits MRL verification recovery greater than upper control limits.
ACRONYMS AND ABBREVIATIONS
CAS
Chemical Abstracts Service Note: Analytes with no known CAS identifiers have been assigned codes beginning with “E”, the EPA ID as assigned by the EPA Substance Registry System (www.epa.gov/srs), or beginning with “R4-”, a unique identifier assigned by the EPA Region 4 laboratory.
MDL
Method Detection Limit The minimum concentration of a substance (an analyte) that can be measured and reported with a 99% confidence that the analyte concentration is greater than zero.
M.R.L
Minimum Reporting Limit Analyte concentration that corresponds to the lowest demonstrated level of acceptable quantitation. The MRL is sample-specific and accounts for preparation weights and volumes, dilutions, and moisture content of soil/sediments.
TIC
Tentatively Identified Compound An analyte identified based on a match with the instrument software’s mass spectral library. A calibration standard has not been analyzed to confirm the compound’s identification or the estimated concentration reported.
-
-
Page 4 of 34
-
El04009 TCLPM TMTL FINAL
1/4/11 10:55
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700
•
D.A.R.T. Id: 10-0629 ‘?L PR3 cDs:.
Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
Total Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: ERBOI Station ID:
E104009-01
Matrix: Equipment Rinse Blank
Date Collected: 9/23/10 13:30 (‘IS .Vn,nher
dnulyte
7429-90-5
Aluminum
7440-36-0
Units
i3fRL
100 U
ugfL
100
12/03/10
12/20/lU
11:07
Antimony
40 U
ug/L
40
12/03/10
7440-38-2
Arsenic
50 U
ug/L
50
13:47 12/20/10 13:47 112010
7440-39-3
Barium
5.0 U
ug/L
5.0
7440-41-7
Beryllium
3.0 U
ugIL
3.0
7440-43-9
Cadmium
5.0 U
ugh..
5.0
7440-70-2
Calcium
250 U
ugIL
250
7440-47-3
Chromium
5.0 U
ug/L
5.0
7440-48-4
Cobalt
5.0 U
ug/L
5.0
7440-50-8
Copper
10 U
ug/L
10
7439-89-6
Iron
100 U
ugfL
100
7439-92-I
Lead
20 U
ug/L
20
7439-95-4
Magnesium
250 U
ug/L
250
7439-96-5
Manganese
5.0 U
ugfL
5.0
7439-98-7
Molybdenum
10 U
ug/L
10
7440-02-0
Nickel
10 U
ugfL
10
7440-09-7
Potassium
1000 1.]
ugj’L
1000
7782-49-2
Selenium
45 U
ughL
7440-22-4
Silver
5.0 U
ug/L
5.0
7440-23-5
Sodium
1000 U
ug/L
1000
7440-24-6
Strontium
5.0 U
ugfL
5.0
7440-28-0
Thallium
30
U
ugIL
30
7440-32-6
Titanium
5.0 U
ug/L
7440-62-2
Vanadium
5.0 U
7440-65-5
Yttrium
7440-66-6
Zinc
PageS of 34
Results Qualifiers
E104009 TCLPM TMTL FINAL
Prepured
11:07 12/03/lU
lnavzed Method
11:07
3:47
12/03/tO 11:07 12103/10 ll:07 12/03/10 11:07 12/03/lU 11:07 12/03/lO 11:07 2 0310 11:07 12/03/10 11:07 l2/03:l0 11:07 12/03/10 11:07 12/03/10 11:07 12/03/10 11:07 12/03/b 11:07 12/03/10 11:07
12/20/10
12/03110
11:07 12/03/10 11:07 l2J03/I0 11:07 12/03/10 11:07 I2/03/lO
13:47 12/20/10 13:47 12/20/10 13:47 2/20/10 13:47 12/20/10 13:47 12/20:10 l3:47 12/20/10 13:47 I2v20/I0 13:47 12/20/10 13:47 12/20/10 13:47 12/20/10 13:47 12/20/10 13:47 12/2W10 13:47 12/20/10 13:47 12)20/10 13:47 12/20/10 13:47 12/20/10 13:47
EPA6OIO EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 60I0
EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010
EPA 6010 EPA
6010
EPA 6010
11:07
I2/20/bo 13:47
EPA 6010
12/03/10 11:07
12/20/10 13:47
EPA 6010
5.0
12/03/lO
11’20/bO
11:07
13:47
ug/L
5.0
12/03/Ia
12/20/la
3.0 U
ug’L
3.0
10 U
ug/L
10
11:07 12103/lU 1:07 12/03/10 11:07
13:47 12/20/10
13:47 12/20/10 13:47
EPA
6010
EPA 6010 EPA 6010 EPA 6010
1/4/lI 10:55
0
D I
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700
“
-,
L
0
DART. Id: 10-0629
Project: 10-0629 Hercules Inc Repoed by Jenny Scifres
o’
-
TCLP Metals
Project: 10-0629, Hercules Inc Lab ID:
Sample ID: ERBOI
E104009-O1
Matrix: Equipment Rinse Blank
Station ID: Date Collected: 9/23/10 13:30 C4S
Number
4na!yte
7440-38-2
Arsenic:
Results Qualifiers
NA-5
Units
4IRL
Prepared
1.0
12/29/10 10-38
12/2910 1041
EPA 6010
12/29/10
12/29/10
1038 12/2910 10-38
0:41 12/29/10 10-41 12/29/ID
EPA 6010
7440-39-3
Barium:
XA-5
010
7440-43-9
Cadmium:
NA-5
0.10
7440-47-3
Chromium:
NA-5
0.10
7439-92-1
Lead:
NA-5
0.40
7782-49-2
Selenium:
NA-5
0.90
7440-22-4
Silver:
NA-5
0.10
Page 6 of 34
E104009 TCLPM TMTL FINAL
12/29/10 10-38 12/29/10 10-38 12/29/10 10-38 12/29/10 l0
.4nalyed
10:41 12/29/10 10:41 12/29/10 10:41 12/29/10 041
lkthad
EPA6OIO EPA 6010 EPA6OIO EPA 6010 EPA6OIO
1/4/I 1 10:55
0
0
UNETED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
Total Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: PBO1 Station ID:
E104009-02
Matrix: Preservative Blank
Date Collected: 9/23/10 13:30 C.4S
Number
.4nalyte
7429-90-5
Aluminum
7440-36-0
Antimony
40 U
ugfL
7440-38-2
Arsenic
50 U
ug/L
Re.s’idis Qualifiers
100 U
Units
‘tIRL
Prepared
ugL
100
12120/10 14:08
EPA 6010
40
2/03/10 11:07 12/03/10 11:07
12/20/10 14:08
EPA 6010
50
12/03110 11:07
12/20/10 14:00
EPA 6010
12/20110
EPA 6010
.tnaly:ed Method
7440-39-3
Barium
5.0 U
ugfL
5.0
12103/10
11:07
14:08
7440-41-7
Beryllium
3.0 U
ugfL
3.0
12/03/10
2120/10
Cadmium
5.0 U
ugIL
5.0
250 U
ug/L
250
5.0 C
ug/L
5.0
11:07 12/03/10 11:07 12103/10 1107 12/03/10 11:07
14.08 12/20/10 14:08 12/20/10 1408 12/20/10 14:08 12/20/10
7440-43-9 740-7Q-2
7440-47-3
Calcium Chromium
7440-48-4
Cobalt
5.0 U
ug/L
5.0
12/03/10 11:07
7440-50-8
Copper
10 U
ugfL
10
12/03/10 11:07
14:08
7439-89-6
Iron
100 U
ug/L
100
7439-92-1
Lead
20 U
ug/L
20
2/OYIO 1107 12/03/10 11:07
12/20/10 14:08 12/20/10 14:08
