FIELD INVESTIGATION REPORT 2011

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UNITED STATES ENVIRONMENTAL PROTECTION REGION 4 Science and Ecosystem Support Division Enforcement and Investigations Branch 980 College Station Road Athens, Georgia 30605-2720

4SESD-EIB

January31, 2011

FEB

SESD Final Field Investigation Report for Hercules Inc., Hattiesburg, Mississippi EPA ID No. MSD 008 182 081; SESD Project No. 10-0629

FROM:

Sharon Matthews, PG Enforcement Section

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THRU:

Laura Ackerman, Chief Enforcement Section

TO:

Larry Lamberth, Chief South Enforcement and Compliance Section RCRA & OPA Enforcement and Compliance Branch RCRA Division Attached is the final Field Investigation Report for the sampling conducted at

Hercules Inc. in Hattiesburg, Mississippi on September 28-29, 2010. If you have any questions, please contact me at matthews.sharon(epa.gov. or at (706) 355-8608.

Attachment

Randy Jackson, RCRA w/attachment Willie McKercher, MDEQ w/attachment Jan Patton, MDEQ w/ attachment

VED —

7 2011

Dept oj Eaviro Office of Poi:JgJitY

MEMORANDUM SUBJECT:

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United States Environmental Protection Agency Region 4 Science and Ecosystem Support Division 980 College Station Road Athens, Georgia 30605-2720 S7. .

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Field Investigation Report Hercules Inc. Hattiesburg, Mississippi Date of Final Report: January 31, 2011 SESD Project Identification Number: 10-0629 Requestor: Randy Jackson South Enforcement & Compliance Section RCRA & OPA ECB, RCRA Division 61 Forsyth Street, SW Atlanta, GA 30303-8960

SESD Project Leader: Sharon Matthews SESD Enforcement Section 980 College Station Road Athens, Georgia 30605-2720

___________ ________

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Title and Approval Sheet

Title: Hercules Inc. Field Investigation Report

Approving Official:

Lau a Ackerman, Section Chief Enforcement Section Enforcement and Investigations Branch

Date

SESD Project Leader:

rj Sharon Matthews, PG Enforcement Section Enforcement and Investigations Branch

SESD PROJECT NO. 10-0629

Date

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0 FIELD INVESTIGATION REPORT Hercules Inc., Hattiesburg, Mississippi SESD Project Identification Number: 10-0629 I. INTRODUCTION On September 28-29, 2010, representatives of the Science and Ecosystem Support Division (SESD) conducted a sampling investigation at the Hercules Inc. facility in Hattiesburg, Mississippi. This field investigation was requested by the EPA South Enforcement & Compliance Section, RCRA Division and the Mississippi Department of Environmental Quality (MDEQ) as part of the EPA Surface Impoundment Initiative. In April 2008, Hercules Inc. informed the MDEQ that an onsite impoundment basin was to be closed. MDEQ requested additional information on closure operations including a request for Hercules to characterize the sludge. After three sampling events, the results indicated some areas of the sludge exhibited hazardous characteristics for benzene. A notice of violation (NOV) was issued in November 2008 to the facility. MDEQ contacted the EPA to see if they would conduct sampling and analysis of the sludge disposal area from prior surface impoundment clean-outs to determine if illegal disposal had occurred. The sludge disposal area is located on the ‘back forty” of the facility’s 170 acres, and spans an area of 6 to 7 acres. Personnel that participated in the investigation included: Randy Jackson Paula Whiting Araceli Bonilla Jan Patton Willie McKercher Gloria Tatum Rick Sumrall Charles Jordan Kipper Montgomery Kevin Simmons Art Masters Bill Simpson Marty Allen Sharon Matthews

EPA Region 4-Atlanta, GA EPA Region 4-Atlanta, GA EPA Region 4-Atlanta, GA MDEQ Jackson, MS MDEQ Jackson, MS MDEQ Jackson, MS MDEQ Jackson, MS Hercules- Hattiesburg, MS Arcadis Baton Rouge, LA EPA Region 4-Athens, GA EPA Region 4-Athens, GA EPA Region 4- Athens, GA EPA Region 4-Athens, GA EPA Region 4-Athens, GA —









(404) 562-8464 (404) 562-9277 (404) 562-9790 (601) 961-5782 (601) 961-5731 (601) 961-5011 (601) 961-5791 (601) 584-3360 (225) 292-1004 (706) 355-8730 (706) 355-8612 (706) 355-8748 (706) 355-8651 (706) 355-8608

II. SUMMARY SESD collected a total of thirteen subsurface waste samples, twelve from the “back forty” area and one from the “wetlands” area. Samples were analyzed for volatile organic compounds (VOC5), semi volatile organic compounds (SVOC5), metals and TCLP. MDEQ and EPA requested the analytical data be compared to residential levels for soil given in the Tier 1 Target Remediation Goals (TRGs) and the most recent USEPA Regional Screening levels (RSLs).

SESD PROJECT NO. 10-0629

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Eighteen volatile organic compounds were detected in the thirteen samples. Benzene failed the TCLP regulatory limit of 0.5 mg/L in six of the samples and was detected in ten samples. Toluene and p-isopropyltoluene were detected in all thirteen samples. Methylcyclohexane and 1, 2, 4-trimethylbenzene were detected in eleven samples and. Cyclohexane was detected in nine samples and ethyl beuzene was detected in eight samples. The remainder of the VOCs were detected in six or less of the samples. Forty SVOCs were detected in the thirteen samples. None of the SVOCs failed TCLP for the thirteen samples. The compound 1, 1 -biphenyl was detected in twelve of the thirteen samples and petroleum product was detected in eleven of the samples. Phenol, hexahydro tetramethylmethanonaphthalene (TIC) and dimethylisopropyiphenanthrene (TIC) were detected in ten of the samples. Nine samples contained camphene, 2-methylnaphthalene, and naphthalene. Eight of the samples contained diphenyl ether (TIC), (3-and/or 4) methylphenol, methyl (methylethyl) benzene (TIC), methyl (methylethyl)cyclohexane (TIC), and trimethyl bicycloheptane (TIC). Seven of the samples contained 2-methyiphenol, fluoranthene and pinene (TIC). The remainder of the SVOCs were detected in six or less of the samples. Twenty-two metals were detected in the thirteen samples with seventeen detected in all of the samples. Arsenic was detected in samples HERCO4-B, HERCO5-A, HERC1O-B and HERC 13-B at levels that exceeded both the MDEQ and EPA regulatory levels with values ranging from 5.0 to 6.4 mg/kg. None of the samples exceeded the MDEQ and EPA regulatory levels for Chromium III; however, all of the samples exceeded the EPA regulatory level of 0.29 mg/kg for Chromium VI. Vanadium was detected in samples HERCO3-B, HERCO4-B, HERCO5A, HERCO8, HERCO9-B, HERC1O-B, HERC1 1-B, HERC12-B and HERC13-B at levels that exceeded the EPA regulatory level of 5.5 mg/kg with values ranging from 5.6 to 18 mg/kg. No other metal concentrations exceeded the MDEQ and EPA regulatory levels. None of the metals failed TCLP for the thirteen samples. III. SITE BACKGROUND The facility is located at 613 West Seventh Street in Hattiesburg, Mississippi (Figure 1). Facility operations, which began in 1923, included wood grinding, shredding extraction, fractionation, refining, distillation and processing of rosin from pine tree stumps. Some of the products that were manufactured included modified resins, polyamides, ketene dimmer, crude tall oil wax emulsions, synthetic rubber and the agricultural pesticide Delnav. Hercules also manufactured specialty organic chemicals for use in paper products. Over 250 products were produced at the facility. Hercules downsized the Hattiesburg operations and has now ceased operations. A state preliminary assessment was completed in December 1989 and indicated two source areas which included about 38 acres of contaminated soil and almost 900,000 cubic feet of surface impoundments. The contaminated soil contained cadmium, cobalt, lead, mercury, toluene, MEK, benzene, PCBs and acetone. Contaminants present in the surface impoundments included arsenic, heavy metals, toluene, MEK and benzene. In April 2008 the facility sent a letter to MDEQ to close an onsite impoundment basin. MDEQ requested additional information on closure operations including a request for Hercules to characterize the sludge. After three sampling events, the results indicated some areas of the SESD PROJECT NO. 10-0629

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sludge exhibited hazardous characteristics for benzene. A notice of violation (NOV) was issued November 2008. Prior surface impoundment clean-outs had been taken to a landfill disposal area located on the ‘back forty” of the facility’s 170 acres, spanning an area of 6 to 7 acres. According to information from MDEQ, the “back forty” had been used to dispose of process wastes, boiler ash and waste treatment sludge from plant activities. A compliance evaluation inspection conducted by MDEQ in March 2009 resulted in several violations involving the surface impoundment and closure/post-closure procedures. MDEQ then requested EPA’s assistance in sampling and testing the sludge disposal area to determine if illegal disposal had occurred. IV. IMSSCUSSION OF FIELD ACTIVITIES SESD personnel arrived at the site Tuesday, September 28, 2010 at around 7:45 am and met with EPA-Atlanta, MDEQ and facility personnel to assess the proposed sampling areas. Using an authoritative sampling design, sampling locations were determined in the field by MDEQ and EPA personnel based on access and prior knowledge of the site. Twelve borings were completed using Geoprobe direct-push technology or hand auger in the ‘back forty” disposal area. Total depth of the sludge had been estimated to be around 14 to 16 feet below land surface but was actually closer to 5 to 8 feet in depth. Two samples had been proposed from the wetlands, but only one could be collected due to the high quantity of vegetative material/roots. Two samples had been proposed from the impoundment outfall, but those sample locations were deleted and added to the samples to be collected from the “back forty”. Samples from the sludge disposal area were collected based on visual observations and screening results obtained with the Thermo Toxic Vapor Analyzer (TVA) 1000B. All samples were analyzed for VOCs, SVOCs, metals and TCLP. Table 1 gives information on the waste samples. Sampling locations are shown on Figures 3, 4 and 5. Photographs taken during the investigation are included in Appendix A. Waste Samples Under the direction of EPA-Atlanta and MDEQ personnel, sample HERCO1-A was collected from the “back forty” using Geoprobe direct-push equipment to a depth of 0 to 4 feet below land surface (BLS). The core was screened with a Thenno Toxic Vapor Analyzer (TVA) 1 000B. The sample was described as a black organic rich material with a strong odor of pine. The waste sample core was placed in a glass pan and using a stainless steel spoon, three 8-ounce glass containers were filled for the VOC, SVOC and total metals analyses. The VOC sample was collected first, and then the remainder of the sample was homogenized in the glass pan. The facility elected to split with EPA for all samples and supplied one 4-ounce amber glass container for VOCs, one 16-ounce glass container for SVOCs and one 8-ounce plastic container for metals. For sample EIERCO2-B, a stainless steel hand auger was used to auger to 5 feet BLS. The waste sample was collected from 3.5 to 5 feet BLS and was described as a tan to black sticky material. EPA and facility containers were filled for the VOC, SVOC and total metals analyses using the same procedure described above.

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Sample HERCO3-B was also collected with a stainless steel hand auger from some of the oldest part of the “back forty” sludge disposal area. The waste sample was collected from 4 to 5 feet BLS and was described as a black organic material with a strong odor, sandier at depth. Native material of sand and gravel was noted at about 6 feet BLS. EPA and facility containers were filled for the same analyses using the same procedure described above. Sample HERCO4-B was collected with a stainless steel hand auger from the older part of the “back forty” sludge disposal area. The waste sample was collected from 6 to 7 feet BLS and was described as a black organic material with some odor. EPA and facility containers were filled for the same analyses using the same procedure described previously. Sample HERCO5-A was collected with a stainless steel hand auger from the older part of the “back forty” sludge disposal area. The waste sample was collected from 5.5 to 6.5 feet BLS and was described as a dark organic sludge with a strong odor. EPA and facility containers were filled for the same analyses using the same procedure described before. Sample HERCO6-B was collected with a stainless steel hand auger from 4.5 to 5.5 feet BLS and was described as a dark gray to black sludge with a strong odor, drier material at the surface that became moister and sandier with depth. The sand that was encountered at 5.5 to 6 feet BLS is the sand layer that sits on top of the Hattiesburg clay in this area, indicating native material. EPA and facility containers were filled for the same analyses using the same procedure described previously. Sample HERCO7-B was collected with a stainless steel hand auger from 5.5 to 6 feet BLS and was described as a drier dark organic material which became moister with depth. EPA and facility containers were filled for the same analyses using the same procedure described before. Sample HERCO8 was collected with a stainless steel scoop from the “wetlands” area from a depth of about 3 to 4 inches. The material was mostly cat-tails and detritus with some stratified sludgy material with no odor. Two samples had been proposed from the wetlands, one around the influent and one from the effluent, but only the influent sample could be collected due to the high amount of vegetative material/roots around the effluent area. EPA and facility containers were filled for the same analyses using the same procedure described previously. Sample HERCO9-B was collected from the “back forty” using Geoprobe direct-push equipment. The first core was 0 to 4 feet BLS and was a black organic material. The second core was collected from 4 to 8 feet BLS and was black sludge for the first foot, then native sand. Because the core was compacting inside the core barrel, it was decided to hand auger this and subsequent samples to collect enough material io fill all the EPA and facility sample containers. The sample was collected from 5 to 6 feet BLS and described as a black sludge material. EPA and facility containers were filled for the same analyses using the same procedure described before.

SESD PROJECT NO. 10-0629

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Sample HERC1O-B was collected with a stainless steel hand auger from 5 to 6 feet BLS. Native sand was encountered at 6 feet BLS. The black sludge sample was collected above the sand and some odor was noted during sampling. EPA and facility containers were filled for the same analyses using the same procedure described previously. Sample HERC11-B was collected with a stainless steel hand auger from 5 to 6 feet BLS. Native sand was encountered at 6 feet BLS. The sample was collected above the sand and was described as a black organic sludge with some odor. EPA and facility containers were filled for the same analyses using the same procedure described before. Sample HERC12-B was collected with a stainless steel hand auger from 4.5 to 5.5 feet BLS. Native sand was encountered at 5.5 feet BLS. The sample was collected above the sand and was described as a black sludge with some odor. EPA and facility containers were filled for the same analyses using the same procedure described previously. Sample HERC13-B was collected with a stainless steel hand auger from 4.5 to 5.5 feet BLS. Native sand was encountered at 5.5 feet BLS. The sample was collected above the sand and was described as a black sludge material with a strong odor and an oily sheen. EPA and facility containers were filled for the same analyses using the same procedure described before. V. RESULTS OF ANALYSES Samples were analyzed for VOCs by SW-846 Methods 8260C, for SVOCs by SW-846 Method 8270D and for total metals by SW-846 Method 6010. Analytical results for the VOC detected analytes in the waste samples are given in Table 2 and the TCLP results are given in Table 3. The MDEQ Tier 1 TRG and EPA Regional Screening Levels (RSLs) for VOCs in residential soils are listed in Table 4. Results for the SVOC-detected analytes are given in Table 5. Because no compounds failed TCLP for SVOCs, there is no TCLP table. The MDEQ Tier 1 TRG and EPA RSLs for SVOCs in residential soils are listed in Table 6. Analytical results for total metals are given in Table 7 and the MDEQ Tier 1 TRG and EPA RSLs for metals are given in Table 8. Because no compounds failed TCLP for metals, there is no TCLP table. The complete set of results generated by the SESD laboratory is included as Appendix B. The following analytes were detected in samples collected at the facility: Volatile Organic Compounds- (Tables 2,3 and 4) Eighteen volatile compounds were detected in the thirteen samples (Table 2). Toluene and p-isopropyltoluene were detected in all thirteen samples. Methylcyclohexane and 1,2,4trimethylbenzene were detected in eleven samples and benzene was detected in ten samples. Cyclohexane was detected in nine samples and ethyl benzene was detected in eight samples. The remaining VOCs were detected in six or less of the samples. Benzene failed the TCLP regulatory limit of 0.5 mg/L in six of the samples (Table 3). Analytical data was compared to the MDEQ and EPA regulatory levels referenced in Table 4. Exceedences are listed below: HERCO 1-A Analytes exceeding the reference standard or level: benzene (18 mg/kg), toluene (7100 mg/kg) -

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HERCO2-B Analytes exceeding the reference standard or level: benzene (37 mg/kg), ethyl benzene (6.5 J, 0 mg/kg), toluene (16000 mg/kg) -

HERCO3-B Analytes exceeding the reference standard or level: benzene (3.4 mg/kg) -

HERCO4-B Analytes exceeding the reference standard or level: benzene (19 mg/kg), toluene (3000 mg/kg) -

HERCO5-A Analytes exceeding the reference standard or level: benzene (14 mg/kg), toluene (5300 mg/kg) -

HERCO6-B Analytes exceeding the reference standard or level: toluene (280 mg/kg) -

HERCO7-B Analytes exceeding the reference standard or level: toluene (1400 mg/kg) -

HERCO8 Analytes exceeding the reference standard or level: none -

HERCO9-B Analytes exceeding the reference standard or level: benzene (170 mg/kg), toluene (1100 mg/kg) -

HERC 10-B Analytes exceeding the reference standard or level: benzene (140 mg/lcg), toluene (3100 mg/kg) -

HERC1 1-B Analytes exceeding the reference standard or level: benzene (77 mg/kg), toluene (2600 mg/kg) -

HERC 12-B Analytes exceeding the reference standard or level: benzene (440 mg/kg), isopropylbenzene (47 mg/kg), toluene (160 mg/kg) -

HERC 13-B Analytes exceeding the reference standard or level: benzene (390 mg/kg), toluene (3400 mg/kg) -

Semi Volatile Organic Compounds (Tables 5 and 6) Forty SVOCs were detected in the thirteen samples (Table 5). The compound 1,1 biphenyl was detected in twelve of the thirteen samples and petroleum product was detected in eleven of the samples. Phenol, dimethylisopropylphenanthrene (TIC), and hexahydro tetramethylmethanonaphthalene (TIC) were detected in ten of the samples. Nine samples contained 2-methylnaphthalene, camphene and naphthalene. Eight of the samples contained diphenyl ether (TIC), (3-and/or 4) methylphenol, methyl(methylethyl)benzene (TIC), methyl(methylethyl)cyclohexane (TIC), and trimethylbicycloheptane (TIC). Seven of the samples contained 2-methyiphenol, fluoranthene and pinene (TIC). The remainder of the SVOCs were detected in six or less of the samples. None of the SVOCs failed TCLP for the thirteen samples. Analytical data was compared to the MDEQ and EPA regulatory levels referenced in Table 6. Exceedences are listed below: -

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HERCO1-A Analytes exceeding the reference standard or level: naphthalene (6.2 mg/kg) -

HERCO2-B Analytes exceeding the reference standard or level: 1,1-biphenyl (3900 mg/kg), naphthalene (8.8 mg/kg) -

HERCO3-B Analytes exceeding the reference standard or level: none -

HERCO4-B Analytes exceeding the reference standard or level: naphthalene (7.8 mg/kg) -

HERCO5-A Analytes exceeding the reference standard or level: naphthalene (8.7 mg/kg) -

HERCO6-B Analytes exceeding the reference standard or level: none -

HERCO7-B Analytes exceeding the reference standard or level: none -

HERCO8 Analytes exceeding the reference standard or level: none -

HERCO9-B Analytes exceeding the reference standard or level: none -

HERC1O-B Analytes exceeding the reference standard or level: naphthalene (6.7 mg/kg) -

HERC 11-B Analytes exceeding the reference standard or level: none -

HERC12-B Analytes exceeding the reference standard or level: naphthalene (3.9 mg/kg) -

HERC1 3-B Analytes exceeding the reference standard or level: naphthalene (5.2 mg/kg) -

Metals (Tables 7 and 8) Twenty-two metals were detected in the thirteen samples (Table 7). Seventeen of the metals were detected in all of the samples. Arsenic was detected in samples HERCO4-B, HERCO5-A, HERC1OB and HERC13-B at levels that exceeded both the MDEQ and EPA regulatory levels with values ranging from 5.0 to 6.4 mg/kg. None of the samples exceeded the MDEQ and EPA regulatory levels for Chromium III; however, all of the samples exceeded the EPA regulatory level of 0.29 mg/kg for Chromium VI with values ranging from 7.7 to 45 mg/kg. Vanadium was detected in samples HERCO3-B, HERCO4-B, HERCO5-A, HERCO8, HERCO9-B, HERC1O-B, HERC1 1-B, HERC12-B arid HERC13-B at levels that exceeded the EPA regulatory level of 5.5 mg/kg with values ranging from 5.6 to 18 mg/kg. No other metal concentrations exceeded the MDEQ and EPA regulatory levels. None of the metals failed TCLP for the thirteen samples. Analytical data was compared to the MDEQ and EPA regulatory levels referenced in Table 8. Exceedences are listed below: HERCO1-A Analytes exceeding the reference standard or level: chromium VI (24 mg/kg) -

HERCO2-B Analytes exceeding the reference standard or level: chromium VI (11 mg/kg) -

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HERCO3-B Analytes exceeding the reference standard or level: chromium VI (7.7mg/kg), vanadium (8.7 mg/kg) -

HERCO4-B Analytes exceeding the reference standard or level: arsenic (6.4 mg/kg), chromium VI (29 mg/kg), vanadium (5.6 mg/kg) -

HERCO5-A Analytes exceeding the reference standard or level: arsenic (5.6 mg/kg), chromium VI (45 mg/kg), vaiadium (6.6 mg/kg) -

HERCO6-B Analytes exceeding the reference standard or level: chromium VI (20 J,O mg/kg) -

HERCO7-B Analytes exceeding the reference standard or level: chromium VI (32 mg/kg) -

HERCO8 Analytes exceeding the reference standard or level: chromium VI (20 mg/kg), vanadium (18 mg/kg) -

HERCO9-B Analytes exceeding the reference standard or level: chromium VI (20 mg/kg), vanadium (5.9 mg/kg) -

HERC 10-B Analytes exceeding the reference standard or level: arsenic (5.0 mg/kg), chromium VI (26 mg/kg), vanadium (7.6 mg/kg) -

HERC1 1-B Analytes exceeding the reference standard or level: chromium VI (25 mg/kg), vanadium (7.2 mg/kg) -

HERC 12-B Analytes exceeding the reference standard or level: chromium VI (18 mg/kg), vanadium (7.5 mg/kg) -

HERC13-B Analytes exceeding the reference standard or level: arsenic (5.6 mg/kg), chromium VI (36 mg/kg), vanadium (9.0 mg/kg) -

VI. RESULTS OF FIELD QUALITY CONTROL SAMPLES Field quality control samples for this investigation consisted of equipment rinse blanks collected from the liners used for the Geoprobe cores. No VOCs, SVOCs or metals were detected in the blanks. No metals were detected in the blank of the preservative used for the equipment rinse blank for metals analysis. VII. METHODOLOGY Field activities were conducted in accordance with the Region 4 SESD Field Branches Quality System and Technical Procedures. Specific field procedures applicable to this investigation included the following: Soil Sampling, SESDPROC-300-Rl Waste Sampling SESDPROC-302-Rl

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Sediment Sampling, SESDPROC-200-R2 SESD Operating Procedure for Sample and Evidence Management, SESDPROC-005-Rl Global Positioning System, SESDPROC-l l0-R2 Management of Investigation Derived Waste, SESDPROC-202-Rl Field Equipment Cleaning and Decontamination, SESDPROC-205-Rl Packing, Marking, Labeling and Shipping of Environmental & Waste Samples, SESDPROC-209-R 1 Field quality control measures were in accordance with the SESD Operating Procedure for Field Sampling Quality Control, SESDPROC-01 1-R2, and 40 CFR Part 136, Table IIRequired Containers, Preservations Techniques, and Holding Times, Revised as of July 1, 2007. All field measurement instruments and equipment were maintained in accordance with the SESD Operating Procedure for Equipment Inventory and Management, SESDPROC- 1 08-R3. Samples were analyzed at the SESD laboratory in accordance with the SESD Analytical Support Branch Laboratory Operations and Quality Assurance Manual, January 2010. The laboratory is accredited by the national Environmental Laboratory Accreditation Program (NELAP).

REFERENCES Personnel communication: Kevin Koporec to Sharon Matthews regarding RSLs, 1/19/11 “Site Inspection” for Hercules Inc. prepared by B&V Waste Science and Technology Corp. for the US EPA Region 4. April, 1993. USEPA Regional Screening Levels (11/10) Mississippi Department of Environmental Quality Tier 1 TRG Table (2/28/02)

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FIGURE 1

FACILITY LOCATION MAP HERCULES, INC. HATTIESBURG, MISSISSIPPI

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SESD PROJECT NO. 10-0629

“Wetlands

FIGURE 2 —SITE LOCATION MAP HERCULES, INC., HATTIESBURG, MISSISSIPPI

•11

Approximate Hercules ;— Boundary

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0.05

0.1

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SESD PROJECT NO. 10-0629

FIGURE 3- SAMPLE LOCATIONS HERCULES, INC., IIATTIESBIJRG, MISSISSIPPI Page 14 of 41

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FIGURE 4- “BACK 40” SAMPLE LOCATIONS Expanded view HERCULES, iNC., UATTIESBURG, MISSISSIPPI Page 15 of 41

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FIGURE 5- “WETLANDS” SAMPLE LOCATION Expanded view HERCULES, INC., HATTIESBURG, MISSISSIPPI Page 16 of 41

©

HERCO1-A

HERCO2-B HERCO3-B

HERCO4-B HERCO5-A HERCO6-B

HERCO7-B

HERCO8

HERCO9-B

HERC1O-B HERC11-B

HERC12-B

HERC13-B

HERCO1

HERCO2 HERCO3

HERCO4 HERCO5 HERCO6

HERCO7

HERCO8

HERCO9

HERC1O HERC11

HERCI2

HERC13

WA

WA

WA WA

WA

WA

WA

WA WA WA

WA WA

WA

Media Code

SESD PROJECT NO. 10-0629

Sample ID

Station 1D

9/29/10

9/29/10

9/29/10 9/29/10

9/29/10

9/29/10

9/28/10

9/28/10 9/28/10 9/28/10

9/28/10 9/28/10

9/28/10

Sample Date

31.34377

3 1.34354

3 1.34329 3 1.34335

31.34329

3 1.33928

31.34380

31.34425 3 1.34402 31 .343 89

31.34344 31.34417

31.34350

Latitude

89.31358 ±10’

89.31357±11’

89.3 1323 ±12’ 89.3 1285 ±12’

89.31363 ±16’

89.30500 ±12’

89.31316 ±10’

89.31284±15 89.31318 ±11’ 89.31351 ±12’

,

89.31308 ±13’ 89.31328 ±16’

89.31332±10’

Longitude

-

Hit sand at 6 feet bls; some odor Black organic sludge; some odor; into sand at 6 feet BLS Black sludge; some odor; into sand at 5.5 feet BLS Black sludge material; strong odor, oily sheen; into sand at 5.5 feet BLS

Black organic rich material; very strong odor; pine smell Tan to black sticky material Oldest material in “back 40”: black organic material; strong odor; sandier at depth Back organic material; some odor Dark organic sludge; strong odor Drier material; dark gray to black sludge; strong odor; moister & sandier w/depth Drier dark organic material; moister w/depth Only “wetland” sample; mostly cattails, some sludgy material; no odor Black sludge material into sand at 6 feet BLS

Sample Description

TABLE 1 SAMPLE DESCRIPTIONS HERCULES INC. BATTIESBURG, MISSISSIPPI



hand auger





hand auger

hand auger

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4.5 to 5.5 feet



hand auger

-

4.5 to 5.5 feet

5 to 6 feet



3 to 4 inches scoop 5 to 6 feet tried Geoprobe; had to handauger to get enough sample 5 to 6 feet—hand auger

5.5 to 6 feet hand auger —

4.5 to 5.5 feet





4 to 5 feet hand auger 6 to 7 feet hand auger 5.5 to 6.5 feet—hand auger

-

0 to 4 feet Geoprobe 3.5 to 5 feet—hand auger

Sample Interval (BLS)/ Sample Method

K

D

5.1 3,0 3.9J,O U 18 5.3 J,0 110 2.4 3,0 U U U 6.9 J,0 U U 1100 U 7100 U U

1{ERCO1 J{ERCO1-A WA 9/28/10 U 7.OJ,O U 37 U 190 6.5 J,O U U U 17 J,0 U U 1700 U 16000 U U

HERCO2 HERCO2-B WA 9/28/10 0.76 J,0 2.1 U 3.4 U U 0.62 J,0 U 0.72 J,0 U 8.6 1.2 0.5 3,0 420 1.4 0.82J,0 40 NJ 20 NJ

HERCO3 1{ERCO3-B WA 9/28/10 5.8 J,0 4.6 J,0 25 19 5.6 J,0 910 2.2 3,0 U U U 20 U U 3500 U 3000 U U

HERCO4 HERCO4-B WA 9/28/10 4.6 J,O 4.0 3,0 6.3 J,0 14 3.6 J,0 420 2.6 J,0 U U 4.6 J,0 22 U U 3500 U 5300 U U

HERCO5 RERCO5-A WA 9/28/10

U 0.40 J,0 U U 0.42 J,0 U U U U U 0.24 J,0 U U 38 U 280 U U

HERCO6 1{ERCO6-B WA 9/28/10

SESD PROJECT NO. 10-0629

Page Th of 41

Numbers in BOLD exceed the USEPA Regional Screening Levels (11/10) and/or values in the MDEQ Tier 1 TRG Table (2/28/02) J= the identification of the analyte is acceptable; the reported value is an estimate NJ = Presumptive evidence that analyte is present; reported as a tentative identification (TIC) with an estimated value. 0 = other qualifiers have been assigned providing additional information and are defmed in the analytical data sheets included as Appendix B of this report U= the analyte was not detected at or above the reporting limit

Analyte (m- and/or p-)Xylene 1 ,2,4-Trimethylbenzene 1,2-Dichlorobenzene Benzene Carbon disulfide Cyclohexane Ethyl Benzene Isopropylbenzene Methyl Acetate Methyl Isobutyl Ketone Methylcyclohexane n- Butylbenzene o-Xylene p-Isopropyltoluene tert-Butylbenzene Toluene Dimethyloctane (TIC) Ethylmethylcyclohexane (TIC)

Station JD Sample ID Media Code Sample Date Units mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/lcg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg

TABLE 2 Detected Volaffle Organic Compounds Hercules Inc., Hattiesburg, Mississippi

HERCO8 HERCO8 WA 9/29/10 U U U U U U U U U U U U U 2.6 U 34 U U

I{ERCO7 HERCO7-B WA 9/28/10 2.9 1.3 J,O U U 0.78 J,0 U 0.92 J,O U U U U U 0.73 J,0 170 U 1400 U U 3.2 3.0 U 170 U 29 1.0 J,O U U U 8.2 U 1.0 J,0 610 U 1100 U U

HERCO9 HERCO9-B WA 9/29/10 U 7.OJ,0 34 140 U 1500 4.0 J,0 U U U 12 J,0 U U 3400 U 3100 U U

F{ERC1O HERCIO-B WA 9/29/10 -

U U U 77 U 100 U U U U 7.4 J,0 U U 720 U 2600 U U

-

HERC1 1 1{ERC1 1-B WA 9/29/10 U 5.OJ,O U 440 U 48 U 47 U U 11 J,0 U U 2400 U 160 U U

HERC12 HERC12-B WA 9/29/10 -

U 5.5 J,O 31 390 U 870 U U U 11 J,0 10 J,0 U U 3100 U 3400 U U

HERC13 HERC13-B WA 9/29/10

SESD PROJECT NO. 10-0629

Page 19 of 41

Numbers in BOLD exceed the USEPA Regional Screening Levels (11/10) and/or values in the MDEQ Tier 1 TRG Table (2/28/02) J= the identification of the analyte is acceptable; the reported value is an estimate NJ = Presumptive evidence that analyte is present; reported as a tentative identification (TIC) with an estimated value. 0= other qualifiers have been assigned providing additional information and are defmed in the analytical data sheets included as Appendix B of this report U= the analyte was not detected at or above the reporting limit

Station ID Sample ID Media Code SamDle Date Analyte Units (m- and/or p-)Xylene mg/kg 1 ,2,4-Trimethylbenzene mg/kg 1 ,2-Dichlorobenzene mg/kg Benzene mg/kg Carbon disulfide mg/kg Cyclohexane mg/kg Ethyl Benzene mg/kg Isopropylbenzene mg/kg Methyl Acetate mg/kg Methyl Isobutyl Ketone mg/kg Methylcyclohexane mg/kg Butylbenzen ne mg/kg o-Xylene mg/kg p-Isopropyltoluene mg/kg tert-Butylbenzene mg/kg Toluene mg/kg Dimethyloctane (TIC) mg/kg Ethylmethylcyclohexane (TIC) mg/kg

TABLE 2 (con’t) Detected Volatile Organic Compounds Hercules Inc., Hattiesburg, Mississippi

Analyte

Station ID Sample ID Media Code Sample Date Units mg/L NA-S

f{ERCO7 HERCO7-B WA 9/28/10 NA-5

HERCO8 HERCO8 WA 9/29/10

0.21

HERCO1 l{ERCO1-A WA 9/28/10

1.8

RERCO9 HERCO9-B WA 9/29/10

0.62 J,O

HERCO2 HERCO2-B WA 9/28/10

SESD PROJECT NO. 10-0629

Numbers in BOLD exceed the EPA Regulatory Level of 0.5 mg/L for benzene.

Benzene

Benzene

Analyte

Station ID Sample 1D Media Code Sample Date Units mg/L I



2.2

I{ERC1O HERC1O-B WA 9/29/10

NA-5

HERCO3 HERCO3-B WA 9/28/10

TABLE 3 Volatile Organic Compounds TCLP Results Hercules Inc., Hattiesburg, Mississippi

0.54 J,O

HERC11 HERC11-B WA 9/29/10

0.22

RERCO4 HERCO4-B WA 9/28/10

1.8

3.6

HERC13 HERC13-B WA 9/29/10

NA-5

HERCO6 HERCO6-B WA 9/28/10

Page 20 of 41

HERC12 HERCI2-B WA 9/29/10

0.23

HERCO5 F[ERCO5-A WA 9/28/10

Units mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg -

MDEQ Tier 1 TRG Soil Unrestricted mg/kg m 418; p 461 3910 279 0.887 7.97 NS 395 9.43 78200 6260 NS 3130 413 NS 3130 38 NS NS EPA RSLs Soil Residential 3400 62 1900 1.1 820 7000 5.4 2100 78000 5300 NS NS 3800 NS NS 5000 NS NS —

mg/kg

SESD PROJECT NO. 10-0629

Page 21 of 41

Regulatory levels are taken from the USEPA Regional Screening Levels (11/10) and the MDEQ Tier 1 TRG Table (2/28/02) NS = No Regulatory Standard/Level

Analyte (m- and/or p-)Xylene 1,2,4-Trimethylbenzene 1 ,2-Dichlorobenzene Benzene Carbon disulfide Cyclohexane Ethyl Benzene Isopropylbenzene (AKA cumene) Methyl Acetate Methyl Isobutyl Ketone Methylcyclohexane n- Butylbenzene o-Xylene p-Isopropyltoluene tert-Butylbenzene Toluene Dimethyloctane (TIC) Ethylmethylcyclohexane (TIC)

MDEQ Tier 1 TRG Soil Restricted mg/kg m 418; p 461 102000 279 1.36 7.97 NS 395 9.43 2040000 163000 NS 81800 413 NS 81800 38 NS NS

TABLE 4 EPA and MDEQ Regulatory Levels for Volaffle Organic Compounds Hercules Inc., Hattiesburg, Mississippi

0

SESD PROJECT NO. 10-0629

Station ID Sample ID Media Code Sam :ile Date Analyte Units (3-and/or 4-)Methylphenol mg/kg 1,1 -Biphenyl mg/kg 2,4-Dimethyiphenol mg/kg 2-Methylnaphthalene mg/kg 2-Methyiphenol mg/kg Acenaphthene mg/kg Dibenzofuran mg/kg Fluoranthene mg/kg Fluorene mg/kg Naphthalene mg/kg Phenanthrene mg/kg Phenol mg/kg Pyrene mg/kg (Dimethylethyl)ethoxybenzene (TIC) mg/kg (Dimethylethyl)methylphenol (TIC) mg/kg (Menthenol)terpineol (TIC) mg/kg (Methvlvropyl)benzene (TIC) ma/ku Bis(methylethyl)biphenyl (TIC) mg/kg Camphene (TIC) mg/kg Camphor (TIC) mg/kg Chiorotrimethylbicycloheptane (TIC) mg/kg Cycloisolongifolene (TIC) mg/kg Decahydroftmethyhethylenemethanoamlene mg/kg (TIC) Dimethylisopropyiphenanthrene (TIC) mg/kg Diphenyl ether (TIC) mg/kg Ethyl(methylethyl)benzene (TIC) mg/kg HERCO2 HERCO2-B WA 9/28/10 50 3900 U 5.6 4.7 J,O 2.9 4.1 9.8 3.4 8.8 5.5 J,O 5.4 J,O U 300 TN U 60 NJ U U 200 NJ U U 80 NJ U U U 70 NJ

FIERCO1 ITERCO1-A WA 9/28/10 20 J,O 1600 U 4.6 7.8 J,O U U 11 J,O 3.0 6.2 U 5.3 J,O 16 100 NJ U 90 NJ U U 200 NJ U U 80 NJ U

U 1000 NJ 60 NJ

200 NJ 800 NJ U

U 130 U U U U U U U U U 8.9 J,O U U U U U U U U U U U

HERCO3 HERCO3-B WA 9/28/10 HERCO4 HERCO4-B WA 9/28/10

200 NJ U U

53 1800 6.0 J,O 8.4 4.3 J,O 3.8 3.0 U 2.7 7.8 3.0 J,N 71 3.6 U U 300 NJ U U 300 NJ 200 NJ 100 NJ U U

TABLE 5 Detected Semi Volatile Organic Compounds Hercules Inc., Hattiesburg, 1’lississippi

100 NJ U U

100 1200 U 14 4.9 J,O 2.8 U 11 U 8.7 U 31 5.7 U U 300 NJ U U 200 NJ U 100 NJ 200 NJ 400 NJ

HERCO5 HERCO5-A WA 9/28/10

200 NJ 600 NJ U

78 330 U U 17 J,O U U U U U U U U U U U U U U U U U U

FIERCO7 FIERCO7-B WA 9/28/10

Page 22 of 41

200 NJ 200 NJ U

U 120 U U U U U U U U U U U U U U U U U U U U U

I{ERCO6 HERCO6-B WA 9/28/10

mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 1000 NJ 300 NJ 2000 NJ 800 NJ U U N U 500 NJ U U 70 J 600 NJ U 300 NJ 2000 NJ U 200 NJ U U U U 300 NJ 3000 J

U

U U U 3000 NJ 600 NJ U U N U 200 NJ 50 NJ U 900 J

HERCO3 HERCO3-B WA 9/28/10

HERCO2 HERCO2-B WA 9/28/10

1000 NJ U U U U U N U 700 NJ 200 NJ 300 NJ 2000 J

U

HERCO4 HERCO4-B WA 9/28/10

400 NJ 700 J

U U U U U U N 200 NJ 900 NJ

400 NJ

HERCO5 HERCO5-A WA 9/28/10

2000 NJ U U U U U N U U U U 6000 J

U

HERCO6 HERCO6-B WA 9/28/10

1000 NJ U U U U U N U U U U 5000J

U

HERCO7 HERCO7-B WA 9/28/10

SESD PROJECT NO. 10-0629

Page 23 of 41

Numbers in BOLD exceed one or both of the USEPA Regional Screening Levels (11/10) or the MDEQ Tier 1 TRG Table (2/28/02) J= the identification of the analyte is acceptable; the reported value is an estimate NJ = Presumptive evidence that analyte is present; reported as a tentative identification (TIC) with an estimated value. 0 = other qualifiers have been assigned providing additional information and are defmed in the analytical data sheets included as Appendix B of this report U= the analyte was not detected at or above the reporting limit TIC = Tentatively Identified Compound

Analyte Hexahydrodimethyl(methylethyl)naphthalene (TIC) Hexahydrotetramethylmethanonaphthalene (TIC) Limonene (TIC) Methyl(methylethyl)benzene (TIC) Methyl(methylethyl)cyelohexane (TIC) Methyl(methylethyl)cyclohexene (TIC) Methyl(methylethyl)phenanthrene (TIC) Petroleum Product Phenanthrenecarboxylic acid (TIC) Pinene (TIC) Propyiphenol (TIC) Trimethylbicycloheptane (TIC) Unidentified Compound(s)

Station H) HERCO1 Sample ID HERCO1-A Media Code WA Sample Date 9/28/10 Units mg/kg U

TABLE 5 (con’t) Detected Semi Volatile Organic Compounds Hercules Inc., Hattiesburg, Mississippi

ti-I

Cl)

C

p 0

.

tD

.

J)

0

CcJQ

©

; O —. Cl)

—. (M

mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 200 NJ U U U U U U N U U U U 2000 J U U U 7000 NJ 4000 NJ U U N U 2000 NJ 200 NJ 200 NJ 2000 3

U

U 2000 NJ U 600 NJ 700 NJ 1000 NJ 100 NJ U N U U U 100 NJ 1000 J

HERC1O HERCIO-B WA 9/29/10

HERCO9 HERCO9-B WA 9/29/10

1000 NJ U 100 NJ 700 NJ 2000 NJ U U N U 100 NJ U 200 NJ 2000 J

U

I{ERC11 }{ERC1 1-B WA 9/29/10

500 NJ U U 3000 NJ 2000 NJ 80 NJ U N U U 300 NJ 200 NJ 1000 J

U

HERC12 HERC12-B WA 9/29/10

1000 NJ U U 7000 NJ 4000 NJ 200 NJ U U U 2000 NJ 200 NJ 200 NJ 2000 NJ

U

KERC13 HERC13-B WA 9/29/10

SESD PROJECT NO. 10-0629

Page 25 of 41

Numbers in BOLD exceed one or both of the USEPA Regional Screening Levels (11/10) or the MDEQ Tier 1 TRG Table (2/28/02) J= the identification of the analyte is acceptable; the reported value is an estimate NJ = Presumptive evidence that analyte is present; reported as a tentative identification (TIC) with an estimated value. 0= other qualifiers have been assigned providing additional information and are defmed in the analytical data sheets included as Appendix B of this report U= the analyte was not detected at or above the reporting limit TIC = Tentatively Identified Compound

Analyte Hexahydrodimethyl(methylethyl)naphthalene (TIC’> Hexahydrotetramethylmethanonaphthalene (TIC) Limonene (TIC) Menthene (TIC) Methyl(methylethyl)benzene (TIC) Methyl(methylethyl)cyclohexane (TIC) Methyl(methylethyl)cyclohexene (TIC) Methyl(methylethyl)phenanthrene (TIC) Petroleum Product Phenanthrenecarboxylic acid (TIC) Pinene (TIC) Propylphenol (TIC) Trimethylbicycloheptane (TIC) Unidentified Compound(s)

Station U) HERCO8 Sample ID HERCO8 Media Code WA Sample Date 9/29/10 Units mg/lcg U

TABLE 5 (con’t) Detected Semi Volatile Organic Compounds Hercules Inc., Hattiesburg, Mississippi

0

SESD PROJECT NO. 10-0629

NS No Regulatory Standard/Level TIC = Tentatively Identified Compound

Analyte (3-and/or 4-)Methylphenol 1,1-Biphenyl 2,4-Dimethyiphenol 2-Methylnaphthalene 2-Methyiphenol Acenaphthene Dibenzofuran Fluoranthene Fluorene Naphthalene Phenanthrene Phenol Pyrene (Dimethylethyl)ethoxybenzene (TIC) (Dimethylethyl)methylphenol (TIC) (Menthenol)terpineol (TIC) (Methylpropyl)benzene (TIC) Bis(methylethyl)biphenyl (TIC) Camphene (TIC) Camphor (TIC) Chiorotrimethylbicycloheptane (TIC) Cycloisolongifolene (TIC) Decahydrotrimethylmethylenemethanoazulene (TIC) Dimethylisopropylphenanthrene (TIC) Diphenyl ether (TIC) Ethyl(methylethyl)beiizene (TIC) Hexahydrodimethyl(methylethyl)naphthalene (TIC) Units mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg -

MDEQ Tier 1 TRG Soil Restricted mg/kg 102000/10200 10200 40800 40900 102000 123000 8180 81700 81700 247 61300 123000 61300 NS NS NS NS NS NS NS NS NS NS NS NS NS NS -

MDEQ Tier 1 TRG Soil Unrestricted mg/kg 3910/391 3910 1560 1560 3910 4690 313 3130 3130 194 2350 46900 2350 NS NS NS NS NS NS NS NS NS NS NS NS NS NS

TABLE 6 EPA and MDEQ Regulatory Levels for Semi Volatile Organic Compounds Hercules Inc., Hattiesburg, Mississippi

-

mg/kg

Page 26 of 41

EPA RSLs Soil Residential 7500 3900 1200 310 3100 3400 78 2300 2300 3.6 NS 18000 1700 NS NS NS NS NS NS NS NS NS NS NS NS NS NS

0

SESD PROJECT NO. 10-0629

NS = No Regulatory Standard/Level TIC = Tentatively Identified Compound

Analyte Hexahydrotetramethylmethanonaphthalene (TIC) Limonene (TIC) Menthene (TIC) Methyl(methylethyl)benzene (TIC) Methyl(methylethyl)cyclohexane (TIC) Methyl(methylethyl)cyclohexene (TIC) Methyl(methylethyl)phenantbrene (TIC) Petroleum Product Phenanthrenecarboxylic acid (TIC) Pinene (TIC) Propyiphenol (TIC) Trimethylbicycloheptane (TIC) Unidentified Compound(s) Units mg/kg mg/kg mg/lcg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg NS NS NS NS NS NS NS NS NS NS NS NS NS

MDEQ Tier 1 TRG Soil NS NS NS NS NS NS NS NS NS NS NS NS NS

MDEQ Tier 1 TRG Soil

TABLE 6 (con’t) EPA and MDEQ Regulatory Levels for Semi Volatile Organic Compounds Hercules Inc., flattiesburg, Mississippi

NS NS NS NS NS NS NS NS NS NS NS NS NS

Page 27 of 41

EPA RSLs Soil

6600 U U 18 U U 75J,0 24 7.9 69 3,0 1200 3,0 23 65 4.6 8.0 71 3,0 U U U 170 3,0 2.1 U 32 4.3 0.58 270 3,0

HERCO1 HERCO1-A WA 9/28/10 4900 U U 18 U U 58 11 14 44 1600 60 45 3.8 3.1 120 U U U 150J,0 1.6 U 17 2.1 0.57 120

HERCO2 HERCO2-B WA 9/28/10

5700 U U 21 U U 210 7.7 2.9 29 4300 9.1 230 31 U 80 180 U U U 2.1 U 62 8.7 1.2 68

HERCO3 HERCO3-B WA 9/28/10

5200 U 6.4 27 U 0.46 400 29 14 100 3400 26 76 14 4.0 200 96 U U 130 3,0 6.1 U 42 5.6 0.99 510

I{ERCO4 HERCO4-B WA 9/28/10

5100 U 5.6 35 U 0.49 2000 45 17 84 4600 34 170 32 4.8 210 110 U U 460 3,0 8.9 U 51 6.6 1.1 690

HERCOS FIERCO5-A WA 9/28/10 5800 U U 100 3,0 U U 5000 20J,O 7.2 27 3,0 4000 3,0 22 440 3,0 200 3,0 21 J,0 543,0 160 U U 180 3,0 34 3,0 U 56 3,0 3.9 1.9 500J,0

HERCO6 HERCO6-B WA 9/28/10

6700 U U 23 U 0.48 710 32 9.5 26 5200 23 62 37 40 44 U U U 130 3,0 8.9 U 22 2.8 1.7 650

HERCO7 HERCO7-B WA 9/28/10

Numbers in BOLD exceed one or both of the USEPA Regional Screening Levels (11/10) or the MDEQ Tier 1 TRG Table (2/28/02) J= the identification of the analyte is acceptable; the reported value is an estimate 0= other qualifiers have been assigned providing additional information and are defmed in the analytical data sheets included as Appendix B U= the analyte was not detected at or above the reporting limit SESD PROJECT NO. 10-0629 Page 28 of 41

Analyte Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Silver Sodium Strontium Thallium Titanium Vanadium Yttrium Zinc

Station ID Sample ID Media Code Sam)le Date Units mg/kg mg/kg mg/lcg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg

TABLE 7- Metals Data Hercules Inc., Hattiesburg, Mississippi

7900 U U 61 U U 250 20 2.7 17 8300 24 240 350 37 8.2 210 U U U 2.6 U 98 18 2.7 130

HERC08 HERCO8 WA 9/29/10 7100 U U 23 U U 530 20 10 110 3500 25 160 39 13 150 160 U 1.0 150J,O 4.6 U 46 5.9 2.0 220

HERCO9 HERCO9-B WA 9/29/10 6400 U 5.0 33 U U 2800 26 14 210 3200 23 200 36 6.4 340 220 U U 210J,O 7.3 U 61 7.6 1.2 570

HERC1O HERC1O-B WA 9/29/10 7000 U U 23 U U 350 25 10 93 1900 23 170 14 4.0 140 160 U U 180J,O 4.2 U 52 7.2 1.2 270

HERC11 HERC1 1-B WA 9/29/10 6700 U U 30 U U 1200 18 13 110 4700 18 210 36 2.8 270 170 U U 240J,O 8.5 U 54 7.5 1.6 370

l{ERC12 I{ERC12-B WA 9/29/10 6800 U 5.6 45 U U 1700 36 21 210 3100 36 150 15 5.6 490 190 U U 230J,O 8.9 U 76 9.0 1.2 480

HERC13 HERC13-B WA 9/29/10

Numbers in BOLD exceed one or both of the USEPA Regional Screening Levels (11/10) or the MDEQ Tier 1 TRG Table (2/28/02) J= the identification of the analyte is acceptable; the reported value is an estimate O = other qualifiers have been assigned providing additional information and are defmed in the analytical data sheets included as Appendix B U= the analyte was not detected at or above the reporting limit SESD PROJECT NO. 10-0629 Page 29 of 41

Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Silver Sodium Strontium Thallium Titanium Vanadium Yttrium Zinc

Analyte

Station ID Sample ID Media Code Sample Date Units mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg

-

TABLE 7 Metals Data (con’t) Hercules Inc., Hattiesburg, Mississippi

Units mg/kg mg/lcg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg -

MDEQ- Soil Restricted mg/kg 2040000 81.7 3.82 14300 1020 1020 NS 3070000 381 12300 8170 613000 1700 NS 4080 1020 4080 NS 1020 1020 NS 123000 143 8180000 1430 NS 61300 -

MDEQ- Soil Unrestricted mg/kg 78200 31.3 0.426. 5480 156 39.1 NS 117000 227 4690 3130 23500 400 NS 1560 391 1560 NS 391 391 NS 46900 5.48 313000 548 NS 23500 —

-

EPA RSLs Soil Residential mg/kg 77000 31 (metallic) 0.39 (inorganic) 15000 160 ( & compounds) 70 (diet) NS 120000 0.29 23 3100 55000 400 ( & compounds) NS 1800 (non-diet) 390 1500 (soluble salts) NS 390 390 NS 47000 NS NS 5.5 (metallic) NS 23000 (metallic)

SESD PROJECT NO. 10-0629

Page 30 of 41

Regulatory levels are taken from the USEPA Regional Screening Levels (11/10) or the MDEQ Tier 1 TRG Table (2/28/02) NS = No Regulatory Standard/Level

Vanadium Yttrium Zinc

Titanium

Analyte Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium III Chromium VI Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Silver Sodium Strontium (stable) Thallium

TABLE 8- EPA and MDEQ Regulatory Levels for Metals Hercules Inc., Hattiesburg, Mississippi

0

0

APPENDIX A PHOTOGRAPHS OF SAMPLING ACTIVITIES Hercules Inc., Hattiesburg, Mississippi SESD Project Identification Number: 10-0629

SESD PROJECT NO. 10-0629

Page 31 of4l

o

0

Photograph 1 Example of waste/sludge from the “Back 40”

Photograph 2 Assessing the HERCO3-B sample location

Photograph 3 Example of waste/ sludge from the “Back 40”

SESD PROJECT NO. 10-0629

Page32of4l

0

0

Photograph 4 Example of waste! sludge from the “Back 40”

Photograph 5 Collecting sample HERCO3-B

Photograph 6 Air monitoring during HERCO3-B sample collection

SESD PROJECT NO. 10-0629

Page 33 of 41

0

0

Photograph 7 Sample location HERCO5-A

Photograph 8 Sample location HERCO4-B

Photograph 9 Sample BERCO6-B

,1

SESD PROJECT NO. 10-0629

Page 34 of4l

0

C Photograph 10 Sample HERCO7-B

Photograph 11 Hand augering sample HERCO7-B

SESD PROJECT NO. 10-0629

Page 35 of 41

C

C

Photograph 12 Sampling “wetlands” to collect HERCO8

Photograph 13 Sample HERCO8 note dense root system —

SESD PROJECT NO. 10-0629

Page36of4l

0

0

Photograph 14 Sample HERCO8 note dense root system —

Photograph 15 Attempting to collect another sample from the “wetlands” dense root system prevented sample collection -

SESD PROJECT NO. W-0629

Page37of4l

0

‘I

-.