7439-95-4
Magnesium
250 U
ug/L
250
12/03/10
12/20/10
7439-96-5
Manganese
5.0 U
ug/L
5.0
11:07 12/03/10 11:07
14:08 12/20/10 14:08
7439-98-7
Molybdenum
JO U
uWL
10
12/03/10 11:07
12/20/10
7440-02-0
Nickel
7440-09-7
Potassium
7782-49-2 7440-22-4
12/03/10 11:07 12/03/10 11:07 12/03/10 11:07 12/03/10 11:07 12/23/10 11:07 12/03/10 11:07 12/03/10
10 U
ug/L
10
1000 U
ug/L
1000
Selenium
45 U
ugfL
Silver
5.0 U
ug/L
5.0 1000
7440-23-5
Sodium
1000 U
ug/L
7440-24-6
Strontium
5.0 U
ug/L
5.0
7440-28-0
Thallium
30 U
ug/L
30
7440-32-6
Titanium
5.0 U
ug!L
7440-62-2
Vanadium
5.0 U
ug/L
5.0
7440-65-5
Yttrium
3.0 U
ug/L
3.0
7440-66-6
Zinc
10 U
ug/L
10
Page 7 of 34
E104009 TCLPM TMTL FINAL
4.08 12/20/10
14:08 12/20/10 14:08 12/20/10 14:08 12)20/10 14:08 12/20/10 14:08 12/20/10 14:08 12120/10
14:08 12/20/10
11:07
14:08
12/03/10 11.07 12/03/10 11:07 12/03/10 11:07 12/03/10
12120/10 14:08 12120/10 14:08 12/20/10 14:08 12/20/10
11:07
14:08
EPA 6010 EPA 6010 EPA 6010 EPA
6010
EPA 6010
EPA 6010 EPA 6010 EPA 6010 EPA 6010
EPA 6010 EPA 6010
EPA 6010 EPA 6010
EPA 6010 EPA 6010 EPA 6010
EPA 6010 EPA 6010 EPA 6010
EPA 6010 EPA 6010 EPA
6010
1/4/11 10:55
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
TCLP Metals Project: 10-0629, Hercules Inc Lab 1D
Sample ID: PBO1
E104009-02
Matrix: Preservative Blank
Station ID: Date Collected: 9/23/10 13:30 C4S u,nher
dnalyte
7440-38-2
Arsenic:
7440-39-3 7440-43-9 7440-47-3 7439-92-I 7782-49-2 7440-22-4
Page 8 of34
Results Qualifiers
NA-5
Barium:
NA-5 NA-5
Cadmium: Chromium:
NA-5
Lead:
NA-5
Selenium:
NA-5
Silver:
NA-5
E104009 TCLPM TMTL FINAL
Units
MRL
1.0 0.10 0.10 0.10 0.40 0.90 0.10
Prepared
1nu1ved Method
12/29/10
EPA 6010
12/0
12129)10
EPA 6010
22910
12/2910
EPA 6010
12/29/10
92:/i10
EPA 6010
12/2910
12910
EPA 6010
12/29/10 12/29iW
EPA 6010 12,29/10
EPA6OIO
1/4/11 10:55
0
0
UNTTED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700
Z
D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Repoed by Jenny Scifres -
Total Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO1-A Station ID: HERCO1
E104009-03
Matrix: Waste
Date Collected: 9/28/10 10:10 ClS ,Vurnher
.4.al;’re
7429-90-5
Aluminum
7440-36-0
Antimony
7440-38-2
Arsenic
7440-39-3
Barium
7440-41-7
Results Qualifiers
Units
7tIRL
Prepared
.4nidwzed
12/09/10
14:01 12109/10
ii:oi
12/20/10 15:10 12120/10 15:10 12/20110 1510
licEhod
mg/kg
9.3
3.7 U
mg/kg
37
4.7 U
mg/kg
4.7
12109/10 41)1
18
mg/kg
0.47
Beryllium
0.28 Ii
mg/kg
0.28
7440-43-9
Cadmium
0.47 U
mg/kg
0.47
7440-70-2
Calcium
75 J, QM-2, Qvl-3
mg/kg
23
7440-47-3
Chromium
24
mg/kg
0.47
7440-48-4
Cobalt
7.9
mg/kg
0.47
7440-50-8
Copper
69 J, QM-2, QM-3
mg/kg
0.93
7439-89-6
Iron
7439-92-1
Lead
23
mg/lcg
1.9
7439-95-4
Magnesium
65
mg/kg
23
7439-96-5
Manganese
4.6
mg/kg
0.47
7439-98-7
Molybdenum
8.0
mg/kg
0.93
7440-02-0
Nickel
71 J, QM-2, QM-3
mg/kg
0.93
7440-09-7
Potassiuns
93 U
mg/kg
93
7782-49-2
Selenium
4.2 U
mg/kg
4.2
7440-22-4
Silver
0.47 U
mg/kg
0.47
7440-23-5
Sodium
170 3, QR-2
mg/kg
12/09/10 14:01 12109/10 14:01 12/09/10 14:01 12./09/10 1401 12/09/10 14:0! 12/0910 1401 12/09/10 14:01 12109/10 14:01 12/09/10 14:01 1209/10 1401 12/09/10 14:01 12109/10 14:01 12/09/10 14:01 12/09/lU 1401 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01
12/20/10 15:10 12120/10 15:10 12/20/10 15:10 12/20/10 15:10 12/20/10 15:10 12/20/10 15:10 12/20/10 15:10 12/20/tO 15:10 12/20/10 15:10 12:20/10 1510 12/20/10 15:10 12/20/10 15:10 12/20/10 15:10 12/20/10 15:10 12120/10 15:10 12/20/10 15:10 12/20/10 15:10
7440-24-6
Strontium
2.1
mg/kg
0.47
12.09,10
12i20/l0
7440-28-0
Thallium
2.8 U, J, QM-1
mg/kg
2.8
14:01 12109/10 14:01
15:10 12120/10 15:10
EPA
12/20:10 15:10
EPA 6010 EPA 6010
7440-32-6
Titanium
7440-62-2
Vanadium
7440-65-5
Yttrium
7440-66-6
Zinc
Page 9 of 34
6600
1200 J. QM-2
E104009 TCLPM TMTL FINAL
mg/kg
32
mg/kg
0.47
12/09:10 14.01
4.3
mg/kg
0.47
12/09/10
12120/10
0.58
mg/kg
0.28
270 J, QM-2, QM-3
mg/kg
1401 12J09/l0 14:01 12/09/10 14:01
15:10 12/20/10 15:10 12/20/10 15:10
.
1.9
EPA 6010
EPA 6010 EPA
6010
EPA 6010 EPA 6010
EPA 6010 [P\
6010
EPA 6010 EPA6OIO EPA 6010 EPA
6010
EPA
6010
EPA 6010 EPA
6010
EPA 6010
EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA6OIO
6010
EPA 6010 EPA
6010
1/4/11 10:55
0
C)
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
TCLP Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: IIERCOI-A
E104009-03
Matrix: Waste
Station ID: IIERCOI Date Collected: 9/28/10 10:10 C4S her
7440-38-2
.dnalyfr
ResuIt Quali:/ier.s
Arsenic:
NA-5
Unjs
MRL
1.0
7440-39-3
Barium:
NA-5
0.10
7440-43-9
Cadmium:
NA5
0.10
7440-47-3
Chromium:
NA-5
0.10
7439-92-1
Lead:
NA-5
0.40
7782-49-2
Selenium:
NA-5
0.90
7440-22-4
Silver:
NA-5
0.10
Page 10 of34
E104009 TCLPM TMTL FINAL
Prepared 12129/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 0:38
.1navzed iltethod 12129/10 10:41
12/29/10 10:41 12129/10 10:41 12/29/10 10:41 12/29/10 10:41 12/29/10 10:41 12/29/10 10:41
EPA
6010
EPA 6010 EPA 6010
EPA6O1O EPA6OIO
EPA 6010 EPA6OIO
1/4/11 10:55
0
0 ST
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700
I
D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Jenny Scifres
P9O
-
Total Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO2-B Station ID: HERCO2
E104009-04
Matrix: Waste
Date Collected: 9/28/10 10:55 (‘AS Vumber
.4na!yte
7429-90-5
Aluminum
7440-36-0
Antimony
7440-38-2
Arsenic
7440-39-3
Barium
7440-41-7
7440-43-9
7440-47-3
Results Qualifiers
4900
Units
mg/kg
3.9 U
mg/kg
4.9 U
mg/kg
MRL
9.8
Prepared
.4navzed
12/09/tO 14:01 12109)10 14:01
12/20/10 15:33 12)20/10 15:33 12/20110 5:33 12/20/10 15:33 2r20/Io 15:33 12/20/10 15:33 2/20/10 15:33
18
mg/kg
0.49
Beryllium
0.29 U
mg/kg
0.29
Cadmium
0.49 U
mg/kg
0.49
Calcium
58
mg/kg
25
14:01 12109/10 14:01 12/09/10 l4:01 12/09/10 14:01 12/09/tO 1401
Chromium
11
mg/kg
0.49
12/09/10 14:01
12/20/10 15:33
Cobalt
14
mg/kg
0.49
12/09/10 14:01 12/09/10 14:01 2,09:10 14:01 12/09/10 14:01 12/09/10 14:01
12/20/10 15:33 12/20/to 15:33 220/10 15:33 12/20/10 15:33 12/20/10 15:33
12/09/10
12/20/10 15:33 12/20/10 5:33
7440-50-8
Copper
4-89-6
Iron
7439-92-1 7439-95-4
44
mg/kg
0.98
1600
mg/kg
9.8
Lead
60
mg/kg
2.0
Magnesium
45
mg/kg
25
7439-96-5
Manganese
3.8
mg/kg
7439-98-7
Molybdenum
3.1
mg/kg
0.98
14:01 12109/10 14:01
7440-02-0
Nickel
120
mg/lcg
0.98
12/09/10 14:01
12/20/10
7440-09-7
Potassium
98 U
mg/kg
98
7782-49-2
Selenium
4.4 U
mg/kg
12/20/10
7440-22-4
Silver
0.49 U
mg/kg
12/09/tO 14:01 12/09/10 14:01 12/09/tO 1401
7440-23-5
Sodium
12109/10
12/20/10
7440-24-6
0.49
0.49
150 J, QR-2
mg/kg
98
Strontium
1.6
mg/kg
0,49
7440-28-0
Thallium
2.9 U
mg/kg
2.9
7440-32-6
Titanium
17
mg/kg
0.49
7440-62-2
Vanadium
2.1
mg/kg
0.49
7440-65-5
Yttrium
0.57
mg/kg
0.29
7440-66-6
Zinc
120
mg/kg
2.0
Page 11 of34
E104009 TCLPM TMTL FINAL
14:0] 12109/tO 14:01 12/09/10 14:01 120910 14:01 12/09/10 14:01 12/09/tO 14:01 12/09/tO 14.01
15:33 12/20/tO 15:33 15:33 12/20/10 15:33 15:33 12/20/10 15:33 12120/tO 15:33 12/20:10 15:33 12/20/10 5:33 12/20/10 15:33 12120/10 15:33
Method
EPA 6010
EPA
6010
EPA 6010
EPA 6010 EPA 6010 EPA 6010 EPA 6010
EPA 6010 EPA 6010 EPA 6010 EPA 6010
EPA 6010 EPA 6010
EPA 6010 EPA 6010
EPA 6010 EPA 6010 EPA 6010 EPA 6010
EPA 6010 EPA6OIO EPA 6010 EPA 6010 EPA6OIO EPA 6010 EPA 6010
1/4/Il 10:55
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, HercuIs Inc Reported by Jenny Scifres -
TCLP Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO2-B
E104009-04
Matrix: Waste
Station ID: HERCO2 Date Collected: 9/28/10 10:55 C4S Nninber
.4nalyte
7440-38-2
Arsenic:
7440-39-3 7440-43-9 7440-47-3 7439-92-1 7782-49-2
7440-22-4
Page 12of34
,IIRL
Prepured
NA-5
1.0
Barium:
NA-5
0.10
12129/10 038 12/29/10
12129,10 1041 12/29/JO
Cadmium:
NA5
0.10
10:38 12129/10 0:38
041 12,29/10
12/29/10
12/29/10
Results Qualifiers
Chromium:
A-5
Lead:
NA-5
Selenium:
NA-5
Silver:
NA-5
E104009 TCLPM TMTL FINAL
Units
0.10 0.40
10:38 I2/29/l0 038
0.90
12/29/10 IO’38
0.10
!2/29I0 1039
.4nu1zed ,lfethod
1041
EPA 6010 EPA6OIO EPA 6010
1041
EPA 6010
12/29/10 1041 12/29/10
EPA 60l0
1O4l
EPA 6010
12/2910 041
EPA 6010
1/4/11 10:55
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
Total Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO3-B Station ID: HERCO3
E104009-05
Matrix: Waste
Date Collected: 9/28/10 13:15 C ES ,\umher
.4na!te
7429-90-5
Aluminum
RexulI Qualifiers
5700
Units
MRL
mg/kg
.
Prepared
12109/10
-
.4nalyzed Method
12120/10 1541 12)20/10 15:41
EPA 6010
7440-36-0
Antimony
3.7 U
mg/kg
7440-38-2
Arsenic
4.6 U
rng:kg
4.6
1109/10 1401
7440-39-3
Barium
21
mg/kg
0.46
7440-41-7
Beryllium
0.27 U
mg/kg
0.27
7440-43-9
Cadmium
0.46 U
mg/kg
0.46
12/09/10 1401 I20910 (401 12/09/10 1401
7440-70-2
Calcium
210
mg/kg
12109/10 14:01
744b47-3
Chromium
7.7
mg/kg
7440-48-4
Cobalt
2.9
mg/kg
0.46
12)09/10 1401 12/09/10 140I
15:41
EPA 6010
7440-50-8
Copper
29
mg/kg
0.92
12/09/10 1401
12/20/10 15:41
EPA 6010
7439-89-6
Iron
4300
mg/kg
9.2
Lead
9.1
mg/kg
1.8
7439-95-4
Magnesium
230
mg/kg
23
7439-96-5
Manganese
31
mg/kg
0.46
7439-98-7
Molybdenum
0.92 U
mg/kg
0.92
7440-02-0
Nickel
7440-09-7
Potassium
7782-49-2
Selenium
7440-22-4
Silver
7440-23-5
Sodium
7440-24-6
I2/20/I0 15:41 12/20/10 15:41 2/20/b 15:41 12/20/10 15:41 12/20/10 15:41 12/20/10 (5:41 12/20/10 15:41 12/20/10 15:41 2/20/10 (5:41 (2/20/10 15:41 12/20/10 15:41 12/20/10 15.41 12/20/10 15:41 12120/10 15:41 12/20/10 15:41 12/20/10 1541
EPA 6010
7439-92-1
12/09/10 1401 12109/10 14:01 l2/09/Io 14:01 12/09/10 1401 12/09/10 1401 12/09/10 1401 2109/10 1401 12/09/10 14:01 12/09/10 (401 12/09/10 14:01 12/09/10 1401 12/09/10 1401 12/09/10 1401 12/09/10 1401 12/09/10 1401 12/09/10 14:0!
-,
0.46
80
mg/kg
0.92
180
mg/kg
92
4.1 15
mg/kg
4.1
0.46 U
mg/kg
0.46
92 15
mg/kg
Strontium
2.1
mg/kg
0.46
7440-28-0
Thallium
2.7 U
mg/kg
2.7
7440-32-6
Titanium
62
mg/kg
0.46
7440-62-2
Vanadium
8.7
mg/kg
0.46
7440-65-5
Yttrium
1.2
mg/kg
0.27
7440-66-6
Zinc
68
mg/kg
l.oo
Page 13 of34
E104009 TCLPM TMTL FINAL
12/09/10 14:01
EPA
6010
ll’20l0
15:41 15:41 2120/10 5:41 12/20/10 15:41 12/20/10 15:41
12/20/10 15:41 I2’20/I0
EPA 6010 EPA 6010
EPA 6010 EPA 6010 EPA
6010
EPA 6010 EPA 6010 EPA 6010 EPA 6010
EPA 6010 EPA6OIO EPA 6010 EPA
6010
EPA
6010
EPA 6010
EPA 6010 EPA 6010
EPA 6010 EPA6OIO EPA 6010
1/4/11 10:55
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 I).A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
TCLP Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO3-B
E104009-05
Matrix: Waste
Station ID: HERCO3 Date Collected: 9/28/JO 13:15 (ZIS .Vumher
.4nalyte
7440-38-2
Arsenic:
7440-39-3 7440-43-9 744047-3
7439-92-1 7782-49-2 7440-22-4
Page I4of34
Results Qualifiers
NA-5
barium:
NA-5
Cadmium:
NA-S
Chromium:
NA-S
Lead:
NA-5
Selenium:
NA-5
Silver:
NA-5
E104009 TCLPM TMTL FiNAl.