1

Sample HERCO6-B

-

-S

-:

•‘)-

•‘.4_ ,. ;-.--

-

-

-

L. -



:

:7

-

‘.

J_HERCO7-B

Photograph 16 Locations for samples HERCO6-B and HERCO7-B

I

Photograph 17— General area of sample HERCO5-A

SESD PROJECT NO. 10-0629

I Page 38 of 41

0

Photograph 18 General area of sample HERCO4-B

Photograph 19 Coring HERCO9-B using Geoprobe

a SESD PROJECT NO. 10-0629

: ç ;

Photograph 20 Collecting sample HERCO9-B with hand auger

Page39of4l

0

0

L

Photograph 21 Collecting sample HERC 1 1-B

Photograph 22 Collecting sample HERC11-B

Photograph 23 Collecting sample HERC 12-B

SESD PROJECT NO. 10-0629

Page 40 of 41

0

0

APPENDIX B SESD ANALYTICAL DATA SHEETS Hercules Inc., Hattiesburg, Mississippi SESD Project Identification Number: 10-0629

Semi-Volatile Organic Compounds Volatile Organic Compounds Metals

=

34 pages

SESD PROJECT NO. 10-0629



=

=

59 pages

60 pages





issued 11/1/10

issued 11/8/10

issued 1/4/11

Page 41 of 41

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

November 1, 2010 4SESD-ASB

MEMORANDUM SUBJECT:

FINAL Analytical Report Project: 10-0629, Hercules Inc Civil Enforcement

FROM:

Janet Muse OCS Chemist

THRU:

Sallie Hale, Chief ASB Organic Chemistry Section

TO:

Sharon Matthews

Attached are the final results for the analytical groups listed below. These analyses were performed in accordance with the Analytical Support Branch’s (ASB) Laboratory Operations and Quality Assurance Manual (ASB LOQAM) found at www.epa.gov/region4/sesdlasbsop. Any unique project data quality objectives specified in writing by the data requestor have also been incorporated into the data unless otherwise noted in the Report Narrative. Chemistry data have been verified based on the ASB LOQAM specifications and may have been qualified if the applicable quality control criteria were not met. For a listing of specific data qualifiers and explanations, please refer to the Data Qualifier Definitions included in this report. The reported results are representative only of the samples as received by the laboratory.

Analyses Included in this report:

Method Used:

Semi Volatile Organics (SVOA) Semivolatile organic compounds

EPA 8270D

TCLP SemiVolatiles (TCLPS) Semivolatile organic compounds

Page 1 of 59

E104009 SVOA TCLPS FINAL

EPA 8270D

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

Sample Disposal Policy

Because of the laboratory’s limited space for long term sample storage, our policy is to dispose of samples on a periodic schedule. Please note that within 60 days of this memo, the original samples and all sample extracts and/or sample digestates will be disposed of in accordance with applicable regulations. The 60-day sample disposal policy does not apply to criminal samples which are held until the Laboratory is notified by the criminal investigators that case development and litigation are complete. These samples may be held in the laboratory’s custody for a longer period of time if you have a special project need. If you wish for the laboratory to hold samples beyond the 60-day period, please contact our Sample Control and provide a reason for holding samples Coordinator, Debbie Colquitt, by e-mail at beyond 60 days

Page 2 of59

E104009 SVOA TCLPS FfNAL

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

SAMPLES INCLUDED IN THIS REPORT

Project: 10-0629, Hercules Inc Sample ID

Laboratory ID

Matrix

Date Collected

Date Received

ERBO1

E104009-01

EquipmentRinse Blank

9/23/10 13:30

10/1/10 8:35

HERCO1-A

E104009-03

Waste

9/28/10 10:10

10/1/10 8:35

HERCO2-B

E104009-04

Waste

9/28/10 10:55

10/1/10 8:35

IIERCO3-B

E104009-05

Waste

9/28/10 13:15

10/1/10 8:35

HERCO4-B

E104009-06

Waste

9/28/10 13:50

10/1/10 8:35

HERCO5-A

E104009-07

Waste

9/28/10 14:05

10/1/10 8:35

HERCO6-B

E104009-08

Waste

9/28/10 14:55

10/1/10 8:35

HERCO7-B

E104009-09

Waste

9/28/10 15:25

10/1/10 8:35

HERCO8

E104009-10

Waste

9/29/10 08:50

10/1/10 8:35

FIERCO9-B

E104009-11

Waste

9/29/10 14:20

10/1/10 8:35

HERCIO-B

E104009-12

Waste

9/29/10 14:15

10/1/10 8:35

HERC11-B

E104009-13

Waste

9/29/10 14:30

10/1/10 8:35

HERC12-B

E104009-14

Waste

9/29/10 14:50

10/1/10 8:35

HERC13-B

E104009-15

Waste

9/29/10 15:10

10/1/10 8:35

Page 3 of 59

E104009 SVOA TCLPS FINAL

11/1/10 16:40

0 0 Sr

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700

V

DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

DATA QUALIFIER DEFINITIONS

U H—7 j

N NA-5 NJ 0-2

The analyte was not detected at or above the reporting limit. Recommended preparation holding time exceeded The identification of the analyte is acceptable; the reported value is an estimate. There is presumptive evidence that the analyte is present; the analyte is reported as a tentative identification. Not Analyzed. Cannot exceed TCLP regulatory levels based on Total Scan analyses. Presumptive evidence that analyte is present; reported as a tentative identification with an estimated value. Result greater than MDL but less than MRL.

OL-2

Laboratory Control Spike Recovery greater than method control limits

OL-3

Laboratory Control Spike Precision outside method control limits

OM-1

Matrix Spike Recovery less than method control limits

OM-6

Matrix Spike Recovery less than 10%

R

The presence or absence of the analyte can not be determined from the data due to severe quality control problems. The data are rejected and considered unusable.

ACRONYMS AND ABBREVIATIONS

CAS

Chemical Abstracts Service Note: Analytes with no known CAS identifiers have been assigned codes beginning with “E”, the EPA 11) as assigned by the EPA Substance Registry System (www.epa.gov/srs), or beginning with “R4-”, a unique identifier assigned by the EPA

Region 4 laboratory.

IvIDL

Method Detection Limit The minimum concentration of a substance (an analyte) that can be measured and reported with a 99% confidence that the analyte concentration is greater than zero.

I\’IRL

Minimum Reporting Limit Analyte concentration that corresponds to the lowest demonstrated level of acceptable quantitation. The MRL is sample-specific and accounts for preparation weights and volumes, dilutions, and moisture content of soil/sediments.

TIC

Tentatively Identified Compound An analyte identified based on a match with the instrument software’s mass spectral library. A calibration standard has not been analyzed to confirm the compound’s identification or the

-

-

-

estimated concentration reported.

Page 4 of 59

EI04009 SVOA TCLPS FINAL

11/1/10 16:40

C

C

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc

-

Reported by Janet Muse

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: ERBOI Station ID:

E104009-01

Matrix: Equipment Rinse Blank

Date Collected: 9/23/10 13:30 C4S Niunber

.4nalyie

1319-77-3

(3-and’or 4-)Methylphenol

92-52-4

Results Qualifiers

Units

1IRL

9.8 U, J. 1-1-7

ugiL

9.8

10/13/10 7:44

EPA 82700

1,1 -Biphenyl

2.0 U, J, [-1-7

ug/L

2.0

10/13/10 17:44

EPA 8270D

95-94-3

I ,2,4,5-Tetrachlorobenzene

9.8 U, J, H-7

ug;L

9.8

1%0/l0

10.13,10 17:44

EPA 82700

95-50-1

1 ,2-Dichlorobenzene

9.8 L’,J,H-7

uWL

9.8

100)0

541-73-1

1 ,3-Dichlorobenzene

9.8 U, J, 1-1-7

ug/L

9.8

0)10

10/13/10 17:44 10/13/10

106-46-7

I ,4-Dichlorobenzene

9.8 U,J,H-7

ug/L

9.8

90-12-0

I -Methylnaphthalene

2.0 U, J, H-7

ug!L

2.0

58-90-2

2,3,4,6-Tetrachiorophenol

9.8 U, J, 1-1-7

ug/L

9.8

95-95-4

2,4,5-Trichiorophenol

9.8 U, J, H-7

ugfL

Prepured

17:44

10/13/10 17:44 10/13/10 ‘7:44 10/13/10 17:44

9.8

l0?0

10/13/10 17:44

9.8

lOflO

10/13/10 17:44 10/13/10 7:44 10/13/10 17:44 10/13/10 17:44 10/13/10 17:44 10/13/10 7:44 10/13/10 17:44 10/13/10

88-06-2

2,4,6-Trichlorophenol

9.8 U, J, H-7

120-83-2

2,4-Dichiorophenol

9.8 U, J, H-7

ug/L

9.8

I0310

105-67-9

2,4-Dimethyiphenol

9.8 U, J, H-7

ug/L

9,8

‘°°

ugfL

.4naIy.ed ,‘ileihod

51-28-5

2,4-Dinitrophenol

9.8 U. 3, 11-7

ug/L

9.8

12 1-14-2

2,4-Dinitrotoluene

9.8 U, 3, H-7

ug/L

9.8

606-20-2

2,6-Dinitrotoluene

9.8 U, J, H-7

ug!L

9.8

91-58-7

2-Chloronaphthalene

9.8 U, J, H-7

ugJL

9.8

95-57-8

2-Chlorophenol

9.8 U,J,H-7

ug/L

534-52-1

2-Methyl-4,6-dinitrophenol

9.8 U, J, F1-7

ug/L

9.8

91-57-6

2-Methylnaphthalene

2.0 U, J, H-7

ug/L

2.0

I0/7I0 l0/0

1010

lO/04/l0 6.57

17:44

10/13/10 17:44 10/13/10 17.44 10/I 3/10 17:44

95-48-7

2-Methylphenol

9.8 U,J,H-7

ugfL

9.8

88-74-4

2-Nitroaniline

9.8 U, 3, H-7

uWL

9.8

88-75-5

2-Nitrophenol

9.8 U, J. H-7

ugfL

9.8

I01i0

91-94-1

3,3’-Dichlorobenzidine

9.8 U, J, H-7

ug!L

9.8

I0/0O

99-09-2

3-Nitroaniline

9.8 U,J,H-7

ug/L

9.8

10/04/10

10,13/10 7:44 10)13/10 17.44 10/13/10 17:44 10/13/10

101-55-3

4-Bromophenyl phenyl ether

9.8 U, J, H-7

ug!L

9.8

I0/07I0

10/13/10

59-50-7

4-Chloro-3-methylphenol

9.8 U, J, H-7

ugJL

9.8

0/04/10

10/13)10

106-47-8

4-Chioroaniline

9.8 U, J, H-7

ug’L

9.8

7005-72-3

4-Chiorophenyl phenyl ether

9.8 U. J. H-7

ug/L

9.8

I0)0

100-01-6

4-Nitroaniline

9.8 U, J, H-7

ug/L

9.8

0/ 6 I0/ W 7

100-02-7

4-Niliophenol

9.8 U, J, H-7, QL-3

ugIL

9,8

10/04/10

Page 5

of 59

E104009 SVOA TCLPS F[-NAL

17:44 1744

17:44 1013/10 17:44

10/13/10 17:44 10/13/10

EPA 8270D EPA 82700 EPA 82700 EPA 8270D EPA 82700 I/PA 82701)

EPA 8270D EPA 8270D EPA

82700

EPA 82700 EPA 82700 EPA 8270D EPA 8270D EPA 82700

EPA 8270D EPA 82700 EPA

8270D

EPA 82700 EPA

8270D

EPA 8270D EPA 82700 EPA 82700 EPA 8270D EPA 8270D EPA 8270D

17:44

EPA 8270D

10/13/10 7:44

EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id; 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: ERBOI

E104009-0l

Matrix: Equipment Rinse Blank

Station ID: Date Collected: 9/23/10 13:30 C4S

Number

.4nalyte

83-32-9

Acenaphthene

Units

IIRL

2.0 U, 3, H-7

uglL

2.0

Results Qualifiers

208-96-8

Acenaphthylene

2.0 U,JH-7

ugIL

2.0

98-86-2

Acetophenone

9.8 U, J, 11-7

ug/L

9.8

120-12-7 1912-24-9 100-52-7 56-55-3 50-32-8

Anthracene Atrazine Benzaldehyde

Benzo(a)pyrene

17:44

2.0 U, J, 11-7

ug/L

2.0

9.8 U. J. H-7

ug/L

9.8

I0/0

9.8

°°

2.0 U, 3. H-7 2.0 U, J, H-7

ug/L

ugIL

2.0

ug/L

2.0 10/04/10 6:57

205-99-2

Benzo(b)tluoranlhene

2.0 U. J, 11-7

ug!L

7 0

191-24-2

Benzo(g,h,i)perylene

2.0 U, 3, H-7

ug/L

2.0

1O/600

70

0/04/10

207-08-9

Benzo(k)tluoranthene

2.0 U, J, II-?

ug/L

9.8 9.8

100-51-6

Benzyl alcohol

9.8 L, J, H-7

ug!L

85-68-7

Benzyl butyl phthalate

9.8 U, J. 1-1-7

ug/L

9.8

111-91-1

Bis(2-chloroethoxy)methane

9.8 U. J, H-7

ug/L

111-44-4

bis(2-Chloroethyl) Ether

9.8 U, 3, 11-7

ug!L

9.8

39638-32-9

Bis(2-chloroisopropyl) ether

9.8 U, J, 11-7

ug/L

9.8

117-81-7

Bis(2-ethylhexyl) phthalate

9.8 U, J, 11-7

ug/L

9.8

105-60-2

Caprolactam

9.8 U, J, H-7, QL-3

ug/L

9.8

86-74-8

Carbazole

2.0 U, 3, 11-7

ug!L

2.0

218-01-9

Chrysene

2.0 U, J, 1-1-7

ug!L

2.0

53-70-3

Dibenz(a,h)anthracene

2.0 U. J, 11-7

132-64-9

Dibenzofuran

2.0 U, 3, H-7

ugfL

2.0

9.8 U, J. H-7

ug/L

9.8

84-66-2 13 1-1 1-3

Diethyl phthalate Dimethyl phthalate

9.8 U, J, 1-1-7

ug/L

7:44

I0/l0

206-44-0

Fluoranthene

2.0 U, J, 1-1-7

ug/L

2.0

‘°°

2.0 U, J, 1-1-7

ug/L

2.0

10/710

I%0

67-72-1

Page 6 of59

Hexachloroethane

E104009 SVOA TCLPS FINAL

9.8

9.8 U. 3, 11-7

ug/L

9.8

EPA 82700 EPA 8270D EPA 82700 EPA 8270D EPA 82700

10/13/10 17:44 10/13/10

9.8 U, J, 1-1-7

9.8 U. 3,11-7

EPA 82700 EPA 8270D

10/04/10

117-84-0

Hexachlorocyclopentadiene (HCCP)

EPA 82700 EPA 82700

EPA 8270D

9.8

77-47-4

EPA 82700

EPA 82700

9.8

9.8

EPA 82701)

1013.10 17:44

ugJL

ug/L

EPA 82700

‘°°

ugfL

ug!L

0/13/10 17:44 10/13/10 17:44 10/13/10 17:44 10/13/10 17:44 10/13/10 17:44 10/13/10 17:44

9.8

9.8 U, 3,11-7

EPA 8270D

10/13/10 17:44 10/13/10 17:44 10/13/10 17:44

I0/13/l0 17:44

9.8 U, J. H-7

Hexachlorobenzene (HCB)

EPA 82700

10/13/10 17:44

17:44

Di-n-butylphtha late

118-74-I

EPA 8270D EPA 82700

°°

Di-n-octylphthalate

Fluorene

EPA 82700

7:44

10/13/10 17:44 10/13/10

io;o

EPA 82700 EPA 8270D

01/13/40 17:44

6:57

84-74-2

86-73-7

101310 17:44 10/13/10 17:44 10/13/10

10/13/tO 17:44

2.0

ugIL

.4m4rzed /tfefhod 10/13/10 17:44 10/13/to

10/04/10

9.8 U,J,F1-7

Benzo(a)anthracene

Prepared

10)0

i0)I0

10/13/10 17:44 10/13/10 17:44 10/13/10 17:44 10/13/10 17:44 loll 3/JO 17:44 I0/13/10 17:44 10/13/tO 17:44 10/13:10

17:44

EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc

-

Reported by Janet Muse

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: ERBO1 Station ID:

E104009-O1

Matrix: Equipment Rinse Blank

Date Collected: 9/23/10 13:30 C.4S Nn,nher

Results Qualifiers

.4nalyte

Units

MRL

Prepared

.lnalyed 10/13/10 17:44

lfethod

193-39-5

Indeno (1,2.3-cd) pyrene

2.0 U, J, H-7

ug/L

2.0

10/04/10 6:57

78-59-I

Isophorone

9.8 U, J, H-7

ugIL

9.8

10/04/10

10/13/10

91-20-3

Naphthalene

2.0 U, J, H-7

ug/L

2.0

10/04/10 6:57

17:44 1013/10 17.44

98-95-3

Nitrobenzene

9.8 U, J, H-7

ug/L

9.8

10/04/10 6:57

10/13/10 17:44

EPA 8270D

621-64-7

n-Nitroso di-n-Propylamine

9.8 U. J, 11-7

ug/L

9.8

1004/10 6:57

10:13110 17:44

EPA 82700

9.8

10/04/10

10/13/10

EPA 8270D

122-39-4

n-Nitrosodiphenylamine/Diphenylamine

9.8 U, J, H-7

ugJL

g74,’:

Pentachlorophenol

9.8 U, J. 11-7

ug/L

9.8

85-01-8

Phenanthrene

2.0 U. J, H-7

ug/L

2.0

108..’

Phenol

9.8 Ii. J, H-7

ug/L

9.8

129-00-0

Pyrene

2.0 U, 3, H-7

ug/L

ug/L

657

6:57 10/04/10 6:57 10/04/10 6:57

17:44 10/13)10

17:44 10/13/10 17:44

EPA 8270D

EPA 8270D EPA 82700

EPA 82700 EPA 827013

10/04/10

10/13.10

2.0

6:57 10/04/10 6:57

17:44 10/13/10 17:44

EPA 82700

10

10/04/10 657

10/13/10 1744

EPA 82700

EPA

8270D

Tentatively Identified Compounds: R4-0000

Page 7 of 59

Tentatively Identified Compounds

E104009 SVOA TCLPS FTNAL

10 U

11/1/10 16:40

0 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercu’es Inc

-

Reported by Janet Muse

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: IIERCOI-A

E104009-03

Matrix: Waste

Station ID: HERCOI Date Collected: 9/28/10 10:10 CAS Nwnber

1319-77-3 92-52-4 58-90-2 95-95-4

Results Qualifiers

4nalyte

(3-and/or 4-)Methylphenol

20 J. Q-2

1600

1,1 -Biphenyl 2,3,4,6-Tetrachlorophenol 2,4,5-Trichlorophenol

Units

mg/kg

mg/kg

MRL

Prepared

26

10/05/10 12:00

26

10/05/10 12:00

.4navzed ,Sfethod 10/09/10

23:16 10/09/10 23:16 1009/)0

mg/kg

10/05/10

2:00

23:16

26 U

mg/kg

10/05/10 12:0))

10/09/10 23:16 10/09/10 23:16 10/09/10 23:16

26 U

26

88-06-2

2,4,6-Trichiorophenol

26 U

mg/kg

120-83-2

2,4-Dichlorophenol

26 U

mg/kg

10/05/10 12:00 10/05/10 12:00

26 U

mg/kg

‘3

0/05/10 12:00

26

10/05/10 12:00

2316 10/09/10 23:16

10/05/10

10/09/10

12:00

23:16 10/09/10 23:16 0/09/10

105-67-9

2,4-Dimethylphenol

26

51-28-5

2,4-Dinitrophenol

26 U, R. QM-6

mg/kg

121-14-2

2,4-Dinitrololuene

26 U

mg/kg

., ..,



606-20-2

2,6-Dinitrotoluene

26 U

mg/kg

91-58-7

2-Chloronaphthalene

26 U

mg/kg

26

10/05/10

12:00 10/05/10 12:00 10/05/10 12:00

95-57-8

2-Chiorophenol

26 U

mg/kg

.,;

534-52-1

2-Methyl-4,6-dinitrophenol

26 Li

mg/kg

26

10/05/10

2•6

10/05/1))

91-57-6 95-48-7

88-74-4 88-75-5 91-94-1

2-Methylnaphthalene

4.6 7.8 J, Q-2

2-Methyiphenol 2-Nitroaniline

2-Nitrophenol 3,3’-Dichlorobenzidine

mg/kg mg/kg

-•‘3

26 1.;

mg/kg

•,i

26 U

mg/kg

26

26 U

mg/kg

‘,

., ‘3

99-09-2

3-Nitroaniline

26 U

mg/kg

101-55-3

4-Bromophenyl phenyl ether

26 U

mg/kg

26

mg/kg

-, ‘3

59-50-7

106-47-8 7005-72-3

4-Chloro-3-methylphenol

26 U 26 U

4-Chioroaniline 4-Chiorophenyl phenyl ether

mg/kg

120-12-7 1912-24-9

Page 8 of 59

Anthracene Atrazine

E104009 SVOA TCLPS Ffl’,’AL

10/09/10 23:16

EPA 8270D EPA 82700

2:00 10/05/10

1009/10

12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 0/05/10 12:00 10/05/10 12:00 10/05/10 12:00

23:16 10/09/10 23:16 10/09/10

10/05/10

23:16

EPA 82700 EPA 82700 EPA 8270D

10/09/10 23:16 10/09/10 23:16 10/09/10 23:16

EPA 82700

1009/10 23:16

EPA 82700

10/09/TO 23:16

EPA 82700

EPA 82700

EPA 82700

mg/kg

EPA 82700

mg/kg

)0/05/10 2:00

10/09/10

23:16

EPA 82700

10/05/10

10/09/10 2316

EPA 8270D

10/09/TO 23:16

EPA 82700

2.6 U

mg/kg

26 U

EPA 82700 EPA 8270D

10/09/10 23:16

mg/kg

Acetophenone

EPA 82700 EPA 82700

10/05/10 12:00

26 -, ‘3

26 U 26 U

98-86-2

EPA 82700 EPA 82700

EPA 82700

4-Nitroaniline

2.6 U

EPA 8270D

EPA 82700

4-Nitrophenol

Acenaphthylene

EPA 82700

10/1)9/10

mg/kg

100-02-7

208-96-8

EPA 82700

10/09/10 2316

10/09/10 23.16

12:01) 10/05/10

EPA 82700

10/05/10 2:1))) 10/05/10 12:00 10/05/10 12:00

26 U

100-01-6

Acenaphthene

23:16

EPA 82700

10/09/10 2316

mg/kg

83-32-9

26

2:00

10/09/10

EPA 8270D

26

e

26

2.6 U

mg/kg

26

26 U

mg/kg

.,

12:00

12:00 10/05/10

12:00

23:16 10/09/10

23:16 10/09/10 23:16

EPA 8270D EPA 8270D

11/1/10 16:40

C)

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: IIERCOI-A Station ID: HERCOI

E104009-03

Matrix: Waste

Date Collected: 9/28/10 10:10 CAS

Number

.4nalyte

100-52-7

Benzaldehyde

26 U

56-55-3

Benzo(a)anthracene

2.6

U

Results Qualifiers

Units

MRL

Prepared

.1 nalyed

mg/kg

26

050 2 T 1

mg/kg

2.6

12:00 12:00

10:09,10 23:16 10109110 23:16 10/09/10 23:16 10/09/10 23:16 1009/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/11) 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 10/09/10 23:16 1009/10 23:16

50-32-8

Benzo(a)pyrene

2.6 U

mg’kg

2.6

205-99-2

Benzo(b)fluoranthene

2.6 U

mg/kg

2.6

191-24-2

Benzo(g,h.i)perylene

2.6 U

mg/kg

2.6

207-08-9

Benzo(k)fluoranthene

2.6 U

mg/kg

2.6

85-68-7

Benzyl butyl phthalate

26 U

mg/kg

26

111-91

26

12:00 1TO 1l/0

ii:io

Bis(2-chloroethoxy)methane

26 U

mg/kg

111-44-4

bis(2-Chloroethyl) Ether

26 U

mg/kg

26

°

39638-32-9

Bis(2-chloroisopropyl) ether

26 U

mg/kg

26

1//T0

117-81-7

Bis(2-cthylhexyl) phthalate

26 U

mg/kg

26

105-60-2

Caprolactam

26 U, R, QM-6

mg/kg

26

1201

86-74-8

Carbazole

2.6 U

mg/kg

2.6

U/O50

218-01-9

Chrysene

2.6 U

mg/kg

2.6

53-70-3

Dibenz(a,h)anthracene

2.6 U

mg/kg

2.6

132-64-9

Dibenzofuran

2.6 U

mg/kg

2.6

84-66-2

Diethyl phthalate

26 U

mg/kg

26

131-11-3

Dimethyl phthalate

26 U

mg/kg

26

84-74-2

Di-n-butylphthalate

26 U

mg/kg

26

117-84-0

Di-ri-octylphthalate

26 U

mg/kg

26

19/20:0

206-44-0

Fluoranthene

11 J,QM-1

mg/kg

2.6

04 1 9 °

86-73-7

Fluorene

3.0

mg/kg

2.6

H/1:5o/r0

118-74-1

Hexachlorobenzene (HCB)

26 U

mg/kg

26

-

12:00 11/0 9/20:50/T0

ll/0

12.

87-68-3

Hexachiorobutadiene

26 U

mg/kg

26

77-47-4

Hexachiorocyclopentadiene (HCCP)

26 U, J, QM-l

mg/kg

26

67-72-1

Hexachloroethane

26 U

mg/kg

26

‘9’°

193-39-5

Indeno (1,2.3-cd) pyrene

2.6 U

mg1g

2.6

1f1:5I0

78-59-1

Isophorone

26 U

mg/kg

26

91-20-3

Naphthalene

6.2

mg/kg

2.6

‘‘°

98-95-3

Nitrobenzene

26 U

mg/kg

26

19/2050

621-64-7

n-Nitroso di-n-Propylamine

26 U

mg/kg

26

20

Page 9 of 59

E104009 SVOA TCLPS FINAL

12:00 IT/305O

llethod EPA 8270D

EPA 8270D EPA 82700 EPA 8270D EPA 82700

EPA 8270D EPA 82700

EPA 8270D EPA 82700 EPA 8270D EPA 82700

EPA 8270D EPA 8270D

EPA 8270D EPA 82700 EPA 82700 EPA 82700

EPA 8270D EPA 8270D

EPA 8270D EPA 82700

EPA 8270D EPA 827/3D EPA 827/3D

EPA 82700 EPA 827/3D

EPA 82700 EPA 827/3D EPA 827/3D EPA 827/3D EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART, Id: 10-0629 Inc Reported by Janet Muse Hercules 10-0629, Project: -

Semi Volatile Organics ProjecI: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCOI-A

Matrix:

Station ID: HERCO1

E104009-03 Waste

Date Collected: 9/28/10 10:10

c4s N,unber 122-39-4

Results Qualifiers

.4nalyfr n-Nitrosodiphenylamine/Diphenylamine

26 U

Units mg/kg

MRL

Prepared

26

10/05/10 12:00 10/OS/ID 1200 10/05/10 12:00 10/05/10

87-86-5

Pentachiorophenol

26 U

mg/kg

26

85-01-8

Phenanthrene

2.6 U

mg/kg

2.6

108-95-2

Phenol

5.3 J, Q-2

mg/kg

26 2.6 26

129-00-0

Pyrene

16

mg/kg

I 10-86-1

Pyridine

26 U

mg/kg

100 NJ

mg/kg

90 NJ

mg/kg

inaly:ed Method

12:00

10/09/10 23:16 10/09/10 23:16 10/09/10 23:I6 10/09/10 23:I6

10:05/10

10/09/10

12:00 10/05/10 12:00

23:16 10/09/10 23:16

10/05/10 12:00 10/05/10 12:00

10/09/10 23:16 10/09/10 23:16

10/05/10

10/09/10

12:00 10/05/10 12:00 10/05/10

23:16 10/09/10 23:16 10/0910 23:16 10/09/10 23-6 10/09/10 2316

EPA 8270D

EPA 8270D EPA

8270D

EPA 8270D EPA 8270D EPA 8270D

Tentatively Identified Compounds: R4-8000900 R4-6552 R4-653 I

(Dimethylethyl)ethoxybenzene (TIC) (Menthenol)terpineol (TIC) Camphene (TIC)

R4-8000904

Cycloisolongifolene (TIC)

R4-8000535

Diphenyl ether (TIC)

R4-8000898

Ethyl(methylethyl)benzene (TIC)

R4-8000899

Hexahydrotetramethylmethanonaphthalene (TIC)

R4-7545

Limonene (TIC)

R4-6584

Methyl(methylethyl)benzene (TIC)

R4-8000897

MethyI(methylethyl)cyclohexane (TIC)

R4-6500

Petroleum Product:

R4-6520

Pinene (TIC)

R4-650I

[nidentified Compounds

Page 10 of59

E104009 SVOA TCLPS FfNAL

200 NJ

mg/kg

80 NJ

mg/kg

1000 NJ

mg/kg

60 NJ

mg/kg

1000 NJ

mg/kg

300 NJ

mg/kg

12:00

10/05/10 1200 10/05/10 12:00

500 NJ

mg/kg

10/05/10 12:00

0/09/10 23:16 10/09/10 23:16 10/09/I)) 23:16 10/09/10 23:16 10/09/10 23:16

70 J

mg/kg

100510 1200

1009:10 2316

2000 NJ

mg/kg

800 NJ

mg/kg

N

10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00

EPA 8270D EPA 8270D EPA 8270D

EPA 8270D EPA 8270D

EPA 8270D EPA 8270D

EPA 8270D EPA 8270D EPA 8270D

EPA 8270D EPA 8270D EPA 8270D

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

TCLP SemiVolatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCOI-A Station ID: IIERCOI

E104009-03

Matrix: Waste

Date Collected: 9/28/10 10:10 C.4S Niunber

.4nalyte

1319-77-3

(3-andlor4-)Methylphenol:

58-90-2

2,3,4,6-Tetrachlorophenol:

XA-5

0.10

95-95-4

2,4.5-Trichlorophenol:

NA-5

0.10

Results Qualifiers

NA-5

Units

bIRL

0.10

88-06-2

2,4,6-Tnchlorophenol:

NA-5

0.10

121-14-2

2,4-Dintro1o1uene:

NA-S

0.10

95-48-7

2-Methylphenol:

NA-S

0.10

118-74-1

1-lexachloroberizene (HCB):

NA-5

0.10

87-68-3

-

Hexachlorobutadiene:

NA..5

0.10

flexachioroethane

NA 5

0 10

98-95-3

Nitrobenzene:

NA-5

0.10

87-86-5

Pentachlorophenol:

NA-5

0.10

110-86-1

Pyridine:

Page 11 of59

NA-5

E104009 SVOA TCLPS FINAL

0.10

Prepared

nav:ed .‘.lethod

I0JI0

‘%°‘°

EPA 8270D

0 j 1 190

10/90I0

EPA 8270D EPA8270[) EPA 8270D

°‘°

hI’A

1%o/1o

8270D

EPA 8270D

‘°

EPA 8270D

10/05/10

EPA 8270D

1005/10

1009/10

‘°2°

10/09/ID

1O10

Il/409/0

EPA 87OD

EPA827OD EPA 8270D EPA827OD

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO2-B

E104009-04

Mairix: Waste

Station ID: HERCO2 Date Collected: 9/28/10 10:55 CAS Number

1319-77-3

Results Qualifiers

4nulyte

(3-andlor4-)Methylphenol

Units

50

mg/kg

3900

MRL

25

92-52-4

1,1-Biphenyl

mg/kg

51

58-90-2

2,3,4,6-Tetrachlorophenol

25 U

mg/kg

25

95-95-4

2,4,5-Trichlorophenol

25

U

mg/kg

25 25

88-06-2

2,4,6-Trichlorophenol

25 U

mg/kg

120-83-2

2,4-Dichlorophenol

25 U

mg/kg

25

105-67-9

2,4-Dimelhylphenol

25 U

mg/kg

25

51-28-5

2,4-Dinitrophenol

25 U

mg/kg

25

121-14-2

2,4-Dinitrotoluene

25 U

mg/kg

25

606-20-2

2,6-Dinitrotoluene

25 U

mg/kg

25

9 1-58-7

2-Chloronaphthalene

25 U

mg/kg

25

95-57-8

2-Chlorophenol

25 U

mg/kg

25

534-52-1

2-Methyl-4.6-dinitrophenol

25 U

mg/kg

25

91 -57-6

2-Methylnaphthalene

5.6

mg/kg

2.5

95-48-7

2-Methylphenol

4.7 J, Q-2

mg/kg

25

88-74-4

2-Nitroaniline

25 U

mg/kg

25

88-75-5

2-Nitrophenol

25 U

mg/kg

25

91-94-1

3,3’-Dichlorobenzidine

25 U

mg/kg

25

25

99-09-2

3-Nitroartiline

25 U

mg/kg

101-55-3

4-Bromophenyl phenyl ether

25 U

mg/kg

25 25

59-50-7

4-Chloro-3-methylphenol

25 U

mg/kg

106-47-8

4-Chloroaniline

25 U

mg/kg

25

7005-72-3

4-Chlorophenyl phenyl ether

25 U

mg/kg

25

100-01-6

4-Nitroaniline

25 U

mg/kg

25

100-02-7

4-Nitrophenol

25 U

mgkg

25 2.5

2.5

83-32-9

Acenaphthene

2.9

mg/kg

208-96-8

Acenaphthylene

2.5 U

mg/kg

98-86-2

Acetophenone

25 U

mg/kg

25

120-12-7

Anthracene

2.5 U

n/g’kg

2.5

1912-24-9

Alrazine

25 U

mg/kg

25

Page 12 of59

E104009 SVOA TCLPS FINAL

Prepared 0/05/10 12:00 10/05/10 12:00 10)05/10 1200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 100510 1200 10/05,10 12:00 10/05/10 12:00 10/05/10 1200 0/05/10 12:00 10/os/la 2:00 10/05/10 12:00 10/85/10 12:00 10/05/10 12-00 10/05/10 12:00 10/05/10 1200 10105/10 12:00 10,05/10 12:00 10/05/10 12:00 I0(05/I0 12:00 10105/10 12:00

1nuvzed ,Otethod 10/09/10 23:51 10/09/10 23:51 10.09110 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10(09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10.’09/10 23:5! 10/09/10 23:51 10/09/10 2351 10/09/10 2351 10/09/10 23:5! 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 l0’09/10 23:5! 10/09/10 23:51 10/09/10 23:5! 10/09/10 23:51 10/09/10 23:51

EPA 8270D

EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA 8270[) EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 8270D EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700

11/1/10

16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO2-B Station ID: HERC02 Date Collected:

E104009-04

Matrix: Waste

9/28/10 10:55

C4S Vgrnber

.4na!yte

100-52-7

Benzaldehyde

25 U

56-55-3

Benzo(a)anthracene

2.5

50-32-8

Benzo(a)pyrene

205-99-2

Results Qualifiers

Units

hfRL

Prepared

lnatr:ed

mg/kg

25

U

mg/kg

2.5

2.5 U

mg/kg

2.5

10/05/10 12:00 10/05/10 12:00 1005/10

Benzo(b)fluoranthene

2.5 U

mg/kg

2.5

10/05/10

191-24-2

Benzo(g,h.i)perylerse

2.5 U

mg/kg

2.5

00510 2-00

207-08-9

Benzo(k)fluoranthene

2.5 U

mg/kg

2.5

85-68-7

Benzyl butyl phthalale

25 U

mg/kg

25

10/05/ID 12:00 10/05/10

10/09,10 23:51 10/09/10 23:51 10/0910 23:51 10/09/10 23:51 1009.10 23:51 10/09/10 23:51 10/09)10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:5! 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:5! 10/09/10

111—91—1

Bis(2-chloroethoxy)methane

25 U

mg/kg

25

111-44-4

bis(2-Chloroethyl) Ether

25 U

mg/kg

25

39638-32-9

Bis(2-chloroisopropyl) ether

25 U

mg/kg

25

117-81-7

Bis(2-ethylhexyl) phthalate

25 U

mg/kg

25

105-60-2

Caprolactam

25 U

mg/kg

25

86-74-8

Carbazole

2.5 U

mg/kg

2.5

218-01-9

Chrysene

2.5 U

mg/kg

2.5

53-70-3

Dibenz(a,h)anthracene

2.5 U

mg/kg

2.5

132-64-9

Dibenzofuran

4.1

mg/kg

2.5

84-66-2

Diethyl phthalate

25 U

mg/kg

25

131-11-3

Dimethyl phthalate

25 U

mg/kg

25

84-74-2

Di-n-butylphthalate

25 U

mg/kg

25

117-84-0

Di-n-octylphthalate

25 U

mg/kg

25

206-44-0

Fluoranthenc

9.8

mg/kg

2.5

86-73-7

Fluorene

3.4

mg/kg

2.5

118-74-1

I-lexachlorobenzene (IICB)

25 U

mg/kg

25

87-68-3

Hexachlorobutadiene

25 U

mg/kg

25

77-47-4

Hexachlorocyclopentadiene (HCCP)

25 U

mg/kg

25

67-72-1

Hexachioroethane

25 U

mg/kg

25

193-39-5

Indeno (1,2.3-cd) pyrene

2.5 U

mg/kg

2.5

78-59-1

Isophorone

25 U

mg/kg

25

91-20-3

Naphthalene

8.8

98-95-3

Nitrobenzene

25 U

mg/kg

25

621-64-7

n-Nitroso di-n-Propylamine

25 U

mg/kg

25

Page 13 of59

E104009 SVOA TCLPS FINAL

2.5

1200 12:00

12:00

10/05/10 12:00 0/05/ID 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 0/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 1200 10/05/10 12:00 1005:10 12:00 10/05/10 12.00 10/05/10 12:00 10/05/10 12:00 10 05’IO 2:00

23:51

10.09/10 23:51 0/09/10 23:51

10/09/10 23:5! 10/09/10 23:51 10,09/10 23:5! 10/09/10 23:51 1009/10 23:5!

herhod

EPA 8270D EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA 02701) EPA 8270D EPA 82700 EPA 8270D EPA 8270D EPA 8270D EPA 82700 EPA 82700 EPA 8270D EPA 8270D EPA 82700 EPA 8270D EPA 8270D EPA 8270D EPA 8270D EPA 8270D EPA 8270D EPA 8270D EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Janet Muse -

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO2-B

E104009-04

Matrix: Waste

Station ID: HERCO2 Date Collected: 9/28/10 10:55 C.4S .‘,unher

Resulls Qualifiers

.4nalyte

122-39-4

n-Nitrosodiphenylamine/Diphenylamine

Units

25 U

mg/kg

MRL

Prepared

25

10/05/10 2:00 10/05/JO 1200 b/OS/lU 1200 10/05/10 12:00 10/05/10 2:00 10/05/10 12:00

10/09/10 23:51 10/09/10 235J 10/09/10 2351 10/09/10 23:51 10/0910 23:51 10/09/JO 23:51

10/05/10 12:00 10/05/10 12:00 10105/jO

10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 I0/09/I0 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 10/09/10 23:51 100910 235!

87-86-5

Pentachlorophenol

25 U

mg/kg

25

85-01-8

Phenanthrene

5.5 J, QL-2

mg/kg

2.5

108-95-2

Phenol

5.4 J, Q-2

mg/kg

25 2.5 25

129-00-0

Pyrene

2.5 U

mg/kg

110-86-1

Pyridine

25 U

mg/kg

300 NJ

mg/kg

60 NJ

mg/kg

Analyzed 0k/hod EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA 8270D

Tentatively Identified Compounds: R4-8000900

(Dimethylethyl)ethoxybenzcnc (TIC)

R4-6552

(Menthenol)terpineol (TIC)

R4-6531

Camphene (TIC)

200 NJ

mg/kg mg/kg

200 NJ

mg/kg

50 NJ

mg/kg mg/kg

1005.10 200

R4-8000904

Cycloisolongifolene (TIC)

80 NJ

R4-8000898

Ethyl(methylethyl)benzene (TIC)

70 NJ

mg/kg

3000 NJ

mg/kg

600 NJ

mg/kg

R4-6584

Methyl(rnethylethyl)benzene (TIC)

R4-8000897

Methyl(methylethyl)cyclohexane (TIC)

R4-6500

Peholeum Product:

R4-6520

Pinene (TIC)

R4-8000466

Propylphenol (TIC)

R4-6501

Unidentified Compounds

Page 14 of59

E104009 SVOA TCLPS FINAL

12:00

10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 I0/05/bO 2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00

N

900 J

EPA 8270D

EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 82700

EPA 8270D EPA 82700 EPA 82700

EPA 8270D

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

TCLP SemiVolatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: 1{ERCO2-B Station ID: HERCO2

E104009-04

Matrix: Waste

Date Collected: 9/28/10 10:55 (*IS .Vuuther

.4nalyte

1319-77-3

(3-and/or 4-)Methylphenol:

Results Qualifiers

NA-5

Units

jlfRL

0.10

58-90-2

2,3,4,6-Tetrachlorophenol:

NA-5

0.10

95-95-4

2,4,5-Trichlorophenol:

NA-5

0.10

88-06-2

2,4,6-Trichlorophenol:

NA-S

0.10

121-14-2

2,4-Dinitrotoluene:

NA-S

0.10

95-48-7

2-Methylphenol:

NA-S

0.10

118-74-1

I-lexachlorobenzene (11CR):

NA-5

0.10

Hexachlorobutadiene:

NA-5

0.10

NA-5

0.10

87-68-3--.

-..