Units
MRL
1naly.ed
12/29/10
12/29/10
12/29/10
1229,I0
EPA 6010
‘°
12129/10
EPA 6010
EPA 6010
1.0 0.10 0.10 0.10
0.40 0,90 0.10
lh’thod
Prepared
I229/i0
EPA 6010
‘° 1229/i0
EPA 6010
EPA 6010 I229/IO
EPA 6010
1/4/11 10:55
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
Total Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO4-B Station ID: HERCO4
E104009-06
Matrix: Waste
Date Collected: 9/28/10 13:50 C.4S Number
.4nalyw
Rc,,lIy Qualifiers
Units
31RL
Prepared
.4nulyzed
12/20/10 15:49 ll’20:l0 5:49 12/20/10 15:49 12120/10 15:49 12/20/10 15:49 12/20/10 15:49 12/20/10 15:49 12/20/10 15:49 12120/10 15:49
7429-90-5
Aluminum
7440-36-0
Antimony
3.6 U
mg/kg
7440-38-2
Arsenic
6.4
mg/kg
4.6
7440-39-3
Barium
27
mg/kg
0.46
7440-41-7
Beryllium
0.27 U
mg/kg
0.27
7440-43-9
Cadmium
0.46
mg/kg
0.46
7440-70-2
Calcium
400
mg/kg
23
7440-47-3
Chromium
29
mg/kg
0.46
7440-48-4
Cobalt
14
mg/kg
0.46
7440-50-8
Copper
100
mg/kg
0.91
12109/10 14:01 12/09/10 14:01 1209/10 14:01 12/09/10 14:01 12/09/10 14:01 12J09/10 14:01 12/09/10 4:01 12/09/10 14:01 12/09/10 14:01 12109/10 14:01
7439-89-6
Iron
3400
mg/kg
9.1
2/09/10 14:01
7439-92-1
Lead
26
mg/kg
1.8
7439-95-4
Magnesium
76
mg/kg
23
7439-96-5
Manganese
0.46
7439-98-7
Molybdenum
7440-02-0
Nickel
7440-09-7
Potassium
7782-49-2
Selenium
7440-22-4
Silver
7440-23-5
Sodium
7440-24-6
Strontium
7440-28-0
Thallium
7440-32-6
Titanium
7440-62-2
Vanadium
7440-65-5 7440-66-6
12/09/10 14:01 12’09/I0 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12109/10 I40l 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 1401 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01
Page 15 of34
5200
mg/kg
9.1 3.6
14
mg/kg
4.0
mg/kg
0.91
200
mgllcg
0.91
96
mg/kg
91
4.1 U
mg/kg
4.1
0.46 U
mg/kg
0.46
mg/kg
91
6.1
mg/kg
0.46
2.7 U
mg/kg
2.7
42
mg/kg
0.46
5.6
mg/kg
0.46
Yttrium
0.99
mg/kg
0.27
Zinc
510
mg/kg
1.8
130 J, QR-2
E104009 TCLPM TMTL FINAL
12/20/10 15:49
12i20/I0
I5:49 12/20/10 15:49 12/20/10 15:49 12/20/10 15:49 12/20/10 15:49 12/20/10 15:49 12/20/10 15:49 12/20/10 15:49 12120/10 15:49 12/20/10 15:49 12/20/10 5:49 12/20/10 15:49 12/20/10 15:49 12/20/10 15:49 12/20/10 15:49 12/20/10 15:49
lh’thod
EPA 6010 EPA
6010
EPA 6010 EPA 6010 EPA 6010 EPA
6010
EPA 6010
EPA 6010 EPA 6010 EPA
6010
EPA 6010
EPA 6010 EPA 6010
EPA 6010 EPA6OIO
EPA6OIO EPA 6010
EPA6OIO EPA 6010 EPA 6010 EPA 6010
EPA 6010 EPA 6010 EPA
6010
EPA 6010 EPA6OIO
1/4/11 10:55
0
CD
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
TCLP Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO4-B
E104009-06
Matrix: Waste
Station 1D: HERCO4 Date Collected: 9/28/10 13:50 C4S Number
.4nalyte
7440-38-2
Arsenic:
7440-39-3
Results Qualifiers
NA-S
Barium:
XA-5
Units
MRL
1.0 0.10
7440-43-9
Cadmium:
NA-5
0.10
7440-47-3
Chromium:
NA-S
0.10
7439-92-I
Lead:
NA-5
0.40
7782-49-2
Selenium:
NA5
0.90
7440-22-4
Page 16of34
Silver:
NA-S
E104009 TCLPM TMTL FINAL
0.10
Prepared 32)29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:30 12/29!I0 030
.4nusvzed Slethod 2)29/10
10:4 I 32/29/10
10:41 12)29/10 I0:41 1229/10 10:43 12/29/30 10:41 12/29/10 30:43 2/29/Il/
EPA 6010
EPA
6010
EPA 6010 EPA6OIO
EPA 6010 EPA
6010
EPA 6010
1/4/11 10:55
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
Total Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCOS-A
E104009-07
Matrix: Waste
Station ID: HERCO5 Date Collected: 9/28/10 14:05 C4S
Number
4nalyte
7429-90-5
Aluminum
Results Qual:jiers
5100
Units
mg/kg
tIIRL
9.7
7440-36-0
Antimony
3.9 U
mg/kg
7440-38-2
Arsenic
5.6
mg/kg
7440-39-3
Barium
35
mg/kg
0.49
7440-41-7
Beryllium
0.29 U
mg/kg
0.29
7440-43-9
Cadmium
0.49
mg/kg
0.49
7440-70-2
Calcium
2000
mg/kg
24
7440-47-3
Chromium
45
mg/kg
0.49 0.49 0.97
7440-48-4
Cobalt
17
mg/kg
7440-50-8
Copper
84
mg/kg
7439-89-6
Iron
7439-92-1
Lead
7439-95-4
kIagnesium
7439-96-5
Manganese
7439-98-7
Molybdenum
4600
mg/kg
34
mg/kg
1.9
1556 12/20/10 15:56 1120/lU 15:56 12/20/10 15:56
EPA 6010 EPA 6010
0.49
mg/kg
0.97 0.97 97
2/0910 140I
12/20/10 15:56
12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12109/10 14:01 12/09/10 14:01 1309/10 14:01 12/09/10 14:01 12/09/10 401 12/09/10
12/20/10 15.56 12/20/10 5:56 12/20/10 15:56 l2120l0 15:56
210 110
mg/kg
7782-49-2
Selenium
4.4 U
mg/kg
7440-22-4
Silver
0.49 U
mg/kg
7440-23-5
Sodium
460 3, QR-2
mg/kg
97
7440-24-6
Strontium
8.9
mg/kg
0.49
7440-28-0
Thallium
2.9 U
mg/kg
2.9
7440-32-6
Titanium
51
mg/kg
0.49
7440-62-2
Vanadium
6.6
mg/kg
0.49
1.1
mg/kg
0.29
690
mg/kg
1.9
E104009 TCLPM TMTL FINAL
12.2010
32
Potassium
Page 17 of34
l209 10
4.8
Nickel
Yttrium
l5:56 12/20/10 15:56 12/20/10 l5:56 12/20/10 15:56 12/20/10 15:56 12/20/10 15:56 1220110 15:56 /2(2/10 15:56
12/20/b
1401 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01
24
0.49
EPA 6010
12/09/10 14:01 2/09/10 1401 12/09/10 14:01 12/09/b 14:01 12/09/10 14:01 12/09/tO I4Ol 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/lO 4:01 12/09/10 14:01
mg/kg
7440-09-7
Zinc
12120/10 15:56 12/20/10 15:56 12/20/10 l556 12/20/10 15:56
mg/kg
7440-02-0
7440-66-6
2/09/10
Analyzed Method
170
mg/kg
7440-65-5
Prepared
14:01
12/20/10
1556 1220/10 15:56 12/20/10 15:56 12/20/10 1556 12/20/10 15:56
EPA
6010
EPA 6010
EPA 6010 EPA
6010
EPA 6010 EPA 6010 EPA
6010
EPA 6010 EPA 6010 EPA 6010
EPA6OIO EPA
6010
EPA 6010 EPA 6010
EPA
6010
EPA 6010 EPA
6010
EPA 6010 EPA
6010
EPA6OIO EPA
6010
EPA6OIO
EPA6OIO
1/4/11 10:55
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 1 0-0629, Hercules Inc Reported by Jenny Scifres -
TCLP Metals Project: 10-0629, Flercules Inc Lab ID:
Sample ID: HERCO5-A
E104009-07
Matrix: Waste
Station ID: HERCO5 Date Collected: 9/28/10 14:05 CAS Nunber
.4naiyte
7440-38-2
Arsenic:
7440-39-3
Results
Qualifiers
NA-5
Barium:
>A-5
Units
MRL
1.0 0.10
7440-43-9
Cadmium:
NA5
0.10
7440-47-3
Chromium:
NA-5
0.10
7439-92-1
Lead:
NA-5
0.40
7782-49-2
Selenium:
NA-5
0.90
7440-22-4
Silver:
NA-5
0.10
Page 18 of34
E104009 TCLPM TMTL FINAL
Prepared
•trwly:ed lfethod
12/29/10 10:38
12/29/10
12/29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:38
12/29/10
10:41
10:41 12/29/10
10:41 12129/10 10:41 12/29/10 10:41 12/29/10 10:41 12/29/10 10:41
EPA 6010 EPA6O1O EPA 6010
EPA 6010 EPA 6010
EPA 6010 EPA6OIO
1/4/11 10:55
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Jenny Scifres
ZLpRo1”
-
Total Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO6-B Station 1D: HERCO6
E104009-08
Matrix: Waste
Date Collected: 9/28/10 14:55 ( IS N,u,zhs’r
.4nulyre
7429-90-5
Aluminum
7440-36-0
Antimony
3.9 U, I, QM-1
mg/kg
7440-38-2
Arsenic
4.9 U
mg/kg
7440-39-3
Barium
100 J, QM-2
mg/kg
0.49
7440-41-7
Beryllium
0.30 U
mg/kg
0.30
7440-43-9
Cadmium
0.49 U
mg/kg
0.49
7440-70-2
Calcium
5000
mg/kg
25
7440-47-3
Chromium
mg/kg
0.49
7440-48-4
Cobalt
mg/kg
0.49
7440-50-8
Copper
27 J, QM-1, QM-3
mg/kg
0.99
7439-89-6
Iron
4000 J, QM-2. QM-3
mg/kg
Results Qualifiers
5800
20 J, QM-1
7.2
Units
1fRL
12109/10 14:01 12/09)10
mg/kg
14:01
7439-92-1
Lead
7439-95-4
Magnesium
440 J, QM-2
mg/kg
25
7439-96-5
Manganese
200 J, QM-2, QM-3
mg/kg
0.49
7439-98-7
Molybdenum
21 J, Q\1-l
mg/kg
0.99
7440-02-0
Nickel
54 J, QM-2
mg/kg
0.99
7440-09-7
Potassium
160
mg/kg
7782-49-2
Selenium
4.4 U
mg/kg
22
mg/kg
2.0
EPA 6010 EPA 6010
12/20/10
6:04 12/20/10 16:04 12/20/10 16:04 12/20/10 16:04 12/20/10 16:04 12/20/tO 16:04 12/20/10 604 12/20/10 16:04 12/20/10
1401
1604
12/20/10 16:04 12120/10 16:04
99
34 J, QM-2
mg/kg
0.49
12/09/10 4:0!
12/20/10
mg/lcg
3.0
12/09/10
12/20/10
mg/kg
0.49
14:0! 12/09/10 14:01 12/09/10 14:01 12/09/10
16:04 12/20/10 1604 12/20/tO 16:04 12/20/10
7440-24-6
Strontium
7440-28-0
Thallium
7440-32-6
Titanium
7440-62-2
Vanadium
3.9
mg/kg
0.49
7440-65-5
Yttrium
1.9
mg/kg
0.30
0.49 U
3.0 U, 3, QM-1
56 3, QM-2
500 .1, QM-1, QM-3
El 04009 TCLPM TMTL FINAL
16:04
12/09)10 14:0! 1209/10 4:0!
mg/kg
mg/kg
0.49
2.0
EPA 6010
EPA 6010
12,20/10 16:04
mg/kg
Sodium
Page 19 of 34
14:01
12/09/10 14:01 12/09/tO 14:01 12/OWlS
12/20/10 16:04 12/20/10 04 12120/10
180 J, QR.-2
Silver
7440-23-5
Zinc
14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10
.dnalyzed Method
12109/10 14:01 12/09/10 140! 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01
7440-22-4
7440-66-6
Prepared
12/20/tO 16:04 12/20/10 16:04 12/20/10 16:04 12120:10 16:04 12/20/10 16:04 1604
EPA 6010
EPA 6010 EPA 6010 EPA 6010 EPA 6010
EPA 6010 EPA 6010
EPA 6010 EPA 6010 EPA 6010
EPA 6010 EPA 6010 EPA 6010
EPA 6010 EPA 6010 EPA 6010
EPA 6010
EPA 6010 EPA 6010 EPA 6010
14:01
16:04
EPA 6010
12109/10 14:01
12/20/tO 16:04
EPA 6010
1/4/11 10:55
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
TCLP Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERC06-B
E104009-08
Matrix: Waste
Station 1D: HERCO6 Date Collected: 9/28/10 14:55 C4S Niunber
.4nalyte
7440-38-2
Arsenic:
Results Qualifiers
NA-5
Units
MRL
1.0
7440-39-3
Barium:
NA-5
0.10
7440-43-9
Cadmium:
NA-5
0.10
7440-47-3
Chromium:
NA5
0.10
7439-92-I
Lead:
NA-5
0.40
7782-49-2
Selenium:
XA-5
0.90
7440-22-4
Silver:
NA-5
0.10
Page 20 of34
E104009 TCL.PM TMTL FINAL
Prepared
.4nalvzed
12J291l0 1038 12/29/10 10:38 12/29/10 1038 12/29/10 10:38 12/29/10 1038 12/29/10 10:38 12/29/10 1038
12129/10 10:41 12/29/10 0:41 12129/10 10:41 12/29/10 10:41 1129/10 10:41 12/29/10 10:41 12/29/10 10:41
‘81ethod
EPA 6010 EPA 6010 EPA 60(0 EPA 6010 EPA6OIO
EPA 6010 EPA6OIO
1/4/lI 10:55
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700
-
D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
Total Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO7-B Station ID: HERCO7
E104009-09
Matrix: Waste
Date Collected: 9/28/10 15:25 ClS .Vu,,ther
.4nulvle
Results Qualifiers
7429-90-5
Aluminum
7440-36-0
Antimony
3.8 U
7440-38-2
Arsenic
7440-39-3
Barium
7440-41-7 7440-43-9
Units
MRL
Prepared
lnalvzed
9.5
12/09/10
12/20/10 704
mg/kg
3.8
12109/10
12/20/10
4.8 U
mg/kg
4.8
23
mg/lcg
0.48
Beryllium
0.29 U
mg/kg
0.29
Cadmium
0.48
mg/kg
0.48
710
mg/kg
24
32
mg/kg
0.48
Cobalt
9.5
mg/kg
0.48
12109/10
14:01
17:04 12/20/10 17:04 12/20/10 17:04 12/20/10 17:04 12/20/10 (704
7440-50-8
Copper
26
mg/kg
0.95
12109/10
12/20/10
14:01
7439-89-6
Iron
5200
mg/kg
7439-92-1
Lead
23
mg/kg
7439-95-4
Magnesium
62
mg/kg
24
7439-96-5
Manganese
37
mgllcg
0.48
17:04 12125/10 7:04 12/20/10 17:04 12/20/10 17:04 12/20/10 17:04
6700
Calcium
7440-47-3
Chromium
mg/kg
12109/10 14:01 12/09/10 4:01 12/09/10 14:01 12/09/10
14:01 12109/10 14:01
12/09/10
1.9
7439-98-7
Molybdenum
40
mg/kg
0.95
7440-02-0
Nickel
44
mg/kg
0.95
7440-09-7
Potassium
95 U
mg/kg
95
7782-49-2
Selenium
4.3 U-
mg/lcg
7440-22-4
Silver
7440-23-5
Sodium
7440-24-6
0.48 U
14:01 12109110
14:01 12/09/10 14:01 12/0910
1401 12109/10 14:01
1704 12120/10
12/20/10 17:114 2120/10
12/09/10
1220/10
14:01 12/09/10 14:01 12/09/10
7:04 12120/10 17:04 2/20/10
tfethod
EPA 6010
EPA 6010 EPA 6010 EPA 6010 EPA6OIO
EPA 6010 EPA 60(0 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 60(0 EPA 6010 EPA 6010
14:01
1704
12/09/10 14:01 12/09/10 14:01
12/20/10 17:04 12/20/10
EPA 6010
EPA6OIO
mg/kg
0.48
130 J, QR-2
mg/kg
95
12/09/10
Strontium
8.9
mg/kg
0.48
7440-28-0
Thallium
2.9 U
mg/kg
2.9
7440-32-6
Titanium
22
mg/kg
0.48
7440-62-2
Vanadium
2.8
mg/kg
0.48
12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01
12/20/10 17:04 12-20,10 17:04 2/20)10 17:04 12120/10 17:04 2/20/10 17:04
7440-65-5
Yttrium
1.7
mg/kg
0.29
2091(0 1401
1220:10 7-04
EPA6OIO
7440-66-6
Zinc
1.9
12/09/10 14:01
12/20/10 17:04
EPA 60(0
Page 21 of 34
650
E104009 TCLPM TMTL FINAL
mg/kg
.