67-72-1 Hexachioroethane: 98-95-3

Nitrobenzene:

NA-5

0.10

87-86-5

Pentachlorophenol:

NA-5

0.10

110-86-1

Page 15 of 59

Pyridine:

NA-5

E104009 SVOA TCLPS FINAL

0.10

Prepared

10/05/10

1naI’zed

I0’09’I0

944

41)4

10/05/10

10/09/10 14:04 0/09/10 1404 10/09/b 14:04 0/09/10

944

10,051)0 944 10/05/ID 9:44 10/05/10

10/05/10 944 10/OS/b 944 10/05/10 9:44 b/OS/b 9:44

10/05/10 944

10/09/10 14:04 10109/10 14:04 10/09/10 14:04 10/09/10 4:04 10/09/10 14:04

0:05/)0

10/09/10

944

404 10/09/10 14:04

10/05/10

944

Ofethod

EPA 8270D

EPA 8270D EPA 8270D

EPA 8270D EPA 8270D

EPA 8270D EPA 8270D

EPA

8270D

EPA 8270D

EPA 8270D EPA 8270D EPA 8270D

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id. 10-0629

/

Project: 10-0629, Hercules Inc

-

Reported by Janet Muse

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO3-B

E104009-05

Matrix: Waste

Station ID: IIERCO3 Date Collected: 9/28/10 13:15 CIS Nwnher

.4nalyte

1319-77-3

(3-and/or 4-)Methylphenol

Re.si,Il Qualifiers

24 U

MRL

Prepared

.4nalvzed

24

10/05/10

mg/kg

2.4

10/05/10

mg/kg

24

10/09/10 22:06 10/09/10 22:06 10/09/10 2206 10/09/10 22:06 10/09:10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10:09:10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/tO 22:06 10/09/10 22.06 10:091)0 22:06 10/09/10 22:06 10/09/10 22:06 10’09/10 22:06 10.09.10 22:06 10/09/10 22:06 10/09:10 22:06 10/09/10 22:06

Un/ta

mg/kg

92-52-4

1,1-Biphenyl

58-90-2

2,3,4,6-Tetrachlorophenol

24 U

95-95-4

2,4,5-Trichlorophenol

24 lj

mg/kg

24

24 U

mg/kg

24

88-06-2 120-83-2

130

2.4,6-Trichlorophenol 2,4-Dichlorophenol

24 U

mg/kg

24 24

105-67-9

2,4-Dirnethylphenol

24 U

mg/kg

51-28-5

2,4-Dinitrophenol

24 U

mg/kg

24

121-14-2

2,4-Dinitrotoloene

24 U

mg/kg

24 24

606-20-2

2,6-Dinib-otoluene

24 U

mg/kg

9 1-58-7

2-(’hloronaphthalene

24 U

mg/kg

24

95-57-8

2-Chiorophenol

24 U

mg/kg

24

534-52-1

2-Methyl-4,6-dinitrophenol

24 U

mg/kg

24

91-57-6

2-Methylnaphthalene

2.4 U

mg/kg

2.4

95-48-7

2-Methylphenol

24 U

mg/kg

24 24

88-74-4

2-Nitroaniline

24 U

mg/kg

88-75-5

2-Nitrophenol

24 U

mg/kg

24

91-94-1

3,3’-Dichlorobenzidine

24 ii

mg/kg

24 24 24

99-09-2

3-Nitroaniline

24 U

mg/kg

101-55-3

4-Bromophenyl phenyl ether

24 U

mg/kg

59-50-7

4-Chloro-3-methylphenol

24 U

mg/kg

24

106-47-8

4-Chloroaniline

24 U

mg/kg

24

7005-72-3

4-Chlorophenyl phenyl ether

24 U

mg/kg

24

100-01-6

4-Nitroaniline

24 U

mg/kg

24

100-02-7

4-Nitrophenol

24 U

mg/kg

24

83-32-9

Acenaphthene

2.4 U

mg/kg

2.4

208-96-8

Acenaphthylene

2.4 U

mg/kg

2.4

98-86-2

Acetophenone

24 U

mg/kg

24

120-12-7

Anthracene

2.4 U

mg/kg

2.4

19 12-24-9

Atrazine

24 U

mg/kg

24

Page 16of59

E104009 SVOA TCLPS FINAL

12:00 12:00 10/05/10 •0 10/05/10 12:00 10/05/10 12:00

10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 1200 10/05/10 12:00 1005/10 2:00 10/05/10 12:00 10/05/10 12:00 0/05/10 12:00 10/05/10 12:00 10/05/10 12:0)) 10/05/10 2:00 10/05/10 12:00 0/05/10 12:00 10/05/10 12:00 10/05/10 2:00 0/05/10 12:00 1005/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00

tiethod

EPA 82700

EPA 8270D EPA 8270D EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA827OD EPA 82700

EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82701) EPA

82700

EPA 82700 EPA 8270D EPA 82700 EPA

8270D

EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA

8270D

EPA 82700 EPA 82700 EPA

82700

EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercu’es Inc Reported by Janet Muse -

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO3-B

E104009-05

Matrix: Waste

Station ID: HERCO3 Date Collected: 9/28/10 13:15 C4S Number

Results Qualifiers

lna!yte

Linit9

MRL

Prepared 10/05/10 12:00 10/05/10 12:00 0/05/10 200 10/05/10 12:00 10/05/10 1200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 l2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 b/OS/b 1200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 b/OS/b 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 0/05/10 12:00 b/OS/b 12:00 10/05/10 12:00 10/05/10 12:00

100-52-7

Benzaldehyde

24 U

mg/kg

24

56-55-3

Benzo(a)anthracene

2.4 U

mg/kg

2.4

50-32-8

Benzo(a)pyrene

2.4 U

mg/kg

2.4

205-99-2

Benzo(b)fluoranthene

2.4 C

mg/lcg

2.4

191-24-2

Benzo(g,h,i)perylene

2.4 U

mg/kg

2.4

207-08-9

Benzo(k)fluoranthene

2.4 U

mg/kg

2.4

85-68-7

Benzyl butyl phthalate

24 U

mg/kg

24

111-91-1

Bis(2-chloroethoxy)methane

24 U

mg/lcg

24

111-44-4

bis(2-Chlorocthyl) Ether

24 U

mg/kg

24

39638-32-9

Bis(2-chloroisopropyl) ether

24 U

mg/kg

24

117-81-7

Bis(2-ethylhexyl) phthalate

24 U

mg/kg

24

105-60-2

Caprolactam

24 U

mg/kg

24

86-74-8

Carbazole

2.4 U

mg/kg

2.4

218-01-9

Chrysene

2.4 C

mg/kg

2.4

53-70-3

Dibenz(a,h)anthracene

2.4 U

mg/kg

2.4

132-64-9

Dibenzofuran

2.4 U

mg/kg

2.4 24

84-66-2

Diethyl phthalate

24 U

mg/kg

131-11-3

Dimethylphthalate

24 U

mg/kg

24

84-74-2

Di-n-butylphthalate

24 U

mg/kg

24

117-84-0

Di-n-octylphthalate

24 U

mg/kg

24

206-44-0

Fluoranthene

2.4 U

mg/kg

2.4

86-73-7

Fluorene

2.4 U

mg/kg

2.4

118-74-I

Hexachlorobenzene (HCB)

24 U

mg/kg

24

87-68-3

Hexachlorobutadiene

24 U

mg/kg

24

77-47-4

Hexachlorocyclopentadiene (HCCP)

24 U

mg/kg

24

67-72-1

Hexachloroethane

24 U

mg/kg

24

193-39-5

Indeno (1,2,3-cd) pyrene

2.4 U

mg/kg

2.4

78-59-1

Isophorone

24 L

mg/kg

24

91-20-3

Naphthalene

2.4 U

mg/kg

2.4

98-95-3

Nitrobenzene

24 U

mg/kg

24

62 1-64-7

n-Nitroso di-n-Propylamine

24 U

mg/kg

24

Page 17 of59

E104009 SVOA TCLPS FINAL

.inalrzed /‘Jethad 10/09/10 22:06 10/09/10 22:06 10/09/10 2206 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/I 0 22:06 10/09/lO 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 2206 10/09/10 22:06 I0/09/b0 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 b0/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/b 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06

EPA 8270D EPA 8270D EPA 8270D EPA 8270D EPA 8270D

EPA 8270D EPA 8270D

EPA 8270D EPA

8270D

EPA 8270D EPA 8270D

EPA 8270D EPA 8270D

EPA 8270D EPA 8270D

EPA 8270D EPA 8270D

EPA827OD EPA

8270D

EPA 8270D EPA 8270D EPA

8270D

EPA 8270D

EPA 8270D EPA 8270D EPA

82700

EPA 8270D EPA

8270D

EPA 8270D EPA

8270D

EPA 8270D

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 1 0-0629, Hercules Inc Reported by Janet Muse -

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: LIERCO3-B

E104009-05

Matrix: Waste

Station ID: IIERCO3 Date Collected: 9/28/10 13:15 C4S [Viunher

Resnils Qualifiers

4naly:e

Units

MRL

Prepared

lnalvzed

24

10/05/10 12:00 10/05/10 12:00

10/09/10 22:06 10,09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06

122-39-4

n-Nitrosodiphenylamine/Diphenylamine

24 U

mg/kg

87-86-5

Penlachlorophenol

24 U

mg/kg

24

85-01-8

Phenanthrene

2.4 U

mg/kg

2.4

108-95-2

Phenol

8.9 3, Q-2

mg/lcg

24 2.4 24

129-00-0

Pyrene

2.4 U

mg/kg

110-86-1

Pyridine

24 U

mg/kg

200 NJ

mg/kg

800 NJ

mg/kg

10/05110

12:00 10/05/10 2:00 10/05/10 2:00 10/05/10 12:00

‘ifethod

EPA 82700

EPA 8270D EPA 82700 EPA 8270D EPA 82700

EPA 8270D

Tentatively Identified Compounds: R4-6603 R4-8000535

Dimethylisopropyiphenanthrene (TIC) Diphenyl ether (TIC)

R4-8000899

Hexahydrotetramethylmethanonaphlhalene (TIC)

600 NJ

mg4cg

R4-6584

Methyl(methylethyl)benzene (TIC)

300 NJ

mg/kg

R4-8000897

Methyl(methylethyl)cyclohexane (TIC)

2000 NJ

mg/kg

R4-6514

Methyl(methylethyl)phenanthrene (TIC)

200 Nj

mg/kg

R4-8000901

Trimethylbicycloheptane (FEC)

300 NJ

mg/kg

R4-6501

Page 18of59

Unidentified Compounds

E104009 SVOA TCLPS FINAL

3000 3

mg/kg

10/05/10 12:00 0/05)10 12:00 10/05/10 12:00

10/05/10 12:00 10/05/10 2:00

10/05/10 12:00 10/05/10

10/09/10 22:06 10/09/10 22:06

10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10 22:06 10/09/10

12:00

22:06

10/05/10 12:00

10/09/10 22:06

FPA 62701) EPA

8270D

EPA 82700

EPA 8270D EPA 8270D

EPA 82700 EPA 8270D EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules mc- Reported-by Janet Muse

TCLP SemiVolatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO3-B Station ID: HERCO3

E104009-05

Matrix: Waste

Date Collected: 9/28/10 13:15 C4S Nu,a her

.4nalvte

1319-77-3

(3-andlor4-)Methylphenol:

Results Qualifiers

NA-5

Units

MRL

0.10

58-90-2

2,3,4,6-Tetrachlorophenol:

NA-5

0.10

95-95-4

2,4,5-Trichlorophenol:

NA-5

0.10

88-06-2

2,4,6-Trichlorophenol:

NA-S

0.10

121-14-2

2,4-Dinitrotoluene:

NA-S

0.10

95-48-7

2-Methylphenol:

NA-S

0.10

118-74-1

I-Iexachlorobenzene (FICB):

NA-S

0.10

87-68-3

Hexachiorobutadiene:

NA-S

0.10

67-72-1

Flexachloroethane:

NA-5

0.10

98-95-3

Nitrobenzene:

NA-5

0.10

87-86-5

Pentachlorophenol:

NA-S

0.10

110-86-1

Pyridine:

XA-5

0.10

Page 19 of59

E104009 SVOA TCLPS FINAL

Prepared 10/05/10

Analyzed Method

10105/10 944 10/05/b 944 10/05/10 944 10/05/10 9:44 10/05/10 944

10/09/10 4.04 10/09/10 14:04 10/09/10 1404 0/09/10 14:04 10/09/10 1404 10/09/10 14:04

10/05/10

0/09/10

944 10/05/10 944 10/05/10 944 10/05/10 9:44 10/05/10 944 10/05/10 9:44

4:04

EPA 82700

10/09/10 14:04 10/09/10 1404 10/09/10 1404 10/09/10 1404 10/09/10 14:04

EPA 8270D

EPA 8270D EPA 8270D EPA 82700 EPA

8270D

EPA 82700

EPA 8270D

EPA

82700

EPA 82700 EPA 82701)

EPA 8270D

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 1O-0629, Hercules Inc Reported by Janet Muse -

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: UERCO4-B Station ID: HERCO4

E104009-06

Matrix: Waste

Date Collected: 9/28/10 13:50 C4S Number

.4nalyre

1319-77-3

(3-and/or4-)Methylphenol

Results Qual,fiers

Units

MRL

53

mg/kg

25

1800

mg/kg

25 25

92-52-4

1,1-Biphenyl

58-90-2

2,3,46-Tetrachlorophenol

25

U

mg/kg

95-95-4

2,4,5-Trichlorophenol

25 U

mg/kg

25

88-06-2

2,4,6-Trichlorophenol

25 U

mg/kg

25

120-83-2

2,4-Dichlorophenol

25 U

mg/kg

25

105-67-9

2,4-Dirnethylphenol

6.0 3, Q-2

mg/kg

25

5 1-28-5

2,4-Dinitrophenol

25 U

mg/kg

25

121-14-2

2,4-Dinitrotoluene

25 U

mg/kg

25

606-20-2

2,6-Dinitrotoluene

25 U

mg/kg

25

9 1-58-7

2-Chloronaphthalene

25 U

mg/kg

25

95-57-8

2-Chlorophenol

25 U

mg/kg

25

534-52-1

2-Methyl-4,6-dinitrophenol

25 U

mg/kg

25

91-57-6

2-Methylnaphthalene

8.4

mg/kg

2.5

95-48-7

2-Methylphenol

43 J Q-2

mg/kg

25

88-74-4

2-Nitroaniline

25 U

mg/kg

25

88-75-5

2-Nitrophenol

25 U

mg/kg

25

91-94-1

3,3-Dichlorobenzidine

25 U

mg/kg

25

99-09-2

3-Nitroaniline

25 U

mg/kg

25

101-55-3

4-Bromophenyl phenyl ether

25 1.

mg/kg

25

59-50-7

4-Chloro-3-methylphenol

25 U

mg/kg

25

106-47-8

4-Chloroaniline

25 U

mg/kg

25

7005-72-3

4-Chlorophenyl phenyl ether

25 U

mg/kg

25

100-01-6

4-Nitroaniline

25 U

mg/kg

25

100-02-7

4-Nitrophenol

25 U

mg/kg

25

83-32-9

Acenaphthene

3.8

mg/kg

2.5

208-96-8

Acenaphthylene

2.5 U

mg/kg

2.5

98-86-2

Acetophenone

120-12-7

Anthracene

1912-24-9

Atrazine

Page 20 ofS9

E104009 SVOA TCLPS FINAL

25 U

mg/kg

25

2.5 U

mg/kg

2.5

25 U

mg/kg

25

Prepared

1 nutyzed

10/05/10 1201) I01 12:00 10/05/10 (2:00 0/05/10 2:00 10/05/10 2:00 10/05/10 12:00 10/05/10 (2:00 10/05/10 12:00 10/05/10 200 (0/05/10 12:00 10/05/10 12:00 (0/05/10 12:00 10/05/10 (2:00 10/05/10 200 10/05/10 1200 10/05)10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10)05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 (2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 2:0(1 (0/05/10 12:00 10/05/10 (2:00

10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10)10 0:26 10/10/10 0:26 10/10/10 0:26 10/10)10 026 10/10)10 0:26 10/10/10 0:26 10/10/10 026 (0/10/(0 0:26 0:26 10/10/10 0:26 1(1/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10)10/10 0:26 10/10/10 026 10/10/10 026

Olethod

EPA 82700 EPA

8270D

EPA 82700 EPA

8270D

EPA 8270D EPA

8270D

EPA 8270D EPA

82700

EPA 8270D EPA

82700

EPA 82701) EPA 82700 EPA

82700

EPA 82700 EPA 8270D EPA

8270D

EPA 82700 EPA

82700

EPA 8270D EPA

82700

EPA 82700 EPA

8270D

EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700

11/1/10 16:40

0

0 -

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700

LE]

DART. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Janet Muse

PRD

-

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO4-B Station ID: HERCO4

E104009-06

Matrix: Waste

Date Collected: 9/28/10 13:50 C4S Number

4nalyre

RsuIls QI4ahjiers

U,zigs

8fRL

100-52-7

Benzaldehyde

25 U

mg/kg

25

56-55-3

Benzo(a)anthracene

2.5 U

mg/kg

2.5

50-32-8

Benzo(a)pyrene

2.5 U

mg/kg

2.5

205-99-2

Benzolb)fluoranthene

2.5 U

mg/kg

2.5

19 1-24-2

Benzo(g.h.i)perylene

2.5 U

mg/kg

2.5

207-08-9

Benzo(k)fluoranthene

2.5 U

mg/kg

2.5

85-68-7

Benzyl butyl phthalate

25 U

mg/kg

25

111-91-1

Bis(2-chloroethoxy)methane

25 U

mg/kg

25

111-44-4

bis(2-Chloroethyl) Ether

25 U

mg/kg

25

39638-32-9

Bis(2-chLoroisopropyl) ether

25 U

mg/kg

25

117-81-7

Bis(2-ethylhexyl) phthalate

25 U

mg/kg

25

105-60-2

Caprolactam

25 U

mg/kg

25

86-74-8

Carbazole

2.5 U

mg/kg

2.5

218-01-9

Chrysene

2.5 U

mg/kg

2.5

53-70-3

Dibenz(a,h)anthracene

2.5 U

mg/kg

2.5

132-64-9

Dibenzofuran

3.0

mg/kg

2.5

84-66-2

Diethyl phthalate

25 U

mg/kg

25

131-11-3

Dimethyl phthalate

25 U

mg/kg

25

84-74-2

Di-n-butylphthalatc

25 U

mg/kg

25

117-84.0

Di-n-octylphthalate

25 U

mg/kg

25

206-44-0

Fluoranthene

2.5 U

mg/kg

2.5

86-73-7

Fluorene

2.7

mg/kg

2.5

118-74-1

Hexachlorobenzene (IICB)

25 U

mg/kg

25

87-68-3

Hexachlorobutadiene

25 U

mg/kg

77-47-4

Hexachlorocyclopentadiene (FICCP)

25 U

mg/kg

25 25

67-72-1

Hexachloroethane

25 U

mg/kg

25

193-39-5

Indeno (1,2.3-cd) pyrene

2.5 U

mg/kg

2.5

78-59-1

Isophorone

25 U

mg/kg

25

91-20-3

Naphthalene

7.8

mg/kg

2.5

98-95-3

Nitrobenzene

25 U

mg/kg

25

62 1-64-7

n-Nitroso di-n-Propylarnine

25 U

mg/kg

25

Page 21 of59

E104009 SVOA TCLPS FINAL

Prepared

inaly;ed Method

b/OS/b

10/10110

12:00 I0’05/lO 2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 l2:00 10/05/10 12:00 l0/05,’I0 12:00 10/05/10 12:00 10:05:10 12:00 10/05/10 12:00 10/05/10

0:26 lO/lO/lO 026 10/10/W 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/b/b 0:26 10/10/10 0:26 10/10)10 0:26 10/10/10 0:26 10/10/10 0:26 b/b/b 0:26 10)10/10 0:26 10/10/10 0:26 10/10/10 0:26 b/b/ID 0:26 b/b/b 0:26 10/10/10 0:26 b/b/b 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 1010/10 0:26 10/10/10 0:26

12:00

10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 b/OS/b 12:00 10/05/b 12:00 10/05/10 12:00 10/05/10 12:00 b/OS/b 12:00 10/05/10 I2:00 10/05/10 l2:00 10/05/10 12:00 10/05/10 12:00 10/05/10

12:00 10/05/tO

b0/l0:l0

12:00 10/05/10 2:00

0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 b/b/b 0:26 0)10/10 0:26

b/Os/b

b/b/b

12:00

0:26

I2:00

10/05/10 12:00 10/05)10 12:00 10)05/10 12:00 0/05/10

EPA 8270D EPA 8270D EPA 82700 EPA

82700

EPA 82700 EPA

8270D

EPA 82700 EPA

8270D

EPA 82700 EPA 82700 EPA 8270D EPA

8270D

EPA 82700 EPA

82700

EPA

82700

EPA

82700

EPA 8270D

EPA 8270D EPA 82700 EPA

82700

EPA 82700 EPA 8270D EPA 82700

EPA 82700 EPA 82700 El’A 82700 EPA 8270D

EPA 82700 EPA 8270D EPA 8270D EPA 82700

11/1/10 16:40

0

C

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700

4kz

k

D.A.R.T. Id. 10-0629

Project: 10-0629, Hercules Inc

-

Reported by Janet Muse

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO4-B

E104009-06

Matrix: Waste

Station ID: 1{ERCO4 Date Collected: 9/28/10 13:50 (•1S Number

122-39-4

Results Qualifiers

(nalyre

n-Nitrosodiphenylamine/Diphenylamine

Units

MRL

Prepared

.4na(v:ed

10/05/10 12:00 10/05/10 1200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00

10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26

25 U

mg/kg

25

87-86-5

Pentachlorophenol

25 U

mg/kg

25

85-01-8

Phenanthrene

3.0 J, QL-2

mg/kg

2.5

108-95-2

Phenol

71

mg/kg

25 2.5 25

129-00-0

Pyrene

3.6

mg/kg

110-86-1

Pyridine

25 U

mg/kg

lie/hod EPA 8270D

EPA 82700 EPA 82700 EPA 8270D EPA 82700

EPA 82700

Tentatively Identified Compounds: R4-6552

(Menthenol)terpineol (TIC)

300 >,‘J

mg/kg

R4-6531

Camphene (TIC)

300 NJ

mg/kg

R4-8000520

Camphor (TIC)

200 NJ

mg/kg mg/kg

R4-8000903

Chlorotrimethylbicycloheptane (TIC)

100 NJ

R4-6603

Dimethylisopropylphenanthrene (TIC)

200 NJ

mg/kg

1000 NJ

mg/kg

R4-8000899 R4-6500

Hexahydrotetramethylmethallonaphthalene (TIC) Petroleum Product:

N mg/kg

10/05/10

0/10/10

12:00 10/05/10

0:26 10/10/10

12:00 100510

EPA

10)05/10 12:00 10/05/10 12:00 10/05/10 12:00

0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26 10/10/10 0:26

10/05/10 12:00 10/05/10

10/10/10 0:26 10/10)10

EPA 82700

12:00 10/05/10 2:00

0:26 10,10/10

12:00

R4-6520

Pinene (TIC)

700 NJ

R4-8000466

Propylphenol (TIC)

200 NJ

mg/kg

300 NJ

mg/kg

I0/05’10

mg/kg

10/05/10 12:00

R4-800090I

Trimethylbicycloheptane (TIC)

R4-6501

Unidentified Compounds

Page 22 of59

E104009 SVOA TCLPS FINAL

2000 J

2:00

0:26 10/10110 0:26 10/10/10 0:26

EPA 82700

82700

EPA 8270D EPA 82700 EPA 82700 EPA 8270D

EPA 82700 EPA 82700

EPA 82700 EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTiON AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.AR.T. Id: 10-0629

Project: 10-0629, Hercules nc- Reported by Janet Muse

TCLP SemiVolatfies Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO4-B Station ID: HERCO4

E104009-06

Matrix: Waste

Date Collected: 9/28/10 13:50 C4S

Number

.4natyte

1319-77-3

(3-andlor4-)Methylphenol:

NA-5

58-90-2

2,3,4,6-Tetrachlorophenol:

NA-5

0.10

95-95-4

2,4,5-Trichlorophenol:

NA5

0.10

8 8-06-2

2,4,6-Trichlorophenol:

NA-5

0.10

121-14-2

2,4-Dinitrotoluene:

NA-5

0.10

95-48-7

2-Methylphenol:

NA-5

0.10

Ilexachlorobenzene (HCB):

NA-5

0.10

Il 8-74-1

87-68-3

.

--

Results Qualifiers

Hexachlorobutadiene:

67-72-t•ëxachloroethane:

Units

MRL

0.10

9:44

NA5

0.10

NA-5

0.10

bO,05/b0 9:4-I

Nitrobenzene:

NA-5

0.10

87-86-5

F’entachlorophcnol:

NA-5

0*10

110-86-1

Pyridine:

NA-5

0.10

E104009 SVOA TCLPS FINAL

10/05/10 9:44 10/05/10 9:44 10/05/10 10/05/10 9:44 0/05/10 944 10/05/10 9:44 b/OS/b 9:44 10/05/10 9:44

98-95-3

Page 23 of59

Prepared

10/05/10 9:44 005/10 944 30/05/10 9:44

Anaivzed Method 10/09/10 14:04 10/09/10 14:04 10/09/10 14:04 10/09/10 14:04 10/09/tO 404 10/09/10 14:04 10/09/10 14:04 10/09/10 14:04 100410

14:04 10/09/10 14:04 10/09/b 14:04 10/09/10 14:04

EPA 82700

EPA 8270D EPA 82700 EPA 8270D EPA 82700

EPA 82700 EP\ 82700

EPA 82700 EPA

82700

EPA 82700 EPA 82700 EPA

82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROThCTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

Semi Volatile Organics Project: 10-0629, Hercu’es Inc Lab ID:

Sample ID: HERCO5-A

E104009-07

Matrix: Waste

Station ID: HERCO5 Date Collected: 9/28/10 14:05 CIS Number

.4nalyte

1319-77-3

(3-andlor4-)Methylphenol

92-52-4

1,1-Biphenyl

Results Qualijiers

Units

MRL

Prepared

1200 10/05/10 12:00

100

mg/kg

24

1200

mg/kg

24

58-90-2

2,3,4,6-Tetrachlorophenol

24 U

mg’lg

95-95-4

2,4,5-Trichlorophenol

24 U

mg/kg

24

88-06-2

2,4,6-Trichlorophenol

24 L

mg/kg

24

120-83-2

2,4-Dichiorophenol

24 U

mg/kg

24

105-67-9

2,4-Dimethylphenol

24 U

mg/kg

24 24

24

51-28-5

2,4-Dinitrophenol

24 U

mg/kg

121-14-2

2,4-Dinitrotoluene

24 Ii

mg/kg

24 24

606-20-2

2,6-Dinitrotoluene

24 U

mg/kg

91-58-7

2-Chloronaphthalenc

24 U

mg/kg

24

95-57-8

2-h1orophenol

24 U

mg/kg

24

534-52-1

2-Methyl-4.6-dinitrophenol

24 U

mg/kg

24

91-57-6

2-Methylnapht.halene

14

mg/kg

2.4

95-48-7

2-Methylphenol

4.9 J, Q-2

mg/kg

24

88-74-4

2-Nitroaniline

24 U

mg/lcg

24 24

88-75-5

2-Nitrophenol

24 U

mg/kg

91-94-1

3,3-Dichlorobenzidine

24 U

mg/kg

24 24

99-09-2

3-Nitroaniline

24 U

mg/kg

101-55-3

4-Bromophenyl phenyl ether

24 U

mg/kg

24

59-50-7

4-Chloro-3-methylphenol

24 U

mg/kg

24

106-47-8

4-Chloroaniline

24 U

mg/kg

24

7005-72-3

4-Chtorophenyl phenyl ether

24 U

mg/kg

24 24

100-01-6

4-Nitroaniline

24 U

mg/kg

100-02-7

4-Nitrophenol

24 U

mg/kg

24 2.4 2.4

83-32-9

Acenaphthene

2.8

mg/lcg

208-96-8

Acenaphthylene

2.4 U

mg/kg

98-86-2

Acetophenone

24 U

mg/kg

24

120-12-7

Anthracene

2.4 U

mg/kg

2.4

1912-24-9

Atrazine

24 U

mg/kg

24

Page 24 of59

E104009 SVOA TCLPS FINAL

10105fl0

12:00 10/05/10 12:00 10/05/10 12:00 10/05)10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10.05,10 200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 2:00 10/05/10 12:00 0/05/10 12:00 10/05)10 12:00 10:05/10 12:00 10/05/Ill 12.00 10/05)10 12:00 10/05/10 12:00 10/05/Jo 12:00 10/05)10 12:00 10/05)10 12:00 10/05/10 1200

.lnalw;ed fethod

1:01 10/10/10 1:01 10.10.10 1:01 10/10/10 1:01 10:1010 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10110110

1:01 10/10/10 1:01 I0I0I0 1:01 10/10/10 1:01 10,10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:1)1 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1,01 10/10/10 1:01 10/10/10 1:01

EPA 8270D

EPA 82700 EPA 8270D EPA 82700 EPA 8270D EPA 8270D EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 8270D EPA

82700

EPA 8270D EPA 82700 EPA /12701) EPA 82700 EPA 8270D EPA 8270D EPA 8270D EPA

8270D

EPA 82700 EPA 8270D EPA 82700 EPA 8270D EPA 8270D EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO5-A Station ID: HERCO5

E104009-07

Matrix: Waste

Date Collected: 9/28/10 14:05 (‘AS Number

.4nalyte

100-52-7

Benzaldehyde

56-55-3

205-99-2

Benzob)fluoranthene

Results Qualifiers

Units

tIIRL

Prepared 10/05/10 2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 1200

24 U

mg/kg

24

Benzo(a)anthracene

2.4 U

mg/kg

2.4

Benzo(a)pyrene

2.4 U

mg/kg

2.4

2.4 U

mg/kg

2.4

L91-24

Benzo(g,h,i)perylene

2.4 U

mg/kg

2.4

207-08-9

Benzo(k)fluoranthene

2.4 U

mg/kg

2.4

85-68-7

Benzyl butyl phthalate

24 U

mg/kg

24

111-91-1

Bis(2-chloroethoxy)methane

24 U

mg/lcg

24

111-44-4

bis(2-Chloroethyl) Ether

24 1/

mg/kg

24

39638-32-9

Bis(2-chloroisopropyl) ether

24 U

mg/kg

24

117-81-7

Bis(2-ethyllsexy) phlhalate

24 U

mg/kg

24

105-60-2

Caprolactam

24 U

mg/kg

24

86-74-8

Carbazole

2.4 U

mg/kg

2.4

218-01-9

Chrysene

2.4 U

mg/kg

2.4

53.70.3

Dibenz(a.h)anthracene

2.4 U

mg/kg

2.4

132-64-9

Dibenzofuran

2.4 U

mgllcg

2.4

84-66-2

Diethyl phthalate

24 U

mg/kg

24

131-11-3

Dimethylphthalate

24 U

mg/kg

24

84-74-2

Di-n-butylphthalate

24 U

mg/kg

24

117-84-0

Di-n-octylphthalate

24 U

mg/kg

24

206-44-0

Fluoranthene

11

mg/kg

2.4

86-73-7

Fluorene

2.4 U

mg/kg

2.4

118-74-1

Hexachlorobenzene (HCB)

24 U

mg/kg

24

87-68-3

Hexachlorobutadiene

24 U

mg/kg

24

77-47-4

Hexachlorocyclopentadiene (HCCP)

24 U

mg/kg

24

67-72-1

Hexachloroethane

24 U

mg/kg

24

193-39-5

Indeno (1,2,3-cd) pyrene

2.4 U

mg/kg

2.4

78-59-1

Isophorone

24 U

mg/kg

24

91-20-3

Naphthalene

8.7

mg/kg

2.4

98-95-3

Nitrobenzene

24 U

mg/kg

24

621-64-7

n-Nitroso di-n-Propylamine

24 U

mg/kg

24

Page 25 of 59

E104009 SVOA TCLPS FINAL

Analyzed Method 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1.0! 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:0! 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 101

EPA 8270D EPA 8270D EI’A

8270D

EPA

8270D

EPA 8270D

EPA 82700 EPA 8270D EPA

8270D

EPA 8270D EPA 8270D EPA

82700

EPA 82700 EPA 82700 EPA

8270D

EPA 82700 EPA

8270D

EPA

8270D

EPA 82700 EPA

8270D

EPA 82700 EPA 8270D EPA 8270D EPA 8270D

EPA

8270D

EPA 8270D EPA

8270D

EPA 8270D EPA 82700 EPA 8270D EPA 8270D EPA 8270D

11/1/10 16:40

0

0

UNiTED STATES ENViRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Ed: 10-0629

Project: 10-0629, Hercules Inc

-

Reported by Janet Muse

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCOS-A

E104009-07

Matrix: Waste

Station ID: HERCO5 Date Collected: 9/28/10 14:05 C4S Nwnher

Results Qualifiers

.4nalvie

Units

MRL

Prepared

.lnaly;ed

24

10/05/10 12:00 10105110 12:00 0/05/10 12:00 10/05/10 12:00 1005/10 2:00 10/05/10 12:00

10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01 I0I10I0 1:01 10/10/10 1:01

10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00

122-39-4

n-Nitrosodiphenylamine/Diphenylamine

24 U

mg/kg

87-86-5

Pentachlorophenol

24 U

mg/kg

24

2.4

85-01-8

Phenanthrene

2.4 U

mg/kg

108-95-2

Phenol

3]

mg/kg

24

5.7

mg/kg

2.4

24 U

mg/kg

24

300 NJ

mg/kg mg/kg

129-00-0

Pyrene

110-86-1

Pyridine

11cr/md EPA 82700 EPA

82700

EPA 82700 EPA 8270D EPA 82700

EPA 8270D

Tentatively Identified Compounds:

R4-8000904

Cycloisolongifolene (TIC)

200 NJ

mg/kg

R4-6506

Decahydrotrimethylmethylenemethanoazu lene (TIC)

400 NJ

mg/kg

10/05/10

12:00

10/10/10 1:01 10/10/10 1:0] 10/10/10 1:01 10/10/10 1:01 10/10/10 1:01

R4-6603

Dimethylisopropylphenanthrene (TIC)

100 NJ

mg/kg

R4-6539

Hexahydrodimethyl(methylethyl)naphthal ene (TIC)

400 NJ

mg/kg

10/05/10 12:00 10/05/10

10/10/10 1:01 10/10/10

12:00

1:01

EPA 8270D

R4-6500

Petroleum

10/10/10 1:01

EPA 82700

R4-6519

Phenanthrenecarboxylic acid (TIC)

200 NJ

mg/kg

10/10/10

EPA 8270D

R4-6520

Pinene (TIC)

900 NJ

mg/kg

R4-800090I

Trimethylbicycloheptane (TIC)

400 NJ

mg/kg

R4-6501

Unidentified Compounds

700 J

mg/kg

10/05/10 12:00 10/05/10 12:00 10/05/10 1200 0/05/10 12:00 10/05/10 12:00

R4-6552

(Menthcnol)terpineol (TIC)

R4-6531

Camphene (TIC)

200 \J

R4-8000903

Chlorotrimethylbicycloheptane (TIC)

100 NJ

mg/kg

Page 26 of59

Product:

E104009 SVOA TCLPS FINAL

1:0] 10/10/10 1.01 10/10/10 1:01 10/10/10 1:01

EPA 8270D EPA 8270D EPA 82700

EPA 8270D EPA 82701)

EPA 8270D

EPA 8270D EPA 8270D EPA 8270D

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

TCLP SemiVolatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO5-A Station ID: HERC05

E104009-07

Matrix: Waste

Date Collected: 9/28/10 14:05 C4S Number

.4nalyte

Results Qualifiers

Units

MRL

(3-andior4-)Methylphenol:

2,3,4,6-Tetrachiorophenol:

XA-5

0.10

95-95-4

2.4,5-Trichlorophenol:

NA-5

0.10

88-06-2

2,4,6-Trichlorophenot:

NA-S

0.10

121-14-2

2,4-Dinitrotoluene:

NA-S

0.10

,

95-48-7

2-Methyiphenol:

NA-S

0.10

118-74-1

Flexachlorobenzenc (HCB):

NA-5

0.10

Hexachlorobutadiene:

NA-5

0.10

NA-S

0.10

87-68-3

-

-

—-

--

67-72-I

xachloroethane:

98-95-3

Nitrobenzene:

NA-S

0.10

87-86-5

Pentachlorophenol:

NA-5

0.10

110-86-1

Pyridine:

NA-S

0.10

Page 27 of59

E104009 SVOA TCLPS FINAL

.-lnalyzed Method

o. 10

13 19-77-3

58-90-2

NA-5

Prepared

EPA 8270D 1OE1O

EPA 82700

l%olO

‘9’

‘°°

ltJ/O

1%OO

I/O9/O

1%O1O 0,05/JO

EPA 8270D

EPA 82700 EPA827OD EPA 8270D

I009I0

EPA 8270D EPA 8270D

10/05/10 10/05/10

1O/9OO

EPA 82700 10/09/10

EPA 8270D

/O 0 It/09

EPA 8270D

I/:9/O

EPAS2700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 90 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO6-B

E104009-08

Matrix: Waste

Station ID: HERCO6 Date Collected: 9/28/10 14:55 C4S Number

.4nalyie

1319-77-3

(3-and/or 4-)Methylphenol

92-52-4

1,1-Biphenyl

Results Qualijiers

26 U 120

MRL

Prepared

mg/kg

26

mg/kg

2.6 26

10/05/10 12:00 10/05510 12:00 10/05/10 12:00 10/05/10 12:00 10.05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 2:00 10,05/10 12:00 10/05/10 12:00 10/05/10 2:00 10/05/10 12:00 10/00 2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00

Units

58-90-2

2,3,4,6-Tetrachlorophenol

26 U

mg/kg

95-95-4

2,4,5-Trichlorophenol

26 U

mg/kg

26

88-06-2

2.4,6-Trichlorophenol

26 U

mg/kg

26

120-83-2

2,4-Dichlorophenol

26 U

mg/kg

26

105-67-9

2,4-Dimethylphenol

26 U

mg/kg

26

51-28-5

2,4-Dinitrophenol

26 U

mg/kg

26

121-14-2

2,4-Dinitrotoluene

26 U

mg/kg

26

26

606-20-2

2,6-Dinitrotoluene

26 C

mg/kg

91-58-7

2-Chloronaphthalene

26 U

mg/kg

26

95-57-8

2-Chlorophenol

26 U

mg/kg

26

534-52-I

2-Methyl-4,6-dinitrophenol

26 U

mg/kg

26

91-57-6

2-Methylnaphthalene

2.6 C

mg/kg

2.6

95-48-7

2-Methylphenol

26 U

mg/kg

26

88-74-4

2-Nitroaniline

26 C

mg/kg

26

26 U

mg/kg

26

88-75-5 9 1-94-1

2-Nilrophenol 3,3’-Dichlorobenzidine

26 C

mg/kg

26 26

26

99-09-2

3-Nitroaniline

26 U

mg/kg

101-55-3

4-Bromophenyl phenyl ether

26 C

mg/kg

59-50-7

4-Chloro-3-methylphenol

26 U

mg/kg

26

106-47-8

4-Chloroaniline

26 U

mg/kg

26

7005-72-3

4-Chlorophenyl phenyl ether

26 U

mg/kg

26 26

100-01-6

4-Niti-oaniline

26 U

mg/kg

100-02-7

4-Nitrophenol

26 U

mg/kg

26

2.6 2.6

83-32-9

Acenaphthene

2.6 C

mg/kg

208-96-8

Acenaphthylene

2.6 U

mg/kg

98-86-2

Acetophenone

26 U

mg/kg

26

120-12-7

Anthracene

2.6 U

mg/kg

2.6

1912-24-9

Atrazine

26 C

mg/kg

26

Page 28 of 59

E104009 SVOA TCLPS FINAL

10/os/jo

2:00 10/05/10 2:00 10/05510 12:00 Io:o5,’Io 12:00 10/05/10 12:00 1005.10 12.000 10,05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 0/05/10 12:00 10/05/10 12:00 10/85/10 12:00

.lnalvzed ,Stcthod 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10:09,10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10,09/10 20:56 10/09/10 20:56 10/09:10 20:56 10/09/10 20:56 10/09/10 20:56 0/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20.56 10/09/10 20:56 10/09/10 20:56 1009:10 20:56 10/09/10 20:56 10:09/10 20:56 10/09/10 20:56 10/09/10 20:56 0/09/10 20:56 10/09/10 20:56 10/09/10 20.56

EPA 82700

EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA82700 EPA 82700 EPA 82700 EPA

8270D

EPA 8270D EPA 82700

EPA 82700 EPA 8270[) EPA 82700 EPA 9270D EPA 8270D

EPA 8270D EPA

8270D

EPA82700

EPA 82700 EPA 82700 EPA 82700 EPA 82700

EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENViRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 3 0605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc

-

Reported by Janet Muse

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO6-B

E104009-08

Matrix: Waste

Station ID: UERCO6 Date Collected: 9/28/10 14:55 C4S Number 100-52-7 56-55-3

Results Qualifiers

4nalyte

Benzaldehyde

26 U

Benzo(a)anthracene

2.6 U

Units mg/kg mg/kg

MRL ..,

2

50-32-8

Benzo(a )pyrene

2.6 U

mg/kg

2 •6

Benzo(b)fluoranthene

2.6 C’

mg/kg

2

191-24-2

Benzo(g,h.i)perylene

2.6 U

mg/kg

2•



207-08-9

Benzo(k)fluoranthene

2.6 U

85-68-7

Benzyl butyl phthalate

26 U

mg/kg

26

111—91—1

Bis(2-chloroethoxy)methane

26 U

mg/kg

-,

111-44-4

bis(2-Chloroethyl) Ether

26 U

mg/kg

.,

39638-32-9

Bis(2-chloroisopropyl) ether

26 U

mg/kg

-,

117-81-7

Bis(2-ethylhexyl) phthalate

26 U

mg/kg

26

105-60-2

Caprolactam

26 U

mg/kg

2’

86-74-8

Carbazole

2.6 U

mg/kg

2 •6 ‘

218-01-9

Chrysene

2.6 U

mg/kg

2

53-70-3

Dibenz(a.h)anlhracene

2.6 U

mg/kg

2 6

2.6 U

mg/kg

.,

84-66-2

Diethyl phthalate

26 U

mg/kg

26

13 1-11-3

Dimethyl phthalate

26 U

mg/kg

2’

84-74-2

Di-n-butylphthalate

26 U

mg/kg

26

117-84-0

Di-n-octyiphthalate

26 U

mg/kg

‘,

206-44-0

Fluoranthene

2.6 U

mg/kg

.,

.,

86-73-7

Fluorene

2.6 U

118-74-I

Hexachlorobenzene (HCB)

26 U

mg/kg

-,



87-68-3

Hexachlorobutadiene

26 U

mg/kg

i

77-47-4

Hexachlorocyclopentadiene (HCCP)

26 U

mg/kg

‘,

57-72-1

Hexachioroethane

26 U

mg/kg

‘,

193-39-5

Indeno (1,2,3-cd) pyrene

U

mg/kg

26

mg/kg

•,

78-59-1

26 U

Isophorone

91-20-3

Naphthalene

2.6 U

mg/kg

98-95-3

Nitrobenzene

26 U

mg/kg

521-64-7

n-Nitroso di-n-Propvlamine

26

U

mg/kg

Page 29 of 59

F 104009 SVOA TCLPS FINAL

10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 2:00

10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00

mg/kg

2.6

10/05/10 12:00 10105/10 12:00 10/05/10 12:00 005/IC 2:00



mg/kg

Dibenzofuran

10/05/10 12:00

205-99-2

132-64-9

Prepared

-,



2’

10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00

10105/10 12:00 0/05/10 12:00 10/05/10 12:00 0 05/10 2:00

.inq1ed lie/hod 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 1009 10 20:56 10/09/ID 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 1009/l0 20:56 10/09/10 20:56 1009/10 20:56 10/09,10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/IC 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 10/09/10 20:56 1009 10 20:56

EPA 82700 EPA 82700 EPA

82700

EPA 8270D EPA 82700 EPA

82700

EPA 8270D EPA 82700 EPA 82700 EPA 8270D EPA %270D

EPA 82700 EPA 8270D EPA 8270D EPA 62700 EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 8270D

EPA 82700 EPA 82700 EPA 82700 EPA 82700

11/1/10 16:40

C

C

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

1

Project: 10-0629, Hercules Inc Reported by Janet Muse -

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO6-B

E104009-08

Matrix: Waste

Station ID: HERCO6 Date Collected: 9/28/10 14:55 (‘1S Vuwher

Results Qualifiers

.4nalyre

122-39-4

n-Nilrosodiphenylamine/Diphenylamine

Units

26 U

mg/kg

MRL

Prepared

.lnaty;ed

26

10/05/10 12:00 10/05/10 12:00 10/00 12:00 b/OS/b 12:00 10/05/10 12:00 10/05/10 12:00

10/09/10 20:56 10/09/1(1 20:56 10/09/10 20:56 10109/10 20:56 10/09/10 20:56 10/09/10 20:56

10/09/10 20:56 10’09/J0 20:56 10:09/10 20:56 10/09/10 2056 1009/10 2056

87-86-5

Pentachlorophenol

26 U

mg/kg

26

85-01-8

Phenanlhrene

2.6 U

mg/kg

2.6

108-95-2

Phenol

26 U

mg/kg

26

129-00-0

Pyrene

2.6 U

mg/kg

2.6

110-86-1

Pyridine

26 U

mg/kg

26

200 NJ

mg/kg

200 NJ

mg/kg

2000 NJ

mg/kg

10/05/10 12:00 10/05/10 12:00 10/05/10 12:00

mg/kg

10/05/b 1200 (0 0510 (200

lfethod EPA 82700

EPA 82700 EPA 82700

EPA 82700 EPA 8270D EPA 8270D

Tentatively Identified Compounds: R4-6603

Dimelhyllsopropylphenanthrene (TIC)

R4-8000535

Diphenyl ether (TIC)

R4-8000899

flexahydrotetramethylmethanonaphthalene (TIC)

R46500

Petroleum Product:

R4-6501

Unidentified Compounds

Page 30 of 59

E104009 SVOA TCLPS FINAL

N 6000 J

EPA 82700

EPA 82700 EPA 82700

EPA 8270D EPA 8270D

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

TCLP SemiVolatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO6-B Station ID: HERCO6

E104009-08

Matrix: Waste

Date Collected: 9/28/10 14:55 C4S Nu,nl’er

Ana!yrc

Results Qualifiers

Units

1IRL

Prepared 10/05110 9:44 10/05/10

1319-77-3

(3-andlor4-)Methylpheno[:

NA-5

010

5 8-90-2

2,3,4,6-Tetrachiorophenol:

NA-5

0.10

95-95-4

2,4,5-Trichorophenol:

NA-5

0.10

88-06-2

2,4,6-Trichlorophenol:

NAS

0.10

121-14-2

2,4-Dinitrotoluene:

NA-S

0.10

95-48-7

2-Methyiphenol:

NA5

0.10

118-74-I

Hexachlorobenzene (1-ICO):

NA-5

0.10

Hexachlorobutadiene:

NA5

87683

---

67-72-I

Hexachioroethane:

98-95-3

Nitrobenzene:

0.10

0.10 NA-S

0.10

87-86-5

Pentachlorophenol:

NA-5

0.10

110-86-1

Pyridine:

NA-5

0.10

Page 31 of59

E104009 SVOA TCLPS FINAL

9:44

10/05110 944 10/05/10 9:44 10/05/10 9:44 10/05/10 9:44 10/OSlO 9-44 10/05/10 944 10/05/10 10/05/10 9:44 lObS/b 9-44 10/05/10 9:44

.4naty:ed ,01rhod l0/09/lO l4:04 10/09/10 14:04 1009:10 14:04 10/09/10 14:04 10/09/10 404 10/09/10 14:04 10/09/10 14:04 10/09/10 14:04 10:09/10 4-04 10/09/10 14:04 10/09/10 404 10/09/10 14:04

EPA 82700 EPA 82700

EPA 82700

EPA 8270D EPA 82700 EPA 8270D

EPA 827(11) EPA

82700

EPA 82700 EPA 82700 EPA 82700 EPA 8270D

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

Semi Volatile Organics Project: 16-0629, Hercules Inc Lab ID:

Sample ID: HERCO7-B

E104009-09

Matrix: Waste

Station ID: HERCO7 Date Collected: 9/28/10 15:25 C4S

Results Qualifiers

Niunber

.4nalyte

1319-77-3

(3-andlor4-)Methylphenol

92-52-4 58-90-2

1,1-Biphenyl

mg/kg

78

mg/kg

330

2,3,4,6-Tetrachlorophenol

Units

24 U

mg/kg

Prepared

24

10/05/10 1200

2131

24

10/05/10 1200 10/05/10

10/09/10

2131

EPA 82700

oO9l0 21:31 10/09/10 21:31 10/09/10 21:3! 10/09/10 21:31 10/09/10 273! 10/09/10 21:31 10/09/10 213! 10/09/10 21:3! 10/09/10 213! 10/09/10 21:31 10/09/10 21:31 10/09/10 2137 10.09/10 2131 10/09/10 27:31 10/09/10 21:31 0/09/10 21:3! 10/09/10 2131 10/09/10 27:31 0/09/70 21:31 10/09/10 21:31 10/09/10 2131 10/09/10 21:31 10/09/10 21:31 0/09/lU 2:3! 10,09/10 27:31 10i09/10 27:3! 10/09/10 21:31 10/09/10 21:37

EPA 82700

24

2,4,5-Trichlorophenol

24 ij

88-06-2

2,4,6:rrichlorophenol

24 U

mg/kg

24

120-83-2

24-Dichlorophenol

24 U

mg/kg

24

105-67-9

2,4-Dimethylphenol

24

U

mg/kg

24 24

95-95-4

mg/kg

MRL

24

51-28-5

2,4-Dinitrophenol

24 U

mg/kg

12 1-14-2

2,4-Dinitrotoluene

24 U

mg/kg

24

606-20-2

2,6-Dinitrotoluene

24

U

mg/kg

24

91-58-7

2-Chloronaphthalene

24 U

mg/kg

24

95-57-8

2-Chlorophenol

24 U

mg/kg

24

534-52-1

2-Methyl-4.6-dinitrophenol

24 U

mg/kg

24

91-57-6

2-Methylnaphthalene

2.4 U

mg/kg

2.4

95-48-7

2-Methylphenol

17 J. Q-2

mglg

24

88-74-4

2-Nitroaniline

24 U

mg/kg

24

24 U

mg/kg

24

88-75-5

2-Nitrophenol

92-94-1

3,3’-I)ichlorobenzidine

24 U’

mg/kg

24

99-09-2

3-Nitroaniline

24 U

mg/kg

24

101-55-3

4-Bromophenyl phenyl ether

24 1.,

mg/kg

24

59-50-7

4-Chloro-3-methylphenol

24 U

mg/kg

24

106-47-8

4-Chloroaniline

24 U

mg/kg

24

7005-72-3

4-Chlorophenyl phenyl ether

24 U

mg/kg

24 24 24

100-01-6

4-Nitroaniline

24 LI

mg/kg

100-02-7

4-Nitrophenol

24 U

mg.”kg

83-32-9

Acenaphthene

2.4 U

mg/kg

2.4

208-96-8

Acenaphthylene

2.4 U

mg/kg

2.4

98-86-2

Acetophenone

120-12-7

Anthracene

1912-24-9

Alrazine

Page 32 of59

E104009 SVOA TCLPS FINAL

24 U

mg/kg

24

2.4 U

mg/kg

2.4

24 U

nlg/kg

24

12:00

10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 1005/10 200 10/05/10 12:00 10/05/10 2.00 10/05/10 12:00 10/05/10 1200

10/05/10 12:00 10/05/10 12:00 10/05/70 200 10/05/10 12:00 10/05/10 12:00 I005/l0 1200

10/05/10 1200 0/05/10 1200 10/05/10 1200 10/05/10 72:00

10/05/10 12:00 10/05/10 1200 10/05/10 209 10/05/10 12:00 0/05/70

7200 lOiOs/IO 12:00

10/05/70 1209 10/05/10 7200

10/05/10 12.013

lnalyzed ?fethod

10/09/10

EPA 82700

EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA

8270D

EPA 82700 EPA

82700

EPA 8270D

EPA 82700 EPA 82700 EPA 82700 EPA 82700

EPA 82700 EPA 82700 EPA 82700

EPA 82700 EPA 82700 EPA 82700 EPA

8270D

EPA

82700

EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA

82700

EPA 82700 EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART, Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Janet Muse -

Semi Volatile Organics Project: 10-0629, hercules Inc Lab TD:

Sample ID: HERCO7-B

E104009-09

Matrix: Waste

Station ID: HERCO7 Date Collected: 9/28/10 15:25 C4S Number

.4nulyte

100-52-7

Benzaldehyde

24 U

mg/kg

24

56-55-3

Benzo(a)anthracene

2.4 U

mg/kg

2.4

50-32-8

Benzo(a)pyrene

2.4 U

mg;kg

2.4

205-99-2

Benzo(b)fluoranthene

2.4 U

mg/kg

2.4

2.4

Results Quahjiers

Units

MRL

191-24-2

Benzo(g,h,i)perylene

2.4 U

mg/kg

207-08-9

Benzo(k)fluoranthene

2.4 U

mg/kg

2.4 24

85-68-7

Benzyl butyl phthalale

24 U

mg/kg

111-91-1

Bis(2-chloroethoxy)methane

24 U

mg/kg

24

111-44-4

bis(2-Chloroethyl) Ether

24 U

mg/kg

24

39638-32-9

Bis(2-chloroisopropyl) ether

24 U

mg/kg

24

117-81-7

Bis(2-cthylhexyl) phthalate

24 U

mg/kg

24 24 2.4

105-60-2

Caprolactam

24 U

mg/lcg

86-74-8

Carbazole

2.4 U

mg/kg

2.4

218-01-9

Chrysene

2.4 L

mg/kg

53-70-3

Dibenz(a.h)anthracene

2.4 U

mg/kg

2.4

132-64-9

Dibenzofuran

2.4 U

mg/kg

2.4

84-66-2

Diethyl phthalate

24 U

mg/kg

24

131-11-3

Dimethylphthalate

24 U

mg/kg

24

24

84-74-2

Di-n-butylphthalate

24 U

mg/kg

117-84-0

Di-n-octylphthalate

24 L

mg/kg

24 2.4

206-44-0

Fluoranthene

2.4 U

mg/kg

86-73-7

Fluorene

2.4 U

mg/kg

2.4

Hexachlorobenzene (I-ICB)

24 U

mg/kg

24

87-68-3

ilexachlorobutadiene

24 U

mg/kg

24

77-47-4

Hexachiorocyclopentadiene (IICCP)

24 U

mg/kg

24 24

118-74-1

67-72-1

Ilexachloroethane

24 U

mg/kg

193-39-5

Indeno (1,2,3-cd) pyrene

2.4 U

mg/kg

2.4 24 2.4

78-59-1

Isophorone

24 U

mg/kg

91-20-3

Naphthalene

2.4 U

mg/kg

98-95-3

Nitrobenzene

24 U

mg/kg

24

62 1-64-7

n-Nitroso di-n-Propylamine

24 U

mg/kg

24

Page 33 of 59

E104009 SVOA TCLPS FINAL

Prepared 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 l0.05l0 12.00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 1200 10/05/10 12:00 lU/OS/b 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05110 12:00 10/05/JO 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10:05/10 2:00 10,05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10

2:00

10/05/10 12:00 10/05/10 1200 10/05/10 12:00 10/05/10 12:08 10/05/10 12:00

.lnulv:ed ltethod 10/09/10 21:31 10/09/10 2131 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21 31 10/09/10 21:31 1009/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 1009/10 21:31 10/09/10 21.31 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21:31 10/09/10 21 31 10.!09/10 21:31 10/09/10 2131 10/09/10