7:04
EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010
1/4/11 10:55
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART, Id: 10-0629
Prolect: 10-0629, Hercules Inc Reported by Jenny Scifres -
TCLP Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO7-B
E104009-09
Matrix: Waste
Station ID: HERCO7 Date Collected: 9/28/10 15:25 C4S Number
lna!yte
7440-38-2
Arsenic:
NA-S
1.0
7440-39-3
Barium:
NA-5
0.10
Results Qualijiers
Units
MRL
7440-43-9
Cadmium:
NA-S
0.10
7440-47-3
Chromium:
NA-S
0.10
7439-92-1
7782-49-2 7440-22-3
Page 22 of 34
NA-5
Lead:
NA-S
Selenium:
NA-S
Silver:
E104009 TCLPM TMTL FINAL
0.40
0.90
0.10
Prepared
.lnalrzed ,Olethod
12/29/10 038 12)29110 10:38
12/29/10 10:41 12/29/10 10:41
1129/10 10:30 12/29/10 10:38
12/29/10 10:41 12/29/10 10:41
12/29/10
12/29/10
EPA 6010 EPA 6010 6010
EPA6O1O
0:38
1041
EPA 6010
12/29/10
12/29/10
EPA 6010
10:38
1041
1229 0 039
112910
1041
EPA 6010
1/4/11 10:55
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
Total Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO8 Station ID: HERCO8
E104009-10
Matrix: Waste
Date Collected: 9/29/10 8:50 C IS lnalvte
Results Qualifiers
Units
MRL
Prepared 12/09/10 1401 12/09/10 14:01 1209/10
7429-90-5
Aluminum
7440-36-0
Antimony
3.9 U
mg/kg
7440-38-2
Arsenic
4.8 U
mg/kg
4.8
7440-39-3
Barium
61
mg/kg
0.48
12/09/10
744041-7
Beryllium
0.29 u
mg/kg
0.29
12/09/10
7440-43-9
Cadmium
0.48 U
mg/kg
0.48
7440-70-2
Calcium
250
mg/kg
24
7440-47-3
Chromium
20
mg/kg
0.48
7440-48-4
Cobalt
2.7
mg/kg
0.48
7440-50-8
Copper
7439-89-6
Iron
7439-92-1
Lead
7439-95-4
Magnesium
7439-96-5
Manganese
7439-98-7
Molybdenum
7440-02-0
Nickel
7440-09-7
7900
mg/kg
9.6
17
mg/kg
8300
mg/kg
9.6
24
mg/kg
1.9
240
mg/kg
24
350
mg/lcg
0.48
37
mg/lcg
0.96
8.2
mg/kg
0.96
Potassium
210
mg/kg
96
7782-49-2
Selenium
4.3 U
mg/kg
7440-22-4
Silver
7440-23-5
Sodium
7440-24-6
Strontium
7440-28-0
Thallium
7440-32-6
Titanium
7440-62-2
Vanadium
18
mg/kg
7440-65-5
Yttrium
2.7
mg/kg
7440-66-6
Zinc
130
mg/kg
1.9
Page 23 of 34
0.48 U
mg/kg
96 U
mg/kg
2.6
mg/kg
2.9 U
mg/kg
2.9
mg/kg
0.48
98
El 04009 TCLPM TMTL FTNAL
0.96
0.48
14:01
14:01
14:01 12/09/10 14:01 12109,10 1401 12/09/10 14:01 1209’lO
.4nutyzed Method 12/20/10 17:1 12/20/10 17:11 12/20/10 17:11
12/20/10 17:11 12/20/10 1711 12/20/10 17:11 12/20/10 17:11 12/20/10 17:11 122010
EPA 6010
EPA 6010 EPA 6010 EPA 6010
EPA 60W EPA 6010 EPA6OIO EPA 6010
14:01
17:11
EPA 6010
12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01
12/20/10 17:11
EPA6OIO
12/09/to
4:01 12/09/10 14:01 t109!O
12/20/10
7:!! 12/20/10 17:11 2120/10 17:11 12/20/10 17:11 12/20/10
17:11 12/20/10 17:11 12/20/10 17:11 12/20/tO 17:11 2/20/to
1401
17:11
96
12/09/10 14:01
12/20/10
0.48
2/09.10
1Z’20110
14:0! 12/09/10 14:01 12/09/10
14:01
17:11 12/20/to 17:11 12/20/tO 17:1!
0.48
12/09/10
12/20/10
14:01
17:1!
0.29
12/09/10
12/20/10
14:01 12/09/10 14:01
17:11 12/20/10 17:11
17:11
EPA 6010 EPA 6010
EPA 6010 EPA 6010 EPA
6010
EPA
6010
EPA 6010 EPA 6010 EPA 6010
EPA 6010 EPA6OIO EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010
1/4/11 10:55
C
CD
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 L).A.RT. Id: 10-0629
Project: 10-0629, Hercu?es Inc Reported by Jenny Scifres -
TCLP Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO8
E104009—10
Matrix: Waste
Station ID: HERCOS Date Collected: 9/29/10 8:50 ( IS Niuither
lnu4’re
Results Qua/fliers
7440-38-2
Arsenic:
NA-5
7440-39-3
Barium:
\A-5
7440-43-9 7440-47-3 7439-92-I 7782-49-2
7440-22-4
Page 24 of 34
Cadmium:
NA-5
NA-5
Chromium:
NA-5
Lead: Selenium:
NA-S
Silver:
NA-5
E104009 TCLPM TMTL FINAL
Units
MRL
Prepared
inulvzed
12/29110
0.10 0.10 0.10
0.40 0.90 0.10
Ofethod
EPA6OIO
EPA 6010
‘‘(° 122910
l2::0
EPA6OIO
12/29/10
1.0
EPA 6010
12/29/10 12/29110
EPA 6010 12129/10
EPA 6010
12//10
EPA 6010
1/4/11 10:55
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
Total Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO9-B Station ID: HERCO9
E104009-11
Matrix: Waste
Date Collected: 9/29/10 14:20 C IS .Vu,nhr
4na1fr
7429-90-5
Aluminum
Results QualifIers
7100
Units
mg/kg
MRL
9.6
7440-36-0
Antimony
3.8 U
mg/kg
7440-38-2
Arsenic
4.8 U
mg/kg
4.8
7440-39-3
Barium
23
mg/kg
0.48
7440-41-7
Beryllium
0.29 U
mg/kg
0.29
7440-43-9
Cadmium
0.48 U
mg/kg
0.48
7440-70-2
530
mg/kg
24
7440-47-3
Chromium
20
mg/kg
0.48
7440-48-4
Cobalt
10
mg/kg
0.48
7440-50-8
Copper
110
mg/kg
0.96
7439-89-6
Iron
3500
mg/kg
9.6
7439-92-1
Lead
25
mg/Icg
1.9
7439-95-4
Magnesium
160
mg/kg
24
7439-96-5
Manganese
39
mg/kg
0.48
7439-98-7
Molybdenum
13
mg/kg
0.96
7440-02-0
Nickel
150
mg/leg
0.96
7440-09-7
Potassium
160
mg/kg
96
7782-49-2
Selenium
4.3 U
mg/kg
7440-22-4
Silver
1.0
mg/kg
0.48
,
Calcium
3.8
7440-23-5
Sodium
150 J, QR-2
mg/kg
96
7440-24-6
Strontium
4.6
mg/kg
0.48
7440-28-0
Thallium
2.9 U
mg/kg
2.9
7440-32-6
Titanium
46
mg/kg
0.48
7440-62-2
Vanadium
5.9
mg/kg
0.48
7440-65-5
Yttrium
2.0
mg/kg
0.29
7440-66-6
Zinc
220
mg/kg
1.9
Page 25 of34
E104009 TCLPM TMTL FINAL
Prepared
lnalv:ed .lfethod
lZ’09’IO
12)20/10
14:01 12109110 14:01
l212o/lo
I2’09/IO
12120i10
14:01 12/09/lu l4:01 12/09/10 14:01 12)09/10 14:01 12/09/10 1401
17:19 12/20/10 17:19 2/20/10 7:19 12/20/10 17:19 2/20/10 7:19
12/09/10
12/20/10
14:01 12/09/10 14.01 12/09/10 14:01 12109/10 140I 12/09/10 14:01 12/09/10 4:01 12/09/10 14:01 12109/10 l4:0I 12/09/10 14:01 12/04/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 4:01 12/09/10 14:01 12/09/10 4:01 12/09/10 14:01 I2/09/I0 14:01 2/09/10 14:01
17:19 12/20/10 17:I9 12120/10 17:19 2/20/10 I7I9 12/20/10 17:19 12/20/tO 7:19 12/20/10 17:19 12/20/tO l7:I9 12/20/10 17:19 12)20/10 17:19 12120/10 7:19 12/20/IS 17:19 12)20/10 7:19 12/2010 17:19 12/20/10 7:19 12)20/b 17:19 2/20/10 17:19 12)20/10 17:19 2/20/ID 17:19
17:19 17:19
EPA6OIO EPA 6010 EPA 6010
EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010
EPA 6010
EPA 6010 EPA 6010
EPA6OIO EPA
60I0
EPA 6010 EPA 6010 EPA6OIO EPA6OIO EPA
6010
EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA
6010
EPA6OIO EPA 6010 EPA6OIO
1/4/11 10:55
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
TCLP Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERCO9-B
E104009-I1
Matrix: Waste
Station ID: HERCO9 Date Collected: 9/29/10 14:20 C4S Number
.4na!yte
7440-38-2
Arsenic:
7440-39-3
7440-43-9 7440-47-3 7439-92-1
7782-49-2 7440-22-4
Page 26 of 34
Results Qualifiers
V
Barium:
NA-5 NA-5
Cadmium:
NA-5
NA-S
Chromium: Lead:
NA-5
Selenium:
NA-S
Silver:
NA-5
E104009 TCLPM TMTL FINAL
Units
9IRL
1.0 0.10
0.10 0.10
0.40 0.90
0.10
Prepared 1212
.4nalyzed ;Otethod 120
12/0 12129,10
EPA 6010
EPA 6010 12129r10
12/29/10
EPA
6010
EPA 6010
‘°
1229/10
EPA 6010
‘°
12/29/10
EPA 6010
1229/10
1229,10
EPA 6010
1/4/11
10:55
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules nc- Reported by Jenny Scifres
Total Metals Project: 10-0629, Hercules Inc Lab 1D:
Sample ID: HERCIO-B Station ID: HERCIO
E104009-12
Matrix: Waste
Date Collected: 9/29/10 14:15 C4S Number
(nalyte
7429-90-5
Aluminum
Results Qualifiers
6400
Units
mg/kg
MRL
9.6
Prepared 12/09/10
.1nwy;ed iltethod 2/20/10
14:01
17:27
12/20/10
14:01
17:27 12/20/10 17:27 12/20/10 17:27
EPA 6010
7440-36-0
Antimony
3.9U
mg/kg
12/09/10
7440-38-2
Arsenic
5.0
mg/kg
4.8
12/09/10
7440-39-3
Barium
33
mg/lcg
0.48
7440-41-7
Beryllium
0.29 U
mg/kg
029
7440-43-9
Cadmium
0.48 U
mg/kg
0.48
7440-70-2
Calcium
2800
mg/kg
24
7440-47-3
Chromium
26
mg/kg
0.48
7440-48-4
Cobalt
14
mg/kg
0.48
7440-50-8
Copper
210
mg/kg
0.96
12109/10
17:27
EPA 6010
7439-89-6
Iron
3200
mg/kg
9.6
12/09/10 14:01
1120:10 17:27
EPA6OIO
12)20/10
7439-92-1
Lead
7439-95-4
Magnesium
7439-96-5
Manganese
7439-98-7
Molybdenum
7440-02-0
Nickel
7440-09-7
Potassium
7782-49-2
Selenium
7440-22-4
,
14:01 12)09/10 14:01 2/09/10
14:01 12/09/10 14:01 12/09/10 1401 12)09/10 14:01 12/09/10 14:01
14:01
12/20/10
17:27 12/20/10 17:27 12/20/10
17:27 12/20/10
17:27 12/20/10 17:27 12/20/10
EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010
23
mg/kg
1.9
14:01
17:27
200
rngkg
24
120910 14:1)1
12.20.10 17:27
EPA 6010
12/09/10 14:0!