EPA 82700 EPA 82700 EPA

82700

EPA

82700

EPA 82700

EPA 8270D EPA 8270D EPA 8270D EPA 82700

EPA 82700 EPA 82700

EPA 8270D EPA 8270D EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA

82700

EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 82700

EPA 8270D EPA 02700

EPA 82700 EPA 8270D EPA

82700

21:31

EPA 8270D

10/09/10 21:31 100910 21:31

EPA 82700 EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc

-

Reported by Janet Muse

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO7-B

E104009-09

Matrix: Waste

Station 1D: HERCO7 Date Collected: 9/28/10 15:25 CAS Nwnber

122-39-4

Resalts Qualifiers

4na!yte

n-Nitrosodiphenylamine/Diphenylamine

24 U

Units

mg/kg

MRL

Prepared

24

10/05/10 12:00 10/05/10

87-86-5

Pentachlorophenol

24 U

mg/kg

24

85-01-8

Phenanthrene

2.4 U

mg/kg

2.4

108-95-2

Phenol

24 U

mg/kg

24

129-00-0

Pyrene

2.4 U

mg/kg

2.4

110-86-1

Pyridine

24 U

mg/kg

24

12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00

lnalyzed Method 10/09/10 21:31 10/09)10 21:31 10/09/10 21:31 10/09/10 2131 10/09/10 2131 10/09/10 21:31

EPA 8270D EPA 8270D EPA 8270D EPA 82700 EPA 8270D EPA 82700

Tentatively Identified Compounds: R4-6603

Dimethylisopropylphenanthrene (TIC)

200 NJ

mgrkg

R4-8000535

Diphenyl ether (TIC)

600 NJ

mg/kg

1000 NJ

rng:kg

R4-8000899

Hexahydrotetrarnethylmethanonaphthalene

10/05/10 12:90 10/05/10 2:00 10/05/10 12:00

10/09/10 21:31 21:3 I 10/09/10 21:31

10/05/10 12:00 10/05/10 12:00

10/09/10 21:31 10/09/10 21:31

EPA 8270D

EPA 8270D EPA 8270D

(TIC)

R4-6500

Petroleum Product:

R4-6501

Unidenlilied Compounds

Page 34 of59

E104009 SVOA TCLPS FINAL

N 5000 .1

mg/kg

EPA 8270D EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules mc- Reported by Janet Muse

TCLP SemiVolatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO7-R Station ID: HERCO7

E104009-09

Matrix: Waste

Date Collected: 9/28/10 15:25 C.4S Number

.4naiyre

1319-77-3

(3-and/or 4-)Methylphenol:

58-90-2

2,3,4,6-Tetrachlorophenol:

NA-5

0.10

95-95-4

2,4,5-Trichlorophenol:

NA-5

0. 10

8 8-06-2

2,4,6-Trichlorophenol:

NA-S

0.10

121-14-2

2,4-Dinitrotoluene:

NA-5

0.10

95-48-7

2-Methyiphenol:

NA-S

0.10

118-74-I

Hexachlorobenzcne (1 ICB):

NA-S

0.10

87-68-3

Hexachiorobutadiene:

NA-S

0.10

Hexachioroethane:

NA-5

0.10

67-72-I

Results Qualifiers

‘-

NA-5

Units

MRL

Prepared

0.10

1005/10 9:44

10/09/10

10/05/10

1005/10

10/09/10 1404 10/09/10 14:04 10/09/10 14:04 10,09/10 1404 10/09/10 14:04 10/0910 404

EPA 8270D

10/05/10

10/09/10

9:44 10/05/10

14:04 10/09/10

EPA 82700

10/05/10

10/09/10

10/05/10 9:44

10/05/10 9:44 1005:10 10/05/10

.4natyzed Method

1404

EPA 8270D

EPA 8270D EPA 8270D EPA 82700 EPA 8270D EPA

82700

EPA 8270D

98-95-3

Nitrobenzene:

NA-S

0.10

9:44

14:04

EPA 82700

87-86-5

Pentachlorophenol:

NA-S

0.10

10/05/10 944

10/0910 404

EPA 8270D

110-86-1

Pyridine:

NA-S

0.10

10/05/10 9:44

10/09/10 14:04

EPA 82700

Page 35 of 59

E104009 SVOA TCLPS FINAL

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART, Id: 10-0629

Project: 10-0629, Hercules Inc

-

Reported by Janet Muse

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO8

El 04009-10

Matrix: Waste

Station ID: HERCO8 Date Collected: 9/29/10 8:50 (Z4S Number

1319-77-3 92-52-4

Results Qualijiers

I nu1te

(3-and!or4-)Methylphenoi 1,1-Biphenyl

24 U

Units

mg/kg

MRL

Prepared

.1 natvzed

24

10/05/10 12:00

10/09/10 22:41

10/05/10

10/09/10

1200 10/05/10 200 10/05/10 12:00 10/05/10 (2:00 10/05/10 2:00 10/05/10 12:00 10/05/10 2:0(1 10/05/10 200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 (2:00 10/05/10 12:00 10/05/10 (2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 005/10 12:00 10/05/10 12:00 10/05/10 (2:00 10/05/10 (2:00 10/05/10 1200 10/05/10 12:00 10/05/10 12:00

22:4 I 1009/lU 224 10/09/10 22:41 10/09/10 22:41 10/09/10 22:41 10/09/10 22:41 10/09/10 22:41 10/09/10 224 10/09/10 22:41 10/09/10 22:41 10/09/10 22:4! 10/09/10 22:41 10/09/1(1 22:41 10/09/10 22:41 (0/09/10 22:41 10/09/10 22:41 10/09/10 2241 0/0910 2241 10/09/10 22:41 10,09/10 22:4! 10/09/10 22:4! 10/09/10 22:41 0/09/10 22:4! 1009/10 22:41

EPA 8270D

005)10

10/09/10

EPA 82700

2.4 U

mg/kg

2.4 24

58-90-2

2,3,4,6-Tetrachlorophenol

24 U

mg/kg

95-95-4

2,4,5-Trichlorophenol

24 U

mg/kg

24 24 24

88-06-2

2,4,6-Trichlorophenol

24 U

mg/kg

120-83-2

2,4-Dichlorophenol

24 U

mg/kg

24 U

mg/kg

24

mg/kg

24 24

105-67-9

2,4-Dimethylphenol

5 1-28-5

2,4-Dinitrophenol

24 U

12 1-14-2

2,4-Dinitrololuene

24 U

mg/kg

24

606-20-2

2,6-Dinitrotoluene

24 U

mg/kg

9 1-58-7

2-Chloronaphthalcne

24 U

mg/kg

24

95-57-8

2-Chlorophenol

24 U

mg/kg

24

534-52-1

2-MeIhyl-4,6-dinitrophenol

24 U

mg/kg

24

2.4 U

mg/kg

2.4 24

9 1-57-6

2-Methylnaphthalene

95-48-7

2-Methylphenol

24 U

mg/kg

88-74-4

2-Nitroaniline

24 U

mg/kg

24 24

88-75-5

2-Nitrophenol

24 U

mg/kg

91-94-1

3,3’-Dichlorobenzidine

24 U

mg/kg

24 24

99-09-2

3-Nitroaniline

24 U

mg/kg

101-55-3

4-Bromophenyl phenyl ether

24 U

mg/kg

24

59-50-7

4-Chloro-3-methylphenol

24 U

mg/kg

24

106-47-8

4-Chloroaniline

24 U

mg/kg

24

7005-72-3

4-Chlorophenyl phenyl ether

24 U

mg/kg

24

mg/kg

24 24

100-01-6

4-Nitroaniline

24 U’

100-02-7

4.Nitrophenol

24 U

mg/kg

2.4 2.4

83-32-9

Acenaphthene

2.4 U

mg/kg

208-96-8

Acenaphthylene

2.4 U

mg/kg

98-86-2 120-12-7

1912-24-9

Page 36 of 59

Acetophenone

24 U

mg/kg

24

Anthracene

2.4 U

mg/kg

2.4

24 U’

Alrazine

E104009 SVOA TCLPS FINAL

mg/kg

24

2:00 10/05/10 (2:00 10/05/10 2:00

10/05/10 (2:00 10/05/10

12:00

2241 10/09/10 22:4! 10/09/10 22:4! 10/09/10 22:41

0/09/10 22:4!

:1t4’tIlud

EPA 8270D

EPA 8270D EPA 8270D EPA 82700 EPA

8270D

EPA 8270D EPA

82700

EPA 8270D EPA

82700

EPA 82700 EPA

8270D

EPA 92701) E1’A 82700 EPA 92701) EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700

EPA 82700 EPA

8270D

EPA 8270D

EPA 8270D

EPA 82701) EPA 82700

EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700

,

\o

00•1

D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Janet Muse -

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO8 Station ID: HERCO8

E104009-10

Matrix: Waste

Date Collected: 9/29/10 8:50 CAS Number

.lnalyte

100-52-7

Bcnzaldehyde

24 U

56-55-3

Benzo(a)anthracene

50-32-8

Benzo(a)pyrcne

205-99-2

Results Qualifiers

Units

MRL

Prepared

mg/kg

24

2.4 U

mg/kg

2.4

2.4 U

mg/kg

2.4

Benzo(b)fluoranthene

2.4 U

mg/kg

2.4

191-24-2

Benzo(g,h,i)perylene

2.4 U

mg/kg

2.4

207-08-9

Benzo(k)fluoranthene

2.4 U

mg/kg

2.4

100510 12:00 10/05110 12:00 10/05/10 12:00 10/05/10 12:00 1010510 12:00 10/05/10 12:00

85-68-7

Benzyl butyl phlhalalc

24 U

mg/kg

24

10/05/10

2:00

22:41

11 1-91-1

Bis(2-chloroethoxy)methane

24 U

mg/kg

24

10/05/10

24 U

mg/kg

24

10/09/10 22:41 10/09/10

111-44-4

‘‘bis(2-Chloroethyl) Ether

39638-32-9

Bis(2-chloroisopropyl) ether

24 U

mg/kg

1 17-81-7

Bis(2-ethylhexyl) phthalate

24 U

mg/kg

24

105-60-2

Caprolactam

24 U

mg/kg

24

86-74-8

Carbazole

2.4 U

mg/kg

2.4

218-01-9

Chrysene

2.4 U

mg/kg

2.4

24

53-70-3

Dibenz(a,h)anthracene

2.4 U

mg/kg

2.4

132-64-9

Dibenzofuran

2.4 U

mg/kg

2.4

84-66-2

Diethyl phthalate

24 U

mg/kg

24

131-11-3

Dimethylphthalate

24 U

mg/kg

24

84-74-2

Di-n-butylphthalate

24 U

mg/kg

24

117-84-0

Di-n-octylphthalate

24 U

mg/kg

24

206-44-0

Fluoranthene

2.4 U

mg/kg

2.4

86-73-7

Fluorene

2.4 U

mg/Icg

2.4

I 18-74-I

Hexachlorobenzene ([1(B)

24 U

mg/kg

24

87-68-3

Hexachlorobutadiene

24 U

mg/kg

77-47-4

1-lexachlorocyclopentadiene (IICCP)

24 U

mg/kg

24

67-72-1

Hexachloroethane

24 U

mg/kg

24

193-39-5

Indeno (1,2.3-cd) pyrene

2.4 U

mg/kg

2.4

78-59-1

Isophorone

24 U

mg/kg

24

24

91-20-3

Naphthalene

2.4 U

mg/kg

2.4

98-95-3

Nitrobenzene

24 U

mg/kg

24

621-64-7

n-Nitroso di-n-Propylamine

24 U

mg/kg

24

Page 37 of 59

E104009 SVOA TCLPS FINAL

12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/00/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10

.1 nalv:ed ,llethod 10/09/10 22:41 10/09/10 22:41 10/09/10 2241 10/09/10 22:41 1009.10 22:4 I 10/09/10 22:41 10/09/10

22:41

10/09/10 22:41 10/09/10 22:41 10/09/10 22:41 10/09/10 22:41 10/09/10 22:41 0/09/10 22:41 10/09/10 22:41 10/09/10 22:41 0/09/10 22:41 10/09/10 22:41

10/09/10 22:41 10/09/10

EPA82700 EPA 8270D EPA 8270D

EPA 82700 EPA 82700 EPA

82700

EPA 82700 EPA 82700 EPA 82700

EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA

82700

EPA 82700 EPA 82700 EPA 82700 EPA

82700

EPA 8270D EPA

8270D

22:41

EPA 8270D

10/09/10 22:41 10/09/10

EPA 82700

12:00

22:41

10/05/10 12:00 10:’OS/lO 12:00 10/05/10 12:00 10/05/10

10/09/10 22:41 10/09/10 22:41 10/09/10 22:41 1009/10

12:00

22:41

10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 0 0510 12:00

0/09/10 22:41 100910 22.41 10/09/10 22:41 00910 22:41

EPA 82700 EPA

82700

EPA 82700

EPA

82700

EPA 8270D EPA

8270D

EPA 82700 EPA 82701) EPA 8270D

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 0-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO8

E104009-10

Matrix: Waste

Station ID: HERCO8 Date Collected: 9/29/10 8:50

cis Niunber

Re,sulls Qualifiers

.dnalt’te

Units

MRL

Prepared 10/05/10 12:00 10)05/10

10/09/10 22:41 10/09(10

10/05/10 12:00 10/05/ID 12:00 10)05/10

10/09/lO 22:41 10/09/10 22:41 10/09/10

122-39-4

n-Nitrosodiphenylamine/Diphenylamine

24 U

mg/kg

24

87-86-5

Pentachlorophenol

24 U

mg/kg

24

85-01-8

Phenanthrene

2.4 U

mg/kg

2.4

108-95-2

Phenol

24 C

mg/kg

24

2.4 U

mg/kg

2.4

129-00-0

110-86-I

Pyrene

Pyridine

24 U

mg/kg

70 NJ

mg/kg

400 NJ

mg/kg

200 NJ

mg/kg

24

12:00

.1naled Method

22:41

EPA 82700

EPA 8270D EPA 82700 EPA 8270D

12:00

22:41

EPA 8270D

10/05/10 12:00

10/09/10 22:41

EPA 8270D

10/05/10

0/09/10

12:00 10/05/10 12:00 10/05/10

22:41 10/09/10 22:41 10:09/10

12:00

22:41

10/05/ID

10/09/10

22:41

EPA 82700

1005 10 200

0/09/10 2241

EPA 82700

Tentatively Identified Compounds: R4-6558

Bis(methylethyl)biphenyl

(TIC) (TIC)

R4-6603

Dimethylisopropylphenanthrene

R4-8000899

Hexahydrotetramethylmethanonaphthalene (TIC)

R4-6500

Petroleum Product:

R4-6501

Page 38 of59

Unidentified Compounds

E104009 SVOA TCLPS FINAL

2:00

2000 J

mg/kg

EPA 82700 EPA 82700 EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse

PRO’

-

TCLP SemiVolatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO8 Station ID: IIERCO8

E104009-10

Matrix: Waste

Date Collected: 9/29/10 8:50 C4S Number

.4na!yre

1319-77-3

(3-and/or4-)Methylphenol:

Results Qualifiers

NA-S

Units

MRL

0.10

58-90-2

2,3,4,6-Tetrachlorophenol:

NA-5

0.10

95-95-4

2,4,5-Trichlowphenol:

NA-S

0.10

88-06-2

2,4,6-Trichlorophenol:

NA-5

0.10

121-14-2

2,4-Dinitrotoluene:

NA-5

0.10

95-48-7

2-Methyiphenol:

NA-S

0.10

118-74-1

Flexachlorobenzene (HCB):

NA-5

0.10

87-68-3

-HexachIorobutadiene:

NA-S

0.10

NA 5

0 10

98-95-3

Nitrobenzene:

NA-5

0.10

87-86-5

Pentachlorophenol:

NA-5

0.10

110-86-1

Pyridine:

Page 39 of59

NA-5

E104009 SVOA TCLPS FINAL

0.10

Prepared

•lnalv:ed Method

1010

EPA827OD

1%0Io

9l09/0

IO)0

l9:09/O

EPA 8270D

‘°2°

‘?°

EPA 8270D

I0J/O

EPA 8270D

EPA 8270D EPA 8270D

10/05/10

0/09/10

EPA 8270D

10/05/10

10/09/10

EPA 8270D

10/05/10

10/09/10

‘°° °° ‘°°

EPA 8270D EPA 8270D

/09 9 I / 0 0

EPA 8270D EPA827OD

11/1/10 16:40

0

C

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse

PRD

-

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO9-B

E104009-11

Matrix: Waste

Station ID: HERCO9 Date Collected: 9/29/10 14:20 C4S :V,unber

.4nalyte

13 19-77-3

(3-and/or 4-)Methylphenol

Results Qualifiers

25 U

MRL

Prepared

mg/kg

25

mg/kg

2.5

25

10/05/10 12:00 10/05/]0 zoo 10105/Io 2:00 0/00/10 12:00 10/05/10 12:00 10/05/10 12:110 10.05/10 1200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 2:00 10/05/10 12:00 10/05/10 12:00 10/05/10

Units

92-52-4

1,1-Biphenyl

58-90-2

2,3,4,6-Tetrachlorophenol

25 U

mg/kg

95-95-4

2,4,5-Trichiorophenol

25 15

mg/kg

25 25

290

88-06-2

2,4,6-Trichlorophenol

25 IJ

mg/kg

120-83-2

2,4-Dichlorophenol

25 15

mg/kg

25

105-67-9

2.4-Dirnclhylphenol

25 U

mg/kg

25

51-28-5

2,4-Dinitrophenol

25 U

mg/kg

25

121-14-2

2,4-Dinitrotoluene

25 U

mg/kg

25

606-20-2

2,6-Dinitrotoluene

25 15

mg/kg

25

9 1-58-7

2-Chloronaphthalene

25 U

mg/kg

25

95-57-8

2-Chlorophenol

25 15

mg/kg

25

534-52-1

2-Methyl-4.6-dinitrophenol

25 U

mg/kg

25

91-57-6

2-Methylnaphihalene

mg/kg

2.5

95-48-7

2-Methylphenol

25 U

mg 1g

25

88-74-4

2-Nitroanjljne

25 15

mg/kg

25

88-75-5

2-Nitrophenol

25 U

mg’kg

25

91-94-1

3,3’-Dichlorobenzidine

25 1.

mg/kg

25

99-09-2

3-Nitroaniline

25 U

mg/kg

25

101-55-3

4-Bromophenyl phenyl ether

25 15

mg/kg

25 25

2.6

59-50-7

4-Chloro-3-methylphenol

25 U

mg/kg

106-47-8

4-Chloroaniline

25 15

nig/kg

25

7005-72-3

4-Chlorophenyl phenyl ether

25 U

mg/kg

25

100-01-6

4-Nitroaniline

25 15

mg/kg

25

100-02-7

4-Nitrophenol

25 U

mg/kg

25 2.5

2.5

83-32-9

Acenaphthene

2.5 15

ing/kg

208-96-8

Acenaphthylene

2.5 U

mg/kg

98-86-2

Acetophenone

120-12-7

Anthracene

1912-24-9

Atrazine

Page 40 of59

13104009 SVOA TCLPS FINAL

25 15

mg/kg

25

2.5 U

mg/kg

2.5

25 15

mg/kg

25

12:00

10/05/10 12:00 10/05/10 12:00 10/05/10 12.00 10/05/ID 1200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10,05/10 12:00 10/05/b 12:00 10/05/10 1200 10.05/10 12:00 10/05/10 1200 10)05/H) 12:00 10/05/Ill 12011 10/05/10 12:00 10/05/10 12:00

lna(vzed Method 10/10/10 1:37 10/10/ID 1:37 10110! 10 1:37 10/10/10 1:37 10/10/10 1:37 10/10/10 137 10/lO/lO 37 10/10/10 1:37 10/10/10 1:37 10/10/10 1:37 10/10/10 1:37 10/10/10 1:37 10/10/10 1:37 10/10)10 1:37 1010/10 1:37 10/10/10 1:37 10/10/10 1:37

10/10/10 1:37 10.1010 1:37 10/10/10 1:37 10/10110 1:37

10/10/10 1:37 10/10/10 1:37 10/10/10 1:37 lO/lO/lO 1:37 10/10110 137 10/10/10

EPA 8270D

EPA 82700 EPA 82700

EPA 82700 EPA 8270D EPA 8270D EPA 82701) EPA 8270D EPA 82700 EPA

8270D

EPA 8270D EPA 8270D EPA 8270D EPA 8270D EPA 8270D EPA

82700

EPA 8270D EPA 8270D EPA 82700 EPA

82700

EPA 82700 EPA 8270D EPA 82700 EPA 82700

EPA 82700 EPA 8270D

1:37

EPA 8270D

1000/10 1:37

EPA 82700

1:37 10/10/10 1:37

EPA 82700 EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc Repoed by Janet Muse -

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO9-B

E104009-11

Matrix: Waste

Station ID: HERCO9 Date Collected: 9/29/10 14:20 CAS

MRL

Prepared

mg/kg

25

2.5 U

mg/kg

2.5

2.5 U

mg/kg

2.5

2.5 U

mg/kg

2.5

10/05/10 12:00 10/05)10 12:00 10/05/tO 12.00 10/05/10 12:00 10/05/10 12:00 10)05/10 2:00 10/05110 12:00 10)05/10 12:00

Re,suIIy Qual/fiers

Number

.4milyre

100-52-7

Benzaldehyde

25 U

56-55-3

Benzo(a)anthracene

50-32-8

Benzo(a)pyrene

205-99-2

Benzo(b)fluoranthene Bcnzo(g,h.)perylene

19 1-24-2

Units

2.5 U

mg/kg

2.5 25

207-08-9

Benzo(k)fluoranthene

2.5 U

mg/kg

85-68-7

Benzyl butyl phthalate

25 U

mg/kg

111-91-1 111-44-4

.

2.5

Bis(2-chloroethoxy)methane

25 U

mg/kg

25

bis(2-Chloroethyl) Ether

25 U

mg/kg

25

39638-32-9

Bis(2-chloroisopropyl) ether

117-81-7

Bis(2-ethylhexyl) phthalate

105-60-2

Caprolactam

25 U

mg/kg

25 U

mg/kg

25 U

25 25

mg/kg

25

86-74-8

Carbazole

2.5 U

mg/kg

2.5

218-01 -9

Chrysene

2.5 U

mg/kg

2.5

53-70-3

Dibenz(a,h)an0hracene

2.5 U

mg/lcg

2.5

Analyzed ,lfethod 1:37 10/10/10 1:37 10/10/10 1:37 10/10/10 1:37 10/10)10 1:37

10/10/10 1:37 10/10/10 1:37 10/10/10

EPA 82700

12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/tO 12:00

10:10:10 1:37

EPA 82700

10/10/10 1:37 10/10/10 1:37 10/10/tO 1:37

EPA 82700

10/10/10

0/0510

to/I 0/10

1:37

2.5

12:00

1:37

84-66-2

Diethyl phthalate

25 U

mg/kg

25

10/05/tO

10/10/10

12:00

1:37

25 U

mg/kg

25

10/05/to

10/10/10

2:00

25

10/05/10

1:37 10/10/10

mg/kg

25 2.5

117-84-0

Di-n-octylphthalate

25 U

mg/kg

206-44-0

Fluoranthene

6.8

mg/kg

86-73-7

Fluorene

2.5 U

mg/kg

2.5

118-74-I

I-lexachlorobenzene (FICB)

25 U

mg/kg

25

87-68-3

Hexachlorobutadiene

25 U

mg/kg

25

77-47-4

Hexachlorocyclopentadiene (FICCP)

25 U

mg/kg

25

67-72-1

Ilexachloroethane

25 U

mg/kg

25 2.5

193-39-5

Indeno (1,2,3-cd) pyrene

2.5 U

mg/kg

78-59-1

Isophorone

25 U

mg/kg

25

91-20-3

Naphthalene

3.1

mg/kg

2.5

98-95-3

Nitrobenzene

25 U

mg/kg

25

621-64-7

n-Nitroso di-n-Propylarnine

25 U

mg/kg

25

Page 41 of 59

E1O4009SVOATCLPSFINAL

EPA 82700

EPA 82700

mg/lcg

25 U

EPA 82700

10/10/10 1:37

12:00 10/05/10 12:00

2.5 U

Di-n-butylphthalate

EPA 82700

EPA 82700

Dibenzofuran

84-74-2

EPA 82700

1:37

132-64-9

Dimethylphthalate

EPA 82700

10/10/10 1:37

10/05/10

10/05/10

131-11-3

EPA 82700 EPA 82700

12:00 10/05/10 12:00

10/05/tO 12:00

10/05/to

12:00 10/05/10 12:00 10/05/10 2:00 10/05/tO 12:00 10/05/10 12:00

10:05/10

1:37

10/10/10 1:37

EPA 82700

EPA 82700 EPA 8270D EPA 8270D EPA 82700 EPA827OD EPA 82700 EPA 82700

10/10/10 1:37

EPA

10/10/10 1:37

EPA 82700

10/10/10

EPA 82700

1:37 10/10/1 0 :37 tO/I 0t0 1:37

EPA

82700

82700

EPA 82700

10/10/10 1:37

EPA 82700

10/10/10 1:37

EPA 82700

12:00 10/05/10 12:00 10/05/tO 12:00 10/05/10 12:00 10/05/tO

10/10/10 :37 10/10/10

2:00

1:37

10/10/10 1:37 10/10/tO 1:37

EPA 82700

EPA 82700

EPA 82700 EPA 82700

11/1/10 16:40

0 S r

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700

/

I.

0

5t

DART. Id: 10-0629 Inc Reported by Janet Muse Hercules Project: 10-0629,

\ZY

-

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

SampIelD:HERCO9-B

E104009-11

Matrix: Waste

Station ID: HERCO9 Date Collected: 9/29/10 14:20 C4S Nmnhpr

Resulls Qnalrjlers

.4naiyte

122-39-4

n-Nitrosodiphenylamine/Diphenylaxnine

Units

25 U

mg/kg

MRL

Prepared

.lna(vzed

25

10105/10 12:00 10105/10 2:00 10/05/10 12:00 10/05/10 12:00

10/10/10 1:37 10/10/10 1:37 10/10/10 1:37 10/10:10 :37

10/05/10

10/10/10

2:00 10/05/10 12.00

1:37 10/10/10 1:37

87-86-S

Pentachlorophenol

25 U

mg/kg

25

85-01-8

Phcnanthrene

3.1 J, QL-2

mg/kg

2.5

108-95-2

Phenol

7.2 J, Q-2

mg/kg

25

129-00-0

Pyrene

3.5

mg/kg

2.5

110-86-1

Pyridine

25 U

mg/kg

25

100 NJ

mg/kg

Ifethad EPA 82700 EPA 8270D EPA 82700 EPA 8270D EPA 82700

EPA

8270D

Tentatively Identified Compounds: R4-8000682

(Dimethylethyl)methylphenol (TIC)

1005.10

2:00 10/05/10 12:00

10/10/10 1:37

10/10/10 1:37 10/10:10

EPA 8270D

EPA 8270D

R4-653 I

Camphene (TIC)

100 NJ

mg/kg

R4-6506

Decahydrotrimethylmethylenemethanoazu

300 NJ

mg/kg

biOS/b

12:00

1:37

EPA 82700

400 Xi

mg/kg

10/05/10 12:00

10/10/10 1:37

EPA 8270D

1000 NJ

mg/kg

10/05/10 12:00

10/10/10 1:37

EPA 82700

2000 NJ

mg/kg

10/05/10 12:00

10/10/10 1:37

EPA 8270D

600 NJ

mg/kg

10/05/10 12:00 10/05/10 12:00 10/05/10 12:00

0/10/10

EPA 82701)

Ienc (TIC)

R4-6603 R4-8000535

Dimethylisopropylphenanthrene (TIC) Diphenyl ether (TIC)

R4-8000899

Hexahydrotetramethylmethanonaphthalene (TIC)

R4-8000907

Menthene (TIC)

R4-6584

Methyl(methylethyl)benzene (TIC)

R4-8000897

Methyl(methylethyl)cyclohexane (TIC)

R4-8000906

Methyl(methylethyl)cyclohexene (TIC)

R4-6500

Petroleum Product:

R4-800090I

Trimethylbicycloheptane (TIC)

R4-6501

Unidentified Compounds

Page 42 of 59

E104009 SVOA TCLPS FINAL

700 NJ

mg/kg

1000 NJ

mg/kg

100 N.I

mg/kg

N 100 NJ

1000 J

mg/kg mg/kg

10/05/10

2:00 10/05/10 1200 10/05/10 12:00 10/05/10 12:00

1:37

10/10/10 1:37

10/10/10 1:37 10/10/10 1:37 10/10/10 137

10/10/10 1:37 10/10/10 1:37

EPA 8270D EPA 8270D EPA

8270D

EPA 82700 EPA 8270D EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc - Reported by Janet Muse

TCLP SemiVolatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO9-B Station ID: HERCO9

E104009-11

Matrix: Waste

Date Collected: 9/29/10 14:20 C.4S Number

.4nalyte

1319-77-3

(3-andior 4-)Methylphenol:

58-90-2

2,3,4,6-Tetrachlorophenol:

NA-S

0.10

95-95-4

2.4.5-Trichlorophenol:

NA-S

0.10

88-06-2

2,4,6-Trichlorophenol:

\A-5

0.10

121-14-2

2,4-Dinilrotolucne:

NA-5

0.10

95-48-7

2-Methylphenol:

118-74-1

Resulty Qualifiers

::.HexachIorobenzene (IICB):

NA-5

Units

1IRL

Prepared

0. 10

I%OIO

NA-S

0.10

NA-5

0.10

87-683

Hexach1orobutadiene:

NA-5

0.10

6772 1

exachloroethane

NA 5

0 10

98-95-3

Nitrobenzene:

NA-5

0.10

87-86-5

Pentachlorophcnol:

NA-5

0.10

110-86-1

Pyridine:

Page 43

of 59

NA-5

E104009 SVOA TCLPS FINAL

0.10

4nal:ed llethod l00

EPA 8270D

1t/190

EPA 8270D

I0JI0 14:04

1%oo

EPA 8270D

EPA 8270D

1005/10

EPA 8270D

1%010

EPA 8270D

10/05/10

10/09/10

10/05/10

10/09/10

I0’05/10

009/0

944 10/05/10

1404

105/l0 1010

EPA 8270D EPA 8270D EPA8 70D

EPA 8270D

0 j 1

EPA 8270D

1/409f0

EPA 8270D

11/1/10 16:40

0

0

UNITEI) STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCIO-B

E104009-12

Matrix: Waste

Station ID: HERC1O Date Collected: 9/29/10 14:15 CAS

Niunher

.4nalyte

1319-77-3

(3-and/or 4-)Methylphenol

92-52-4

1,1 -Biphenyl

Results Qualifiers

25 U

1600

MRL

Prepared

mg/kg

2S

mg/kg

25

10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/TO 2:00 10)05/10 1200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 1005/10 2:00 10/05/TO 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10)05/10 12:00 1005/10 12:00 10/05/10 12:00 10/05/10 12:00 10,05/10 12:00 10)05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10)05/10 12:00

Units

58-90-2

2,3,4,6-Tetrachlorophenol

25 U

mg/kg

95-95-4

2,4,5-Trichiorophenol

25 U

mg/kg

88-06-2

2.4,6-Trichiorophenol

25 U

mg/kg

120-83-2

2,4-Dichlorophenol

25 U

mg/kg

25

105-67-9

2,4-Dimethylphenol

25 U

mg/kg

2S 2S 25

51-28-5

2,4-Dinitrophenol

25 U

mg/kg

121-14-2

2,4-Dinitrotoluene

25 U

mg/kg

25

2S

606-20-2

2,6-Dinitrotoluene

25 U

mg/kg

25

91-58-7

2-Chloronaphthalene

25 U

mg/kg

-

95-57-8

2-Chiorophenol

25 U

mg/kg

2—

534-52-1

2-Methyl-4,6-dinitrophenol

25 U

mg/kg

25

91-57-6

2-Methylnaphthalene

4.6

mg/kg

-,

-,

-‘

95-48-7

2-Methylphenol

25 U

mg/kg

88-74-4

2-Nitroaniline

25 U

mg/kg

2S 2S

25

88-75-5

2-Nitrophenol

25 U

mg/kg

91-94-I

3,3’-Dichlorobenzidine

25 U

mg/kg

25

99-09-2

3-Nitroanihne

25 U

mg/kg

2S

101-55-3

4-Bromophenyl phenyl ether

25 U

mg/kg

59-50-7

4-Chloro-3-rnethylphenol

25 U

mg/kg

—-‘

2S

106-47-8

4-Chioroaniline

25 U

mg/kg

7005-72-3

4-Chiorophenyl phenyl ether

25 U

mg/kg

2S 25

100-01-6

4-Nitroaniline

25 U

mg/kg

100-02-7

4-Nitrophenol

25 U

mg/kg

2S

83-32-9

Acenaphthene

2.5 U

mg/kg



208-96-8

Acenaphthylene

2.5 U

mg/kg

25

98-86-2

Acetuphenone

25 U

mg/kg

2.5 U

mg/kg

25 U

mg/kg

120-12-7

Anthracene

1912-24-9

Atrazine

Page 44 of59

E104009 SVOA TCLPS FINAL

2—:2 0

•-‘

2S

.lnatyzed Method 10/10/10 2:12 10/10)10 2:12

EPA 8270D

1010/10

EPA 8270D

2:12 10/10/10 2:12 1010/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10 10:10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2 12 10/10/10 2:12 10/10/10 2:12 10/10:10 2:12 10/10/10 2:12 10/10/10 2:12 10/10)10 2:12 10/10)10 2:12 10/10/TO 2:12 10/10/10 2:12 10/10/10 2:12

EPA 8270[)

EPA 82700 EPAO27OD EPA

82700

EPA 82700 EPA 82700 EPA R270D

EPA 82700 EPA 82701) EPA 82700 EPA 8270D EPA 82700 EPA 8270D

EPA 82700 EPA 8270D EPA 8270D EPA 8270D EPA 82700 EPA 827012 EPA 8270D EPA 82700 EPA 8270D

EPA 8270D EPA 82700 EPA 82700 EPA 827012

EPA 8270D EPA 827012

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 10-0629, Hercules nc Reported by Janet Muse -

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERC1O-B

E104009-12

Matrix: Waste

Station ID: HERCIO Date Collected: 9/29/10 14:15 C.4S

Vu,nber

Results Qualifiers

4nulyte

Units

MRL

25 U

mg/kg

25

Benzo(a)anthracene

2.5 U

mg/kg

2.5

50-32-8

Benzo(a)pyrene

2.5 U

mg/kg

2.5

205-99-2

Benzo(b)fluoranthene

2.5 U

mg/kg

2.5

191-24-2

Benzo(gh.i)perylene

2.5 U

mg/kg

2.5

207-08-9

Benzo(k)fluoranthene

2.5 U

mg/kg

2.5

85-68-7

Benzyl butyl phthalale

25 U

mg/kg

25

100-52-7

Benzaldehyde

56-55-3

111-91-1

Bis(2-chloroethoxy)methane

25 U

mg/kg

25

111-44-4

bis(2-Chloroethyl) Ether

25 1

mg/kg

25

39638-32-9

Bis(2-chloroisopropyl) ether

25 U

mg/kg

25

117-81-7

Bis(2-ethylhexyl) phthalate

25 U

mg/kg

25

105-60-2

Caprolactam

25 U

mg/kg

25

2.5

86-74-8

Carbazole

2.5 U

mg/kg

218-01-9

Chrysene

2.5 U

mg/kg

2.5

53-70-3

Dibenz(a,h)anthracene

2.5 U

mg/kg

2.5

132-64-9

Dibenzofuran

2.5 U

mg/kg

2.5

84-66-2

Diethyl phthalate

25 U

mg/kg

25

131-1 1-3

Dimethyl phthalate

25 U

mg/kg

25

84-74-2

Di-n-butylphthalate

25 U

mg/kg

25 25

117-84-0

Di-n-octylphthalate

25 U

mg/kg

206-44-0

Fluoranthene

2.5 U

mg/kg

2.5

86-73-7

Fluorene

2.5 U

mg/kg

2.5

118-74-I

Hexachlorobenzene (HCB)

25 U

mg/kg

25

87-68-3

Hexachlorobutadiene

25 U

mg/kg

25

77-47-4

Hexachlorocyclopentadiene (HCCP)

25 U

mg/kg

25

67-72-1

Hexachloroethane

25 U

mg/kg

25

193-39-5

Indeno (1,2.3-cd) pyrene

2.5 U

mg/kg

2.5

78-59-1

Isophorone

25 U

mg/kg

25

91-20-3

Naphthalene

6.7

mg/kg

2.5

98-95-3

Nitrobenzene

25 U

mg/kg

25

62 1-64-7

n-Nitroso di-rb-Propylamine

25 U

mg/kg

25

Page 45 of 59

E104009 SVOA TCLPS FINAL

Prepared 10105/10 2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 b/OS/b 12:00 10/05/10 12:00 10/05/10 12:00 10/0510 12:00 10/05/10 12:00 10/00/10 12:00 b/oS/b 12:00 l005/I0 12:00 10/05/10 12:00 10/05/10 12:00 b/OS/b 12:00 10/05/10 12:00 10/05/10 12:00 10:05/10 12:00 bO/05/10 12:00

b/OS/b 12:00 10/05/10 12:00 10/05/10 12:00

10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 2:00 bO/05/bo 12:00 l0/05/I0 12:00 10/05/10 12:00 10/05/10

2:00

.4naly;ed Method 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/lO 2:12 10/10/10 2:12 10/b/b 2:12

10/10/10 2:12 I0/10/b0 2:12 10/10/10 2:12 l010l0 2:12 10/10/10 2:12 010:10 2:12 10/10/10 2:12 10/1010 2:12 10/10/10 2:12 b/b/b 2:12 10/10/10 2:12 l0:IOilO 2:12 10/10/10 2:12 10/10:10 2:12 10/b/b 2:12 101010 2:12 b/b/b 2:12 IO/b0/l0 2:12 10/10/10 2:12 lO/lO/lO 2:l2 10/10/10 2:12 b/b/b 2:12 b/b/b 2:12 10/10/10 2:12

EPA 82700

EPA 82700 EPA 82700 EPA

8270D

EPA 8270D

EPA 8270D EPA 82700 EPA 8270D EPA 82700

EPA 82700 EPA 82700 EPA 8270D EPA 82700

EPA 82700 EPA 82700

EPA 82700 EPA 82700 EPA

8270D

EPA 82700 EPA 8270D

EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 8270D

EPA 8270D EPA 82700 EPA 82700 EPA

82700

11/1/10 16:40

C

C

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project 10 0629 Hercules Inc Reported by Janet Muse -

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ED:

Sample ID: HERCIO-B

E104009-12

Matrix: Waste

Station ID: HERCIO Date Collected: 9/29/10 14:15 C4S Number

122-39-4

Results Qualifiers

.4nal’te

n-Nitrosodiphenylamine/Diphenylamine

25 U

Units mg/kg

IIRL

Prepared

25

10/05/10 12:00

0/05/10

87-86-5

Pentachlorophenol

25 U

mg/kg

25

85-01-8

Phenanthrene

2.5 U

mg/kg

2.5

108-95-2

Phenol

129-00-0

Pyrene

110-86-1

Pyridine

mg/kg

25

3.4

mg/kg

2.5

25 L

mg/kg

25

200 NJ

mg/kg

90 NJ

mg/kg

18 .1, Q-2

.4nulyzed herhod

12:00 10/05/10 2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00

10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 0/10/10 2:12 1010/l0 2:12

10/05/10 2:00 10/05/10 12:00 10/05/10 2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00

10/10/10 2:12 10/10/10 2:12 010/10 2:12 10/I W10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12 10/10/10 2:12

EPA 82700

EPA 82700 EPA 8270D EPA 8270D EPA 82700 EPA 82700

Tentatively Identified Compounds: R4-6552

(Menthenol)terpineol (TIC)

R4-6583

(Methylpropyl)benzene (TIC)

R4-653l

Camphene (TIC)

R4-8000535

Diphenyl ether (TIC)

R4-6584

Methyl(methylethyl)benzene (TIC)

R4-8000897

Methyl(methylethyl)cyclohexane (TIC)

R4-6500

Petroleum Product:

1000 NJ

mg/kg

200 NJ

mg/kg

7000 NJ

mg/kg

4000 NJ

mg/kg

N

2000 NJ

mg/kg

R4-6520

Pinene (TIC)

R4-8000466

Propyiphenol (TIC)

200 NJ

mg/kg

R4-8000901

Trimethylbicycloheptane (TIC)

200 NJ

mg/kg

R4-6501

Unidentified Compounds

Page 46 of 59

E104009 SVOA TCLPS FINAL

2000 J

mg/kg

EPA 8270D

EPA 82700 EPA 82701) EPA

82700

EPA 8270D EPA 8270D

EPA 8270D EPA 82700 EPA 82700 EPA

82700

EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Janet Muse -

TCLP SemiVolatfies Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERC1O-B Station ID: HERC1O

E104009-12

Matrix: Waste

Date Collected: 9/29/10 14:15 CAS Number

.4nalvte

13 19-77-3

(3-andior4-)Methylphenol:

Resulls Qualifiers

NA-5

Uuits

iIRL

0.10

58-90-2

2,3,4,6-Tetrachiorophenol:

NA-5

0.10

95-95-4

2.4.5-Trichlorophenol:

NA-5

0.10

88-06-2

2,4,6-Trichlorophenol:

NA-5

0.10

121-14-2

2,4-DinitrotoIucn:

95-48-7

2-Methylphenol:

NA-S

0.10

118-74-1

Flexachlorobenzene (FICB):

NA-5

0.10

87-68-3

Hexachlorobutadiene:

NA-S

0.10

67-72-1

Hexachloroethane:

NA-5

0.10

98-95-3

Nitrobenzene:

NA-5

0.10

87-86-5

Pentachlorophenol:

NA-5

0.10

110-86-1

Pyridine:

Page 47 of 59

NA-5

NA-S

E104009 SVOA TCLPS FINAL

0.10

0.10

Prepared

10/05/10

Analyzed Ole/hod

10/05/10

10/09/10 4:04 10/09/10 14:04 10/09/10 404 10/09/10 14:04 10/09/10 14-04 10/09/10 14:04 10/09/10 1404 10/09/10 14:04 10/09/10 14:04 10/09/10 14:04 10/09/10 404 10/09/10

9-44

14:04

9:44

10/05/10 9:44 10/05/10 9-44

10/05/10 10/05/10 10/05/10 9:44 10/05/10 944 10/05/10 9:44 1005/10 944 10/05110 10:05/10 944

EPA 8270D EPA 8270D EPA 82700 EPA

8270D

EPA 82700

EPA 8270D EPA 82701)

EPA 8270D EPA 82700 EPA 8270D EPA 8270D EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 [).A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERC1I-B

E104009-13

Matrix: Waste

Station ID: HERC1I Date Collected: 9/29/10 14:30 C4S Nuin her

.dna!yte

13 19-77-3

(3-andlor4-)Methylphenol

Resnils Qualijiers

MRL

Prepared

.4nuivzed

mg/kg

25

mg/kg

25

10/10/10 2:48 10/10/10 2:48

mg/kg

25

10/10/10

Units

95-95-4

2,4,5-Trichlorophenol

25 U

mg/kg

25

88-06-2

2,4,6-Trichlorophenol

25 U

mg/kg

25

120-83-2

2,4-Dichloropheno!

25 U

mg/kg

25 25 25

0105/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/tO 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:1)0 10/05/10 12:00

92-52-4

1,1-Biphenyl

58-90-2

2,3,4,6-letrachlorophenol

13 J. Q-2 480 25 U

105-67-9

2,4-Dimethylphenol

25 U

mg/kg

51-28-5

2,4-Dinitrophenol

25 U

mg/kg

121-14-2

2,4-Dinitrotoluene

25 U

mg/kg

25

606-20-2

2,6-Dinitrotoluene

25 U

mg/kg

25

91-58-7

2-Chloronaphthalene

25 U

mg/kg

25

95-57-8

2-Chlorophenol

25 U

mg/kg

25

534-52-1

2-Methyl-4.6-dinitrophenol

25 U

mg/kg

25

2.5 25

10/05/10 12:00 10/05/10 12:00

10/05/10 12:00 10/05/10 1200 10/05/10 12:08 10/05/tO

10/10/10

EPA 82700 EPA 8270D

2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/tO 2:48

mg/kg

25

25 U

mg/kg

25

12:00

9 1-94-1

3,3’-Dichlorobenzidine

25 U

mg/kg

25

10/05/10

10/10/10

25

10,05/10 12:00

2:48

10/05/10 12:00 10/05/10

10/10/10 2:48 1010/10 2:48 10,10/10 2:48 10/10/10 2:48 Ia/to/to 2:48 10/10/10 2:48 to/jo/la 2:48 10/10/10

3.8 J, Q-2

mg/kg

99-09-2

3-Nitroaniline

25 U

10 1-55-3

4-Bromophenyl phenyl ether

59-50-7

4-Chloro-3-methylphenol

106-47-8

4-Chloroaniline

7005-72-3

4-Chlorophenyl phenyl ether

mg/kg

25 U

mg/kg

25

25 U

mg/kg

25

25 U

mg/kg

25

25 U

mg’kg

25

25 U

mg/kg

25

4-Nitrophenol

25 U

mg/kg

25

Acenaphthene

2.5 U

mg/kg

2.5

208-96-S

Acenaphthylene

2.5 U

mg/kg

2.5

98-86-2

Acetophenone

25 U

mg/kg

25

120-12-7

Anthracene

2.5 U

mg/kg

2.5

25 U

mg/kg

100-01-6

4-Nitroaniline

100-02-7

83-32-9

19 12-24-9

Page 48 of59

Atrazine

E104009 SVOA TCLPS FINAL

25

12:00

to/os/to 12:00 10/05/10 12:00

12:00

10/05/10 12:00 10/05/10 12:00

10/05/10 12.00 10/05/10 12:00 10/05/10 1200 10/05/10

EPA 8270D EPA 82700

EPA 8270D

25 U

2-Methylphenol

EPA 82701)

2:48 10/10)10 2:48

2-Nitrophenol

95-48-7

EPA 8270D

EPA 82700

2-Nitroaniline

2.6

EPA 82700

2:48 10/10/10 2:48

88-75-5

2-Methylnaphthalene

EPA 82700

2:48

88-74-4

91-57-6

EPA 8270D

ooo

248 10/10/10 2:48 l0/lOilO 2:48 10/10/to 2:48 10/10/10 2:48

mg/kg

lie/hod

2.48 10/10:10

12:00

2:48

10/05)10 12:00 0/05/10

10/10/10 2:48 10/10/10

EPA 8270D

EPA 8270D EPA 8270D EPA 8270D EPA 8270D EPA 8270D

EPA 8270D EPA

8270D

EPA 8270D EPA 8270D EPA 8270D t’P\ 82700

EPA827OD EPA 82700 EPA 82700 EPA 82700

EPA 82700

t2:00

2:48

EPA 8270D

10/05/10 12:08

10/10/10 2:48

EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Janet Muse

L 4

cDs:.