12/20110 17:27
EPA 6010
12r09’IO
12/2010
14:01 12/09/10 14:01
17:27 12/20/10
36
mg/kg
0.48
mg/kg
0.96
340
mg/kg
0.96
220
mg/kg
4.3 C
mg/kg
Silver
0.48 U
mg/kg
0.48
7440-23-5
Sodium
210 J, QR-2
mg/kg
7440-24-6
Strontium
7.3
7440-28-0
Thallium
2.9 U
96
12/09/10
17:27 12/20/10
EPA6OIO EPA 6010 EPA 6010
1401
17:27 12)20)10
14:01 1109:10 14:01
12/20:10 17:27
EPA 6010
96
12/09/10
12)20/10
14:01
17:27
EPA 6010
mg/kg
0.48
12,09/10
1220/10
mg/kg
2.9
17:27
1401
‘27
12)09)10
12)20/10
EPA 6010 EPA
6010
17:27 12/2010 17:27
EPA 6010
12/20/10
EPA 6010
7440-32-6
Titanium
61
mg/kg
0.48
Vanadium
7.6
mg/kg
0.48
12)09/10
14:01
17:27
7440-65-5
Yttrium
1.2
mg/kg
0.29
12/09/10
12/20/10
14:01
17:27
7440-66-6
Zinc
1.9
12109/10
12/20/10
14:01
17:27
mg/kg
EPA 6010
14:01
7440-62-2
570
EPA6O1O
12/09/10
120910 l4 0!
El 04009 TCLPM TMTL FINAL
EPA 6010 EPA 6010
12109/10
6.4
Page 27 of 34
EPA 6010
EPA
6010
EPA 6010
1/4/11 10:55
C
0
UNITED STATES ENVIRONMENTAL PROTECTiON AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629
Project: 10-0629, Hercules nc- Reported by Jenny Scifres
TCLP Metals Project: 10-0629, Hercules Inc Lab
Sample ID: HERC1O-B
m:
E104009-12
Matrix: Waste
Station ID: HERC1O Date Collected: 9/29/10 14:15 C.4S Number
.4nalyre
7440-38-2
Arsenic:
7440-39-3
7440439 7440-47-3 7439 92 1 7782-49-2 7440 22-4
Page 28 of 34
Results Qualijidrs
Units
NA-5
Banum:
NA-5
Cadmium
NA 5
Chromium:
\A-5
Lead
NA 5
Selenium:
NA-5
Silver
NA 5
E104009 TCLPM TMTL FINAL
MRL
Prepared
1.0
‘‘),°
0.10
-4l
010 0.10 0 40 0.90 0 10
2
Analyzed Method
EPA 6010 10
EPA 6010
12129110
l’’IO
1/10
12/0
12/29/10
12/29/10
hA 6010
12/29/10
2/29/10
EPA 6010
12/29/10
12’9/I0
EPA 6010
EPA 6010 EPA6O1O
1/4/11 10:55
0
0 **t
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700
t\
\
D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
Total Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERC1I-B
E104009-13
Matrix: Waste
Station ID: HERC1I Date Collected: 9/29/10 14:30 CIS N,,mhor
.4nalyte
7429-90-5
Aluminum
Results Qualifiers
7000
Units
mg/kg
7440-36-0
Antimony
3.9 U
mg/kg
7440-38-2
Arsenic
4.9 U
mg/kg
MRL
Prepared
9.8
12109fl0 14:01
1220110
4.9
12/09/10 14:0! 12/09/tO 14:01
12/20/10 17:34 2/20/10 1734 12/20/10 17:34 12/20/10
7440-39-3
Barium
23
mg/kg
0.49
12/09/10 14:01
7440-41-7
Beryllium
0.29 Ii
mg/kg
0.29
12)09/b l4:01
7440-43-9
Cadmium
0.49 U
mg/kg
0.49
7440-70-2
Calcium
350
mg/kg
25
12/09/10 14:01 12/09/10 14:01
Chromium
25
mg/kg
0.49
7440-47-3
-
7440-48-4
Cobalt
10
mg/kg
0.49
7440-50-8
Copper
93
mg/kg
0.98
7439-89-6
Iron
1900
mg/kg
9.8
7439-92-1
Lead
23
mg/kg
2.0
7439-95-4
Magnesium
170
mg/kg
25
7439-96-5
Manganese
7439-98-7
Molybdenum
14
mg/kg
0.49
4.0
mg/kg
0.98
7440-02-0
Nickel
140
mg/lcg
7440-09-7
Potassium
160
mg/kg
7782-49-2
Selenium
4.4 U
mg/kg
7440-22-4
Silver
0.49 U
mg/lcg
0.49
7440-23-5
Sodium
180 J, QR-2
mg/kg
98
7440-24-6
Strontium
4.2
mg/kg
0.49
7440-28-0
Thallium
2.9 U
mg/kg
2.9
7440-32-6
Titanium
52
mg/kg
0.49
7440-62-2
Vanadium
7.2
mg/lcg
0.49
7440-65-5
Yttrium
1.2
mg/kg
0.29
7440-66-6
Zinc
270
mg/kg
2.0
Page 29 of 34
E104009 TCLPM TMTL FINAL
Analyzed Method
0.98 98
12)09/10 14:01 12/09/10 14:0! 12/09/10 14:0! 2/09/TO
14:01 12)09/10 14:01 12:09/ID
401
1734
17:34 12/20/10 17:34 12/20/10 17:34
12/20/10 17:34 12/20/10 17:34 12/20/10 17:34 12/20/10 17:34 12/20/10 17:34 12/20/10
14:01 12)09/10 14:01
17:34 12/20/1(1 17:34 12/20/10 l7:34
12/09/10
12/20/10
12/09/10
14:01 2/09/10 14:01 12)09/10 14:01 12/09/10 14:01 12/09/10 14:01 2/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12)09/10 14:01 12/09/10 14:01 12/09/10 14:01
EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA6OIO EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010
EPA 6010 EPA 6010
17:34
EPA 6010
12/20/10
EPA 6010
17:34 12/20/10 17:34 12/20/10 17:34 12/20/10 17:34 12/20/10 17:34 12/20/10 17:34 12/20/10 17:34 12)20/10 17:34 12/20/10 17:34 12/20/10 17:34
EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010
1/4/11 10:55
0
. 9 i:
C
UNiTED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700
cJ
D.A.R.T. Ed: 10-0629 Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
TCLP Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERC1I-B
E104009-13
Matrix: Waste
Station ID: HERC1I Date Collected: 9/29/10 14:30 ( IS .Vu,nhcr
.4nalyte
7440-38-2
Arsenic:
Resulis Qualifiers
NA-5
Units
MRL
1.0
7440-39-3
Barium:
NA5
0.10
7440-43-9
Cadmium:
NA-S
0.10
7440-47-3
Chromium:
NA-5
0.10
7439-92-1
Lead:
NA-5
0.40
7782-49-2
Selenium:
NA-S
0.90
7440-22-4
Siher:
NAS
0.10
Page 30
of34
B 104009 TCLPM TMTL FINAL
Prepared 2129110 0:38
12/29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:38
Analyzed 12/29/10 10:41 12/29/10 10:41 12/29/10 10:41 12/29/10 10:41 12/29/10 10:41 12/29/10 10:41 12129/10 10:41
llethod
EPA6OIO EPA 6010 EPA6OIO EPA6OIO EPA 6010
EPA 6010 EPA 6010
1/4/11 10:55
0
0 t’aO ST 61
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Suppo Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Jenny Scifres
PR
-
Total Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERC12-B Station ID: HERCI2
E104009-14
Matrix: Waste
Date Collected: 9/29/10 14:50 .‘V,,,nher
4nolyte
7429-90-5
Aluminum
7440-36-0
Antimony
3.7 U
mg/kg
7440-38-2
Arsenic
4.6 U
mg/kg
Results Qualifiers
6700
Units
mg/kg
1IRL
9.1
4.6
7440-39-3
Barium
30
mg/kg
0.46
7440-41-7
Beryllium
0.27 U
mg/kg
0.27
7440-43-9
Cadmium
0.46 U
mg/kg
0.46
7440-70-2
Calcium
1200
mg/kg
23
7440-47-3
Chromium
18