-

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERC11-B Station ID: ITERC1I

E104009-13

Matrix: Waste

Date Collected: 9/29/10 14:30 C.4S Number

.tnalvre

100-52-7

Benzaldehyde

Results Qualifiers 25 U

Units mg/kg

MRL 25

56-55-3

Benzo(a)anthracene

2.5 U

mg/kg

2.5

50-32-8

Benzo(a)pyrene

2.5 U

mg/kg

2.5

205-99-2

Benzo(b)fluoranthene

2.5 U

mg/kg

2.5

191-24-2

Benzo(g,h.i)perylene

2.5 U

mg/kg

2.5

207-08-9

Benzo(k)fluoranthene

2.5 U

mg/kg

2.5

85-68-7

Benzyl butyl phthalate

25 U

mg/kg

25

Bis(2-chloroethoxy)methane

25 U

mg/kg

25

bis(2-Chloroethyl) Ether

25 U

mg/kg

25

111-91-I 111-44-4

-

39638-32-9

Bis(2-chloroisopropyl)

25 U

mg/kg

25

117-81-7

Bis(2-ethylhexyl) phthalate

25 U

mg/kg

25

ether

105-60-2

Caprolactam

25 U

mg/kg

25

86-74-8

Carbazole

2.5 U

mg/kg

2.5

218-01-9

Chiysene

2.5 U

mg/kg

2.5

53-70-3

Dibenz(a,h)anthracene

2.5 U

mg/kg

2.5

132-64-9

Dibenzofuran

2.5 U

mg/kg

2.5

84-66-2

Diethyl phthalate

25 U

mg/kg

25

131-11-3

Dimethylphthalate

25 U

mg/kg

25

84-74-2

Di-n-butylphthalate

25 U

mg/kg

25

117-84-0

Di-n-octylphthalate

25 U

mg/kg

25

206-44-0

Fluoranthene

10

mg/kg

2.5

86-73-7

Fluorene

2.5 U

mg/kg

2.5

118-74-I

Hexachlorobenzene (I-ICB)

25 U

mg/kg

25

87-68-3

Hexachlorobutadiene

25 U

mg/lcg

25

77-47-4

flexachlorocyclopentadiene

25 U

mg/kg

25

67-72-1

Hexachloroethane

25 U

mg/kg

25

193-39-5

Indeno

2.5 U

mg/kg

2.5

78-59-1

Isophorone

25 U

mg/kg

25

91-20-3

Xaphthalene

33

mg/kg

2.5

98-95-3

Nitrobenzene

25 U

mg/kg

25

621-64-7

n-Nitroso di-n-Propylamine

25 U

mg/kg

25

Page 49 of 59

(HCCP)

(1.2.3-cd) pyrene

E104009 SVOA TCLPS FINAL

Prepared

Analyzed ltethod 10.1010

12:00

2-48

10/05/10

10/10/10

12:00 (00510 (200 10/05/10 12:00 (2:00 10/05/10 12:00 0/05/10 12.00 10/05/10 12:00 10/05/10 12:00

10/05/10 1200 10/05/10 12:00 10/05/10 12:00 I0/05’lo (200

10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00

10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 2.00

2:48

10.10.10 2:48

10/10/10 2:48 10/1010 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 248 10/10/10 2.415

10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:40 10/10/10 2:48 10/10/10 2:48 0/10/10 2:40 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48 10/10/10 2:48

EPA827OD EPA 8270D EPA 8270D

EPA 82700 EPA82700

EPA 82700 EPA 82700

EPA 82700 EPA 82700

EPA 82700 EPA 0270!) EPA

8270D

EPA 82700 EPA

8270D

EPA 82700

EPA 8270D EPA 8270D EPA

82700

EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 8270D EPA 8270D EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERC11-B

E104009-13

Matrix: Waste

Station ID: IIERC1I Date Collected: 9/29/10 14:30 C.4S ;Viginber

Results Qualifiers

4nalyie

Units

MRL

Prepared

25

10/05/10 12:00 10/05/10 12:00 10/05/10 1200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00

10/10/10 2:40 10/10110 2:48 10/10/10 2:48 1010/10 2:48 10/10/10 2:48 10/10/10 2:48

111/05/10 2.00 10/05/10 2:00 10/05.10 12:00 10/05/10 12:00

10/10/10 2:40 1W10/10 2:48 10/10110 2:48 10/10/10 248

10/05/10 12:00 10/05/10 12:00 biOS/b 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 200 10/05/10 12:00

10/10/10 2:48 10/10/10 2:40 0/10/10 2:48 111/10/10 2:48 10/10/10 2:48 10/10/10 248 10/10/10 2:40

25 U

mg/kg

Pentachlorophenol

25 U

mg/kg

25

Phenanthrene

5.0 J, QL-2

mg/kg

2.5

Phenol

6.2 J, Q-2

mg/kg

25

Pyrene

4.8

mg/kg

2.5

Pyridine

25 U

mg/kg

25

122-39-4

n-Nilrosodiphenylamine/Diphenylamine

87-86-5 85-01-8 108-95-2 129-00-0 110-86-1

.lnalyzed Method EPA 82700 EPA 82700 EPA 82700 EPA

8270D

EPA 82700 EPA

82700

Tentatively Identified Compounds: R4-8000682

(Dmethylethyl)methy1phcno1 (TIC)

200 NJ

mg/kg

R4-6531

Camphene (TIC)

100 NJ

mg/kg

R4-6603

Dimethylisopropylphenanthrene (TIC)

R4-8000899

Hexahydrotetramethylmethanonaphthalene (TIC)

R4-8000907

Menthene (TIC)

R4-6584

Methyl(methylethyl)benzene (TIC)

R4-8000897

MethyI(methylethyl)cyclohexane (TIC)

R4-6500

Petroleum Product:

R4-6520

Pinenc (TIC)

R4-800090l

Trimethylbicycloheptane (TIC)

R4-6501

Unidentified Compounds

Page 50 of59

E104009 SVOA TCLPS FINAL

200 NJ

mg/kg

1000 NJ

mg/kg

100 NJ

mg/kg

700 NJ

mg/kg

2000 NJ

mg kg

100 NJ

mg/kg

200 NJ

mg/kg

2000 J

mg/kg

EPA 82700 EPA

82700

EPA 8270D EPA 8270D

EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

TCLP SemiVolatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERC11-B

E104009-13

Matrix: Waste

Station 1D: HERC1I Date Collected: 9/29/10 14:30 C1S

Results Qualifiers

Nu,szh’r

.4na!yte

1319-77-3

(3-andlor4-)Methylphenol:

NA-5

Units

MRL

0.10

58-90-2

2,3,4,6-Tetrachlorophenol:

NA-S

0.10

95-95-4

2,4,5-Trichlorophenol:

NA-5

0.10

88-06-2

2,4,6-Trichlorophenol:

\A.5

0.10

121-14-2

2,4-Dinitrotoluene:

NA-S

0.10

95-48-7

2-Methylphenol:

NA-S

0.10

118-74-I

l4exachlorobenzene (HCB):

NA-5

0.10

87-683

Hexachlorobutadiene:

NA-S

0.10

67 721

1-lexachloroethane

98-95-3

Nitrobenzene:

NA-5

0.10

87-86-5

Pentachlorophenol:

NA-S

0.10

110-86-1

Page 5! of59

Pyridine:

NA

NA-5

E104009 SVOA TCLPS FINAL

0 10

0.10

Prepared

.laqlw;ed Method

l0I0

l/0

10/10

lIO

I0I0

l/11/4i0

1O11O

EPA 8270D

EPA 8270D EPA 8270D

EPA 8270D

I0M5l0

1009,10

EPA827OD

1%01o

Il14090I20

EPA82700

°oo

I009.i0

EPA 0270D

10/05/10

EPA 8270D

10/05/10

100910

10/05/10

10/09/10

ooo ‘%°°

EPA W’70D EPA827OD

lt090

EPA 8270D

1/J0

EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Ed: 10-0629 Project: 1 0-0629, Hercules Inc

-

Reported by Janet Muse

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCI2-B Station ID: HERCI2

E104009-14

Matrix: Waste

Date Collected: 9/29/10 14:50 Number

.4nalvre

MRL

Prepared

1319-77-3

(3-and/or 4-)Methylphenol

3.1 J,Q-2

mg/kg

26

mg/kg

26

26 U

mg/kg

26

2,4,5-Trichlorophenol

2615

mg/kg

26

88-06-2

2,4,6:l’richlorophenol

26 U

mg/kg

26

220-83-2

2,4-Dichiorophenol

26 U

mg/kg

26

105-67-9

2,4-Dimethylphenol

26 U

mg/kg

26

51-28-5

2,4-Dinitrophenol

26 U

mg/kg

.,

121-14-2

2,4-Dinitrotoluene

26 U

mg/kg

26

606-20-2

2,6-Dinitrotoluene

26 15

mg/kg

26

91-58-7

2-Chloronaphthalenc

26 U

mg/kg

26

95-57-8

2-Chlorophenol

26 15

mg/kg

26

534-52-1

2-Methyl-4,6-dinitrophenol

26 U

mg/kg

26

91-57-6

2-Methylnaphthalene

35

mg/kg

2 6

95-48-7

2-Methyiphenol

26 U

mg/kg

26

88-74-4

2-Nitroaniline

26 U

mg/kg

26

88-75-5

2-Nitrophenol

26 U

mg/kg

26

91-94-1

3,3-Dichlorobenzidine

26 U

mg/kg

26 26

26

10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 (2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12-00 10/05/10 12:00 10/05/10 12:00 10/05/10 (2:00 10/05/10 (2:00 10/(15/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 (2:00 10/05/10 12:00 10/05/10 (2:00 10/05/10 12:00 10/05/10 (2:00 10/1(5/10 12:1(11 10/05/10 12:00 10/05/1(1 12:00

92-52-4

1,1 -Biphenyl

500

58-90-2

2,3,4,6-Tetrachlorophenol

95-95-4

Results Quali/lers

Units

99-09-2

3-Nitroaniline

26 U

mg/kg

101-55-3

4-Bromophenyl phenyl ether

26 U

mg/kg

59-50-7

4-Chloro-3-methylphenol

26 U

mg/kg

26

106-47-8

4-Chioroaniline

26 U

mg/kg

26

7005-72-3

4-Chlorophenyl phenyl ether

26 U

mg/kg

26

100-01-6

4-Nitroaniline

26 1]

mg/kg

26

100-02-7

4-Nitrophenol

26 U

mg/kg

26

83-32-9

Acenaphihene

2.6 U

mg/kg

26

208-96-8

Acenaphthylene

2.6 U

mg/kg

2•6

98-86-2

Acetophenone

26 U

mg/kg

26

120-12-7

Anthracene

2.6 U

mg/kg

2•6

1912-24-9

Atrazine

26 U

mg/kg

.,

Page 52 of59

E104009 SVOA TCLPS FINAL

.•tnal;ed ,lfeghod 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 (0/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/I 0/10 3:24 (0/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 0/1010 3:24 10/10/10 324 3:24 10/1(1/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 (0/(0/10 3:24

EPA 8270D EPA 8270D EPA 82700 EPA

82700

EPA 82700 EPA

8270D

EPA 82700 EPA

82700

EPA 8270D

EPA 8270D EPA 82700 EPA

8270D

EPA 8270D EPA

82700

EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 82700 EPA 82700 EPA 8270D EPA 8270D EPA 82700 EPA 82700 EPA 8270D EPA 8270D EPA 8270D EPA 82700 EPA 8270D EPA 8270D

11/1/10 16:40

0

0

UMTED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc

-

Reported by Janet Muse

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERC12-B

Matrix: Waste

Station ID: HERCI2 Date Collected: CAS Number

9/29/10 14:50 Results Qualijiers

inalyte

Benzaldehyde

100-52-7

E104009-14

26 U

MRL

Prepared

mg/kg

26

mg/kg

2



10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00

Units

Benzo(a)anthracene

2.6 U

50-32-8

Benzo(a)pyrene

2.6 U

mg/kg

26

205-99-2

Benzo(b)fluoranthene

2.6 U

mg/kg

‘,

191-24-2

Benzo(g.h,i)perylene

2.6 U

mg/kg

.,

2

56-55-3

e .0 .0

207-08-9

Benzo(k)fluoranthene

2.6 U

mg/kg

85-68-7

Benzyl butyl phthalate

26 U

mg/kg

26

Bis(2-chloroethoxy)methane

26 U

mg/kg

2’

26 U

mg/kg

.,

26 U

mg/kg

.,i O

111-91-1 111-44-4

.-bis(2-C’hIoroethyI) Ether

1 .0

39638-32-9

Bis(2-chloroisopropyl) ether

117-81-7

Bis(2-ethylhexyl) phthalate

26 U

mg

105-60-2

Caprolactam

26 U

mg/kg

-,

2

1 .0 1

-u

86-74-8

Carbazole

2.6 U

mg/kg

218-01-9

Chrysene

2.6 U

mg/kg

2

53-70-3

Dibenz(a,h)anthracene

2.6 U

mg/kg

26

132-64-9

Dibenzofuran

2.6 U

mg/kg

1 1

84-66-2

Diethyl phthalate

26 U

mg/kg

26

13 1-11-3

Dimethyl phthalate

26 U

mg/kg

84-74-2

Di-n-butylphthalate

26 U

mg/kg

-,

117-84-0

Di-n-octylphthalate

26 U

mg/kg

71

mg/kg

i

1

206-44-0

Fluoranthene

9.5

86-73-7

Fluorene

2.6 U

mg/kg

118-74-I

Hexachlorobenzene (HUB)

26 U

mg/kg

2

.,

87-68-3

Hexachiorobutadjene

26 U

mg/kg

‘)l

77-47-4

Hexachlorocyclopentadiene (HCCP)

26 U

mg/kg

26

67-72-1

Hexachioroethane

26 U

mg/kg

193-39-5

Indeno (1,2,3-cd) pyrene

2.6 U

mg/kg

26

78-59-1

Isophorone

26 U

mg/kg

‘-‘

91-20-3

Naphthalene

3.9

mg/kg

26

98-95-3

Nitrobenzene

26 U

mg/kg

11

621-64-7

n-Nitroso di-n-Propylamine

26 U

mg/kg

26

Page 53 of 59

E104009 SVOA TCLPS FINAL

.4nazed Method 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10.1010 324 10/10/10 3:24 10:10:10 3:24

10/10/10 3:24 10/10/10 3:24 10/10/10 324 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 324 10 10:10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24

EPA 8270D EPA 82700 EPA 82700

EPA 8270D EPA 82700 EPA

8270D

EPA 82700 EPA

82700

EPA 82700

EPA 82700 EPA 82700 EPA

82700

EPA 82700 EPA

8270D

EPA 82700 EPA

82700

EPA 82700 EPA

82700

EPA 82700 EPA 82700 EPA 8270D EPA 82700 EPA 8270D EPA

82700

EPA 8270D

EPA 82700 EPA 82700 EPA

82700

EPA 8270D EPA 82700 EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTiON AGENCY Region 4 Science and Ecosystem Support Division 98() College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc

-

Reported by Janet Muse

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERC12-B

E104009-14

Matrix: Waste

Station ID: HERCI2 Date Collected: 9/29/10 14:50 C4S Number 122-39-4

Results Qualifiers

4nalyte n-Nitrosodiphenylamine/Diphenylamine

26 U

Units

mg/kg

MRL

Prepared

Analyzed

26

10/05/10

10/10/10

10/05/10 12:00 10/05/10 2:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00

87-86-5

Pentachlorophenol

26 U

mg/kg

26

85-01-8

Phenanthrene

2.6 U

mg/kg

2.6

108-95-2

Phenol

mg/kg

26 2.6

26

15 J, Q-2

12:00

129-00-0

Pyrene

2.6 U

mg/kg

110-86-1

Pyridine

26 U

mg/kg

200 NJ

mg/kg

1005/10

mg/kg

10/05/10 12:00 10/05/10

3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 1010:10 3:24 10/10/10 3:24

t!ethod EPA 82700

EPA

82700

EPA 82700 EPA 82700

EPA 82700 EPA 82700

Tentatively Identified Compounds: R4-653 I

Camphene (TIC)

R4-6603

Dimethylisopropylphenanthrene (TIC)

R4-8000535

Diphenyl ether (TIC)

R4-8000899

Hexahydrotetramethylmelhanonaphlhalene (TIC)

R4-6584

Methyl(methylethyl)benzene (TIC)

300 \J 2000 NJ

mg/kg

500 >J

mg/kg

10/05/10 200

3000 NJ

mg/kg

10/05/10 12:00 10/05/10

R4-8000897

Methyl(methylethyl)cyclohexane (TIC)

2000 NJ

mg/kg

R4-8000906

Methyl(methylethyl)cyclohexene (TIC)

80 NJ

mg/kg

R4-6500

Petroleum Product:

R4-8000466

Propylphenol (TIC)

R4-8000901

Trimethylbicycloheptane (TIC)

R4-650I

Unidentified Compounds

Page 54 of59

E104009 SVOA TCLPS FINAL

2:00

300 NJ

mg/kg

200 NJ

mg/kg

1000 J

mg/kg

2:00

2:0)) 10/05/10 12:00 (1/05/10 12:0)) (0/05/10 12:00 10/05/10 12:00 10/05/10 (2:00

3:24 10/10/10 3:24 10:1010 3:24 10/10/10 3:24

10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24 10/10/10 3:24

EPA 82700 EPA 82700 1PA 8270D EPA 8270D

EPA 8270D EPA

82700

EPA 8270D EPA 82700

EPA 8270D EPA 8270D

EPA 8270D

11/1/10 16:40

0 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

TCLP SemiVolatiles Project: 10-0629, Hercules Inc E104009-14

Lab ID:

Sample ID: HERC12-B

Matrix: Waste

Station ID: HERC12 Date Collected: 9/29/10 14:50 C IS Vugzb’r

Results Qualifiers

4na!yie

(3-andlor4-)Methylphenol:

13 19-77-3

Units

MRL

0.10

NA-5

2,3,4,6-Tetrachiorophenol:

NA-5

95-95-4

2,4,5-Trichlorophenol:

NA-5

88-06-2

2,4,6-Trichlorophenol:

NA-5

0.10

121-14-2

2,4-Dinitrotoluene:

NA-5

0.10

58-90-2

-

0.10

2-Methylphenol:

\A5

0.10

118-74-1

Hexachlorobenzene (IICB):

NA-5

0.10

67 72 I



r

Hexachiorobutadiene:

Nexachloroethane

NA-5

0.10

NA 5

0 10

98-95-3

Nitrobenzene:

NA-5

0.10

87-86-5

Pentachlorophenol:

NA-5

0.10

110-86-1

Page 55 of 59

Pyridine:

NA-5

E104009 SVOA TCLPS FINAL

-lnalyzed

I%0I0

I1/409/0

10110

1/,09/0

1010

11/09/0

I0I0

919/0

0.10

Otethod

EPA 8270D EPA 8270D

EPA 8270D

0.10

95-48-7

87-68-3

Prepared

10/90 10/05/10

EPA 8270D

EPA 8270D 10/09/10

10/05/10

EPA 82701)

EPA 8270D 10/09/10

10/05/10

EPA 8270D

10/09/10

EPA 8270D EPA827OD

I00I0

9/400

EPA 8270D

1%0I0

1f/0

EPA 8270D

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Janet Muse

li PR -

-

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERC13-B

E104009-15

Matrix: Waste

Station ID: HERC13 Date Collected: 9/29/10 15:10 C4S Niunber

.4nalvte

13 19-77-3

(3-and/or 4-)Methylphenol

Results QualifIers

18 J. Q-2

Units

MRL

Prepared

mg/kg

24

mg/kg

24 24

10/05/10 1200 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 0/05/10 2:00 10/05/10 12:00 10/05)10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10)05/10 12:00 10/05/10 12:00 0/05)10 12:00 10/05/10 12:00 10/05/1)) 12:00 10/05/10 12:00 10/05/10 12:00

92-52-4

1,1-Biphenyl

58-90-2

2,3,4,6-Tetrachlorophenol

24 U

mg/kg

95-95-4

2,4,5-Trichlorophenol

24 U

mg/kg

24

88-06-2

2.4,6-Trichlorophenol

24 U

mg/kg

24

120-83-2

2,4-Dichlorophenol

24 IS

mg/kg

24

105-67-9

2,4-Ditnethylphenol

24 U

mg/kg

24

5 1-28-5

2,4-Dinitrophenol

24 U

mg/kg

24

121-14-2

2,4-Dinitrotoluene

24 U

mg/kg

24

1500

606-20-2

2,6-Dinitrotoluene

24 15

mg/kg

24

9 1-58-7

2-Chloronaphthalene

24 U

mg/kg

24

95-57-8

2-C’hlorophenol

24 UJ

mg/kg

24

534-52-1

2-Methyl-4,6-dinitrophenol

24 U

mg/kg

24

9 1-57-6

2-Methylnaphthalene

4.1

mg/kg

2.4

95-48-7

2-Methylphenol

4.0 J, Q-2

mg/kg

24

88-74-4

2-Nitroaniline

24 U

mg/kg

24

88-75-5

2-Nitrophenol

24 U

mg/kg

24

91-94-1

3,3’-Dichlorobenzidine

24 U

mg/kg

24

99-09-2

3-Nitroaniline

24

U

mg/kg

24

101-55-3

4-Bromophenyl phenyl ether

24 U

mg/kg

24

59-50-7

4-Chloro-3-methylphenol

24 U

mg/kg

24

106-47-8

4-Chloroaniline

24 U

mg/kg

24

7005-72-3

4-Chlorophenyl phenyl ether

24 U

mg/kg

24

100-01-6

4-Nitroaniline

24 U

mg/kg

24

100-02-7

4-Nitrophenol

24 U

mg/kg

24

83-32-9

Acenaphthene

2.4 U

mg/kg

2.4

208-96-8

Acenaphthylene

2.4 U

mg/kg

2.4

98-86-2

Acetophenone

120-12-7

Anthracene

1912-24-9

Atrazine

Page 56 of 59

E104009 SVOA TCLPS FINAL

24 U

mg/kg

24

2.4 U

mg/kg

2.4

24 U

mg/kg

24

.•lnav;ed lfethod 10/10/10 4:00 10/10/10 4:1)0 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10)10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10)10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 1010/10 4:00 10/10/10 4:00 10)10/10 4:00 10/10/10 4:00 10)10/10 4:00 10/10/10 4:00 10/10/10 4:00

EPA 8270D EPA 82700 EPA 8270D EPA 8270D EPA 82700 EPA

82700

EPA 8270D EPA 82700 EPA 8270D EPA 8270D EPA 8270D EPA 8270D EPA 82700 EPA

82700

EPA 82700 EPA 8270D EPA 8270D EPA 8270D

EPA 82700 EPA

82700

EPA 8270D EPA 8270D EPA 82700 EPA 82701) EPA 8270D EPA 82700 EPA 8270D EPA

82700

EPA 82700 EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc

-

Reported by Janet Muse

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERC13-B Station ID: HERC13

E104009-15

Matrix: Waste

Date Collected: 9/29/10 15:10 (IS Niunber

.4nalyte

100-52-7

Benzaldehyde

56-55-3

Results Qualifiers

Units

MRL

24 U

mg/kg

24

Benzo(a)anthracene

2.4 U

mg/kg

A

50-32-8

Benzo(a)pyrene

2.4 U

mg/kg

24

205-99-2

Benzo(b)fluoranthene

2.4 U

mg/kg

) A

191-24-2

Benzo(g,h,i)perylene

2.4 U

mg/kg

A

207-08-9

Benzo(k)fluoranthene

2.4 U

mg/kg

8 5-68-7

Benzyl butyl phthalate

24 U

mg/kg

24

111-91-1

I3is(2-chloroethoxy)methane

‘‘



A

24 U

mg/kg

‘A

bis(2-Chloroethyl) Ether

24 U

mg/kg

2A

39638-32-9

Bis(2-chloroisopropyl) ether

24 U

mg/kg

2A

117-81-7

Bis(2-ethylhexyl) phthalate

24 U

mg/kg

24

105-60-2

Caprolactam

24 U

mg/kg

‘A

111-44-4

.

86-74-8

Earbazole

2.4 U

mg/kg

24

218-01-9

Chrysene

2.4 U

mg/kg

) A

53-70-3

Dibenz(a,h)anthracene

2.4 U

mg/kg

24

132-64-9

Dibenzofuran

2.4 U

mg/kg

24

84-66-2

Diethyl phthalate

24 U

mg/kg

24

131-11-3

Dimethyl phthalate

24 U

mg/kg

24

84-74-2

Di-n-butylphthalate

24 U

mg/kg

24

117-84-0

Di-n-oclylphthalate

24 U

mg/kg

206-44-0

Fluoranthene

7.0

mg/kg

-)

86-73-7

Fluorene

2.4 U

mg/kg

24

118-74-1

Hexachlorobenzene (HCB)

24 U

mg/kg

24 24

2A

87-68-3

Hexachiorobutadiene

24 U

mg/kg

77-47-4

Hexachlorocyclopentadiene (HCCP)

24 U

mg/kg

24

67-72-1

Hexachioroethane

24 U

mg/kg

24

193-39-5

Indeno (1,2,3-cd) pyrene

2.4 U

mg/kg

24

78-59-1

Isophorone

24 U

mg/kg

)A

91-20-3

Naphthalene

5.2

mg/kg

24

98-95-3

Nitrobenzene

24 U

mg/kg

24

621-64-7

n-Nitroso di-n-Propylamine

24 U

mg/kg

24

Page 57 of59

E104009 SVOA TCLPS FINAl..

Prepared 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 2:00 10/05/10 12:00 10/05/10 12:00 10/05,10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 12:00 10/05/10 2:00 10/05/10 12:00 10/05/10 2:00 10/05/10 12:00

tna4zed Method 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 0/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00

EPA 82701)

EPA 8270D ‘EPA 8270D

EPA 82700 EPA 82700 EPA 8270D EPA 82700

EPA 8270D EPA 82700 EPA 8270D

EPA 82700 EPA 8270D EPA 82700

EPA 8270D EPA 8270D

EPA 82700 EPA 82700

EPA 8270D EPA 82700 EPA 8270D EPA 82700 EPA 8270D EPA 8270D

EPA 82700 EPA 82701) EPA 82700 EPA 8270D

EPA 82700 EPA 82700 EPA 82700 EPA 82700

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project; 10-0629, Hercules Inc Reported by Janet Muse -

Semi Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCI3-B

E104009-15

Matrix: Waste

Station ID: HERCI3 Date Collected: 9/29/JO 15:10 (‘IS .‘Vuuzher

Results Qualifiers

.4rndrte

Linli

MRL

Prepared

24

°‘°° 12:00 10/05/jO 2:00 10/05/10 12:00 10/05/10 2:00 10/05!I0 12:00 10/05/10 12:00

122-39-4

n-Nitrosodiphenylamine/Diphenylamine

24 U

mg/kg

87-86-5

Pentachlorophenol

24 U

mg/kg

24

85-01-8

Phenanthrene

2.4 U

mg/kg

2.4

108-95-2

Phenol

28

mg/kg

24 2.4 24

129-00-0

Pyrene

3.1

mg/kg

110-86-1

Pyridine

24 U

mg/kg

400 NJ

mg/kg

1000 NJ

mg/kg

4navzed Mcfhad 10/10/10 4:00 10/10/10 4:00 10/10/10 4:00 4:00 10/10/10 4:00 10/10/10 4:00

EPA 82701)

EPA 8270D EPA 82701) EPA 82700 EPA 82700

EPA 82700

Tentatively Identified Compounds: R4-6552

(Menthenol)terpineol (TIC)

R4-6531

Camphene (TIC)

R4-6603

Dirnethylisopropylphenanthrene (TIC)

200 N.J

mg/kg

10/05/10 12:00 10/05/10 12:00 10/05/10 12:00

10/10/10 4:00 10/10/10 4:00 10/10/10 400 10/10/10 4:00 10/10/10 4:00

R4-8000535

Diphenyl ether (TIC)

5000 NJ

mg/kg

R4-8000899

Ilexahydrotetramethylmethanonaphthalene (TIC)

1000 NJ

mg/kg

12:00 10/05/10 12:00

R4-6584

Methyl(methylethyl)benzene (TIC)

7000 NJ

mg/kg

10/05/10 12:00

10/10/10 4:00 10:10/10

EPA 8270D

EPA 8270D EPA 8270[)

EPA 82700 EPA 82700

EPA

8270D

R4-8000897

Methyl(methylethyl)cyclohexane (TIC)

4000 NJ

mg/kg

10/05/10

12:00

4:00

EPA 8270D

R4-8000906

Methyl(methylethyl)cyclohexene (TIC)

200 NJ

mg/kg

10/05,10 12.00

10/10,10 4:00

EPA 82700

2000 NJ

mg/kg

10/05/10 12:00 0)05)10

10/10/10 4:00 10/10/10

R4-6520

Pinene (TIC)

R4-8000466

Propylphenol (TIC)

200 NJ

mg/kg

R4-800090I

Trimethylbicycloheptane (TIC)

200 NJ

mg/kg

R4-6501

Page 58 of59

Unidentified Compounds

El 04009 SVOA TCLPS FINAL

2000 J

mg/kg

EPA 02701)

1200

400

EPA 82700

10/05/10 12:00 10/05/10 12:00

I0;IO/10 4:00 10/10)10 4:00

EPA 82700

EPA 82700

11/1/10 16:40

-

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Janet Muse -

TCLP SemiVolatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERC13-B Station ID: HERC13

E104009-15

Matrix: Waste

Date Collected: 9/29/10 15:10 C’S N,unher

.dnatyte

1319-77-3

(3-andlor4-)Methylphenol:

58-90-2

2,3,4,6-Tetrachlorophenol:

NA..5

0.10

95-95-4

2.4.5-Trichlorophenol:

NA-5

0.10

88-06-2

2,4,6-Trichiorophenol:

NA-5

0.10

121-14-2

2.4-Dinitrotoluenc:

NA-5

0.10

95-48-7

2-Methylphenol:

NA5

0.10

118-74-1

Hexachlorobenzene (HCB):

NA-5

0.10

87-68-3 67-72-1

-

.

Results Qualifiers

NA-5

Units

MRL

0.10

Hexachlorobutadiene:

\A5

0.10

[lexachloroethane:

NA-S

010

98-95-3

Nitrobenzene:

NA-5

0.10

87-86-5

Pentachlorophenol:

NA-5

0.10

110-86-I

Pyridine:

Page 59 of 59

NA-S

El 04009 SVOA TCLPS FINAL

0.10

Prepared 10/05/10 9:44

10/05/10 944

10.05:10 9:44 10/05/10 9:44 005 0

9:44 10/05/10 9:44

1005/10 9:44

10/05/10 9:44

10.0510

.4na(ed llethad 10/09/10 14:04 10/09/10 14:04 10/09/10 14:04 10/09/10 14:04

EPA 8270D

10/09/10 14:04

EP 8270D

10/09/ID

14:04 10/09/10 14:04 10/09/10 14:04 10/09/10

9:4-I

14:04

10/05/10 9:44 111/05/10

10/09/ID 14:04 10091/)

10/05/10 9:44

10/09/10 14:04

[I’A 8270D

EPA 8270D EPA 82701)

EPA 8270D

EPA 8270D EPA 8270D EPA 270D EPA 8270D EPA 8270D

EPA 8270D

11/1/10 16:40

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

November 8, 2010 4SESD-ASB

MEMORANDUM SUBJECT:

FINAL Analytical Report Project: 10-0629, Hercules Inc Civil Enforcement

FROM:

Kristin Trapp OCS Chemist

THRU:

Sallie Hale, Chief ASB Organic Chemistry Section

TO:

Sharon Matthews

Attached are the final results for the analytical groups listed below. These analyses were performed in accordance with the Analytical Support Branch’s (ASB) Laboratory Operations and Quality Assurance Manual (ASB LOQAM) found at www.epa.gov/region4/sesdlasbsop. Any unique project data quality objectives specified in writing by the data requestor have also been incorporated into the data unless otherwise noted in the Report Narrative. Chemistry data have been verified based on the ASB LOQAM specifications and may have been qualified if the applicable quality control criteria were not met. For a listing of specific data qualifiers and explanations, please refer to the Data Qualifier Definitions included in this report. The reported results are representative only of the samples as received by the laboratory.

Analyses Included in this report:

Method Used:

TCLP Volatiles (TCLPV) Toxicity Characteristic Leaching Procedure Volatile organic compounds

EPA 1311 EPA 8260C

Volatile Organics (VOA) Volatile organic compounds

Page 1 of 60

E104009 TCLPV VOA FINAL

EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Sample Disposal Policy Because of the laboratory’s limited space for long term sample storage, our policy is to dispose of samples on a periodic schedule. Please note that within 60 days of this memo, the original samples and all sample extracts and/or sample digestates will be disposed of in accordance with applicable regulations. The 60-day sample disposal policy does not apply to criminal samples which are held until the laboratory is notified by the criminal investigators that case development and litigation are complete.

These samples may be held in the laboratory’s custody for a longer period of time if you have a special project need. If you wish for the laboratory to hold samples beyond the 60-day period, please contact our Sample Control and provide a reason for holding samples Coordinator, Debbie Colquitt, by e-mail at beyond 60 days

Page 2 of6O

E104009 TCLPV VOA FINAL

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

SAMPLES INCLUDED IN TIllS REPORT

Project: 10-0629, Hercules Inc Sample ID

Laboratory ID

Matrix

Date Collected

ERBO1

E104009-01

Equipment Rinse Blank

9/23/10 13:30

10/1/10 8:35

HERCO1-A

E104009-03

Waste

9/28/10 10:10

10/1/10 8:35 10/1/10 8:35

Date Received

HERCO2-B

E104009-04

Waste

9/28/10 10:55

HERCO3-B

E104009-0S

Waste

9/28/10 13:15

10/1/10 8:35

HERCO4-B

E104009-06

Waste

9/28/10 13:50

10/1/10 8:35

HERCO5-A

E104009-07

Waste

9/28/10 14:05

10/1/10 8:35

HERCO6-B

E104009-08

Waste

9/28/10 14:55

10/1/10 8:35 10/1/10 8:35

HERCO7-B

E104009-09

Waste

9/28/10 15:25

HERCO8

E104009-10

Waste

9/29/10 08:50

10/1/10 8:35

HERCO9-B

E104009-11

Waste

9/29/10 14:20

10/1/10 8:35

HERCIO-B

E104009-12

Waste

9/29/10 14:15

10/1/10 8:35

HERC11-B

E104009-13

Waste

9/29/10 14:30

10/1/10 8:35

HERC12-B

E104009-14

Waste

9/29/10 14:50

10/1/10 8:35

HERC13-B

E104009-15

Waste

9/29/10 15:10

10/1/10 8:35

Page 3 of 60

El 04009 TCLPV VOA FINAL

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

DATA QUALIFIER DEFINITIONS

U D—4 H-S J NA-5

The analyte was not detected at or above the reporting limit.

NJ

Presumptive evidence that analyte is present; reported as a tentative identification with an estimated value.

0-2

Result greater than MDL but less than MRL.

0 C-i OL-1 OL-3 OR-I

Analyte concentration low in continuing calibration verification standard Laboratory Control Spike Recovery less than method control limits Laboratory Control Spike Precision outside method control limits MRL verification recovery less than lower control limits.

MRL elevated due to interferences. Recommended analytical holding time exceeded The identification of the analyte is acceptable; the reported value is an estimate. Not Analyzed. Cannot exceed TCLP regulatory levels based on Total Scan analyses,

ACRONYMS AND ABBREVIATIONS

CAS

Chemical Abstracts Service Note: Anal ytes with no known CAS identifiers have been assigned codes beginning with “E”, the EPA ID as assigned by the EPA Substance Registry System (www.epa.gov/srs), or beginning with “R4-”, a unique identifier assigned by the EPA Region 4 laboratory.

IvIDL

Method Detection Limit The minimum concentration of a substance (an analyte) that can be measured and reported with a 99% confidence that the analyte concentration is greater than zero.

MRL

Minimum Reporting Limit Analyte concentration that corresponds to the lowest demonstrated level of acceptable quantitation. The MRL is sample-specific and accounts for preparation weights and volumes, dilutions, and moisture content of soil/sediments.

TIC

Tentatively Identified Compound An analyte identified based on a match with the instrument software’s mass spectral library. A calibration standard has not been analyzed to confinn the compound’s identification or the estimated concentration reported.

-

-

Page 4 of 60

-

El04009 TCLPV VOA FINAL

Il/S/lO 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: ERBO1 Station ID:

E104009-01

Matrix: Equipment Rinse Blank

Date Collected: 9/23/10 13:30 C4S Niunher

4nalyte

Results Quali/ier.c

Units

MRL

1.0 U

ug/L

1.0 0.50 0.50

R4-7156

(m- andior p-)Xylene

630-20-6

1,1,1,2-Tetrachloroethane

0.50 U

ugIL

71-55-6

1,1,1 -Trichloroethane

0.50 U

ug/L

79-34-5

1,1,2,2-Tetrachioroethane

0.50 U

ug/L

0.50

76-13-1

I,1,2-Irichloro-1,2,2-Trifluoroethane

0.50 U

ug/L

0.50

(Freon 113) 79-00-5

1,1,2-Trichloroethane

0.50 U

ug/L

0.50

734-3

I,1-Dichloroethane

0.50 U

ugfL

0.50

75-35-4

1,1-Dichloroethene (1 ,1-Dichloroethylene)

0.50 U

ug/L

0.50

563-58-6

LI-Dichloropropene

0.50 U

ug/L

0.50

0.50 U

ug/L

0.50

87-61-6

1 ,2,3-Trichlorobenzene

96-18-4

1,2,3-Trichloropropane

0.50 U

ug/L

0.50

120-82-1

1 ,2,4-Trichlorobenzene

0.50 U

ug/L

0.50

95-63-6

1,2,4-Trimethylbenzene

0.50 U

ug/L

0.50

96-12-8

1,2-Dibromo-3-Chloropropane (DBCP)

1.0 U

ug/L

1.0

106-93-4

1,2-Dibromoethane (EDB)

0.50 U

ug/L

0.50

95-50-1

1,2-Dichlorobenzene

0.50 U

ug[L

0.50

107-06-2

1,2-Dichloroethane

0.50 U

ug/L

0.50

78-87-5

1,2-Dichioropropane

0.50 U

ugiL

0.50

108-67-8

1,3,5-Trinlethylbenzene

0.50 U

ugIL

0.50

541-73-1

1,3-Dichlorobenzene

0.50 U

ug/L

0.50

142-28-9

1,3-Dichloropropane

0.50 U

ug/L

0.50

106-46-7

1,4-Dichlorobenzene

0.50 U

ug/L

0.50

594-20-7

2,2-Dichloropropane

0.50 U

ug/L

0.50

67-64-1

Acetone

4.0 U

ugfL

4.0

71-43-2

Benzene

0.50 U

ugJL

0.50

108-86-1

Bromobenzene

0.50 U

ugfL

0.50

74-97-5

Bromochlorornethane

0.50 U

ug/L

0.50

75-27-4

Bromodichloromethane

0.50 U

ugfL

0.50

75-25-2

Bromoform

1.0 LI

ug/L

1.0

PageS of 60

E104009 TCLPV VOA FINAL

Prepared

.4nu(v:ed lkthad

0/04/10

10:0410

9:32 10/04/10 9:32

12:10 10/04/10 12:10

10/04110

10/04/10

9:32 10/04/10 9:32 10/04/10 9:32

12:10 10/04/10 12:10 10/04/10 12:10

10/04/10 9:32 10/04/10 9:32 10/04/10 9:32

10/04/10 12:10 10/04/10 12:10 10/04/10 12:10

10/04/10 9:32 10/04/10 9:32 10/04/10 9:32 10/04/10 9:32 10/04/10 9:32

10/04/10 9:32 10/04/10 9:32 10/04/10 9:32 1004/10 9:32 10/04/10 9:32 I004/10 9:32 10/04/10 9:32 10/04/10 9:32 10/04/10 9:32 10/04/10 9:32 10/04/10 9:32

10/04/jo 9:32 10/04/10 9:32 10/04/10 9:32 0/04/10 9:32 1004/10 932

EPA

8260C

EPA 8260C

EPA 8260C EPA

8260C

EPA 8260C

EPA 8260C EPA 8260C EPA 8260C

1004/10 EPA 8260C 2:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 9260U 12:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 1004/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 I0/04’IO EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 0/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10 10/04/10 EPA 8260C 12:10

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: ERBO1

E104009-01

Matrix: Equipment Rinse Blank

Station ID: Date Collected:

9/23/10 13:30

(Z IS .Vu,nher

.4nalyte

74-83-9

Bromomethane

Res,,IIy Qualifiers

Units

MRL

Prepared

ug/L

2.0

10/04/10

0.50 U

ug/L

0.50

10/04/It 9:32 0/04/10 9:32 10/04/10 9:32 10/04110 9:32

0.50 U

ug’L

0.50

10,04/10 9:32

10/04/10 12:10

EPA 8260C

0.50

10/04/10 9:32

10/04/10 12:10

EPA 8260C

0.50

10/04/I 0 9:32

10/04/10 12:10

EPA 9260C

10/04/10 9:32 10/04/10 9:32

10/04/10 1210

EPA 8260C

1004/10 12:10

EPA 8260C

0.50

10/04/10

10/04/10 12:10

EPA 8260C

1004/10

2.0 U

75-15-0

Carbon disulfide

0.50 U

ug/L

0.50

56-23.5

Carbon Tetrachioride

0.50 U

ug/L

0.50

108-90-7 75..1J{).3

67-66-3 74-87-3

156-59-2 10061-01-5 110-82-7 124-48-1

Chlorobenzene Chioroethane Chloroform Chioromethane cis-1 ,2-Dichloroethene cis- I ,3-Dichloropropene

0.50 U

ugfL

0.50 U, J. QC-l

ug!L

0.50 U 0.50 U 0.50 U

Cyclohexane Dibromochloromethane

lnavzed Method

ug/L ug!L oWL

0.50 0.50

0.50 U

ugL

0.50 0.50 0.50

74-95-3

Dibromomethane

0.50 U

ugIL

75-71-8

Dichlorodifluoromethane (Freon 12)

0.50 U, J, QC-1

ug/L

9:32 9:32 10/04/10 9:32 10/04/10

12:10

EPA 8260C

10/04/10 12:10

EPA 8260C

1004.10 12:10

EPA 8260C

0/04/10 12:10

EPA 8260C

10/04/10 12:10

EPA 8260C

10/04/10 12:10

EPA 8260C

10/04/10 12:10

EPA t26OC

10/04/10

100-41-4

Ethyl Benzene

0.50 U

uWL

0.50

9:32 10/04/10 9:32

12:10

EPA 8260C

87-68.3

Hexachiorobutadierie

0.50 U

ug/L

0.50

1004/10 9:32

10/04/10 12:10

EPA 8260C

0.50 U

ugIL

0.50

10/04/10

10/04/10 12:10

EPA 8260C

98-82-8 79-20-9

Isopropylbenzene Methyl Acetate

1.0 U

ug/L

1.0

591-78-6

Methyl Butyl Ketone

1.0 U

ug/L

1.0

78-93-3

Methyl Ethyl Kclone

1.0 U

ug/L

1.0

108-10-1 1634-04-4 108-87-2 75-09-2 104-51-8 103-65-1 95-49-8 95-47-6

Methyl Isobutyl Ketone Methyl T-Butyl Ether (MTBE) Methylcyclohexane Methylene Chloride

1.0 U

ug/L

1.0

0.50 U

ug/L

0.50

10/04/10

0.50

10/04/10

0.50

10/04/10

0.50 U

ug/L

0.50 U

ug/L ugJL

n-Propylbenzene

0.50 U

ugJL

0.50

o-Chlorotoluene

0.50 U

ug/L

0.50

o-Xylene

0.50 U

ug/L

0.50 0,50 0.50

106-43-4

p.Chlorotoluene

0.50 U

ugIL

99-87-6

p-lsopropyltoluene

0.50 U

ug/L

0.50 U

ug/L

135-98-8 100-42-5

Page 6 of6O

0.50

0.50 U

n.Bulylbenzene

sec-Butylbenzene

2.0 U

Styrene

El04009 TCLPV VOA FINAL

9:32 10/04/10 9:32 10/04/10 9:32 10/04/10 9:32 0/04/It 9:32

ug/L

0.50 2.0

9:32 9:32 9:32 10/04/10 9 32 10/04/10 9:32 10/04/10 9:32 10/04/10 9:32 10/04/10 9:32 10/04/10 9:32 10/04/10 932 10 0410

932

10/04/10 12:10

EPA 8260C

10/04/It 12:10

EPA 8260C

10/04/10 12:10

EPA 8260C’

10/04/10 I2:10

EPA 8260C

1004/10 12:10

EPA 8260C

10/04/10 12:10

EPA 8260C

0/04/tO 12:10

EPA 8260C

10/04/10 12:10 10/04/10 12:10

10/04/10 12:10

10/04/10 12:10 0104110 I2:10 10/04/10 12:10 10/04/10

12:10 10.04/10 12:10

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: ERBO1 Station ID:

E104009-01

Matrix: Equipment Rinse Blank

Date Collected: 9/23/10 13:30

c.1s Number

.dntilyte

Results Qualifiers

98-06-6

tert-Butylbenzene

127-18-4

Units

MRL

Prepared

0.50

10/04/10 932 10/04/10 9:32

10/04/10 1210 10/04/10 12:10

0/04/10

10104/10

932 10/04/10 9:32

10/04/10

10.04/10

1004/10

12:10 10/04/10 12:10

toofred Method

0.50 U

ug/L

Tetrachloroethene (Teti-achloroethylene)

0.50 U

ugfL

0.50

108-88-3

Toluene

0.50 U

ug!L

0.50

156-60-5

tmns-1,2-Dichloroethene

0.50 U, J, QL-1

UgfL

050

10061-02-6

trans-l.3-Dichloropropene

0.50 U

ug/L

0.50

79-01-6

Trichioroethene (Trichloroethylene)

0.50 U

ug/L

0.50

9:32 10/04/10 9:32

75’-69-4

Trichiorofluoromethane (Freon II)

0.50 U

ugIL

0.50

10,04/10 9:32

1004/10 12:10

EPA 8260C

75-01-4

Vinyl chloride

0.50 U

ug/L

0.50

10/04/10 9:32

10/04/10 12:10

EPA 8260C

10 U

ug/L

10

10/04/10 932

10.0310

12:10 12:10

EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C

Tentatively Identified Compounds: R4-0000

Page 7 of 60

Tentatively Identified Compounds

E104009 TCLPV VOA FINAL

210

El’A 9260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules mc- Reported by Kristin Trapp

TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: ERBOI

E104009-01

Matrix: Equipment Rinse Blank

Station ID: Date Collected: 9/23/10 13:30 (‘AS

Resulis Qualifiers

Vu,nher

.4nalyte

75-35-4

Il-Dichloroethene (l.l-Dichloroethylene):

107-06-2

1,2-Dicbloroethane:

106-46-7

l.4-Dichlorohcnzcnc:

NA-5

Unigs

t1fRL

Prepared

0.00050

10/13/10 15:00 10/13/10

\A5

0.00050

NA-5

0.00050

1500

87-68-3

Hexachiorobutadiene:

\A5

0.00050

10/13/10 15:00 10113/10 1500 10/13/10 5:00 10/13/10 15:00 10/13/10 15:00 10/13/10 15:00

78-93-3

Methyl Ethyl Ketone:

NA-S

0.00 10

10/13/10 15:00

127-18-4

Tetrachloroethene (Tetrachloroethylene):

NA-5

0.00050

71-43-2

Benzene:

NA-5

0.00050

56-23-5

Carbon Telrachioride:

NA-S

0.00050

108-90-7

Chlorobenzene:

NA-S

0.00050

67-66-3

Chloroform:

NA-5

0.00050

79-01-6 75-01-4

Page 8 of 60

Trichloroethene (Trichioroethylene): Vinyl chloride:

NA-S NA-5

E104009 TCLPV VOA FINAL

0.00050 0.00050

10/13/11) 151)0

10/13/10

.1 nat rzed lie/hod 10/13/10 15:00 10/13/10 15:00 10/13/10 15:00 10/13/10 151)0 10/13/10 15:00 0/13/10 15:00 10/13/10 15:00 10/13/10 15.00 10/13/10 15:00

10/13/10 1500 10/13/10

15:00

1500

10/13/10 15:00

10/13/10 15:00

EPA 826CC EPA 826CC EPA 8260C EPA

826CC

EPA 826CC EPA

826CC

EPA

826CC

EPA

8260C

EPA 8260C EPA 826CC EPA 826CC EPA 826CC

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO1-A Station ID: HERCO1

E104009-03

Matrix: Waste

Date Collected: 9/28/10 10:10 C4S Number

.4nalyie

Res uii Quai/iers

Units

MRL

R4-7156

(m- and/or p-)Xylene

5.1 J,Q-2

mg/kg

98

630-20-6

1,1,1 ,2-Tetrachloroethane

9.8 U

mg/kg

7.0

7 1-55=6

1,1 ,1-Trichloroethane

9.8 U

mg/kg

(1 Q

79=34-5

1,1 ,2,2-Tetrachloroethane

9.8 U

mg/kg

A 0

76-13-I

1,1 ,2-Trichloro- 1 ,2,2-Trifluoroethane

9.8 U

mg/kg

98

9.8 U

mg/kg

n

Prepared

12:10 10/06/10 12:10 10/06/10 1210 10106/10 12:10 10/06/10 12:10

10/07/10 15:00 10/07/10 15:08 l007 0 15:08 10/07/10 15:08 10/07/10 15:08

10/06/10 12:10 10/06/10 12:10 10/06/10 12:10

10/07/10 15:08 10/07/10 1508 10/07/10 15:08

10/06/10 12:10 10/06/10 12:10 18/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 I0’06’10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10)06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 I2:I0

10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 10/07/10 15-08 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 1007/10 15:08 10/07/10 15:08 I0’07/I0 15:08 10/07/10 15:08 1007/10 15:08 10/07/10 15:08 10/07/10 15:08

10/06110

(Freon 113) 79-00-5

1 ,1,2-Trichloroethane

Q

1,1 -Dichloroethane

9.8 U,J.QL-1

mg/kg

9 8

75-35-4

1 ,l-Dichloroethene (1 ,1-Dichloroethylene)

9.8 U

mg/kg

A 0

563-58-6

1,1 -Dichloropropene

9.8

U

mg/kg

87-61-6

I ,2,3-Trichlorobenzene

9.8

L

mg/kg

96-18-4

I ,2,3-Trichloropropane

9.8 U

mg/kg

9 8

120-82-1

1,2,4-Trichlorobenzene

9.8 U

mg/kg

o o

95-63-6

1 ,2,4-Trimethylbenzene

3.9 J, Q-2, QR-l

mg/kg

9 8

96-12-8

1 ,2-Dibromo-3-Chloropropane (DBCP)

20 U

mg/kg

‘)A

106-93-4

1 ,2-Dibromoethane (EDB)

9.8 U

mg/kg

9 8

95-50-1

1 ,2-Dichlorobenzene

9.8 U

mg/kg

A 0 7.0

107-06-2

1 ,2-Dichloroethane

9.8 U

mg/kg

98

78-87-5

1 ,2-Dichloropropane

9.8 U

mg/kg

A 0

108-67-8

1 ,3,5-Trimethylbenzene

9.8 U

mg/kg

c,

541-73-1

1 ,3-Dichlorobenzene

9.8 U

mg/kg

A 0

142-28-9

1 ,3-Dichloropropane

9.8 U

mg/kg

106-46-7

I ,4-Dichlorobenzene

9.8 U

mg/kg

594-20-7

2,2-Dichloropropane

9.8 U

mg/kg

98

67-64-1

Acetone

78 U

mg/kg

‘,o

mg/kg

o

mg/kg

A 0

mg/kg

9 8

A 0

0

‘°

7 1-43-2

Benzene

108-86-1

Bromobenzene

9.8 U

74-97-5

Bromochioromethane

9.8 U, J,

75-27-4

Bromodichioromethane

9.8 U

mg/kg

A 0

75-25-2

Bromoform

20 U

mg/kg

2O

Page 9 of 60

18

E104009 TCLPV VOA FINAL

QL-1

.4nalv:ed ,8lethod

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA

8260C

EPA 8260C EPA

8260C

EPA 8260C EPA 8260C EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCOI-A

E104009-03

Matrix: Waste

Station ID: HERCOI Date Collected: 9/28/10 10:10 cds Nwnher

.4nalyte

74-83-9

Bromomethane

Results Qualifiers

39 U

Units

mg/kg

75-15-0

Carbon disulfide

5.3 J, Q-2

mg/kg

56-23-5

Carbon Tetrachioride

9.8 U

mg/kg

MRL

Prepared

39

10/06/10 12:10

o

9 8

Q

108-90-7

Chlorobenzene

9.8 U

mg/kg

98

75-00-3

Chloroetharie

9.8 U

mg/kg

9 8

67-66-3

C:hlorofo

9.8 U

mg/kg

9 8 9 8

74-87-3

(‘hioromethanc

9.8 U

mg/kg

156-59-2

cis-1 ,2-Dichloroethene

9.8 U

mg/kg

9 8 9 8

10061-01-5

cis- I ,3-Dichloropropene

9.8 U

mg/kg

110-82-7

Cyclohexane

110

mg/kg

9 8

124-48-1

Dibromochioromethane

9.8 U

mg.’lg

o

74-95-3

Dibromomethane

9.8 U, J, QL-1

mg/kg

98

75-71-8

Dichiorodifluoromethane (Freon 12)

9.8 U

mg/kg

9 8

mg/kg

9 8

mg/kg

9 8

100-41-4

Ethyl Benzene

2.4 J, Q-2

87-68-3

Hexachlorobutadiene

9.8 U

98-82-8

Isopropylbenzene

16 U, D-4

mg/kg

79-20-9

Methyl Acetate

20 U

mg/kg

591-78-6

Methyl Butyl Ketone

20 U

mg/kg

78-93-3

Methyl Ethyl Ketone

20 U

mg/kg

0

I6 2n

2O

108-10-1

Methyl Isobutyl Ketone

20 U

mg/kg

2O

1634-04-4

Methyl T-Butyl Ether (MTBE)

9.8 U

mg/kg

98

108-87-2

Methylcyclohexane

6.9 J, Q-2

mg/kg

9 8 9 8 o

75-09-2

Methylene Chloride

9.8 U

mg/kg

104-51-8

n-Butylbenzene

9.8 U

mg/kg

9

8

9

8

103-65-1

n-Prop lbenzene

9.8 U

mg/kg

95-49-8

o-Chlorotolucne

9.8 U

mg/kg

9.8 U

mg/kg

9 8

9.8 U

mg/kg

9 8

95-47-6

o-Xylene

106-43-4

p-Chlorotoluene

99-87-6

p-lsopropyllolucne

135-98-8

sec-Butylbenzene

100-42-5

Styrene

Page lOof6O

E104009 TCLPV VOA FINAL

mg/kg

98

9.8 U

mg/kg

9 8

39 U

nig’lg

39

1100

10/06/lU 12:10

10:06/10 12:10 10/06/111 12:10 10/06/10 12:10 10/06/10 12,18 10/06/10 12:10 10/06/10 12:10 10:06.10 12:10 10/06/10 12:10 10/06110 12:10 10/06/10 12:10 (0/06/10 12:10 10/06/10 (2:10 10/06/10 12:10 10/061(0 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:1(1 10/06/10 12:10 10/I16/10 12:10 2:10 10/06/10 2:10 10/06/10 12:10 10/06/10 (210 10/06/10 12:10 0/06/10 12(0 10/06/10 12:10

.4nulyzed ,ttethod 10/07/10 15:00 10’07/l0 15:08 10/07/10 15:08 10/07/lU 15:08 10/07/10 15:08 10/07/10 15:08 (0/07/10 (5:08 l007/10 15:08 10.07/10 15:08 10/07/10 15:08 10/07,10 15:00 10/07/10 15:08 10/07/tO 15:00 10/07/10 15:08 10/07/10 15:00 15:08 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 0/07/10 15:08 10/07/10 (5:08 0/07/10 15.08 10/07/10 15:08 0/07/Ia 15:08 10/07/10 15:08 0/07/ID 15:08 10/07/10 15:08 10/07/10 1508 10,07:10 5:08

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA

8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA

8260C

EPA 8260C EPA 8260C EPA 8260C EPA

8260C

EPA

8260C

EPA 8260C EPA

8260C

EPA

8260C

EPA

8260C

EPA 8260C EPA

8260C

EPA

8260C

EPA 8260C EPA

8260C

EPA 8260C EPA 8260C EPA 8260C

11/8/10

9:52

0

0

UNiTED STATES ENWRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO1-A Station JD: HERCO1

E104009-03

Matrix: Waste

Date Collected: 9/28/10 10:10 CAS Number

.4nuiyre

Results Qualifiers

Units

4IRL

Prepared

98-06-6

tert-Butylbenzene

127-18-4

Tetrachloroethene (Tetrachloroethylene)

108-88-3

Toluene

156-60-5

trans-l,2-Dichloroethene

9.8 U

mg/kg

9.8

10061-02-6

trans-1.3-Dichloropropenc

9.8 U

mg/kg

9.8

79-01-6

Trichloroethene (Tnchloroethylene)

9.8 U

mg/kg

9.8

75-69-4

Trichlorofluoromethane (Freon II)

9.8 U

mg/kg

9.8

75-01-4

Vinyl chloride

9.8 U

mg/kg

9.8

10/06110 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10,06/10 12:10 10/06)10 12:10 1006,10 2:10 10/06/10 12:10

200 U

mg/kg

200

10/06/10 12:10

9.8 U

mg/kg

9.8

9.8 U

mg/kg

9.8

7100

mg/kg

.4na!:ed tfethod 10/07/10 15:08 10/07/10 15:08 1008/10 13:10 10/07/10 15:08 10/07/10 15:08 10/07/10 15:08 10/07110 15:08 10/07/10 15:08

EPA 826CC

10/07/10 508

EPA 826CC

EPA 8260C

EPA 826CC EPA 8260C

EPA 826CC

EPA 826CC

EPA 826CC EPA 826CC

Tentatively Identified Compounds: R4-0000

Page 11 of6O

Tentatively Idenlitied Compounds

E104009 TCLPV VOA FINAL

11/8/10

9:52

0 \‘D

_x

0

UN ITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-270() t

DART. Id. 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:

Saniple ID: IIERCO1-A

E104009-03

Matrix: Waste

Station ID: HERCOI Date Collected: 9/28/10 10:10 C4S Niunber

Results Quakfiers

.inulyte

Units

IRL

Prepared

.4navzed Ole/hod

0.10 U

mg/L

0.10

10/13/10 15:00

10/13/b 15:23

107-06-2

1,! -Dichloroethene (1,1 -Dichloroethylene) 1 ,2-Dichloroethane

0.10 U

mgIL

0.10

10/13/10

106-46-7

1,4-Dichlorobenzene

0.10 U

mg/L

0.10

10/13/10 15:00 10/13/10

75-35-4

71-43-2

Benzene

56-23-5

Carbon Tetrachloride

108-90-7 67-66-3 87-68-3

Chlorobenzene Chloroform Hexachlorobutadiene

15-00

15:23

10/13/10

0.21

mg/L

0.10

10/13/Ia 15.00

15:23

0.10 U

mgL

0.10

10(13.10

0.10

10/13/10

0 1310 15:23 10/13/10 1523

0.10 U

mg/L

0.10 U

mg/L

0.10 C

mgJL

0.10 0.10

15:00 15:00 10:13/10

15:00 10/13/10

15:23

Methyl Ethyl Kelone

0.20 U

mg/L

0.20

127-18-4

Tetrachloroethene (Tetrachloroethylene)

0.10 U

mgfL

0.10

10/13,10

79-01-6

Trichloroethcne (Trichloroethylene)

0.10 U

mg/L

0.10

0.10 U

mg/L

0.10

10/13/10 5:00 10/13/la 15:00

Page 12 of6O

E104009 TCLPV VOA FINAL

10/13/10 101310 5:23 10/13/10 15:23 10/13/10 5:23 10/13/10 15:23

78-93-3

Vinyl chloride

l0/13il0 15:23

15:00

0/13-10

75-01-4

15:23

10/13/10

15:00 15:00

EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO2-B

E104009-04

Matrix: Waste

Station ID: HERCO2 Date Collected: 9/28/10 10:55 CAS Number

.dnalyte

R4-71 56

(m- andlor p-)Xylene

630-20-6 71-55-6

Results Qualifiers

Units

MRL

25 U

mg/kg

2S

1,1,1 ,2-Tetrachloroethane

25 U

mg/kg

2S

I ,1,1-Trichloroethane

25 U

mg/kg

25 • ‘S

79-34-5

1,1 ,2,2-Tetrachloroethane

25 U

mg/kg

76-13-1

1,1 ,2-Trichloro- 1 ,2,2-Trifluoroethane (Freon 113)

25 U

mg/kg

25

79-00-5

1,1 ,2-Trichloroethane

25 U

mg/kg

-‘5

1,1-Dichioroethane

25 U,J,QL-1

mg/kg

25

75-35-4

1,1 -Dichloroethene (1,1 -Dichloroethylene)

25 U

mg/kg

2e

563-58-6

1,1 -Dichloropropene

25

mg/kg

25

87-61-6

1 ,2,3-Trichlorobenzene

25 U

mg/kg

-‘5

25

96-18-4

1 ,2,3-Trichloropropane

25 U

mg/kg

120-82-1

I ,2,4-Trichlorobenzerie

25 U

mg/kg

‘S

95-63-6

1 ,2,4-Tnmethylbenzene

7.0 J, Q-2, QR-l

mg/kg

2S

96-12-8

1 ,2-Dibromo-3-Chloropropane (DBCP)

50 U

mg/kg

S”

106-93-4

1,2-Dibromoethane (EDB)

25 U

mg/kg

25

95-50-1

I ,2-Dichloroben.zene

25 U

mg/kg

2S

107-06-2

1 ,2-Dichloroethane

25 U

mg/kg

-,

78-87-5

1 ,2-Dichloropropane

25 1

mg/kg

-‘S

108-67-8

I ,3,5-Trimethylbenzene

25 U

mg/kg

2S 25

541-73-1

I ,3-Dichlorobenzene

25 U

mg/kg

142-28-9

I .3-Dichioropropane

25 U

mg/kg

—,

‘,

106-46-7

1 4-Dich1orobenzene

25 U

mg/kg

594-20-7

2,2-Dichloropropane

25 U

mg/kg

-‘5

mg/kg

-,n

67-64-i

Acetone

71-43-2

Benzene

108-86-1

Bromobenzene

200 U

25

37

mg/kg

25

25 U

mg/kg

-‘5

74-97-5

Bromochioromethane

25 U,J.QL-1

mg/kg

25

75-27-4

Brotnodichioromethane

25 U

mg/kg

25

75-25-2

Bromoform

50 U

mg/kg

5O

Page 13 of6O

E104009 TCLPV VOA FINAL

Prepared

.4naly.ed Method

10/06110 12:10 10/06/10 12:10 1006/10 12:10 10/06/10 12:10 10/06/10 12:10

10/07/10 15:34 10/07/10 15:34 10/07/10 15:34 10/07/10 15:34 10/07/10 15:34

10/06/10 12:10 10/06110 12:10 10/06/10 12:10

10/07/10 15:34 10/07/10 15:34 10/07/10 15:34

EPA 8260C

10/06110 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10i06/l0 12-10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10:06110 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10

100710 15:34 10/07/10 15:34 1007.10 15:34 10/07/10 15:34 10/07/10 15:34 10/07/10 15:34 10i07/I0 15:34 10/07/10 15:34 10/07/10 15:34 10/07/10 15:34 00710 15:34 10/07/10 15:34 1007/10 15:34 10/07/10 15:34 10/07/10 15:34 10/07/10 15:34 10/07/10 15:34 10/07/10 15:34 10/07/10 15:34 10/07/10 15:34 10/07/10 15:34

EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id. 10-0629

Project: 10-0629, Hercules Inc

-

Reported by Kristin Trapp

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO2-B

Matrix: Waste

Station ID: HERCO2 Date Collected: CAS Number

74-83-9

E104009-04

9/28/10 10:55 Results Qiiali/iers

4nu4vte

Bromomethane

UniL6

MRL

Prepared

.4nav:ed Method

100

10/07/10 15:34

EPA 8260C

mg/kg

25

EPA 8260C

25

10/07/10 15:34 10/07/10

100 U

mg/kg

75-15-0

Carbon disulfide

25 U

56-23-5

Carbon Tetrachioride

25 U

mg/kg

25

I/20/c0

15:34

EPA 8260C

25

ICk/0

10/07/10 15:34

EPA 8260C EPA 8260C

108-90-7

Chlorobenzene

25 U

mg/kg

75-00-3

Chloroethane

25 U

mg/kg

67-66-3

Chloroform

74-87-3

Chiorornethane

156-59-2 10061-01-5

110-82-7 124-48-1

cis- I ,2-Dichloroethene cis- I ,3-Dichloropropene Cyclohexane

EPA 8260C

25 U

mg/kg

25

19//0

10,07/10

25 U

mg/kg

25

I9//0

10/07,10

15:34

EPA 8260C

10,06/b

10/07/I 0 15:34

EPA 8260C

9/0

1007/10

EPA 8260C

25 U

mg/kg

25 U

mg/kg

190

Dibromochloromethane

l5:34

10/07/10

25 U

mg/kg mglcg

25 25

15:34 10/07/10

25 25

I5:34

10/06/10

12:10

15:34

EPA 8260C

10/07/I 0 15:34

EPA 0260C

10/137/10 15:34 10/07/10 15:34

EPA 8260C

Dibromomethane

25 L,JQL-l

mg/kg

25

75-71-8

Dichlorodifluoromethane (Freon 12)

25 U

mg/kg

25

100-41-4

Ethyl Benzene

65 I. Q-2

mg/kg

25 1 9’d°

10/07/10 15:34

EPA 8260C

87-68-3

Hexachlorobutadiene

25 U

mg/kg

25

10/07/10 I5:34

EPA 8260C

25 U

mg/kg

25

10/07/10

EPA 8260C

74-95-3

98-82-8 79-20-9

Isopropylbenzene Methyl Acetate

mg/kg 50 50

591-78-6

Methyl Butyl Ketone

50 U

78-93-3

Methyl Ethyl Ketone

50 U

mg/kg

108-10-1 1634-04-4

Methyl lsobutyl Ketone Methyl T-Butyl Ether (MTBE)

108-87-2

Methylcyclohexane

75-09-2

Methylene Chloride

104-51-8 103-65-I

95-49-8

n-Butylbenzene n-Propylbenzene o-Chlorotoluene

50 U 25 U

mg/kg mg/kg

15:34

I 0/07)10

50 U

mg/kg

11/05/10

25

12:10 I9//0

15:34

10/07/10 121

5:34

EPA 8260C

‘9,°

10/07/10 15:34

EPA 8260C

25

I0

25 U

mglcg

25

I/20/0

25

25 U

mg/kg

25

25 U

mg/kg

l9/1/0

25 U

mg/kg

25

25 U

mg/kg

25

10/26/It

mILk e

25

135-98-8 100-42-5

Styrene

Page 14of60

El 04009 TCLPV VOA FINAL

25 U 100 U

mg/kg

EPA 8260C

15:34

o-Xylene

mg/kg

EPA 8260C

10/07/1 0 5:34 10/07/10 I5:34

10/07/10

p-Chlorotoluene

1700

EPA 8260C

2:10

106-43-4

p-Isopropyltoluene

15:34 10.07/10 15:34

25

95-47-6

sec-E3utylbenzene

0/07/10

10/07/10 9/0

99-87-6



15:34 I0/07/l0 I 5:34 I0:07,I0 15:34

10/06/b

100

EPA 8260C

2:10

mg/kg

mg/kg

I5:34

EPA 8260C EPA 8260C

10/07/10

17 J, Q-2

25 U

15:34

10/07/10

EPA 0260C

1210

I(//0

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

I0/07/I0 15:34

EPA 8260C

10/07/10 15:34

EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules nc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: IIERCO2-B Station ID: HERCO2

E104009-04

Matrix: Waste

Date Collected: 9/28/10 10:55 CAS Number

.4nalyte

98-06-6

tert-Butylbenzene

25 U

mg/kg

127-18-4

Tetrachloroethene (Tetrachloroethylene)

25 U

mg/kg

25

108-88-3

Toluene

mg/kg

120

156-60-5

Uans-1,2-Dichloroethene

10061-02-6

trans-1.3-Dichloropropene

79-01-6

Resuli Qualifiers

Units

MRL

25

Prepared

25 U

mg/kg

25

25 U

mg/kg

25

Trichloroethene (Trichloroethylene)

25 U

mg/kg

25

75694

Trichlorofluoromethane (Freon II)

25 U

mg/kg

25

75-01-4

Vinyl chloride

25 U

mg/kg

25

12:10 10/06/10 12:10 °°“° 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10

500 U

mg/kg

500

10/06/10 210

16000

lnalyed 10/07/10 15:34 10/07/10 10/08)10 3:36

10/07/10 15:34 10/07/tO 15:34 10/07/10 15:34 10)07/10 15:34 10/07/10 15:34

Itethod EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C

Tentatively Identified Compounds: R4-0000

Page 15 of6O

Ten1atieIy Identified Compounds

E104009 TCLPV VOA FINAL

10/07/10

EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 1 0-0629, Hercules Inc Reported by Kristin Trapp -

TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO2-B

E1040094J4

Matrix: Waste

Station ID: HERCO2

Date Collected: 9/28/10 10:55 C.4S Results Quahflers

AVU,aber

.4nalyte

75-35-4

l,l-Dichloroethene

Units

MRL

Prepared

0.12 U, J, H-8

mg/L

0.12

10/21/10

10/21/10 15:00 10/21/10

15:00

.4naiy:ed ,lfethod 10/21/10 18:30

EPA 8260C

10/21/10 18:30 10/21/10 18:30 10/21/10 18:30 10/21/10 18:30 10/21/10 18:30 10/21/10 1830 10/21/10 830 10/21/10 18:30 1021/10 1830 10/21/10

EPA 8260C

(1,1 -Dichloroethylene) 107-06-2

1,2-Dichloroethane

0.12 U, J, 14-8

mgfL

0.12

106-46-7

1.4-Dichlorobenzene

0.12 U, J, H-S

mg!L

0.12

71-43-2

Benzene

0.62 J, 1-1-8

mg/L

0.12

56-23-5

Carbon Tetrachloride

0.12 Ii, J, 1-1-8, QL-3

mg/L

0.12

108-90-7

Chlorobenzene

0.12 U, J, H-S

mg/L

0.12 0.12

5:00

10/21/10 15:1)0 10,21/10 1500

10/21/10 1508 10,21/10 1500 10/21/10 15:00 10,21/10

67-66-3

Chloroform

0.12 U, J, H-8

mg/L

87-68-3

Hexachlorobutadiene

0.12 U. J, Fl-S

mgJL

0.12

78-93-3

Methyl Ethyl Ketone

0.25 U, J, H-8

mg/L

0.25

127-18-4

Tetrachloroethene (Tefrachloroethylene)

0.12 U, J, H-S

mg/L

0.12

0/21/10

5.00 15:00

79-01-6

Trichloroethene (Trichloroet.hylene)

0.12 U, J, H-8

mg/L

0. 12

10/21/10 1500

830

75-01-4

Vinyl chloride

0.12 U, J. 11-8

mg/L

0.12

10/21/10 1500

10/21/10 18:30

Page 16of60

E104009 TCLPV VOA FINAL

EPA 8260C EPA

8260C

EPA 8260C

EPA 8260C EPA 8260C EPA

8260C

EPA 8260C EPA

8260C

EPA 8260C EPA

8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc

-

Reported by Kristin Trapp

Volatile Organics Project: 10-0629, Hercules Inc Lab iD:

Sample ID: HERCO3-B

Station ID: HERCO3

E104009-05

Matrix: Waste

Date Collected: 9/28/10 13:15 C4S Number

.4naly:e

R4-7 156

(m- and/or p-)Xylene

630-20-6

Recalls Qualifiers

Unils

MRL

Prepared

.lna(vzed

0.76 J, Q-2

mg/kg

0.97

1,1,1 ,2-Tetrachloroethane

0.97 U

mg/kg

0.97

71-55-6

1,1,1 -Trichloroethane

0.97 U

mg/kg

0.97

79-34-5

1,1 ,2,2-Tetrachloroethane

0.97 U

mg/kg

0.97

10/08/10 16:38 10/08/10 16:38 10/08.10 16:38 10/08/10 16:38

EPA 8260C

76-13-1

1.1 ,2-Trichloro- I ,2,2-Trifluoroethane (Freon 113)

0.97 U

mg/kg

0.97

10/06/10 12:10 10/06/10 12:10 10.06/10 12:10 10/06/10 12:10 10.06/10 12:10

10.08.10 16:38

EPA 8260C

79-00-5

1,1 ,2-Trichloroethane

0.97 U

mg/kg

0.97

10/08/10 16:38

EPA 8260C

75.33

1,1 -Dichloroethane

0.97 U, J, QL-l

mg/kg

0.97

75-35-4

1 ,1-Dichloroethene (1 ,1-Dichloroethylene)

0.97 U

mg/kg

0.97

10/06/10 12:10 10/06/10 12:10 10/06/10 12:10

563-58-6

1,1-Dichioropropene

0.97 U

mg/kg

0.97

87-61-6

1 ,2,3-Trichlorobenzene

0.97 U

mg/kg

0.97

10/08.10 12:10 10/06/10 12:10

96-18-4

1 ,2,3-Trichloropropane

0.97 U

mg/kg

0.97

10.06/10 12:10

120-82-1

1 ,2,4-Trichlorobenzene

0.97 U

mg/kg

0.97

95-63-6

1 ,2,4-Trimethylbenzene

2.1

mg/kg

0.97

10/06/ID 12:10 10/06/10

96-12-8

1 ,2-Dibromo-3-Chloropropane (DBCP)

1.9 U

mg/kg

1.9

106-93-4

I 2-Dibromoethane (EDB)

0.97 U

mg/kg

0.97

95-50-1

1 ,2-Dichlorobenzene

0.97 U

mg/kg

0.97

10/06/10 12:10

107-06-2

1 ,2-Dichloroethane

0.97 U

mg/kg

0.97

10/06/10 12:10

78-87-5

1 ,2-Dichloropropane

0.97 U

mg/kg

0.97

108-67-8

I ,3,5-Irimethylbenzene

0.97 U

mg/kg

0.97

541-73-1

I ,3-Dichlorobenzene

0.97 U

mg/kg

0.97

142-28-9

I ,3-Dichloropropane

0.97 U

mg/kg

0.97

106-46-7

I ,4-Dichlorobenzene

0.97 U

mg/kg

0.97

594-20-7

2,2-Dichioroproparie

0.97 U

mg/kg

0.97

67-64-1

Acetone

7.8 C

mg/kg

7.8

71-43-2

Benzene

108-86-1

Bromobenzene

74-97-5

Bromochioromethane

10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 1006/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 2:10 10/06/10

75-27-4

Bromodichloromethane

75-25-2

Bromoform

1.9 U

Page 17 of6O

12:10

mg/kg

0.97

mg/kg

0.97

0.97 U, J, QL-1

mg/kg

0.97

0.97 U

mg/kg

0.97

10/06/10 12:10

mg/kg

1.9

10/06/10

3.4

0.97 U

E104009 TCLPV VOA F1i’4AL

12:10

10/06/10 12:10 10/06/10

2:10

12:10

10/00/10

16:38 10/08/10 16:38

Ofethod

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

10,08/10 16:38 10/08/10 16:38 10/08110 6:38 10/08/10 16:38 10/08/10 16:38 10/08/10 16:38 10/08/10 16:38 10/08/10 16:38 1008/10 16:38 10/08.’lO 16:38 10/08/10 16:38 10/08/10 16:38 10/08/10 16:38 10/08/10 16:38 10,08/10 16:38 10/08/10 16:38 10/08/10 16:38 10/08/10 16:38 10/08/10 16:38 10/08/10 16:38

EPA 8260C

10/08/10 16:38

EPA 8260C

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EI’A

8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 1 0-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO3-B

E104009-05

Matrix: Waste

Station ID: HERCO3 Date Collected: 9/28/10 13:15 ( I.S .Vituiher

.lnalyte

74-83-9

Bromomethane

Results Qualifiers

Units

MRL

39 U

mg/kg

0.97

75-15-0

Carbon disulfide

0.97 C

mg/kg

56-23-5

Carbon Tetrachloride

0.97 U

mg/kg

0.97

108-90-7

Chlorobenzene

0.97 C

mg/kg

0.97

75-00-3

Chloroethane

0.97 U

mg/kg

0.97

67-66-3

Chloroform

0.97 U

mg/kg

0.97 0.97

0.97

74-87-3

Chloromethane

0.97 U

mg/kg

156-59-2

cis-1,2-Dichloroethene

0.97 C

mg/kg

0.97

0.97

10061-01-5

cis-1,3-Dichloropropene

0.97 U

mg/kg

110-82-7

Cyclohexane

0.97 U

mg/kg

124-48-I

Dibromochloromethane

0.97 U

mg/kg

0.97

mg/kg

0.97 0.97

74-95-3

Dibromomethane

0.97 C

75-71-8

Dichlorodifluoromethane (Freon 12)

0.97 U

mg/kg

0.62 .1, Q-2

mg/kg

0.97

0.97 U

mg/kg

0.97

100-41-4

Ethyl

87-68-3

Flexachlorobutadiene

Benzene

3.9 C, D-4

98-82-8

lsopropylbenzene

79-20-9

Methyl Acetate

59 1-78-6

Methyl Butyl Ketone

78-93-3

mg/kg mg/kg

1.9

1.9 U

mg/kg

1.9

Methyl Ethyl Ketone

1.9 U

mg/kg

1.9

108-10-1

Methyl Isobutyl Ketone

1.9 C

mg/kg

1.9

1634-04-4

Methyl T-Butvl Ether (MTBE)

0.97 U

mg/kg

0.97

108-87-2

Methylcyclohexane

mg/kg

0.97

0.97 U

mg/kg

0.97

1.2

mg/kg

0.97 0.97

0.72 J, Q-2

75-09-2

Methylene Chloride

104-51-8

n-Butylbenzene

8.6

103-65-1

n-Propylbenzene

0.97 U

mg/kg

95-49-8

o-Chlorotoluene

0,97 C

mg/kg

0.97

95-47-6

o-Xylene

0.50 J, Q-2

mg/kg

0.97

106-43-4

p-Chlorotoluene

0.97 t

mg/kg

0.97

99-87-6

p-Isopropyltoluene

135-98-8

sec-l3utylbenzene

100-42-5

Styrene

Page 18 of6O

El 04009 TCLPV VOA FINAL

420

mg/kg

0.97 C

mg/kg

39 C

mg/kg

0.97

Prepurrd

.inuvzed

10j06/l0 12:10 10/06)10 12:10 10.06/10 12:10 10/06/10 12:10 10/06/10 12:10 I0/06/10 12:10

10/08/10 16:38 10/08/10 6:38 10.08/10 16:38 10/08/10 16:38 0/08:10 16:30 10/00/10 16:30

10/06/10

10/08/10

2:10 10/06/10 12:10 10/06)10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10:06/10 12:10 0/06/10 12:10 10/06/10 1210 10/06/10 12:10 6/06/jO 12:10 10/06/10 12:10 10/06/10 12:10 10/06/ID 12:10 10/06/10 12:10 10/06/10 12:10 10/06/ID 12:10 10/06/10 12.10 10/06/10 1210 10/06/tO 12111 10/06/10 12:10 10/06/10 12:10 10/06/10

16:38 1(1/08/10 16:38 10.08/10 16:38 10/08/10 16:38 10/08/10 6:38 10/08/10 16:38 10/08/10 6:38 (0/08/10 16.30 10/08/10 6:38 10/08/10 (6:38 10/08/10 16:38 10/08/10 16:38 10/08/10 16:38 10/00/10 16:38 10/08/10 (6:38 10/88/10 16:38 10/08/10 16:38 (0/08/10 6:38 10/08/10 16:38 10/08/10 16:38 10/08/tO 16:38 10/08/10 16:38 10/07/tO (4:42 (0/08/10 16:38 0:00/10 16:30

12:10

tfethod EPA 8260C EPA 8260C EPA

8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA

8260C

EPA 8260C EPA

8260C

EPA 8260C EPA

8260C

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA

8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA

8260C

EPA 8260C

EPA 0260C

11/8/10 9:52

0

0

UN ITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Td: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules inc Lab ID:

Sample ID: HERCO3-B Station ID: IIERCO3

E104009-05

Matrix: Waste

Date Collected: 9/28/10 13:15

Cis .Vumbcr

Results Qualifiers

.4nalvte

98-06-6

tert-Butylbenzene

127-18-4

Tetrachloroethene (Tetrachloroethylene)

108-88-3

Toluene

156-60-5 10061-02-6

Units

MRL

mg/kg

0.97

0.97 U

mg/kg

0.97

0.82 J, Q-2

mg/kg

0.97

trans-1,2-Dichloroethene

0.97 U

mg/kg

0.97

trans-1.3-Dichloropropene

0.97 U

mg/kg

0.97

79-01-6

Trichloroethene (Trichloroethylene)

0.97 U

mg/kg

0.97

75-69-4

TrichIorofluorome1hane (Freon II)

0.97 U

mg/kg

0.97

0.97 U

mg/kg

0.97

75-01-4

Vinyl chloride

1.4

Prepared

.-lnalyzed .ItetIwd

10/06/10 12:10 10106/10 12:10 10/06/10 12:10 10/06/10 12:10 10/0610 12:10 10/06/10 12:10 10/06/10 120 10/06/10 12:10

10:08/10 638 16:38 10/08/10 16:38 10/08/10 16:38 1008/10 16:38 10/08/10 16:38 10/08/10 638 10/08/10 16.38

EPA 8260C

0/06/10 12:10 10/06/10 12:10

10/08/10 16:38 10/08/10 16:38

EPA 8260C

EPA 8260C EPA 8260C

EP\826OC

EPA 8260C EPA826OC

EPA 8260C EPA 8260C

Tentatively Identified Compounds: R4-8000739

Dimethyloctane (TIC)

40 NJ

R4-8000896

Ethylmethylcyclohexane (TIC)

20 NJ

Page 19 of6O

E104009 TCLPV VOA FINAL

-

mg/kg mg/kg

EPA

8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 90 College Station Road, Athens, Georgia 30605-2700 D.A RT. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO3-B

E104009-05

Matrix: Waste

Station ID: HERCO3 Date Collected: 9/28/10 13:15 C4S Number

,4nalfr

75-35-4

1.1-Dichloroethene (1,1-Dichloroethylene):

107-06-2

1,2-Dichloroethane:

\A5

0.00050

106-46-7

1.4-Dichlorohenienc:

NA-S

0.00050

71-43-2

Benzene:

NA-5

0,00050

56-23-5

Carbon Tetrachioride:

NA-5

0.00050

Results Qualifiers

NA-5

Units

:bIRL

0.00050

108-90-7

Chlorobenz,ene:

NA-S

0.00050

67-66-3

Chloroform:

NA-5

0.00050

87-68-3

flexachlorobutadiene:

78-93-3

Methyl Ethyl Ketone:

127-18-4

Tetrachloroethene (Tetrachloroethylene):

‘çA5

0.00050

79-01-6

Trichloroethene (Trichloroethylene):

NA-S

0.00050

75-01-4

Page 20 of 60

Vinyl chloride:

0.00050 NA-5

NA-S

E104009 TCLPV VOA F[NAL

0.0010

0.00050

Prepared

.na&zed ,lfethod

10113/10 15:00 10/13/10 15:00 10/13/10 15:00 10/13)10 15:00 10/13/10 15:00 I0113/10 15:00 10/13/10 5.00 10/13/10 15.00 10/13/10 500 10/13/10

10/13/10 15:00 10/13/10 15:00 10/13/tO 15:00 10/13/l0 15:0(1 10/13/tO 5:00 10/13/10 15:00 10/13/10 15:00 10/13/10 15:00 I0/I3/10 15:00 I0/13/10

15:00

15:00

10/13/10

10/13/10

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C 1/PA 3260C EPA 8260C EPA 8260C EPA

8260C

EPA 8260C

EPA 8260C

15:00

1500

EPA 8260C

10/13/10 15:00

10/13/10 15:00

EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO4-B Station ID: HERCO4

E104009-06

Matrix: Waste

Date Collected: 9/28/10 13:50 (Is .uuzher

Resith’s Qualifiers

4nalvte

Units

mg/kg

R4-7 156

(m- and/or p-)Xylene

630-20-6

1,1,1 ,2-Tetrachloroethane

10 U

mg/kg

71-55-6

1,1, 1-Trichloroethane

IOU

mg/lg

79-34-5

1,1 ,2,2-Tetrachloroethane

10 U

76-13-I

1,1 ,2-Trichloro- I ,2.2-Trifluoroethane (Freon 113)

10 1;

79-00-5

1,1 ,2-Trichloroethane

344 y?g

1,1 -Dichloroethanc

75-35-4

563-58-6

1,1 -Dichioroethene (1 ,1-Dichloroethylene) 1,1 -Die hioropropene

5.8 J, Q-2

/IIRL

O in ‘

Prepared 10)06110

12:10 10/06/10

lnulyzed llethod 10/07/10 16:26

EPA 8260C EPA 8260C

12:10

10/07/10 16:26

10)06/10 12-10

10 (17-10 6:26

EPA 8260C

mg/kg

I0 in

10/06/10

10/07/la

12:10

16:26

EPA 8260C

mgg

I0

10/06/10 12:10

1007/10 16:26

EPA 8260C

IOU

mg/kg

in

10/06/ID 12:10

10/07/10 16:26

EPA 8260C

10 U,J,QI—I

mg/kg

I0 in

10/06/10 ]2:l0

10/07/10

lOU

mg/kg

lOU

mg/kg

I0 in ‘

87-61-6

1 ,2,3-Trichlorobenzene

96-18-4

1,2,3-Trichioropropane

lOU

mg/kg

120-82-1

I ,2,4-Trichlorobenzene

lOU

mg/kg

I0 in iv

95-63-6

1 ,2,4-Trimethylbenzene

mg/kg

I0

lOU

mg/kg

4.6 J, Q-2, QR-1

10/06/10 12:10

EPA 8260C

16:26 10/07/10 16:26

EPA 8260C

10/06/10 12:10

10/07/10 16:26

EPA 8260C

10/06/10 12:10

10/07/10

EPA 8260C

10’0610

111/07/10 6:26

EPA 8260C

10/07/10 16:26

EPA 8260C

12:10 10/06/10 12:10 10/06/10

16:26

12:10

10/07/10 16:26

EPA 8260C EPA 8260C

96-12-8

I ,2-Dibromo-3-Chloropropane (DBCP)

20 U

mg/kg

2n

10/06/10 12:10

10/07/10 16:26

106-93-4

I ,2-Dibromoethane (EDB)

lOU

mg/kg

I0

10/06/10 12:10

10/07/10 6:26

EPA 8260C

95-50-1

1,2-Dichlorobenzene

25

mg/kg

in

iv

10/06/10 12:10

10/07/10 16:26

EPA 8260C

107-06-2

1 ,2-Dichloroethane

IOU

mg/kg

10/06/10

10/07/10

78-87-5

I ,2-Dichloropropane

IOU

mg/kg

1O in

12:10 10/06/10 12:10

16:26 10/07/10 16:26

EPA 8260C

108-67-8

I ,3,5-Trimethylbenzene

IOU

mg/kg

10/06/10 12:10

10/07/10 6:26

EPA 8260C

541-73-1

I ,3-Dichlorobenzene

lOU

mg/kg

In in

10/06/10

10/07)10 16:26

EPA 8260C

142-28-9

1 ,3-Dichloropropane

IOU

mg/kg

in

10/06/10 12:10

10/07/10

10/06/10 12:10

16:26 10/07)10 16:26

EPA 8260C

in iv I0 on cv

10-06/10

10/07/10

12:10 10/06/10 12:10

16:26 10/07/10 16:26

10/0610 2:10

0/07/10

12:10

106-46-7

I ,4-Dichlorobenzene

lOU

mg/kg

594-20-7

2,2-Dichloropropane

IOU

mg/kg

67-64-1

Acetone

80 U

mg/kg

7 1-43-2

Benzene

19

mg/kg

108-86-1

Bromobenzene

IOU

mg/kg

74-97-5

Bromochloromethane

10 U,J.QL-1

mg/kg

75-27-4

Bromodichioromethane

lOU

mg/kg

in

10/06/10

75-25-2

Bromoform

20 U

mg/kg

2O

12-10

Page 21 of6O

E104009 TCLPV VOA FINAL

-

I0 in in

10/06/10 12:10 10/06/10 12:10 12:10

16:26 10/07/10 16:26 10/07/la

16:26 10/07/10 16:26 100710 16:26

EPA 8260C

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

11/8/10 9:52

0

0

UNiTED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 1 0-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO4-B

E104009-06

Matrix: Waste

Station ID: HERCO4 Date Collected: 9/28/10 13:50 ( .Vnmher

.4nalyte

74-83-9

Bromomethane

75-15-0

Carbon disullide

56-23-5

Carbon Tetrauhloride

Results Qualifiers

Units

tIIRL

Prepared

40 U

mg/kg

4O

10/06/10 12:10

5.6 J, Q-2

mg/kg

I0

10/06/10 12:10

IOU

mg/kg

10

10/0610 1210

i

r

10/06/10 1210 10/06/10 12:10

108-90-7

Chlorobenzene

10 U

mg/kg

75-00-3

Chloroethane

IOU

mg/kg

67-66-3

Chloroform

IOU

mg/kg

IO

10/06/10 12:10

74-87-3

Chioromethanc

IOU

mg/kg



10/06/10 12:10

156-59-2

cis- I ,2-Dichloroethene

10061-01-5

cis- I ,3-Dichloropropene

110-82-7

Cyclohexane

10 U

mg/kg

,O

IOU

mg/kg

i

mg/kg

I0 IO

1O

910

124-48-1

Dibromochioromethane

10 U

mg/kg

74-95-3

Dibromomethane

10 L,J,QL-I

mg/kg

75-71-8

Dichiorodifluoromethane (Freon 12)

100-41-4

Ethyl Benzene

IOU 2.2 J, Q-2

mg/kg



mg/kg

I0

10/06/10 210

1006/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10

12:10 10/06/10 12:10 10/06/10 12:10 10/06/10

87-68-3

[lexachiorobutadiene

IOU

mg/kg

98-82-8

Isopropylbenzene

44 L, D-4

mg/kg

44

20 U

mg/kg

‘I1

2O 2n

10/06110 12:10

79-20-9

Methyl Acetate

591-78-6

Methyl Butyl Ketone

20 U

mg/kg

78-93-3

Methyl Ethyl Ketone

20 U

mg/kg

12:10 10/06/10 12:10 10/06/10

12:10

108-10-I

Methyl Isobutyl Ketone

20 U

mg/kg

2O

10/06/10 12:10

1634-04-4

Methyl T-Butyl Ether (MTBE)

IOU

mg/kg

in

10/06/10

108-87-2

Methylcyclohexane

20

mg/kg

1O

75-09-2

Methylene Chloride

10 U

mg/kg

10

104-51-8

n-ButyIbenzene

10 U

mg/kg

103-65-1

n-Propylbenzene

IOU

mg/kg

I0 n

95-49-8

o-Chlorotoluene

IOU

mg/kg

IO

12:10 10/06/10 2:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12.10 10/06/10

95-47-6

o-Xylene

10 U

mg/kg

I0

106-43-4

p-Chlorotol uene

10 U

mg/kg

1O

99-87-6

p-Isopropyltoluene

mg/kg

50

135-98-8

sec-Butylbenzene

mg/kg

I0

12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10

40

100610 1210

100-42-5

Page 22 of 60

Styrene

3500 10 U 40 U

EIO4009 TCLPV VOA FINAL

mg/kg

.4nalvzed .0k/hod 10/07/10 16:26 10/07/10 16:26

10/07/I 0 16:26 10/07/10 16:26 1007110 16:26 10/07/10 16:26 10.07/10 16:26 10/07/10 16:26 10/07/10 16:26 10/07/10 16:26 10/07/10 16:26 10/07/10 16:26 10/07/10 16:26 10/07/10 16:26 0/07/lU 6:26 10/07/10 16:26 10/07/10 16:26 10/07/10 1626 1007 10 16:26 10/07)10 16:26 10/07/10 16:26 10/07/10 16:26 10/07/10 16:26 10/07/10 16:26 10/07/10 16:26 10/07/10 16:26 1007:10 16:26 10/07/10 16:26 10/08/10 14:28 I 0/67’ 10 1626 I 007: U 16:26

EPA 82€/OC EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 826oc EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 10-0629, Hercu’es Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules inc Lab ID:

Sample ID: HERC04-B Station ID: HERCO4

E104009-06

Matrix: Waste

Date Collected: 9/28/10 13:50 ( IS :Vumher

4nalyte

Results Qualifiers

Units

1IRL

Prepared

inalved 10/07/10 16:26 10/07/10 16:26 10/08/10 14:28 10/07/10 16:26 10:0710 16:26 10/07/10 16:26 100710 16:26 10/07/10 16:26

EPA 8260C

10/07/10 16:26

EPA 8260C

mg/kg

50

10 U

mg/kg

10

10 U

mg/kg

10

Trichloroethene (Trichioroethylene)

10 U

mg/kg

10

75-69-4

Trichlorofluoromethane (Freon Ii)

10 U

mg/kg

10

75-01-4

Vinyl chloride

10 U

mg/kg

10

10/06/10 12:10 10106/10 12:10 tO’06110 2:10 10/06/10 12:10 100610 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10

200 U

mg/kg

200

10/06/10 1210

98-06-6

tert-Butylbenzene

10 U

mg/kg

10

127-18-4

Tetrachloroethene (Tetrachloroethylene)

10 U

mg/kg

10

108-88-3

Toluene

156-60-5

trans-1,2-Dichloroethene

10061-02-6

trans-1,3-Dichloropropene

79-01-6

3000

8k/hod EPA

8260C

EPA

8260C

EPA 8260C EPA

8260C

EPA 8260C

EPA 8260C EPA 6260C

Tentatively Identified Compounds: R4-0000

Page 23 of 60

Tentatively Identified Compounds

E104009 TCLPV VOA FINAL

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-270() DART. Id: 10-0629

Project: 10-0629, Hercules Inc

-

Reported by Kristin Trapp

TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO4-B

E104009-06

Matrix: Waste

Station ID: HERCO4 Date Collected: 9/28/10 13:50 CAS :V,unber

.4nalyte

75-35-4

1,1-Dichloroethene

Resitlis Quabjiers

Unijo

MRL

Prepared

0.10

0/13/10 1500

10/13/10 1619 10/13/10 16:19 10/13/10 16:19 10/13/10 16:19 10:13/10 16:19

0.10 U

mg/L

0.10 U

mg/L

10/13/10

mg/L

0.10

10/1310 15:00

10/13/10 1500 10/13/10 15:00 10/13)10

.4nalw:ed Ofethod

EPA 8260C

(1 ,1-Dichloroethylene) 107-06-2 106-46-7

1,2-Dichloroethane 1,4-Dichlorobenzene

0.10 U

15:01)

71-43-2

Ben2ene

0.22

mgIL

0.10

56-23-5

Carbon Tetrachloride

0.10 U

mg/L

0.10

108-90-7

Chlorobenzene

67-66-3

Chloroform Flexachiorobutadiene

87-68-3

Methyl Ethyl Kelone

78-93-3 127-18-4

Tetrachloroethene (Tetrachloroethylene)

EPA

8260C

0.10

0.10 U

mg/L

0.10

15:011 10/13)10 15:00

6:19 10/13/10 16:19

EPA 8260C

0.10

10/13/10 15.00

10113110 16:19

EPA 8260C

0.20

10:13,10 500

10/13:10 16:19

EPA 9260C

0.10

10/13/10 15:00

10/13/10 1500 111/13/10 15.00

10/13/10 16:19 10/13/10 16:19 10/13/10 16:19

0.10 U

mg/L

0.20 U

mgfL

0.10 U

mg/L

Trichloroethene (Trichloroethylene)

0.10 U

mg/L

0.10

Vinyl chloride

0.10 U

mg/L

0.10

EI04009 TCLPV VOA FINAL

EPA 8260C

mg/i..

79-01-6

24 of 60

EPA 8260C

0.10 U

75-01-4

Page

10/13/10

EPA 8260C

EPA 8260C

EPA 8260C EPA 8260C EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO5-A

E104009-07

Matrix: Waste

Station ID: I{ERCO5 Date Collected: 9/28/10 14:05 CIS .u,nher

.4nalyte

R4-7156

(m- and/or p-)Xylene

4.6 J, Q-2

mg/kg

99

630-20-6

1,1,1 ,2-Tetrachloroethane

9.9 U

mg/kg

n n

71-55-6

1,1,1 -Trichloroethane

9.9 U

mg/kg

99

1,1 ,2,2-Tetrachloroethane

9.9 U

mg/kg

n n

1,1 ,2-Trichloro- 1,2,2-Trifluoroethane (Freon 113)

9.9 U

mg/kg

n n

79-00-5

1,1 ,2-Trichloroethane

9.9 U

mg/kg

n n

75-34-3

1,1 -Dichloroethane

9.9 U, 3, QL-1

mg/kg

99

9.9 U

mg/kg

o o

9.9 U

ing/kg

99

79-34-5 -13-1

75-35-4 563-58.6

Results Qualifiers

1,1 -Dichloroethene (1 ,1-Dichloroethylene) 1,1 -Dichloropropene

Units

MRL



‘‘

87-61-6

I ,2,3-Trichlorobenzene

9.9 U

mg/kg

o o

96-18-4

1 ,2,3-l’richloropropanc

9.9 U

mg/kg

99

120-82-I

1 ,2,4-Trichlorobenzene

9.9 U

mg/kg

o n

95-63-6

I ,2,4-Trimethylbenzene

4.0 J, Q-2. QR-l

mg/kg

99

96-12-8

I ,2-Dibromo-3-Chloropropane (DBCP)

20 U

mg/kg



106-93-4

1 ,2-Dibromoethane (EDB)

9.9 U

mg/kg

99

95-50-I

1 ,2-Dichlorobenzene

6.3 J, Q-2

mg/kg

o o ‘‘

107-06-2

1 ,2-Dichloroethane

9.9 U

mg/kg

99

78-87-5

I ,2-Dichloropropane

9.9 U

mg/kg

o n ‘‘

108-67-8

I ,3,5-Trimethylbenzene

9.9 U

mg/kg

99

U

mg/kg

0 o ‘‘

U

mg/kg

0

mg/kg

o o

mg/kg

9

mg/kg

-o

mg/kg

99

541-73-1

1 ,3-Dichlorobenzene

142-28-9

I ,3-Dichloropropane

9.9 9.9 9.9 9.9 79

U U U

9

106-46-7

1,4-Dichlorobenzene

594-20-7

2,2-Dichloropropane

67-64-I

Acetone

71-43-2

Benzene

108-86-1

Bromobenzene

9.9 U

mg/kg

o o

74-97-5

Bromochioromethane

9.9 U, 3. QL-1

mg/kg

O 0

75-27-4

Bromodichloromethane

9.9 U

mg/kg

o n

75-25-2

Bromoform

20 U

mg/kg

2O

Page 25 of 60

14

El 04009 TCLPV VOA FINAL

0

‘‘

‘‘

Prepared

1 nalyzed

10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10

10/07/10 16:52

EPA 8260C

10/07/10 16:52 10/07/10 16:52 10/07/10 16:52 0/07/TO 16:52

EPA 8260C

10/06/10 12:10 10/06/10 12:10 10/06/10 12:10

10/07/10 16:52 10/07/10 16:52 10/07/10 16:52

EPA 8260C

EPA 8260C

10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10

10/07/10 16:52 10/07/10 16:52

EPA 8260C

12:10 0/06/It 12:10

10/07/10

16:52 10/07/10 16:52 10/07/10

16:52 10/07/TO 16:52

Method

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C

EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C

10/07/10 6:52

EPA 8260C

10/07/10 16:52

EPA 8260C

10/07/tO

EPA 8260C

16:52 10/07/10 16:52

EPA 8260C

10/07/10 16:52

EPA 8260C

10/07/10 16:52

EPA 8260C

10/07/10

EPA 8260C

16:52 10/07/10 16:52 10/07/10 16:52 10/07/10 16:52 10/07/10 16:52 10/07/10 16:52

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

10/07/10 16:52

EPA 8260C

10/07/10

EPA 8260C

16:52 10/07/10 16:52

EPA 8260C

11/8/10 9:52

0 S

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 CoLlege Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

/

Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO5-A

E104009-07

Matrix: Waste

Station ID: I-IERCO5 Date Collected: 9/28/10 14:05

c-is Vu,nher

.4 an!vie

74-83-9

Bromomethane

75-15-0

Results Qualifiers

Carbon disulfide

Units

40 U

mg’kg

3.6 3, Q-2

mg/kg

56-23-5

Carbon Tetrachloride

9.9 U

mg/kg

108-90-7

Chlorobenzene

9.9 U

mg/kg

75-00-3

Chloroethane

9.9 U

mg/kg

67-66-3

Chlorofonn

9.9 U

mg/kg

74-87-3

Chloromethane

9.9 U

mg/kg

156-59-2

cis-1,2-Dichloroethene

9.9 U

mg/kg

9.9 U

mg/kg

10061-01-5

cis-1,3-Dichloropropene

110-82-7

Cyclohexane

420

MRL

Prepared

.ina(vzed

40

10/06/10 12:10 1(1/06/10

9.9

10/06/10 1210 10/06/10 12:10 10/06/10 1210 10/06/10 iio 10/06/10 12:10 (0/06/(0 2:10 0:06/10 1210 10/06/10

10/07/10 6:52 10/07/10 1652 10/07/10 16:52 10/07/10 6:52 10/07/10 16:52 10/07/10 16:52 10/07/10 1652 10/07/10 16:52 10/0710 16:52 10/07/10 (6:52 10/07/10 1652 10/07/10 16:52 10/07/10 1652 10/07/10 16:52 10/07/10 16:52 10/07/10 1652 10/07/10 6:52 0/07/10 16:52 10/07/10 (6:52 10/07/10 6:52 10/07/10 16:52 10/07/10

99

99

mg/kg

124-48-1

Dibromochloromethane

9.9 U

mg/kg

74-95-3

Dibromomethane

9.9 U, I. QL-1

mg/kg

75-71-8

Dichlorodifluoromethane (Freon 12)

9.9 U

mg/kg

100-41-4

Ethyl Benzene

2.6 J, Q-2

mg/kg

87-68-3

Flexachlorobutadiene

9.9 U

mg/kg 28 20

98-82-8

lsopropylbenzene

28 U, D-4

mg/kg

79-20-9

Methyl Acetate

20 U

mg/kg

99

59 1-78-6

Methyl Butyl Ketone

20 U

mg/kg

20

78-93-3

Methyl Ethyl Ketone

20 U

mg/kg

20

108-10-1

Methyl Isobutyl Ketone

4.6 3, Q-2

mg/kg

20

1634-04-4

Methyl T-Butyl Ether (MTBE)

9.9 U

mg/kg

108-87-2

Methylcyclohexane

22

mg/kg

75-09-2

Methylene Chloride

9.9 U

mg/kg

104-51-8

n-Butylbenzene

9.9 U

mg/kg

103-65-1

n-Propylbenzene

9.9 U

mg/kg

95-49-8

o-Chlorotoluene

9.9 U

mg/kg

95-47-6

o-Xylene

9.9 U

mg/kg

106-43-4

p-Chlorotoluene

9.9 U

mg/kg

99-87-6

p-lsopropyltoluene

135-98-8

sec-Butylbenznne

100-42-5

Styrene

Page 26 of6O

E104009 TCLPV VOA FfNAL

3500

1W06/l0 12:10 10/00/10 1210 10/06/10 12(0 10/06/10 12:10 0/06/10 12:10 (0/06/10 2:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 (210 10/06/10 1210 10/06/10 10/06/10 1210 0/06/10

99

mg/kg

9.9 U

mg/kg

9

40 U

mg/kg

40

0/06/10 12:10 10/06/It 2:10 (0/06/10 12:10 0/06/10 1210 (0/06/10 120 10/06/10 (2 0 10/06/10 20

10/07/10 6:52 10/07/10 6:52 (0:07/10 1652 10/07/JO 1652 10107/10 16:52 10/07/10 6:52 10/00/10 1454 0/07/10 652 10/07/10 16:52

,lfetkod

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA

8260C

EPA 8260C EPA

826CC

EPA 8260C EPA 826CC EPA 8260C EPA 8260C

EPA 8260C

EPA 826CC EPA 8260C EPA

826CC

EPA 826CC EPA

826CC

EPA 8260C

EPA 826CC EPA 8260C EPA 826CC EPA 826CC EPA 826CC EPA 8260C EPA 826CC EPA 8260C

11/8/10

9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO5-A Station ID: HERCO5

E104009-07

Matrix: Waste

Date Collected: 9/28/10 14:05 CAS .Vu,nber

4nalyte

Resulls Qualifiers

Unâs

MRL

Prepared

mg/kg

10/06110

mg/kg

.lnalyzed Method

10/06/ID 12:10

10/07/10 16:52 10/07/10 16:52

EPA 8260C

10/06/10 12:10

10/08/10 4:54

EPA 8260C

mg/lcg

10/06/10 12:10

10/07/10 16:52

EPA 8260C

mg/kg

10/06/10 12:10

10/07/10 6:52

EPA 8260C

9.9 U

mg/kg

10/06/10 12:10

10/07/10

EPA 8260C

Trichlorofluoromethane (Freon 11)

9.9 U

mg/kg

10/06/10

10/07/10

Vinyl chloride

9.9 U

mg/kg

12:10 10/06/10 12:10

16:52 10/07/10 16:52

200 U

mg/kg

10/06/10

100710

20

652

98-06-6

tert-Butylbenzene

127-18-4

Tetrachloroethene (Tetrachloroethylene)

108-88-3

Toluene

156-60-5

trans-1,2-Dichloroethene

9.9 C

10061-02-6

trans-1,3-Dichloropropene

9.9 U

79-01-6

Trichloroethene (Trichloroethylene)

75-69-4 75-01-4

9.9 U

9.9 U 5300

mg/kg

1210

50

16:52

EPA 8260C

EPA

8260C

EPAS26OC

Tentatively Identified Compounds: R4-0000

Page 27 of 60

Tentatively Identified Compounds

El 04009 TCLPV VOA FINAL

200

EPA 8260C

11/8/10 9:52

0 ST

,7

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700

\ ‘

DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO5-A

E104009-07

Matrix: Waste

Station ID: HERCO5 Date Collected: 9/28/10 14:05 ( IS

MRL

Prepared

mg/’..