mg/kg
0.46
13
mg/kg
0.46
110
mg/kg
0.91
4700
mg/kg
9.1
7440-48-4
Cobalt
7440-50-8
Copper
7439-89-6
Iron
7439-92-1
Lead
7439-95-4
Magnesium
7439-96-5
Manganese
7439-98-7
Molybdenum
7440-02-0
Nickel
7440-09-7
Potassium
7782-49-2
Selenium
7440-22-4
Silver
7440-23-5
Sodium
7440-24-6
Strontium
7440-28-0
Thallium
18
mg/kg
1.8
210
mg/kg
23
36
mg/lcg
0.46
2.8
mg/kg
0.91
270
mg/leg
0.91
170
mg/kg
91
4.1 U
mg/kg
4.1
0.46 U
mg/kg
0.46
mg/kg
91
8.5
mg/kg
0.46
2.7 U
mg/kg
2.7
240 3, QR-2
7440-32-6
Titanium
54
mg/kg
0.46
7440-62-2
Vanadium
7.5
mg/kg
0.46
7440-65-5
Yttrium
1.6
mg/kg
0.27
7440-66-6
Zinc
370
mg/kg
1.8
Page 31 of 34
El 04009 TCLPM TMTL FINAL
Prepared
.lnatyzed Method
12/09/10
12/20/10
14:01 12/09/10 14:01 12/09/10
17:42 12120/10 17:42 12/20)10
14:01
17:42
12/09/10 14:01 12/09/10
12/20/10 17:42 12/20/tO
14:01
17:42
12/09/10 14:01 12/09/10
12/20/10 17:42 12/20/10
14:01
17:42
12/09/10 14:01 12109/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01
12/20/10 17:42 12/20/10 17:42 12/20/10 17:42 7:42 12/20/10 17:42 12/20/10 17:42 12/20/10 17:42
12109/tO
12/20/10
14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12109/10 14:01
17:42 12/20/10 17:42 12/20/10 17:42 12/20/10 17:42 12/20/10 17:42
12)09/10
12/20/10
14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 1401 12/09/10 14:01
17:42 12120/10 17:42 12/20/10 17:42 12/20/10 17:42 12/20/10 17:42 12/20/10 17:42 12120/10 17:42
12/20/10
EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010
EPA 6010 EPA 6010
EPA 6010 EPA 6010 EPA 6010
EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA6OIO EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010
EPA 6010 EPA 6010 EPA 6010
EPA 6010 EPA 6010
1/4/11 10:55
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
TCLP Metals Project: 1OO629, Hercules Inc Lab ID:
Sample ID: HERCI2-B
E104009-14
Matrix: Waste
Station ID: UERCI2 Date Collected: 9/29/10 14:50
c.is Results Qualifiers
Units
MRL
,Vu,uber
.4nalvre
7440-38-2
Arsenic:
7440-39-3
Barium:
NA-5
0.10
7440-43-9
Cadmium:
NA5
0.10
7440-47-3
Chromium:
A-5
0.10
7439-92-1
Lead:
NA-5
0.40
7782-49-2
Selenium:
NA5
0.90
7440-22-4
Silver:
NA-5
0.10
Page 32 of34
NA-5
E104009 TCLPM TMTL FINAL
1.0
Prepared 12/29/10 1038 12/29/10 0:38 12/29/10 10:38 12129/10 10:30 12/29/10 10:38 12/29/10 10:38 12/29/10 1038
.lnatr;ed llethod 12129/10 0:41 12/29/10 10:41 12/29/tO 10:41 12/29/10 10:41 12/29/10 10:41 12/29/10 10:41 12/29/10 10:41
EPA 6010 EPA6O1O EPA 6010
EPA 6010 EPA 6010 EPA 6010 EPA6OIO
1/4/11 10:55
0
0
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
Total Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: HERC13-B Station ID: HERCI3
E104009-15
Matrix: Waste
Date Collected: 9/29/10 15:10 C4S Niunher
4nalyte
7429-90-5
Aluminum
7440-36-0
Antimony
3.7 U
mg/kg
7440-3t1-2
Arsenic
5.6
mg/kg
4.6
7440-39-3
Barium
45
mg/kg
0.46
7440-41-7
Beryllium
0.27 U
mg/kg
0.27
7440-43-9
Cadmium
0.46 U
mg/kg
0.46
7440-70-2
Calcium
1700
mg/kg
23
7440-47-3
Chromium
36
mg/kg
0.46
7440-48-4
Cobalt
21
mg/kg
0.46
7440-50-8
Copper
7439-89-6
Iron
7439-92-1
Lead
7439-95-4
Magnesium
7439-96-5
Manganese
7439-98-7
Molybdenum
7440-02-0
Results Qualifiers
6800
Units mg/kg
MRL
9.1
12109/10
12/20/10
14:01 12)09/10 14:01 12109/10 1401 12)09/10 14:01 2/09/10
1750 12/20/10 17:50 12120/10 750 12120/10 17:50
12120/10 17:50 12/20/10 1750 12/20/10
14:01 12/09/10
17:50 1120/10
l750 12)20/10 17:50
EPA 6010 EPA6OIO
0.91
mg/kg
9.1
l2Jo9lO 14:01
12120’IO 7:50
12)09)10 14:01 12/09/10
12)20/10 17:50 12/20/10
mg/kg
1.8
mg/kg
23
mg/kg mg/kg
0.91
Nickel
490
mg/kg
0.91
7440-09-7
Potassium
190
mg/kg
91
7782-49-2
Selenium
4.1 U
mg/kg
4.1
7340-22-4
Silver
0.46 U
mg/kg
0.46
7440-23-5
Sodium
230 1, QR-2
mg/kg
91
7440-24-6
Strontium
8.9
mg/kg
0.46
7440-28-0
Thallium
2.7 U
mg/kg
2.7
7440-32-6
Titanium
76
mg/kg
0.46
7440-62-2
Vanadium
9.0
mg/kg
0.46
7440-65-5
Yttrium
1.2
mg/kg
0.27
7440-66-6
Zinc
480
mg/kg
1.8
0.46
[P\ 6010 EPA 6010
12)09/10 14:01 12109/10 14:01 12/09/10
mg/kg
36
EPA 6010
EPA 6010
12120/10 17:50
210
150
llethad
14:01
3100
15
El 04009 TCLPM TMTL FINAL
tnalvzed
12)09/10 14:01
5.6
Page 33 of 34
Prepared
1401
1750
12)09/10 14:01 12/09/10 14:01 12)09/10 1401 12100/10
12/20/10 17:50 12/20/10 17:50 12/20/10 17:50 12/20/10
14:01
750
12/09/10 14:01 12:09/10
12/20/10 17:50 12/20/10
14:01
17:50
12)09/10 14:01 12109/10
12/20/10 17:50 12/20/10
14:01
17:50
12109/10 14:01 12/09/10 14:01
12)20/10 17:50 12/20/10 17:50
12/09/10
12/20/10
14:01 12109/10 14:01 12/09/10 14:01
17:50 12/20/10 17:50 12/20/10 17:50
EPA 6010
EPA 6010 EPA 6010 EPA 6010 EPA 6010
EPA 6010
EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010
EPA 6010 EPA 6010 EPA 6010
1/4/11 10:55
0
0
UN[TED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629
Project: 10-0629, Hercules Inc Reported by Jenny Scifres -
TCLP Metals Project: 10-0629, Hercules Inc Lab ID:
Sample ID: I{ERC13-B
E104009-15
Matrix: Waste
Station ID: HERC13 Date Collected: 9/29/10 15:10 C4S Number
.4ntilvte
7440-38-2
Arsenic:
Results
Qualifiers
NA-S
Units
11RL
1.0
7440-39-3
Barium:
NA-5
0.10
7440-439
Cadmium:
NA-S
0.10
7440-47-3 7439-92-1
Chromium:
NA-S
NA-S
Lead:
0.10 0.40
7782-49-2
Selenium:
NA-S
0.90
7440-22-4
Silver:
NA-S
0.10
Prepured
.4 nO! ‘zed Ofethod
‘°
EPA 6010
j’’°
EPA 6010
I2)2910
122910
EPA 6010
12/29/10
12/2900
EPA 6010
I2r29I0
0
EPA 6010
12)29/10
12/290
EPA 6010
21010
12,29/10
IPA 6010
End of Report
Page 34 of 34
E104009 TCLPM TMTL FiNAL
1/4/11 10:55