0.10

I0/I3/l0

010 U

mg/L

0.10

1,4-Dichlorobenzene

0.10 U

mg/L

0.10

Benzene

0.23

mg/L

0.10

0.10 U

mgIL

0.10

Results Qualifiers

Vu,nher

.4nolyte

75-35-4

0.10 U

107-06-2

1,1-Dichloroethene (1,1 -Dichloroethylene) 1,2-Dichloroethane

106-46-7 71-43-2 56-23-5 108-90-7

Carbon Tetrachloride Chlorohenzene

Units

‘ng/’

0.10

1500 10/13/10 15:00

0.10

10/13/10 1500

67-66-3

Chloroform

0.10 U

87-68-3

Hexachlorobutadiene

0.10 U

nlg/L

0.10

78-93-3

Methyl Ethyl Ketone

0.20 U

mg/L

0.20

127-18-4

Tetrachloroethene (Tetrachloroethylene)

0.10 U

mg/L

0.10

75-01-4

Page 28 ot’60

Trichloroethene (Trichloroe[hylenel Vinyl chloride

E104009 TCLPV VOA FINAL

10/13/Ill

0.10 U

mg/L

79-01-6

10/13/10 15:00 10/13/tO 1500 10/13/10 15:00 10/13/10 15:00

I0/l3/I0 1500 10/13/10 15:00

.Inalyzed Method l0/l3/I0

1645

EPA 8260C

10/13/10 16:45 10/13/10 1645 10/13/10 1645 10/13/10 645 10/13/Ill 1645 10/13/10 16:45

EPA826OC

Ill/li/Ill

1645 10/IllS 1645 10/13/10 16.45 10/13/10 645

0.10 U

mg/L

0.10

IO/13.’IO

0.10 U

mgJL

0.10

10/13/10

10/13/10

15:00

16:45

EPA 8260C EPA 8260C EPA 8260C EPA

8260C

EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 0260C

EPA 8260C

11/8/10 9:52

C UNiTED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 10-0629, Hercules Inc

-

Reported by Kristin Trapp

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO6-B

E104009-08

Matrix: Waste

Station ID: HERCO6 Date Collected: 9/28/10 14:55 C4S Number

.4nalyfr

Resulls Qualifiers

R4-7156

(m- and/or p-)Xylenc

630-20-6

1,1,1 ,2-Tetrachloroethane

LJnit

MRL

Prepared

,4aated

10/06/10 12:10 10/06/10 12:10

12:10

16/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12

10/06/10 12:10

10/08/10 16:12

EPA 8260C

1006/10

10/08/10 16:12

EPA 8260C

10/08/10 16:12

EPA 8260C

1.0 U

mg/kg

1•

U

mg/kg

n

1.0

‘•‘‘

71-55-6

1,1,1 -Trichloroethane

1.0 U

mg/kg

I 0

79-34-5

1,1 ,2,2-Tetrachloroethane

1.0 U

mg/kg

1 A

76-13-1

1,1 ,2-Trichloro- 1 ,2,2-Trifluoroethane (Freon 113)

1.0 U

mg/kg

O

79-00-5

1,1 ,2-Trichloroethane

1.0 U

mg/kg

75-34—3

1,1 -Dichloroethane

75-35-4 563-58-6

1 ,1-Dichloroethene (1 ,1-Dichloroethylene) 1,1 -Dichloropropene



1

A

mg/kg

I 0

1.0 U

mg/kg

1 A

1.0 U

mg/kg

1 0

1.0 U, 3, QL- I

7-61-6

1 ,2,3-Trichlorobenzene

1.0 U

mg/kg

1 A

96-18-4

1 ,2,3-Trichloropropane

1.0 U

mg/kg

1 0

120-82-1

1 ,2,4-Trichlorobenzene

1.0 U

mg/kg

1 A

0.40 J, Q-2

mg/kg

i n

U

mg/kg

‘I A

95-63-6

I ,2,4-Trimethylbenzcne

96-12-8

I ,2-Dibromo-3-Chloropropane (DBCP)

2.0

106-93-4

1,2-Dibromoethane (EDB)

1.0 U

mg/kg

1 0

95-50-1

1 ,2-Dichlorobenzene

1.0 U

mg/kg

‘•‘-‘

1

107-06-2

1 ,2-Dichloroethane

1.0 U

mg/kg

1 0

78-87-5

I ,2-Dichloropropane

1.0 U

mg/kg

1 A

108-67-8

I ,3,5-Tnmethylbenzene

1.0 U

mg/kg

1 0

541-73-1

I ,3-Dichlorobenzene

1.0 U

mg/kg

I A

142-28-9

1 ,3-Dichloropropane

1.0 U

mg/kg

1 0

106-46-7

1 ,4-Dichtorobenzene

1.0 U

mg/kg

1 A

594-20-7

2,2-Dichioropropane

1.0 U

mg/kg

1 A

67-64-1

Acetone

8.0 U

mg/kg

O A °‘

71-43-2

Benzene

1.0 U

mg/kg

1 0 I A

108-86-1

Bromobenzene

1.0 U

mg/kg

74-97-5

Bromochioromethane

1.0 U, 3, QL-1

mg/kg

O

75-27-4

Bromodichloromethane

1.0 U

mg/kg

1 A

75-25-2

Bromoform

2.0 U

mg/kg

20

Page 29 of 60

El 04009 TCLPV VOA FINAL

10/06/10

12:10 10/06/10 12:10 10/06/10

12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10

10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10

10/08/10 16:12 10/08/10 16:12 10/08/ 10 16:12 10/08/10 16:12 10/08/10 16:12

10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12

10/06/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10

16:12

tfeihod

EPA 8260C

EPA

8260C

EPA 8260C

EPA 8260C EPA

8260C

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D ART. Id: 10-0629 Reported by Kristin Trapp

Project: 10-0629, Hercules Inc

-

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO6-B

E104009-08

Matrix: Waste

Station ID: HERCO6 Date Collected: 9/28/10 14:55 C4S Number

.4nalyie

74-83-9

Bromomethane

75-15-0

Carbon disulfide

Results Qualifiers 40 U

0.42 J, Q-2

Units

MRL

Prepared

mg/kg

40

mg/kg

1.0

10106/10 12:10 10/06/10 12:0 10/06/10 12:10 10/06/10 12:10

56-23-5

Carbon Tetrachloride

1.0 U

mg/kg

1.0

108-90-7

Chlorobenzene

1.0 U

mg/kg

1.0

75-00-3

Chloroethane

1.0 U

mg/kg

1.0

67-66-3

Chloroform

1.0 U

mg/kg

1.0

74-87-3

Chloromethane

1.0 U

mg/kg

1.0

156-59-2

cis-1,2-Dichloroethene

1.0 U

mg/kg

1.0

10061-01-5

cis-I,3-Dichloropropene

1.0 U

mg/kg

1.0

110-82-7

Cyclohexane

1.0 U

mg/kg

1.0

124-48-1

Dibromochloromethane

1.0 U

mg/kg

74-95-3

Dibromomethane

1.0 U

mg/kg

1.0

1.0

75-71-8

Dichlorodifluoromethanc (Freon 12)

1.0 U

mg/kg

1.0

100-41-4

Ethyl Benzene

1.0 U

mg/kg

1.0

87-68-3

1-lexachlorobutadiene

1.0 U

mg/kg

1.0

98-82-8

Isopropylbenzene

1.0 U

mg/kg

1.0

79-20-9

Methyl Acetate

2.0 U

mg/kg

2.0

591 -78-6

Methyl Butyl Ketone

2.0 U

mg/kg

2.0

78-93-3

Methyl Ethyl Ketone

2.0 U

mg/kg

2.0 2.0 1.0

108-10-1

Methyl Jsobutyl Ketone

2.0 U

mg/kg

1634-04-4

Methyl T-Butyl Ether (MTBE)

1.0 U

mg/kg

108-87-2

Methylcyclohexane

mg/kg

1.0

75-09-2

Methylene Chloride

1.0 U

mg/kg

1.0

104-51-8

n-Butylbenzene

1.0 U

mg/kg

1.0

103-65-I

n-Propylbenzene

1.0 U

mg/kg

1.0

95-49-8

o-Chlorotoluene

1 .0 U

mg/lcg

1.0

95-47-6

o-Xylene

1.0 U

mg/kg

1.0

106-43-4

p-Chlorotoluene

1.0 U

mg/kg

1.0

99-87-6

p-lsopropyltoluene

38

mg/kg

1.0

135-98-8

sec-Butylbenzene

1.0 U

mg/kg

1.0

100-42-5

Page 30 of6O

Styrene

0.24 J, Q-2

40 U

E104009 TCLPV VOA FINAL

mg/kg

40

10/06/10

12:10 10/06/10 12:10 10/06/10 12:10 10/06,10 12:10 10/06/10

12:10 10/06/10 12:10 10/06/10 (2:10

10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10

.•lnalyzed ,Ofethod 10/08/10 16:12 0/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 (6:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12

10/08/10 6:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10

12:10

16:12

10/06/10 12:10 10/06/10 12:10 10/06/1(1 12.10 10/06/10 12:10 10/06/10 12:10

10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08110 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 (0/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12

10/06/10 12:10 (0/06/10 12:10 10/06/10 12:10 10/06/10 2:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 0/06/10 12:10 10/06/10 12:10 10/06/10 (2:10

10/06/10 12:10

EPA 8260C

EPA 8260C EPA 8260C

EPA826OC EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA

8260C

EPA 8260C EPA

8260C

EPA 8260C

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C

EPA826OC EPA

8260C

EPA 8260C EPA

8260C

EPA 8260C

EPA 8260C EPA

8260C

EPA 8260C

11/8/10

9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO6-B Station ID: HERC06

E104009-08

Matrix: Waste

Date Collected: 9/28/10 14:55 C.4S Niunber

.4nalyte

Results Qualifiers

98-06-6

tert-Butylbenzene

127-18-4

Tetrachloroethene (Tetrachloroethylene)

108-88-3

Toluene

156-60-5

trans-i ,2-Dichloroethene

1.0

10061-02-6

trans-I.3-Dichloropropene

79-01-6

Trichloroethene (Trichloroethylene) 11)

75-01-4

Vinyl chloride

:IIRL

Prepared 10/OMIt 12:10 10/06/10 12:10

10,08/10 16:12 10/08/10 16:12

10/06/10

100710

12:10 10/06/10 12:10

14:16 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12 10/08/10 16:12

EPA 8260C

10/08/10 1612

EPA 8260C

1.0 U

mg/kg

1.0

1.0 U

mg/kg

1.0

mg/kg

10

U

mg/kg

1 .0

1.0 U

mg/kg

1.0

1.0 U

mg/kg

1.0

1.0 U

mg/kg

1.0 U

mg/kg

1.0

12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10

20 U

mg/kg

20

10/06/10 1210

280

(Freon

Units

10/06/10

.lnalvzed ,lIethod EPA 8260C EPA 8260C EPA 826gC EPA 8260C EPA 8260C EPA 8260C EPA 8260C

Tentatively Identified Compounds: R4-0000

Page 31 of6O

Tentatively Identified Compounds

E104009 TCLPV VOA FINAL

11/8/10 9:52

0

C

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Inc Reported by Kristin Trapp Hercules 10-0629, Project: -

TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO6-B

E104009-08

Matrix: Waste

Station ID: HERCO6 Date Collected: 9/28/10 14:55 C4S Vuinhcr

.4naiyte

75-35-4

1,1-Dichloroethenc (1,1-Dichloroethylene):

107-06-2 106-46-7

Results Quail/lees

1,2-Dichloroethane: l,4-Dichlorobenzene:

71-43-2

Benzene:

56-23-5

Carbon Tetrachioride:

NA-S \A-5 NA5

Linus

MRL

0.00050 000050 0.00050

NA-5

0.00050

NA-5

0.00050

108-90-7

Chlorobenzene:

NA-5

0.00050

67-66-3

Chloroform:

NA-5

0.00050

87-68-3

Hexachlorobutadiene:

78-93-3

Methyl Ethyl Ketone:

10/13/10

10/13/10

EPA 8260C

10/13/10

10/13/10 5:00

EPA 8260C

15:01) 10/13/10

15:00 10/13/10 500

1013/10

15:00 10/13/10

10/13/10

500 10/13/10

15:00 10/13/10 15:00

15:00 0/13/10 15:00

10/13/10

10/13/10

EPA 8260C

EPA 8260C

NA-5

10/13/10 15:00

1500 10/13/10 15:00

1013/10

10/13/10

500 10/13/10 15:00

1500 10/13/10 15:00

0.00050

79-01-6

NA-S

0.00050

75-01-4

Vinyl chloride:

NA-5

0.00050

EPA 8260C

EPA 8260C

15:00

0.00 10

NA-5

8260C

10/13/10

0.00050

Trichloroethene(Trichloroethylene):

EPA

EPA 8260C

5:00

NA-S

Tetrachloroethene (Tetrachioroethylene):

El04009 TCLPV VOA FINAL

..tnuly;ed .lfethod

0/13/10 15011 1013/10 15:01)

127-18-4

Page 32 of 60

Prepared

1500 10/13/10

EPA 8260C

EPA 8260C EPA 8260C EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science arid Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO7-B Station ID: HERCO7

E104009-09

Matrix: Waste

Date Collected: 9/28/10 15:25 C4S Vuinber

.4nalvre

Results Qualifiers

R4-7156

(m- and/or p-)Xylene

63 0-20-6

1,1 I ,2-Tetrachloroethane

71-55-6

,

1,1 -Trichloroethane

Units

IJRL

2.9

mg/kg

2.4 U

mg/kg

24

2.4 U

mg/kg

24

79-34-5

I ,I,2,2-Tetrachloroethane

2.4 U

mg/kg

A

76-13-1

1,1 ,2-Trichloro- I ,2,2-Trifluoroethane (Freon 113)

2.4 U

mg/kg

) A

79-00-5

1,1 ,2-Trichloroethane

2.4 U

mg/kg

2•A

75-34-3

1,1 -Dichloroethane

2.4 U,J,QL-l

mg/kg

2 •4

75-35-4

1,1 -Dichloroethene (1 ,1-Dichloroethylene)

2.4 U

mg/kg

2

563-58-6

1,1 -Die hioropropene

2.4 LT

mg/kg

24

87-61-6

I ,2,3-Trichlorobenzene

2.4 U

mg/kg

‘1 A

96-18-4

1 .2,3-Trichloropropane

2.4 U

mg/kg

24

120-82-1

1,2,4-Trichlorobenzene

2.4 U

mg/kg

24

95-63-6

1 ,2,4-Trimethylbenzene

1.3 J,Q-2

mg/kg

2 •4

96-12-8

I ,2-Dibromo-3-Chloropropane (DBCP)

4.9 U

mg/kg

A

106-93-4

I ,2-Dibromoethane (EDB)

2.4 U

mg/kg

i A

95-50-1

1 ,2-Dichlorobenzene

2.4 U

mg/kg

1 A

107-06-2

I ,2-Dichloroethane

2.4 U

mg/kg

24

78-87-5

I ,2-Dichloropropane

2.4 U

mg/kg

A

108-67-8

I ,3,5-Trimethylbenzene

2.4 U

mg/kg

24

541-73-1

1 ,3-Dichlorobenzene

2.4 U

mg/kg

) A

142-28-9

1 ,3-Dichloropropane

2.4 U

mg/kg

1 A

106-46-7

1 ,4-Dichlorobenzene

2.4 U

mg/kg

‘I A

594-20-7

2,2-Dichloropropane

2.4 U

mg/kg

2•4

67-64-1

Acetone

19 U

mg/kg

in ‘

71-43-2

Benzene

2.4 U

mg/kg

24

108-86-1

Bromobenzene

2.4 U

mg/kg

‘) A

74-97-5

Bromochioromethane

2.4 U, J, QL-1

mg/kg

24

75-27-4

Bromodichloromethane

2,4 U

mg/kg

‘1 A

75-25-2

Bromoform

4.9 U

mg/kg

0

Page 33 of 60

E104009 TCLPV VOA FINAL

A







4

Prepared

.1navzed Method 10/08/10 17:04 10/08/10

l0106/l0 12:10 0/06/10 12:10 10/06/jO 12:10 IO/06/lO 12:10 0/06/jO 12:10

10/08/10 17:04 10/08/10 17:04

10/06/ID 12:10 I0/06/I0 12:10 10/06/10 12:10

104)8/10 17:04 0/08/10 17:04 10/08/10 17:04

I0!06/l0 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/b 12:10 10/06/10 12.10 10/06/10 12:10 10/06/10 I2bO 0/06/10 12:10 0/06/10 12:10 10/06/10 I2:10 10/06/10 12:10

10/08/10 7:04 0/08/10 17:04 0/06/0 7:04 10/08/10 17:04 10/08/10 17:04 10/08/10 17:04 10/08/10 7:04 10/08/10 17:04 10/00/10 17:04 10/08/10 17:04 800/b 7:04 l0/08)10 17:04 0/08/IC 7.04 10/08/10 17:04 0/08/10 7:04 I0/08/l0 17.04 10/06/10 7:04 0/08/10 17:04 lO/OS/lO 17:04 I 0/08/10 17:04 10.08/10

17:04

l0/08/lO

7:04

17:04

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 6260C

EPA 8260C

EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

11/8/10

9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO7-B

E104009-09

Matrix: Waste

Station ID: IIERCO7 Date Collected: 9/28/10 15:25

C,ts Vu,nber

74-83-9

Residis Quah:fiers

.4 no!vie

Bromomethane

Units

1fRL

mg/kg

97 U

mg/kg

2.4

75-15-0

Carbon disulfide

56-23-5

Carbon Tetraehloride

2.4 U

mg/kg

2.4

108-90-7

Chlorobenzene

2.4 C

mg/kg

2.4

75-00-3

Chloroethane

2.4 U

mg/kg

2.4

67-66-3

Chloroform

2.4 U

mg/kg

2.4

74-87-3

C’hloromethane

2.4 U

mg/kg

2.4

156-59-2

0.78 J, Q-2

cis-1,2-Dichloroethene

2.4 U

mg/kg

2.4 2.4

10061-01-5

cis-1,3-Dichloropropene

2.4 U

mg/kg

110-82-7

Cyclohexane

2.4

U

mg/kg

2.4

124-48-I

Dibromochloromethane

2.4 U

mg/kg

2.4

74-95-3

Dibromomethane

2.4 U

mg/kg

2.4

75-71-8

Dichlorodifluoromethane (Freon 12)

2.4 U

100-41-4

Ethyl Benzene

87-68-3

Ilexachlorobutadiene

mg/kg

2.4

mg/kg

2.4

2.4 U

mg/kg

2.4

mg/kg

2.4

0.92 J, Q-2

98-82-8

lsopropylbenzene

2.4 U

79-20-9

Methyl Acetate

4.9 U

mg/kg

591-78-6

Methyl Butyl Ketone

4,9 U

mg/kg

78-93-3

Methyl Ethyl Ketone

4.9 U

mg/kg

108-10-I

Methyl lsobutyl Ketone

4.9 U

mg/kg

1634-04-4

Methyl T-Butyl Ether (MTRE)

2.4 U

mg/kg

2.4

108-87-2

Methylcyclohexane

2.4 U

mg/kg

2.4

75-09-2

Methylene Chloride

2.4 U

mg kg

2.4

104-51-8

n.Butylbenzene

2.4 U

mg/kg

2.4 2.4 2.4

.

103-65-1

n-Propylbenzene

2.4 U

mgkg

95-49-8

o-Chlorotoluene

2.4 U

mg/kg mg/kg

2.4

mg/kg

2.4

95-47-6

o-Xylene

106-43-4

p-Chlorotoluene

2.4 1/

99-87-6

p-lsopropylloluene

170

mg kg

2.4

2.4 V

mg/kg

2.4

97 U

mg/kg

13 5-98-8

sec-Butylbenzene

100-42-5

Styrene

Page 34 of 60

0.73 J, Q-2

El04009 TCLPV VOA FINAL

Prepared

.lna!w;ed ,llethod

10/06/10 12:10 0/06/10 12:10 ‘°‘°°° 12:10 10/06/10 12:])) 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 lO;06’IO 12:10 10/06/10 12:10 10.06110 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 (2:10 10/06/10 12:10 (0/06/10 12:10 10/06/10 12:18 10/06/10 12:10 (0/06/10 12:10 10/06/10 12:10 (0/06/10 2.10

10/08/10 17:04 10/08/10 17:04 (0/08/JO 17:04 10/08/10 7:04 10/08/10 17:04 1(1/08,10 17:04 10:08.10

0/06/10

18.08.10 (7:04

EPA 8260C

10,08/10

EPA 8260C

12:10 (1,06/10 12:10 10/06/10 12:10 10/06’lO 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/lU 2:10 10/06/10 12:10

(7:04

1(1/00/10 17.04 1006/10 17:04 10/08/10 17:04 10:08/10 17.03 10/0810 17:04 10,00/10 (7:04 10/08/10 17:04 10/08/10 (7:04 10/08/10 17:04 10/08/10 7:04 (0/08/10 (7:04 10/08/10 17:04 10/08/10 17:04 10/08/10 17:04 10/08/11> 17:04

17:04

(0:08/10 17:04 (0,08/10 17:04 10/081(0 17:04

10/08110 (704 10.08.10 17.04

10/08/10 17:04 10/08/10 (7:04

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C’ EPA

8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C

EPA

8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C

11/8/10 9:52

0

0 is.’

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700

41. fr//

DART. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO7-B

Matrix: Waste

Station ID: HERCO7 Date Collected:

E104009-09

9/28/10 15:25

C4S Nu,nher

.4nalyte

98-06-6

tert-Butylbenzene

2.4 U

127-18-4

Tetrachioroethene (Tetrachloroethylene)

2.4

Results Qualifiers

Units

MRL

Prepared

mg/kg

2.4

U

mg/kg

2.4 2.4

10/08/10 704 10/08/10 17:04 10/07/b 13:51 10/08/10 17:04 l0/08/l0 I7•04 10/08/10 17:04 0/08/10 I7:04 10/08/10 17:04

10/08/tO 17:04

108-88-3

Toluene

156-60-5

trans-1,2-Dichloroethene

2.4 U

mg/kg

10061-02-6

trans-1,3-Dichloropropene

2.4 U

mg/kg

2.4

79-01-6

Trichloroethene (Trichloroethylene)

2.4 U

mg/kg

2.4

75-69-4

Trichlorofluoromethane (Freon Ii)

2.4 U

mg/kg

2.4

75-01-4

Vinyl chloride

2.4 U

mg/kg

2.4

10/06/10 12•l0 10/06/10 12:10 l0/06/1O 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10

50 U

mg/kg

50

l0/06/10 12:10

1400

mg/kg

.

lnalrzed ,lfethod EPA 8260C EPA

8260C

EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

Tentatively Identified Compounds: R4-0000

Page 35 of6O

Tentatively Identified Compounds

E104009 TCLPV VOA FINAL

EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project. 10-0629, Hercules Inc Reported by Kristin Trapp -

TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO7-B

E104009-09

Matrix: Waste

Station ID: HERCO7 Date Collected: 9/28/10 15:25 C4S Nina her

.4nalye

75-35-4

1,1-Dichloroethene (1,1-Dichioroethylene):

Retails Qualifiers

NA5

Linus

MRL

0.00050

107-06-2

1,2-Dichloroethane:

NA-5

0.00050

106-46-7

l,4-Dichlorobenzene:

NA-S

0.00050

71-43-2

Benzene:

NA-S

0.00050

56-23-5

Carbon Tetrachloride:

NA-5

0.00050

108-90-7

Chlorobenzene:

NA-S

000050

67-66-3

Chloroform:

NA-S

0.00050

87-68-3

Hexachlorobutadiene:

NA-S

0,00050

78-93-3

Methyl Ethyl Ketone:

NA-5

0.0010

127-18-4

Tetrachloroethene (Tetrachioroethylene):

\A-5

0.00050

79-01-6

Trichloroethene (Trichloroethylene):

NA-5

0.00050

75-01-4

Vinyl chloride:

Page 36 of6O

NA-S

E104009 TCLPV VOA FINAL

0.00050

Prepared

laalvzed Method

10/13/10 15:00 10/13/10 15:01) 10/13/10 1500 0/13/10 15:00 10/13/10 15:00

10/13/10

15:00

EPA 8260C

10/13/10 15:00 10/13/10 15:00 10/13/10 15:00 10/13/10 15:00

EPA 8260C

10/13/10

10/13/10

15:00 10/13/10 15:00 10/13/10 15:00 10/13/10 15:00 10/13/It 15:01) 10/13/10 5:00 10/13/10 15:00

1500 10/13/10 15:00 10/13/10 15:00 10/13/10 15:00

10/13/10 15:00 10/13/10 15:00 10/13/10 15:00

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 0260C

EPA 8260C

11/8/10 9:52

0

C)

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO8

E104009-10

Matrix: Waste

Station ID: HERCO8 Date Collected: 9/29/10 8:50 C/IS Vu,nher

.dnalyte

R4-7156

(m- and/or p-)Xylene

630-20-6

Results Qualifiers

Units

1fRL

1.0 U

mg/kg

1 0

1,1,1 ,2-Tetrachloroethane

1.0 U

mg/kg

1 A ‘•°

71-55-6

1,1,1 -Trichloroethane

1.0 U

mg/kg

1 0

79-34-5

1,1 ,2,2-Tetrachloroethane

1.0 U

mg/kg

i n 1.

76-13-1

1 I ,2-Trichloro- I ,2,2-Trifluoroethane (Freon 113)

1.0 U

mg/kg

I

79-00-5

1,1 ,2-Trichloroethane

1.0 U

mg/kg

1

75-

1,1 -Dichloroethane

1.0 U, J, QL-1

mg/kg

I n

75-35-4

1,1 -Dichloroethene (1,1-Dichioroethylene)

1.0 (S

mg/kg

‘•

563-58-6

1,1 -Dichloropropene

1.0 U

mg/kg

1 0

87-61-6

1 ,2,3-Trichlorobenzene

1.0 U

mg/kg

A

96-18-4

1 ,2,3-Trichloropropane

1.0 U

mg/kg

I 0

120-82-1

1 ,2,4-Trichlorobenzene

1.0 (5

mg/kg

i

n

95-63-6

I ,2,4-Trimethylbenzene

1.0 U

mg/kg

1

A

96-12-8

1 ,2-Dibromo-3-Chloropropane (DBCP)

2.0 U

mg/kg

n

106-93-4

1,2-Dibromoethane (EDB)

1.0 U

mg/kg

n

95-50-1

I ,2-Dichlorobenzene

1.0 (5

mg/kg

1 A 1.1)

107-06-2

1 ,2-Dichloroethane

1.0 U

mg/kg

I 0

78-87-5

1 ,2-Dichloropropane

1.0 U

mg/kg

1

108-67-8

I ,3,5-Trimethylbenzene

1.0 U

mg/kg

1 0

541-73-I

1 ,3-Dichlorobenzene

1.0 U

mg/kg

1

142-28-9

1 ,3-Dichloropropane

1.0 U

mg/kg

1 0 1 0

A

A

106-46-7

1 ,4-Dichlorobenzene

1.0 U

mg/kg

594-20-7

2,2-Dichloropropane

1.0 U

mg/kg

O

67-64-1

Acetone

8.0 U

mg/kg

0 A

71-43-2

Benzene

1.0 U

mg/kg

i

n

108-86-1

Bromobenzene

1.0 U

mg/kg

1 0

74-97-5

Bromochioromethane

1.0 U, J. QL-1

mg/kg

1

75-27-4

Bromodichloromethane

1.0 U

mg/kg

1 0

75-25-2

Bromoform

2.0 U

mg/kg

2 0

Page 37 of 60

E104009 TCLPV VOA FINAL

A

Prepured

.Inuly.ed Method

10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10

10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20

10/06/10 12:10 10/06/10 12:10 10/06/10 12:10

10/08/10 15:20 10/08/10 15:20 10/08/10 15:20

EPA 8260C

10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10106/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10

10/08/10 15:20 10/08/10 15:20 10/08/10 5:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/00/10 15:20

EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

11/8/10 9:52

0

0

UN ITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 104)629, Hercules Inc Lab ID:

Sample ID: HERCO8

E104009-1O

Matrix: Waste

Station ID: HERCO8 Date Collected: 9/29/10 8:50 U IS .Vuinher

.4nalyte

74-83-9

Bromomethane

75-15-0 56-23-5

Results Qualifiers

Units

MRL

Prepared 10/06/10

10/06/10

12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12.10 10/06/10

15:20 10/08)10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 1520 10/08/10

40 U

mg/kg

40

C’arbon disulfide

1.0 U

mg/kg

1.0

Carbon

1.0 U

mg/kg

Tetrachloride

108-90-7

Chlorobcnzene

1.0 U

mg/kg

1.0

75-00-3

Chloroethane

1.0 U

mg/kg

1.0

67-66-3

Chloroform

1.0 U

mg/kg

1.0 1.0 1.0

74-87-3

Chloromethane

1.0 U

mg/kg

156-59-2

cis-1,2-Dichloroethene

1.0 U

mg/kg

10061-01-5

cis-1,3-Dichloropropene

1.0 U

mg/kg

10

110-82-7

Cyclohexane

1.0 C

mg/kg

1.0

1.0 U

mg/kg

1.0

1.0 L

mg/kg

1.0

1.0 U

mg/kg

1.0 1.0

124-48-1

Dibromochloromethane

74-95-3

Dibromomethane

75-71-8

Dichlorodifluoromethane (Freon

12)

100-41-4

Ethyl Benzene

1.0 U

mg/kg

87-68-3

1-lexachlorobutadiene

1.0 U

mg/kg

1.0 1.0 2.0

98-82-8

lsopropylbenzene

1.0 U

mg/kg

79-20-9

Methyl

2.0 U

mg/kg

Acetate

591-78-6

Methyl Butyl Ketone

2.0 U

mg/kg

2.0

78-93-3

Methyl Ethyl Ketone

2.0 U

mg/kg

2.0

108-10-I

Methyl Isobutyl Ketone

2.0 U

mg/kg

2.0

1634-04-4

Methyl T-ButyI Ether (M3

1.0 U

mg/kg

1.0

108-87-2 75-09-2

BE)

Methylcyclohexane Methylene Chloride

1.0 C

mg/kg

1.0

1.0 U

mg/kg

1.0

12:10

15:20

10/06)10 12:10 10/06)10 12:10 10/06/10 12:10 0/06/10

10/08)10 15:20 1008.10 15:20 10/08/10 15:20 1008/10

12:10

15:20

10/06/10 12:10 10/06/10 12:10 10/06111) 12:10 10/06/10

10/08/10 5:20 10/08/10 15:20 11800/10 15.20 1008/10

12:10

15:20

18/06)10 12:10 10/06/10 12:10 10/06/10 12.10 18.06110 12:10 10/06)10 12:10 10/06/10

10)08/10 15:20 10/08/10 15:20 l0/08i10 15:20 100810

5:20

10)08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 15:20 10/08/10 1520 10/08/10 5:20

103-65-1

n-Propylbenzene

1.0 U

mg/kg

1.0

95-49-8

o-Chlorotoluerie

1.0 U

mg/kg

1.0

95-47-6

o-Xylene

1.0 U

mg/kg

1.0

106-43-4

p-Chlorotoluene

1.0 Ii

mg/kg

1.0

99-87-6

p-lsopropyltoluene

2.6

mg/kg

1.0

sec-Butylbenzene

1.0 U

mg/kg

1.0 40

10:06/10 12:10

135-98-8 100-42-5

Page 38 of6O

n-Butylbenzene

1.0 U

mg/kg

1.0

40 U

Styrene

E104009 TCLPV VOA FINAL

mg/kg

15.20

10/08/10 15:20 1008/10

12.10

10/06/10 12:1(1 10/06/10 1210 0/06/IS 12:10 10/06/10 12:10 10/06/10 12:111 10/06/10 12:10 10/06/10 12:10

104-51-8

.lnulvzed Method EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA

8260C

EPA 8260C EPA

8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C I/PA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

11/8/10 9:52

0

0 6

UNTTED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700

f1

D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO8 Station ID: HERCO8

E104009-10

Matrix: Waste

Date Collected: 9/29/10 8:50 C4S Number

4nalye

Results Qualifiers

98-06-6

tert-Butylbenzene

127-18-4

Un its

MRL

Prepared

1.0

10/06/10 12:10

15:20

10/06/10

10/08/10 15:20 10/08/10 15:20 10108/10 15:20 1008 0

1.0 U

mg/kg

Tetrachloroethene (Tetrachloroethylene)

1.0 U

mg/kg

1.0

108-88-3

Toluene

34

mg/kg

1.0

156-60-5

trans-1,2-Dichloroethene

1.0 U

mg/kg

1.0

10061-02-6

trans-1.3-Dichloropropene

1.0 U

mg/kg

1.0

79-01-6

Trichloroethene (Trichloroethylene)

1.0 U

mg/kg

75-69-4

Triehlorofluoromethane (Freon 11)

1.0 U

mg/kg

1.0

75-01 -4

Vinyl chloride

1.0 U

mg/kg

1.0

20 U

mg/kg

20

1.0

12:10 10/06/10 1210 10/06/10 12:10 I0,’06.’l0 12:10

.4nav;ed Method 10/08/10

5:20

10/06/10 12:10 10:06/10 12:10 10/08/10 12:10

10/08/10 15:20 10/08/10 15:20 10/08/10 15:20

10/06/10

10/08/10

210

520

EPAN26OC

EPA 8260C EPA

8260C

EPA 8260C EPA

8260C

EPA 8260C EPA 8260C EPA 8260C

Tentatively Identified Compounds: R4-0000

Page 39 of 60

Tentatively Identified Compounds

E104009 TCLPV VOA FINAL

8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 1 0-0629, Hercules Inc Reported by Kristin Trapp -

TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO8

E104009-10

Matrix: Waste

Station ID: HERCO8 Date Collected: 9/29/10 8:50

c4s Results Qualifiers

Units

4IRL

Nwnher

.4nalyte

75-35-4

1,1 -Dichloroethene (11 -Dichloroethylene):

NA-5

0.00050

107-06-2

1,2-Dichloroethane:

NA-5

0,00050

106-46-7

l,4-Diclilorobcnzcne:

NA-5

0.00050

71-43-2

Benzene:

\A-5

0.00050

56-23-5

Carbon Tetrachioride:

NA-5

0.00050

108-90-7

Chlnrobenzene:

NA-S

0.00050

67-66-3

Chloroform:

NA-S

0.00050

87-68-3

Flexachlorobutadiene:

NA-s

0.00050

78-93-3

Methyl Ethyl Ketone:

NA-5

0.0010

127-18-4

Tetrachloroethene (Tetrachloroethylene):

NA-S

0.00050

79-01-6

Trichloroethene (Trichioroethylene):

NA-5

0.00050

75-01-4

Page 40 of6O

Vinyl chloride:

NA-5

E104009 TCLPV VOA FINAL

0.00050

Prepared 10/13/10 1500 10/13/Il) 1500 1011310 5:00 10/13/10 5.00 10/13/10 1500 10/13/10 15:00 10/13/JO 1500 10/13/10 15:00 10/13/10 15:00 10/13/10 15:00 10/13/10 500 10/13/10 15:00

.lnaiv:ed Method 10/13/10 1500 10/13/10 15:00 10/13/10 15:00 10/13/JO 15:00 10/13/10 500 10/13/JO 15:00 10/13/10 15:00 10/13/10 15:00 10/13/10 15:00 10/13/10 1500 10/1 3/JO 10/13/10 15:00

EPA 8260C EPA 8260C EPA 8260C EPA

8260C

EPA 8260C EPA

8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

11/8/10 9:52

0

0

UNiTED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO9-B Station ID: HERC09 Date Collected: CIS N,unher

E104009-11

Matrix: Waste

9/29/10 14:20

.4nalyre

Results Qualifiers

R4-7 156

(m- and/or p-)Xylcne

63 0-20-6

Units

MRL

Prepared 10/06110

3.2

mg/kg

25

1,1,1 ,2-Tetrachloroethane

2.5 U

mg/kg



71-55-6

I ,1,1-Trichloroethane

2.5 U

mg/kg

c

79-34-5

1,1 ,2,2-Tetrachloroethane

2.5 U

mg/kg

2 5

12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10

1,1 .2-Trichloro-1 ,22-Trifluoroethane (Freon 113)

2.5 U

mg/kg

25

12:10

1,1 ,2-Trichloroethane

2.5 U

mg/kg



1,1 Dichioroethane

2.5 U,J,QL-1

mg/kg

79-00-5

-

S

S

75-35-4

1,1-Dichloroethene (1 ,l-Dichloroethylene)

2.5 U

mg/kg

5

563-58-6

1,1 -Dichloropropene

2.5 U

mg/kg

2 5

87-61-6

1 ,2,3-Trichlorobenzene

96-18-4

1 ,2,3-Trichloropropane

120-82-1

1 ,2,4-Trichlorobenzene

95-63-6

1 ,2,4-Trimethylbenzene

96-12-8

I ,2-Dibromo-3-Chloropropane (DBCP)

mg/kg

2

2.5 U

mg/kg

2 5

2.5 U

mg/kg

.,

3.0

mg/kg

2 5

5.0 U

mg/kg

5 •n 2 5

2.5 U

e

-

106-93-4

1 ,2-Dibromoethane (EDI3)

2.5 U

mg/kg

95-50-1

I ,2-Dichlorobenzene

2.5 U

mg/kg

2 5

107-06-2

I ,2-Dichloroethane

2.5 U

mg/kg

2 5

78-87-5

1 ,2-Dichloropropane

2.5 U

mg/kg

2

108-67-8

I .3,5-Trimelhylbenzene

2.5 U

mg/kg

2 5

541-73-1

1 ,3-Dichlorobenzene

2.5 U

mg/kg

.,

142-28-9

1 ,3-Dichloropropane

2.5 U:

mg/kg

2 5

106-46-7

I ,4-Dichlorobenzene

2.5 U

mg/kg

2 5

594-20-7

2.2-Dichloropropane

2.5 U

mg/kg

.,

67-64-1

Acetone

20 U

mg/kg

‘A °

7 1-43-2

Benzene

170

mg/kg

)

108-86-1

Bromobenzene

2.5 U

mg/kg

74-97-5

Bromochioromethane

2.5 U, J, QL-1

mg/kg

2 5

75-27-4

Bromodichloromethane

2.5 U

mg/kg

2 5

75-25-2

Bromoform

5.0 U

mg/kg

5 0

Page 41 of6O

El 04009 TCLPV VOA FINAL

-

e

-

-

2 5

-

10/06/10 12:10 10/06/TO 12:10 10/06/10

12:10 10:1/6/TO 12:10

10/06/10 12:10 10/06/TO I2:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/TO 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/TO 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:l0 10/06/10 12:10 10/06/10 12:10 0/06/TO 12:10

Analyzed Method 10/OS/TO 17:30 10/08/10 17:30 008. TO 7:30 10/08/10 17:30 1008/TO 7:30

EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C

10/08/10 17:30

EPA 8260C

10,08:10 17:30

EPA 8260C

10/08/10 17:30

EPA 8260C

0/08/10 7:30 10/08/10 17:30 0/08/TO 17:30 10/08/10 17:30 10/08/TO 17:30 10/08/10 17:30 10/08/10 17:30 10/08/10 17:30 10/08/TO 7:30 10/08/10 17:30 10.00/10 l7:30 10/08/10 17:30 10/08/TO 17:30 10/08/10 17:30 10/08/lO 17:30 10/08/10 17:30 10/08/10 17:30 10/08/10 17:30 b/Os/b 17:30 10/08/10 17:30 10/08/TO 17:30

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: NERCO9-B

Matrix: Waste

Station ID: l-IERCO9 Date Collected:

E104009-11

9/29/10 14:20

U IS ResuII Qualijiers

N,,,,ther

.tnalyre

74-83-9

Bromomethane

100 U

elfRL

Prepared

mg/kg

100

10/06110 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:l0 10/06/10 12:10 10O6/I0 12:10 10106/10 1210 6/06/10 12:10 10/06/10 12:10 10/06/tO 12:10 10/06/10 12:10 10/06/10 12 10 10/06/10 1210 10/06/10 12:18 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 I0’O&IO 12:10 18/06/10 12:10 10/06/10 12:10 10)06)10 12:10 10/06/tO 12:10 b0/06’IO 12:10 10/06/10 12:10 10/06)18 12:18 10/06/10 12:10 10)06/10 12:10 10/06/10 12:10 10/06/JIb 12:111 006 10

Units

75-15-0

Carbon disulfide

2.5 15

mg/kg

2,5

56-23-5

Carbon Tetrachloride

2.5 U

mg/kg

2.5

108-90-7

Chlorobenzene

2.5

15

mg/kg

2.5 2.5

75-00-3

Chloroethane

2.5 U

mg/kg

67-66-3

Chlorofonn

2.5 15

mg/kg

2.5

Chloromethane

2.5 U

mg/kg

2.5

cis-1,2-Dichloroethene

2.5 15

mg/kg

2.5

74-87-3 56.59-2 10061-01-5

cis-1,3-Dichloropropene

2.5 U

rug/kg

2.5

110-82-7

Cyclohexane

29

mg/kg

2.5

124-48-1

Dibromochloromethane

2.5 U

mg/kg

2.5

2.5

74-95-3

Dibromoinethane

2.5 U

mg/kg

75-71-8

Dichlorodifluoromethane (Freon l2

2.5 U

mg’kg

2.5 2.5

100-41-4

Ethyl Benzene

1.0 J, Q-2

mg/kg

87-68-3

Elexachlorobutadiene

2.5 U

mg/kg

2.5

98-82-8

Isopropylbenzene

6.0 15, D-4

mg/kg

6.0

79-20-9

Methyl Acetate

5.0 U

mg/kg

5.0

591 -78-6

Methyl Butyl Ketone

5.0 15

mg/kg

5.0

78-93-3

Mcth1 Ethyl Ketone

5.0 U

mg.’kg

5.0

108-10-1

Methyl Isobutyl Ketone

5.0 L’

mg/kg

5.0 2.5

2.5

1634-04-4

Methyl T-Butyl Ether (MTBE)

2.5 U

mg/kg

108-87-2

Methylcyclohexane

8.2

mg/kg

75-09-2

Methylene Chloride

2.5 U

mg/kg

2.5

104-51-8

n-Butylbenzene

2.5 15

mg/kg

2.5

103-65-1

n-Propylhenzene

2.5 U

mg/kg

2.5

95-49-8

o-Chlorotoluene

2.5 15

mg/kg

2.5

95-47-6

o-Xylene

1.0 J, Q-2

mg/kg

2.5

2.5 15

mg/kg

2.5

mg/kg

25

106-43-4

p-Chlorotoluene

99-87-6

p-lsopropyltoluene

610

135-98-8

sec-Butylbeozene

2.5 15

mg/kg

2.5

100-42-5

Styrene

100 U

mg/kg

100

Page 42 of6O

El04009 TCLPV VOA FINAL

2:10

.4nalyzed ,lh’thod 10/08/10 17:30 10/08/10 17:30 10/08/10 17:30 10/08110 17:30 10:08,10 I7:30 10/08/10 17.30 l0:06,I0 7:30 b/OS/b 17:30 10/08/b 17:30 10/08/10 17:30 10/08/10 17:30 10/08/10 17:30 10/08/10 17:30 10/08/10 17:30 10/08/10 17:30 10)08/10 17:30 l008/l0 17:30 10/08/10 17:30 10/08/10

17:30 10/08/10 17:30 10/08/10 7:30 10/08/tO 17:30 10/08/10 17:30 10/08/10 17:30 10/08/10 17:30 10/08/10 17:30 10/08/10 17:30 10/08110 17:30 10/07/10 17:17 10)08/10 730 1008.10 7:30

EPA 8260C EPA

8260C

EPA 8260C EPA 8260C EPA 8260C EPA

8260C

EPA 8260C EPA

8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA

8260C

EPA %260C EPA 8260C EPA 8260C EPA

8260C

EPA

8260C

EPA 8260C EPA 8260C EPA

8260C

EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO9-B Station ID: I{ERCO9

E104009-11

Matrix: Waste

Date Collected: 9/29/10 14:20 C.4S .V,unber

4nalyte

Results Qualifiers

98-06-6

tert-Butylbenzene

2.5 U

127-18-4

Tetrachloroethene (Tetrachloroethylene)

2.5 U

108-88-3

Toluene

156-60-5

trans-1,2-Dichloroethene

Units

MRL

mg/kg

2.5

mg/kg

2.5

Prepured 0/06/jO

trans-1,3-Dichloropropene

2.5 U

mg/kg

2.5

79-01-6

Trichloroethene (Trichloroethylene)

2.5 U

mg/kg

2.5

Trichiorofluoromethane (Freon 11)

2.5 U

mg/kg

2.5

75-01-4

Vinyl chloride

2.5 U

mg/kg

2.5

12:10 10/06/10 12:10 0/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10

50 U

mg/kg

50

10/06/10 1IO

1100

2.5 U

mg/kg

25

mg/kg

2.5

.inulyzed ‘Jethod 0/08110 7:30 10/08/10 17:30 10/07/10 17:17 10/08/10 17:30 10/08/10 7:30 10/08/jo 17:30 1008/10 7:30 10/08/10 17:30

EPA

8260C

EPA

8260C

10/08/10 1730

EPA 8260C

EPA 8200C EPA 8260C EPA

8260C

EPA 8260C EPA 8260C

EPA 8260C

Tentatively Identified Compounds: R4-0000

Page 43 of 60

Tentatie1y ldentilicd Compounds

E104009 TCLPV VOA FINAL

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO9-B

E104009-11

Matrix: Waste

Station ID: IIERCO9 Date Collected: 9/29/10 14:20 C4S

IIRL

Prepared

mg/L

0.25

0)13/10

10/13/10

1500

1711

0.25 U

mgfL

0.25

0.25 U

mg!L

0.25

10/13/Il) 15.00 l0’13;I0

mgfL

0.25

10/13/10 17:1! 10/13/10 1711 1(1/13/10 17:11 10/1310

Results Qualijiers

Nnrnber

.4nalyte

75-35-4

1,1-Dichloroethene (1,1 -Dichloroethylene)

0.25 U

107-06-2

1,2-Dichioroethane

1/nits

106-46-7

1,4-Dichlorobenzene

71-43-2

Benzene

56-23-5

Carbon Tetrachloride

0.25 U

mg.’L

0.25

108-90-7

Chlorobenzene

0.25 U

mg/L

0.25

67-66-3

Chloroform

0,25 U

mg/L

0.25

025 0.50

1.8

87-68-3

Hexachlorobutadiene

0.25 U

mgfL

78-93-3

Methyl Ethyl Ketone

0.50 U

mg/L

127-18-4

retrachloroethene (Tetrachloroethylene)

025 U

mgIL

0.25

79-01-6

Trichloroethene (Trichloroethylene)

0.25 U

mg/L

0.25

75-01-4

Vinyl chloride

0.25 U

mg/L

0.25

Page 44 of6O

E104009 TCLPV VOA FINAL

10)13/10 15:00 l0;13.l0

.1nalyzed ,lfethod

1500

17:11

(0)13/10 1500 10/13/10 5:00 10/13/10 500 10/13/10

10/13/10 1711 10/13/It 17:11 10/13/10 17:11 10/13/10

1500

1711

(0/13/10 15:00 10)13/10 (5:00 10/13/10 15:00

10/13/10 17:11 10/13/10 17:11 10/13/10 17:11

EPA 0260C’

EPA

8260C

EPA 8260c EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA

8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: I 00629

Project: 10-0629, Hercules Inc Reported by Kristin Trapp

LpRo

-

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERC1O-B Station ID: HERCIO

E104009-12

Matrix: Waste

Date Collected: 9/29/10 14:15 C IS .‘V,,mher

.4nu4’te

R4-7156

(m- and/or p-)Xylene

25 U

mg/kg

25

630-20-6

1,1,1 ,2-Tetrachloroethane

25 U

mg/kg

25

71-55-6

1,1,1-Trichloroethane

25 U

mg/kg

25

10/06/10 12:10

17:43

EPA 8260C

79-34-5

1,1,2,2-Tetrachloroethane

25 U

mg/kg

25

25 U

mg/kg

25

10/07/10 17:43 10)07/10 17:43

EPA 8260C

1,1,2-Trichloro-1,2,2-Trifluoroethane

10/06/10 12:10 10/06/10 12:10

25 U

mg/kg

25

10/07/10 17:43

El’A 8260C

25 U, J, QL-1

mg/kg

25

10/06/10 12:10 10/06/10 12:10 10/06/10

10/07/10

EPA 8260C

76-13-1

Results Qualifiers

Units

MRL

Prepared

.1 nat vzed

10/06/10

10/07/10

12:10 10/06/10

17:43 10/07/10 17:43 10/07/10

12:10

Method

EPA 8260C EPA 8260C

EPA 8260C

(Freon 113) 1,1,2-Trichloroethane

79-00-5 75-34-3 i/

/ 1,1-Dichloroethane

75-35-4

1,1-Dichloroethene

25 U

mg/kg

25

563-58-6

(1 ,1-Dichloroethylene) 1,1-Dichloropropene

25 U

mg/kg

25

87-61-6

1,2,3-Trichlorobenzene

25 U

mg/kg

25

96-18-4

1,2,3-Trichloropropane

25 U

mg/kg

25

120-82-1

1,2,4-Trichlorobenzene

25 U

mg/kg

25

95-63-6

l,2,4-Trimethylbenzene

7.0 J, Q-2, QR-l

mg/kg

25

96-12-8

1,2-Dibromo-3-Chloropropane (DBCP)

50 U

mg/kg

50

106-93-4

1,2-Dibromoethane (EDB)

25 U

mg/kg

25

95-50-1

l,2-Dichlorobenzene

34

mg/kg

25 25

107-06-2

1,2-Dichloroethane

25 U

mg/kg

78-87-5

1 ,2-Dichloropropane

25 U

mg/kg

25

108-67-8

1,3,5-Trimethylbenzene

25 U

mg/kg

25

541-73-1

1,3-Dichlorobenzene

25 U

mg/kg

25

142-28-9

1,3-Dichloropropane

25 U

mg/kg

25

106-46-7

1 ,4-Dichlorobenzene

25 U

mg/lcg

25

594-20-7

2,2-Dichloropropane

25 U

mg/kg

25

67-64-1

Acetone

U

mg/kg

200

71-43-2

Benzene

108-86-1

Bromobenzene

74-97-5

200

mg/kg

25

25 U

mg/kg

25

Bromochloromethane

25 U, J. QL-1

mg/kg

25

75-27-4

Broniodichloromethane

25 U

mg/lcg

25

75-25-2

Bromoform

50 U

mg/kg

50

Page 45 of 60

140

E104009 TCLPV VOA FINAL

12:10

10/06/10 12:10 10/06/10 12:10 10/06/10 2:10 10/06/10 12:10 10)06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10)06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10

12:10

10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10

17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10)07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07)10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43 0/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43

EPA 8260C EPA

8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA S260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA

8260C

EPA

8260C

11/8/10 9:52

0

0

UNiTED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc

-

Reported by Kristin Trapp

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCIO-B

E104009-12

Matrix: Waste

Station ID: HERC1O Date Collected: 9/29/10 14:15 U i.c .Vu,nher

.4rndrte

74-83-9

Bromomethane

Results Qualifiers

Units

MRL

Prepared 10/06/10 12:10 10/06/10 12:10 10/06/10 72:10 10/06/JO 12:10 70/06/70 12:10 0/06/JO 12:10 10/06/10 12:10 10/06/It 12:70 10/0610 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:70 10/06/10 12:10 10/06/10 12:10 10/06/JO 12:10 10/06/70 12:10 10/06/10 12:10 10/06/JO 12:10 10/06/10 12:10 10/06/10 12:71) 10/06/10 12:10 0/06/10 72:10 10/06/10 12:10 10/06/11) 12:10 10/06/10 12:10 10/tO/ID 12:10 10/06/10 12:10 10/06/Ill 1210 0/06/10 12:10 10/06/It 12:70 1006/10 1210

100 U

mg/kg

I°°

2S

75-15-0

Carbon disulfide

25 U

mg/kg

56-23-5

Carbon Tetrachioride

25 U

mg/kg

.,

108-90-7

Chlorobenzene

25 U

mg/kg

2S

75-00-3

Chioroethane

25 U

mg/kg

2S

25 U

mg/kg

7C

67-66-3

Chloroform

74-87-3

Chiorornethane

25 U

mg/kg

156-59-2

cis-1 ,2-Dichloroethene

25 U

mg/kg

2S

25 U

mgkg

-

10061-01-5

cis- 1,3-Dichloropropene

110-82-7

Cyclohexane

1500

mg/kg

.,

124-48-1

Dibromochioromethane

25 U

mg/kg

25

74-95-3

Dibromomethane

25 U,J,QL-l

mg/kg

2S

75-71-8

Dichlorodifluoromethane (Freon 12)

25 U

mg/kg

2S

mg/kg

2S

4.0 J, Q-2

100-41-4

Ethyl I3enzene

87-68-3

Flexachiorobutadiene

25 U

mg/kg

-,

98-82-8

lsopropylbenzene

70 U, D-4

mg/kg

7O

79-20-9

Methyl Acetate

50 U

mg/kg

S0

59 1-78-6

Methyl Butyl Ketone

50 U

mg/kg

78-93-3

Methyl Ethyl Ketone

50 U

mg/kg

108-10-1

Methyl Isobutyl Ketone

50 U

mg/kg

So

1634-04-4

Methyl T-Butyl Ether (MTBE)

25 U

mg/kg

2S

108-87-2

Methylcyclohexane

12 J. Q-2

mg/kg

2S 2S

75-09-2

Methylene Chloride

25 U

mgkg

104-51-8

n-Butylbenzene

25 U

mg/kg

So

=

103-65-I

n-Propylbenzene

25 U

mgkg

2S

95-49-8

o-Chlorotoluene

25 U

mg/kg

2S

95-47-6

o-Xylene

25 U

me kg

‘,

106-43-4

p-Chlorotoluene

25 U

mg/kg

2S

99-87-6

p-lsopropylloluene

mg kg

2S

135-98-S 100-42-5

Page 46 of6O

sec-Butylbenzene

3400 25 U

100 U

Styrene

E104009 TCLPV VOA F[NAL

mg/kg

2S

mg/kg

inn

.ina(vzed 11 fethod 10/07/10 17:43 10/07/10 17:43 10/07/JO 17:43 10/07/10 17:43 I 0/0710 17:43 10.07/10 77:43 10/07/10 ‘7:43 b/Ohio 17:43 1t507.’lO 17:43 111/07/10 17:43 1007.10 17:43 10/07/10 17:43 10/07/10 17:43 10/07)10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 77:43 10/07)70 17:43 70/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 17:43 10/07/10 ‘7:43 10/07/10 17.43 10/07/10 17:43 10/07/10 7:43 10/07/10 17:43 10,07)10 7.43 1007.10 17:43 10/07/10 17:43 10/07/10 17:43

EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 8260C EPA 826CC EPA 8260C EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 8260C EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 826CC EPA 8260C EPA 826CC

11/8/10 9:52

0

C) \D s:e

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Suppofl Division 980 College Station Road, Athens, Georgia 30605-2700

Mt •1

D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Kristin Trapp

PR

-

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCIO-B Station ID: HERC1O

E104009-12

Matrix: Waste

Date Collected: 9/29/10 14:15 CAS Number

4nalyre

Recoils Quahjiers

Unils

IIRL

Prepared

Analyzed lfeckod

98-06-6

tert-Butylbenzene

127-18-4

Tetrachloroethene (Tetrachloroethylene)

108-88-3

Toluene

156-60-5

trans-1,2-Dichloroethene

25 U

mg/kg

10061-02-6

trans-1,3-Dichloropropene

25 U

mg/kg

25

79-01-6

Trichloroethene (Trichloroethylene)

25 U

mg/kg

25

Trichiorofluoromethane (Freon Ill

25 U

mg/kg

25

10/06/tO

10/07/10

75-01-4

25 U 25 U 3100

Vinyl chloride

25

10/06/10 12:10

10/07/10 7:43

EPA 8260C

mg/kg

25

10/06/ID 12:10

10/07/10 17:43

EPA 8260C

mg/kg

25

10/06/tO 12:10

10/07110 17:43

EPA826OC

10/06/10 12:10 10/06/10

10/07/10 17:43

EPA 8260C

mg/kg

25

1210

10/07/10 7:43

EPA 8260C

10/06/10 12:10

10/07/10 17:43

EPA 8260C

20

10/0710

743

25 U

mg/kg

25

10/06/10

12:10

17:43

500 U

mg/kg

500

100610 20

l007 10 743

EPA

8260C

EPA 8260C

Tentatively Identified Compounds: R4-0000

Page 47 of 60

Tentatively Identitieci Compounds

E104009 TCLPV VOA FINAL

EPA

8260C

11/8/10 9:52

0

0

IJNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERC1O—B

E104009-12

Matrix: Waste

Station ID: HERCIO Date Collected: 9/29/10 14:15 C4S Number

Results Qualifiers

.4na!yte

Units

MRL

Prepared

.1nuIzed ,tiethod

75-35-4

1,1-Dichloroethene (1.1 -Dichloroethylene)

025 U

mg/L

0.25

10/13/10 15:00

10/13/10 17:37

EPA 8260C

107-06-2

1,2-Dichloroethane

0.25 C

mg/L

0.25

0.25 U

0.25

10,13/10 17:37 10/13/10 17:37 1o/13.’Io 17:37 10/13/10 17:37 10/13/10 17:37 10/13/10

EPA 8260C

mg/L

10)13/10 5:00 10/13/jo 15.00 10/13/10 15:00 10/13/10 15:00 10/13/10 15:00 10/13/10

106-46-7

1,4-Dichlorobenzene

71-43-2

Benzene

2.2

mgfL

0.25

0.25

EPA

8260C

EPA

8260C

EPA

8260C

EPA

8260C

56-23-5

Carbon Tetrachloride

0.25 U

mg/L

108-90-7

Chlorobenzene

0.25 U

mg/L

0.25

67-66-3

Chloroform

0.25 U

mgfL

0.25

15:00

17:37

EPA 8260C

0.25

0/13/10 15:00

10/13/10 17:37

EPA 8260C

0.50

10/13/10

10/13/10

EPA 8260C EPA 8260C

87-68-3

Hexachlorobutadiene

0.25 C

mg/L

78-93-3

Methyl Ethyl Ketone

0.50 U

mg/L

127-18-4

Tetrachloroethene (Tetrachloroethylene)

0.25 C

mg/L

79-01-6

Trichloroethene (Trichloroethylene)

0.25 U

mgrL

0.25 U

mg/L

75-01-4

Page 48 of6O

Vinyl chloride

E104009 TCLPV VOA FINAL

0.25

10/I 3/la

15:00

10/13/10 17:37

0.25

l0/13’IO

10/13/10

1500 10/13/10 1500

17:37 10/13/10 17:37

0.25

EPA

8260C

EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCII-B Station ID: HERC1I

E104009-13

Matrix: Waste

Date Collected: 9/29/10 14:30

(. IS Nunzhcr

.4nalyre

R4-7156

(m- and/or p-)Xylene

630-20-6

Results Qualifiers

Units

1IRL

Prepared

25

10/06/10 12:10

0/07/10 009

EPA 8260C

10/06/10

10/07/10 18:09

EPA 8260C

25 U

mg/kg

1,1,1 ,2-Tetrachloroethane

25 U

mg/kg

25

71-55-6

1,1,1 -Trichloroethane

25 U

mg/kg

-,

79-34-5

1,1 ,2,2-Tetrachloroethane

25 U

mg/kg

2S

76-13-I

I 1 2 Trichloro 1 2 2 Tnfluoroethane (Freon 113)

25 L

mg/kg

2S

79-00-5

1,1 ,2-Trichloroethane

25 U

mg/kg

2S

25 U,J,QL-1

mg/kg

,1-Dichloroethane

25

12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06110 12:10 10:06/10

10)07/10 18:09

EPA 8260C

12:10

18:09 10/07/10 18:09

EPA 8260C

18/07/10 18:09 10/07/10 18:09

EPA 8260C

25 U

mg/kg

)5

1,1 -Dichloropropene

25 U

mg/kg

25

87-61-6

1 ,2,3-Trichlorobenzene

25 U

mg/kg

25

10/06/10 12:10 10/06/10 12:10

96-18-4

1 ,2,3-Trichloropropane

25 U

mg/kg

25

120-82-1

1 ,2,4-Trichlorobenzene

25 U

mg/kg

25

95-63-6

1 ,2,4-Trimethylbenzene

25 U,J,QR-1

mg/kg

25

96-12-8

1,2-Dibromo-3-Chloropropane (DBCP)

49 U

mg/kg

49

106-93-4

1 ,2-Dibromoethane (EDB)

25 U

mg/kg

25

1 ,2-Dichlorobenzene

25 U

mg/kg

25

107-06-2

I ,2-Djehloroethane

25 U

mg/kg

25

78-87-5

1 ,2-Dichloropropane

25 U

mg/kg

108-67-8

I ,3,5-Trimethylbenzene

25 U

mg/kg

541-73-1

1 ,3-Dichlorobenzene

25 U

142-28-9

I .3-Dichloropropane

25 U

10/06/10

10/07/10

18:09 10/07/10 18:09

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

EPA 8260C

25

1006/10 12:10

10(17 0 16:09

EPA 8260C

mg/kg

25

10/06/10 12:10

10/07/10 18:09

EPA 8260C

mg/kg

25

10/06/10

l0;07/l0

EPA 8260C

25

(8:09 10/07/10 18:09 10/07/10 18:09 10/07/10

0:09 10/07/10 18:09 007/10 1809

1 ,4-Dichlorobenzene

25

U

mg/kg

25 U

mg/kg

25

67-64-1

Acetone

200 U

mg/kg

200

71-43-2

Benzene

77

mg/kg

25

108-86-1

Bromobenzene

25 U

mg/kg

25

74-97-5

Bromochioromethane

25 U,J.QL-1

mg/kg

25

75-27-4

Bromodichioromethane

25 U

mg/kg

25 49

00610 1210

E104009 TCLPV VOA FINAL

10/07/10

EPA 8260C

25

2,2-Dichioropropane

Page 49 of 60

18:09 10/07/10 18:09 10/07/10 8:09 10/07/10 18:09

EPA 8260C

(8.09 10/07/10 18:09

12:10

594-20-7

49 U

10/07/10

EPA 8260C

10/06/10 12:10

12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 2:10 10/06/10 12:10 10/06/10 12:10

Bromoform

1007/10

12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10

106-46-7

75-25-2

EPA 8260C EPA 8260C

1 ,1-Dichloroethene (1,1 -Dichloroethylene)

95-50-1

10/07/10

18:09 10/07/10 18:09 10/07/10 8:09

10/06/10 12:10

75-35-4

.lnatvzed Ofetlwd

mg/kg

18:09

(0/07/10 18:09 10/07/10 18:09 10/07/10

EPA 8260C EPA

8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA

8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athejis, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc - Reported by Kristin Trapp

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCI1-B

E104009-13

Matrix: Waste

Station ID: HERC11 Date Collected: 9/29/10 14:30

c.1,s .Vuwher

74-83-9

Results Qualiliers

.4nalyfr

98

Bromomethane

U

Units

mg/kg

MRL

Prepared

.lnalyzed ,lfetlwd

00

10/06/10 12:10

10/07/10

8:09

EPA 8260C

10/06)10 12.10 10/06/10 12:10

10/07/10 (8:09

EPA 8260C

75-15-0

Carbon disulfide

25 U

mg/kg

2S

56-23-5

Carbon Tetrachioride

25 U

mg/kg

2S

108-90-7

Chlorobenzene

25 U

mg/kg

2S 2S

10/07/10

18:09 10/07/10 18:09

EPA 8260C

EPA 8260C

75-00-3

Chioroethane

25 U

mg/kg

67-66-3

Chloroform

25 U

mg/kg

2S

74-87-3

Chlororncthane

25 U

mg/kg

25

12:10 10/06/10 12:10 0/06/10 12:10 10/06/10 12:10

2S

0/06/10 12:10

10/06/10 12:10

10/07/10

18:09

EPA 8260C

10/07/10

EPA 8260C

156-59-2

cis-l ,2-Dichloroethene

10061-01-5

cis- 1 .3-Dichloropropene

110-82-7

Cyclohexane

124-48-1

Dibromochloromethane

25 U

mg/kg

12:10

18:09

25 U

mg/kg

25

10/06110

b0OTIO l8:09

EPA 8260C

25

(0/07/lU 18:09

EPA 8260C

25

25 U,J,QL-l

Dichiorodifluoromethane (Freon 12)

25 U

mg/kg

100-41-4

Ethyl Benzene

25 U

mg/kg

87-68-3

Flexachlorobutadiene

25 U

mg/kg

12:10 10/06/10 12-10 10/06/10 12:10 0/06/ID 2:10

18:09

b/OS/b (2:10

(0/07/10 18:09

EPA 8260C

26

10/06/10 12:I0

10/07/10 18:09

EPA 8260C

10/06/10

10/07/10 18:09 1(1/07/ID

Isopropylbenzene

26 U, D-4

mg/kg

Methyl Acetate

49 U

mg/kg

591-78-6

Methyl Butyl Ketone

49 U

mg/kg

49

12:10 10/06/10 2:10

78-93-3

Methyl Ethyl Ketone

49 U

mg/kg

49

10/06/10 12:10

108-10-I

Methyl Isobutyl Ketone

49 U

mg/kg

1634-04-4

Methyl T-Butyl Ether (MTBE)

25 U

mg/kg

25

108-87-2

Methylcyclohexane

7.4 J, Q-2

mg/kg

2S

75-09-2

Methylene Chloride

25 U

mg/kg

25

mg/kg

49

2S

10/06/16 1210 10/06/10 12:10 10/01)/JO 12:10 10/06/10 (2:10 0/06/10 12 (0 10/06/10

103-65-I

n-Propylbenzene

25 U

mg/kg

2S

95-49-8

o-Chlorotoluene

25 U

mg/kg

25

95-47-6

o-Xylene

25 U

mg/kg

25

10/06/10 12:10

25 1/

mg/kg

2S

10’86/b0 1210

-‘

0/06/10 12:10

2S

10/06/10 (2:10

98

0/06/10 1210

135-98-8 100-42-5

Page 50 of6O

sec-Butylbenzene

720 25 U

Styrene

98 U

E104009 TCLPV VOA FINAL

mg/kg

mg/kg mg/kg

EPA 8260C

10/07/lU

25

79-20-9

25 U

10/07/10 (8:09

EPA 8260C

98-82-8

p-lsopropyltoluene

EPA 8260C

10/06)10

Dibromomethane

99-87-6

EPA 8260C

2S

75-71-8

p-Chlorotoluene

EPA 8260C

25

74-95-3

106-43-4

EPA 8260C

mg/kg

100

n-Bulylbenzene

18:09 10/07/10 18:09 10/07/10 (8:09 10/07/10 18:09

mg/kg

25 U

mg/kg

104-51-8

007(0

(2:10 10)06/10 12:10

18.09 10/07/10 10:89

EPA 8260C

EPA 8260C EPA 8260C

10/07/lU (8:09

EPA

l0/07/10

EPA 8260C

18:09 (0/07/ID

18:09 (007/10 8:09

10/07/10 1809

10/07/10 18:09 (0/07110 8:09 10’07/10 18:09 (0,87/ID 18.09 10. 0710 18:09 10/07/IC

(8:09 0/07/It (8:09

8260C

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA

8260C.

EPA 8260C EPA 8260C EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules inc Lab ID:

Sample ID: HERCI1-B

E104009-13

Matrix: Waste

Station 1D: HERC11 Date Collected: 9/29/10 14:30 C4S Niun her

Results Qualijiers

4nulyte

Units

MRL

Prepared

.4nalyzed 10/07/10 18:09 10/07/10 18:09 10/07/10 18:09 10/07/10 18:09 10/07/10 809 10/07/10 18:09 10/07/10 18:09 10/07/jo 18:09

EPA 8260C

10/07/10 809

EPA

25 U

mg/kg

25

25 U

mgllcg

25

mg/kg

25

25 U

mg/kg

25

25 U

mg/kg

25

Trichloroethene (Trichloroethylene)

25 U

mg/kg

25

Trichlorofluoromethane (Freon 11)

25 U

mg/kg

25

Vinyl chloride

25 U

mg/kg

25

10/06110 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 1210 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10

500 U

mg/kg

500

10/06/10 1210

98-06-6

tert-Butylbenzene

127-18-4

Tetrachioroethene (Tetrachloroethylene)

108-88-3

Toluene

156-60-5

trans-1,2-Dichloroethene

10061-02-6

trans-1,3-Dichloropropene

79-01-6 75-69-4 75-014

2600

lkthod EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

Tentatively Identified Compounds: R4-0000

Page 51 of6O

Tentatively IdentiEed Compounds

E104009 TCLPV VOA F[NAL

8260C

11/8/10 9:52

0 DSTA,,

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc Repoed by Kristin Trapp -

TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: FIERCII-B Station ID: HERC1J Date Collected: C4S :Vn,nbar

E104009-13

Matrix: Waste

9/29/10 14:30

.4nalyte

Results Qualifiers

Units

MRL

Prepu red

.1 nut ved

10/21/10 00

1021/10 054

FP.\

EPA 8260C

75-35-4

1,1-Dichloroethene (1,1 -Dichloroethylene)

0025 U, J, H-8

mg’L

0.025

107-06-2

1,2-Dichloroethane

0.025 U, J. H-8

mg/L

0.025

10,21/10

10/21/10

106-46-7

1.4-Dichlorobenzene

0.025 U, J, H-8

mg/L

0.025

71-43-2

Benzene

mgfL

0.025

56-23-5

Carbon Tetrachloride

0.025 U, J, H-X, QL-3

mg/L

0.025

10/21/10 5:00 10/21/10 15:00 10/21/10

108-90-7

Chlorobenzene

0.025 C, J. 11-8

mg/L

0.025

67-66-3

Chloroform

0.025 U, J, 11-8

mg/L

0.025

87-68-3

Hexachlorobutadiene

0.025 C. J, }l-8

mg/L

0.025

78-93-3

Methyl Ethyl Ketone

0.050 U. J, Il-s

mg/L

0.050

127-18-4

Tetrachloroethene (Tetrachloroethylene)

0.025 C, J, H-S

rng/L

0.025

79-01-6

Trichloroethene (Trichloroethylene)

0.025 U, J. H-8

mg!L

0.025

10.21:10 0:54 10/21/10 18:54 10/21/10 054 10/21/10 18:54 10/21/10 18:54 10/21/10 18:54 10/21/10 18:54 10/21/18 18:54 10/21/10

75-01-4

Page 52

0.54 3, H-S

0.025 U, J, F1-8

Vinyl chloride

of

60

E104009 TCLPV VOA FINAL

mg/L

0.025

15:00

1500

10/21/10 15:00 10/21/10 15:00 0/21/10 15:00 10/21/10 15:00 10/21/10 15:00 10/21/10 15.00 10/21/10 15:00

18:54

,lfethod

8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

10.54

EPA 8260C

10/21/10 18:54

EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERC12-B

Matrix: Waste

Station ID: HERC12 Date Collected: (‘AS Number

9/29/10 14:50 Results Qualifiers

4nalyte

(m- andlor p-)Xylene

R4-7156

E104009-14

25 U

Units

mg/kg

8IRL

Prepared

4naly;ed

25

10/06110 12:10 10/06/Jo 12:10 10/06/10 12:10 10/06/JO 12:10 10/06/10 12:10

10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 1007/10 18:35

10/06/10 12:10 10/06110 12:10 10/06/10 12:10

10/07/10 18:35 10/07.10 18:35 10/07/10 18:35

18/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/JO 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/JO 12:10 1006/10 12:10 10/06/10 12:10 10)06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 1006/10 12:10

10/07/10 18:35 10/07/10 18:35 10/07/ 10 18:35 10/07)10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 0/07/10 18:35 10)07/JO 18:35 10,07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 1007:10 18:35 10/07/10 18:35 10/07/JO 18:35

63 0-20-6

1,1,1 ,2-Tetrachloroethane

25 U

mg/kg

“S

71-55-6

1,I,1-irichlorocthane

25 U

mg/kg

2S

79-34-S

1,1 ,2,2-Tetrachloroethane

25

U

mg/kg

—‘5

76-13-I

1.1 ,2-Trichloro- 1 2,2-Trifluoroethane (Freon 113)

25 U

mg/kg

25

79-00-5

1,1 ,2-Trichloroethane

25 U

mg/kg

-‘S 25

1,1-Dichioroethane

25 U,J,QL-l

mg/kg

75-35-4

I ,1-Dichloroethene (1 ,1-Dichloroethylene)

25 U

mg/kg

,‘S

563-58-6

1,1 -Dichloropropene

25 U

mg/kg

25

87-61-6

1 ,2,3-Trichlorobenzene

25 U

mg/kg

25

96-18-4

1 ,2,3-Trichloropropane

25 U

mg/kg

25

120-82-1

1 ,2,4-Trichlorobenzene

25 U

mg/kg

25

95-63-6

I ,2,4-Trimethylbenzenc

5.0 J, Q-2, QR-1

mg/kg

25

96-12-8

1 ,2-Dibromo-3-Chloropropane (DBCP)

50 U

mg/kg

50

106-93-4

I .2-Dibromoethane (EDB)

25 U

mg/kg

25 25

75-34-3

.

95-50-1

1 ,2-Dichlorobenzene

25 U

mg/kg

107-06-2

1 ,2-Dichloroethane

25 U

mg/kg

25

78-87-5

1 ,2-Dichloropropane

25 U

mg/kg

25

108-67-8

I ,3,5-Tnmethylbenzene

25 U

mg/kg

25

541-73-1

1 ,3-Dichlorobenzene

25 U

mg/kg

25

142-28-9

1 ,3-Dichloropropane

25 1.

mg/kg

25

106-46-7

1 ,4-Dichlorobenzene

25 U

mg/kg

25

U

mgkg

25

mg/kg

200

594-20-7

2,2-Dichioropropane

67-64-1

Acetone

200 U

71-43-2

Benzene

440

108-86-1

Bromobenzene

25 U

74-97-5

Bromochioromethane

75-27-4

Bromodichloromethane

75-25-2

Bromo form

Page 53 of 60

E104009 TCLPV VOA FTNAL

25

mg/kg

25

mg/kg

25

25 U, J. QL-1

mg/kg

25

25 U

mg/kg

25

50 U

mg/kg

50

lfethod

EPA

8260C

EPA 826CC EPA 826CC EPA

826CC

EPA

8260C

EPA

826CC

EPA 8260C EPA

826CC

EPA

826CC

EPA

826CC

EPA 8260C

EPA 826CC EPA 8260C

EPA 826CC EPA 8260C

EPA 8260C EPA 8260C

EPA 826CC EPA 826CC

EPA 826CC EPA 8260C EPA 826CC EPA 8260C

EPA 826CC EPA 826CC EPA

826CC

EPA 826CC

EPA 826CC EPA 826CC

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTiON AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project; 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: IIERC12-B

Matrix: Waste

Station ID: HERC12 Date Collected: C4S Number

74-83-9

E104009-14

9/29/10 14:50 Results Qualifiers

4nai5’te

Bromomethane

100 U

Units

mg/kg

MRL

100

75-15-0

Carbon disulfide

25 U

mg/kg

25

56-23-5

Carbon Tetrachioride

25 U

mg/kg

25

108-90-7

Chlorobenzene

25 U

mg/kg

25

75-00-3

Chioroethane

25 U

mg/kg

25

67-66-3

Chloroform

25 U

mg/kg

25

74-87-3

Chloromethane

25 U

mg/kg

25

156-59-2

cis- I ,2-Dichloroethene

25 U

mg/kg

25

10061-01-S

cis- I ,3-Dichloropropene

25 U

mg/kg

25

110-82-7

Cyclohexane

48

mg/kg

25

124-48-i

Dibromochioromethane

25 U

mg/kg

25 25

74-95-3

Dibromomethane

25 U, 3, QL-l

mg/kg

75-71-8

Dichlorodjfluoromethane (Freon 12)

25 U

mg/kg

25

100-41-4

Ethyl Benzene

25 U

mg/kg

25

87-68-3

I lexachlorobutadiene

25 U

mg/kg

25

98-82-8

lsopropyibenzene

47

mg/kg

25

79-20-9

Methyl Acetate

50 U

mg/kg

50

591-78-6

Methyl Butyl Ketone

50 U

mg/kg

50

78-93-3

Methyl Ethyl Ketone

50 U

mg/kg

50

108-10-1

Methyl Isobutyl Ketone

50 U

mg/kg

50 25 25

1634-04-4

Methyl T-Butyl Ether (MTBE)

25 U

mg/kg

108-87-2

Methylcyclohexane

lii, Q-2

mg/kg

75-09-2

Methylene Chloride

25 U

mgkg

25

104-51-8

n-Butylbenzene

25 U

mg/kg

25

103-65-I

n-Propylbenzene

25 U

mg/kg

25

95-49-8

o-Chlorotoluene

25 U

mg/kg

25

95-47-6

o-Xylene

25 U

mg/kg

25

25 U

mg/kg

25

mg/kg

25

106-43-4

p-Chlorololuene

99-87-6

p-lsopropyltoluene

135-98-8

sec-Btttylbenzene

100-42-5

Styrene

Page 54 of6O

E104009 TCLPV VOA FINAL

2400 25 U

tug/kg

25

100 U

mg/kg

100

Prepared 10/06/10

12:10

10/06/10 12:10 10/06/10 12:10 10/06/10 2:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/116/10 12:10 10/06/10 12:10 10/06/10 12:10 1006:10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 1006/10 12:10 10/06/10 12:10 1006.10 12:10 0/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06)10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 1006/10 12:10

..lnaly;ed ltethod 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 1835 150710 18:35 10/07/10 18:35 10 07/10 18:35 10/07/10 18:35 1007/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10:07,10 18:35 10/07/10 18:35 1007,10 18:35 10/07/10 18:35 10:07/10 18:35 10/07/18 18:35 10/07/18 18:35 10/07/10 8:35 10/07/10 18:35 10/07/10 18:35 10/07/10 18:35 10/07/Il) 111:35

10/07/10

18:35

EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA S260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERC12-B Station ID: HERCI2

E104009-14

Matrix: Waste

Date Collected: 9/29/10 14:50 C IS Vuather

.4nalyte

Results Qualifiers

98-06-6

tert-Butylbenzene

127-18-4

Tetrachloroethene (Tetrachloroethylene)

108-88-3

Toluene

156-60-5

trans-1,2-Dichloroethene

10061-02-6

trans-1,3-Dichloropropene

79-01-6

Trichloroethene (Trichloroethylene)

75-69-4 75-01-4

Units

‘OIRL

25 U

mg/kg

25 U

mg/kg

25

mg/kg

25

25 U

mg/kg

25

25 U

mg/kg

25

25 U

mg/kg

25

Trichlorofluoromethane (Freon 11)

25 U

mg/kg

25

Vinyl chloride

25 U

mg/kg

25

500 U

mg/kg

500

160

25

Prepared

4natyed

10)06110 12:10 10/06/10 12:10 10,06/10 12:10 10/06/10 12:10 10/06/10 II0 10/06/10 12:10 10/06110 210 10/06/10 12:10

10/07)10 3:35 10/07/10 18:35 1807:10 18:35 10/07/10 18:35 10/07)10 035

i!ethud EPA

8260C

EPA 8260C EPA 8260C EPA

8260C

EPA 8260C

10/07/10 18:35 10/07/ 10 835 10/07/10 18:35

EPA 8260C

1007:10 035

EPA 8260C

EPA 8260C EP 8260C

Tentatively Identified Compounds: R4-0000

Page 55 of 60

Tentatively Identified Compounds

E104009 TCLPV VOA FINAL

1006/10 20

11/8/10 9:52

0

C

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. 1(1: 10-0629 Inc Reported by Kristin Trapp Hercules 10-0629, Project: -

TC1P Volatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: IIERCI2-B

E104009-14

Matrix: Waste

Station ID: IIERC12 Date Collected: 9/29/10 14:50 C IS :v,g,nhei75e,

107-06-2 106-46-7 71-43-2 56-23-5 108-90-7 67-66-3 87-68-3 78-93-3 127-18-4 79-01-6 75-01-4

Page 56 of 60

Re.s,,Ils QualifIers

lrndyre

Unit.’j

MRL

Prepared

11 Dichloroethene (1.1 -Dichloroethylene)

0 25 U

mg/L

0 25

Ii/3O

1,2-Dichloroethane

0.25 U

mg/L

0.25

19/O

l,4-Dichtorobenzene Benzene Carbon Ictrachloride Chlorobenzene Chloroform Hexachlorobutadiene Methyl Ethyl Ketone Tetrachloroethene (Tetrachloroethylene) Trichloroethene (Tricl-iloroethylene)

E104009 TCLPV VOA FINAL

EPA 8260C

i9//O

EPA 8260C

EPA 8260C EPA 8260C

mg/L

0.25

1.8

mgfL

0.25

3 j 1 9 1 0

1t/32/O

0.25 U

mg/L

0.25

‘°

1/O

0.25 U

mg/L

0.25

ll/3fO

0.25 U

rng/L

0.25

°

0.25 U

mg/L

0.50 U

mg!L

0.25 L 0.25 U

mg/I.. mg/L mg/I..

EPA 8260C

9//O

0.25 U

0.25 U

Vinyl chloride

nu1v..ed 1fethod

EPA 8260C EPA 8260C 1//O

EPA 8260C

0.50

i9/3O

O Itf3 / 2

EPA 8260C

0.25

H/3O

l/32/O

EPA 8260C

0.25

‘°

0.25

0.25

EPA 8260C 1/3O

‘‘°

EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERC13-B Station ID: HERC13

E104009-15

Matrix: Waste

Date Collected: 9/29/10 15:10 C4S

Nurn her

.4nalytc

R4-7156

(m- and/or p-)Xylene

25 U

mg/kg

25

630-20-6

1,1,1 ,2-Tetrachloroethane

25 U

mg/kg

L

71-55-6

1,1,1 -Trichloroethane

25 U

mg/kg

25

Re,s,,IIs Qualifiers

Units

MR1.

-‘S

79-34-5

1,1 ,2,2-Tetrachloroethane

25 U

mg/kg

-‘5

76-13-1

1,1 ,2-Trichloro- 1 ,2,2-Trifluoroelhane (Freon 113)

25 U

mg/kg

25

79-00-5

1,1 ,2-Trichloroethane

25 U

mg/kg

e

75-4-3

1,1-Dichloroethane

25 U,J,QL-1

mg/kg

25

75-35-4

1 ,1-Dichloroethene (1 ,1-Dichloroethylene)

25 U

mg/kg

-‘5

563-58-6

1,1 -Dichloropropene

25 U

mg/kg

25

87-61-6

1 ,2,3-Trichlorobenzene

2515

mg/kg

25

96-18-4

1 ,2,3-Trichloropropane

25 U

mg/kg

25

120-82-1

1 ,2,4-Trichlorobenzene

25 U

mg/kg

25

95-63-6

1 ,2,4-Trimethylbenzene

5.5 J, Q-2, QR-1

mg/kg

25

96-12-8

1 ,2-Dibromo-3-Chloropropane (DBCP)

50 U

mg/kg

50

106-93-4

1 ,2-Dibromoethane (EDB)

25 U

mg/kg

25

95-50-1

1 ,2-Dichlorobenzene

31

mg/kg

25

107-06-2

I ,2-Dichloroethane

25 U

mg/kg

25

78-87-5

I ,2-Dichloropropane

25 U

mg/kg

25

108-67-8

1 ,3,5-Trimethylbcnzene

25 U

mg/kg

25

541-73-1

1 ,3-Dichlorobenzene

25 U

mg/kg

25

142-28-9

1 ,3-Dichloropropane

25 U

mg/kg

25

25 U

mg/kg

25 25 200

106-46-7

I ,4-Dichlorobenzene

594-20-7

2,2-Dichloropropane

25 U

mg/kg

67-64-1

Acetone

200 U

mg/kg

7 1-43-2

Benzene

390

108-86-1

Bromobenzene

25 U

mg/kg

25

mg/kg

25

74-97-5

Bromochloromethane

25 U,J,QL-1

mg/kg

25

75-27-4

Bromodichioromethane

25 U

mg/kg

25

75-25-2

Bromoform

50 U

mg/kg

50

Page 57 of 60

El 04009 TCLPV VOA FINAL

Prepared

Analyzed Method

10106/10 12:10 10/06/10 12:10 10/06110 12:10 10/06/10 12:10 10/06/10 12:10

1007/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01

10/06/10 12:10 10/06/10 12:10 10/06/10 12:10

10/07/10 19:01 10/07/10 19:01 10/07/10 19:01

10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06)10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06110 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 2:10 10/06/10 12:10

10/07/10 19:01 10/07/10 19:01 10/07/It 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01

EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: IIERC13-B

E104009-15

Matrix: Waste

Station ID: HERC13 Date Collected: 9/29/10 15:10

C: IS Viun her

Re.cidis Qualifiers

.lnalyte

Units

MRL

mg/kg

74-83-9

Bromomethane

100 U

75-15-0

Carbon disulfide

25 U

mg/kg

2S

56-23-5

Carbon Tetrachioride

25 U

mg/kg

25

108-90-7

(‘hlorobenzene

25 U

mg/kg

2S ‘)C

2S

75-00-3

Chioroethane

25 U

mg/kg

67-66-3

Chloroform

25 U

mg/kg

Prepured 10/06/10 12:10 10/06/10

10/07/10 19:01 10/07/10 19:01 10 07. 10 19:01 10/07/10 19:0) 10/07/10 19:01 10/07/10

EPA 8260C

12:10

19:)))

EPA 8260C

10/07/10 19:0) 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 1007/10 19:0) 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:0) 10/07/10 19:0) 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:0) 0/07/10 19:01 I 0.07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:01 10/07/10 19:0) 10/07/10 19:01 10/07/10 19:0) 1007.10 19:01

EPA 8260C

2:70 10/06/10 12:10 10/06/10

2:10 10/06/10 12:10 l0/1J6/I0

74-95-3

Dibromomethane

25 U,J,QL-1

mg/kg

75-71-8

Dichiorodifluoromethane (Freon 12)

25 U

mg/kg

100-41-4

Ethyl Benzene

25 U

mg/kg

25

87-68-3

Flexachiorobutadiene

25 U

mg/kg

25

mg/kg

33O

10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 2:10

mg/kg

S”°

10/06/10 12:10

74-87-3

Chioromethane

25 U

mg/kg

2S

156-59-2

cis- I ,2-Dichloroethene

25 U

mg/kg

25

10061-01-5

cis- I ,3-Dichloropropene

25 U

mg/kg

2S

mg/kg

‘,

870

110-82-7

Cyclohexane

124-48-1

Dibromochioromethane

98-82-8

lsopropylbenzene

79-20-9

Methyl Acetate

591-78-6

mg’kg

,

-

2S

330 U, D-4 50 U

Methyl Butyl Ketone

—,

25 U

-)

50 U

mg/kg

SO

SO SO

78-93-3

Methyl Ethyl Ketone

50 U

mg/kg

108-10-1

Methyl Isobulyl Ketone

11 J, Q-2

mg/kg

1634-04-4

Methyl T-Butyl Ether (MTBE)

25 U

108-87-2

Methylcyclohexane

10 J, Q-2

mg/kg

2S

75-09-2

Methylene Chloride

25 U

mg/kg

-,

104-51-8

n-Bulylbenzene

25 U

mg/kg

2S

103-65-I

n-Propylbenzene

25 U

mg/kg

2S 25 2S

-,

•-‘

95-49-8

o-Chlorotoluene

25 U

mg/kg

95-47-6

o-Xylene

25 U

mg/kg

25 U

106-43-4

p-Chlorotoluene

99-87-6

p-lsopropyltoluene

135-98-8

sec-Butylbenzene

100-42-5

Styrene

Page 58 ofóO

El 04009 TCLPV VOA FINAL

3100

mg/kg

25

mg/kg

2S

25 U

mg/kg

100 U

mg/kg



inn

.•lnafr:ed Method

10/06/10 2:10 10/06/10 12:10 10/06/10 2:10 10/06/10 12:10 10/06/10 12:10 10/06110 12:10

10/06/jo 12:10 10/06/to 12:10

10/06/10 12.10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10 10/06/10 12:10

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

EPA 8260C EPA 8260C EPA 8260C EPA 8260C

11/8/10 9:52

o

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.ART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

Volatile Organics Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERC13-B Station ID: HERC13

E104009-15

Matrix: Waste

Date Collected: 9/29/10 15:10 C4S Number

4na!yte

Results Qualifiers

98-06-6

tert-Butylbenzene

127-18-4

Tetrachloroethene (Tetrachloroethylene)

108-88-3

Toluene

156-60-5

trans-1,2-Dichloroethene

10061-02-6

trans-1,3-Dichloropropene

Units

MRL

25 U

mg/kg

25

25 U

mg/kg

25

mg/kg

25

25 U

mg/kg

25

25 U

mg/kg

25 25

3400

Prepared

.lnalyzed

10/06110

1007/10 19:01 10/07/10 19:01 1007:10 1901 10/07/10 19:01 I007J0 19:01 10/07/10 19:01 100710 l9-0l 10/07/10 19:01

EPA 8260C

10/07/10 1901

EPA 8260C

12:l0 10/06/10 12:10 10106/10

79-01-6

Tricliloroethene (Trichloroethylene)

25 U

mg/kg

75-69-4

Trichlorofluoromethane (Freon 11)

25 U

mg/kg

25

75-01-4

Vinyl chloride

25 U

mg/kg

25

I2:10 10/06/10 12:10 1006:10 12:10 10/06/10 12:10 0:06.10 12:10 10/06/10 12:10

500 U

mg/kg

500

10/06/10 1210

:tfethod EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C EPA 8260C

Tentatively Identified Compounds: R4-0000

Page 59 of 60

Tentatively Identified Compounds

E104009 TCLPV VOA FINAL

11/8/10 9:52

0

0

UNiTED STATES ENVIRONMENTAL PROTECTION AGENCY Regioll 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-270() DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Kristin Trapp -

TCLP Volatiles Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCI3-B

E104009-15

Matrix: Waste

Station ID: HERC13 Date Collected: 9/29/10 15:10 C4S Number

75-35-4

Resulls Qualifiers

4nalyie

1,1-Dichloroethene

Units

MRL

Prepared

bialyzed ,ltethod

0.25 U

mg/[.

0.25

10/13/10 1500

10/13/10

EPA 8260C

0.25 U

mgJL

0.25

10/13/10

10/13/10

1500

1854 10/13/10

EPA

0/13/10

5:00 10/13/10

18:54

EPA 8260C

10/13/10

18:54

(1,1 -Dichloroethylene) 107-06-2

1,2-Dichloroethane

106-46-7

l,4-Dichlorobenzene

71-43-2

Benzene

56-23-5

Carbon Tetrachloride

108-90-7

Chlorobenzene

67-66-3

mg!L

0.25

mg/L

0.25

0.25 U

mg/L

0.25

0.25 U

mg/L

0.25

10/13/10

10/13/10 10/13/10 18:54 10/13/10 18:54

EPA 8260C

EPA 8260C EPA 8260C

0.25 U

3.6

Chloroform

1500

1854

EPA 8260C

10/1310

10/13/10 1854

EPA 8260C

10/13/10 1854

EPA 8260C

1500

15:00

0.25 U

mg/L

0.25

10/13/10 1500

0.25

10/13/10 1500

0.50

10/13/10 1500

87-68-3

Hexachiorobutadiene

0.25 U

mgfL

78-93-3

Methyl Ethyl Ketone

0.50 U

L 1 mg

18:54

127-18-4

Teachloroethene (Tetrachloroethylene)

0.25 U

mg/L

0.25

10/13/10 1500

10/13/10 18:54

79-01-6

Trichloroethene (Trichloroethylene)

0.25 U

mg/L

0.25

10/13/10 1500

10/13/10 854

0.25

10/13/10

10/13/10

15:00

18:54

75-01-4

Page 60 of 60

0.25 U

Vinyl chloride

E104009 TCLPV VOA FINAL

8260C

mg/L

EPA 8260C

EPA 8260C

EPA 8260C

11/8/10 9:52

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY’

Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

January 4, 2011

4SESD-ASB MEMORANDUM SUBJECT:

FiNAL Analytical Report Project: 10-0629, Hercules Inc Civil Enforcement

FROM:

Jenny Scifres ASB Inorganic Chemistry Section Chief

THRU:

Gary Bennett, Chief Analytical Support Branch

TO:

Sharon Matthews

Attached are the final results for the analytical groups listed below. These analyses were performed in

accordance with the Analytical Support Branch’s (ASB) Laboratory Operations and Quality Assurance Manual (ASB LOQAM) found at www.epa.gov/region4/sesdlasbsop. Any unique project data quality objectives specified in writing by the data requestor have also been incorporated into the data unless otherwise noted in the Report Narrative. Chemistry data have been verified based on the ASB LOQAM specifications and may have been qualified if the applicable quality control criteria were not met. For a listing of specific data qualifiers and explanations, please refer to the Data Qualifier Definitions included in this report. The reported results are representative only of the samples as received by the laboratory.

Analyses Included in this report:

Method Used:

TCLP Metals (TCLPM) TCLPMeLaIs

EPA6OIO

Total Metals (TMTL) Total Metals

Page 1 of34

EPA 6010

E104009 TCLPM TMTL FINAL

1/4/11 10:55

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700

/\ ‘

,

DART. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

Report Narrative

for Work Order E104009, Project: 10-0629

Tin not reported per Project Leader. There is tin in reagents used for digesting the samples. Sample Disposal Policy

Because of the laboratory’s limited space for long term sample storage, our policy is to dispose of samples on a periodic schedule. Please note that within 60 days of this memo, the original samples and all sample extracts and/or sample digestates will be disposed of in accordance with applicable regulations. The 60-day sample disposal policy does not apply to criminal samples which are held until the laboratory is notified by the criminal investigators that case development and litigation are complete. These samples may be held in the laboratory’s custody for a longer period of time if you have a special project need. If you wish for the laboratory to hold samples beyond the 60-day period, please contact our Sample Control and provide a reason for holding samples Coordinator, Debbie Colquitt, by e-mail at beyond 60 days

Page 2 of 34

EIO4009TCLPMTMTLFINAL

1/4/11 10:55

0

0

UNITED STAThS ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

SAMPLES INCLUDED IN TifiS REPORT

Project: 10-0629, Hercuks Inc Sample ID

Laboratory ID

Matrix

ERBO1

E104009-01

PB01

Date Collected

Date Received

EquipmentRinseBlank

9/23/10 13:30

10/1/10 8:35

E104009-02

Preservative Blank

9/23/10 13:30

10/1/10 8:35

HERCOI-A

E104009-03

Waste

9/28/10 10:10

10/1/10 8:35

HERCO2-B

E104009-04

Waste

9/28/10 10:55

10/1/10 8:35

HERCO3-B

E104009-05

Waste

9/28/10 13:15

10/1/10 8:35

HERCO4-B

E104009-06

Waste

9/28/10 13:50

10/1/10 8:35

HERCO5-A

E104009-07

Waste

9/28/10 14:05

10/1/10 8:35

HERCO6-B

E104009-08

Waste

9/28/10 14:55

10/1/10 8:35

HERCO7-B

E104009-09

Waste

9/28/10 15:25

10/1/10 8:35

HERCO8

E104009-10

Waste

9/29/10 08:50

10/1/10 8:35

HERCO9-B

E104009-11

Waste

9/29/10 14:20

10/1/10 8:35

1-IERCIO-B

E104009-12

Waste

9/29/10 14:15

10/1/10 8:35

HERCII-B

E104009-13

Waste

9/29/10 14:30

10/1/10 8:35

HERC12-B

E104009-14

Waste

9/29/10 14:50

10/1/10 8:35

HERCI3-B

E104009-15

Waste

9/29/10 15:10

10/1/10 8:35

Page 3 of 34

E104009 TCLPM TMTL FINAL

1/4/11 10:55

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

DATA QUALIFIER DEFINITIONS

U J

The analyte was not detected at or above the reporting limit.

NA-5

Not Analyzed. Cannot exceed TCLP regulatory levels based on Total Scan analyses.

OM-1 OM-2 OM-3 OR-2

Matrix Spike Recovery less than method control limits

The identification of the analyte is acceptable; the reported value is an estimate.

Matrix Spike Recovery greater than method control limits Matrix Spike Precision outside method control limits MRL verification recovery greater than upper control limits.

ACRONYMS AND ABBREVIATIONS

CAS

Chemical Abstracts Service Note: Analytes with no known CAS identifiers have been assigned codes beginning with “E”, the EPA ID as assigned by the EPA Substance Registry System (www.epa.gov/srs), or beginning with “R4-”, a unique identifier assigned by the EPA Region 4 laboratory.

MDL

Method Detection Limit The minimum concentration of a substance (an analyte) that can be measured and reported with a 99% confidence that the analyte concentration is greater than zero.

M.R.L

Minimum Reporting Limit Analyte concentration that corresponds to the lowest demonstrated level of acceptable quantitation. The MRL is sample-specific and accounts for preparation weights and volumes, dilutions, and moisture content of soil/sediments.

TIC

Tentatively Identified Compound An analyte identified based on a match with the instrument software’s mass spectral library. A calibration standard has not been analyzed to confirm the compound’s identification or the estimated concentration reported.

-

-

Page 4 of 34

-

El04009 TCLPM TMTL FINAL

1/4/11 10:55

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700



D.A.R.T. Id: 10-0629 ‘?L PR3 cDs:.

Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

Total Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: ERBOI Station ID:

E104009-01

Matrix: Equipment Rinse Blank

Date Collected: 9/23/10 13:30 (‘IS .Vn,nher

dnulyte

7429-90-5

Aluminum

7440-36-0

Units

i3fRL

100 U

ugfL

100

12/03/10

12/20/lU

11:07

Antimony

40 U

ug/L

40

12/03/10

7440-38-2

Arsenic

50 U

ug/L

50

13:47 12/20/10 13:47 112010

7440-39-3

Barium

5.0 U

ug/L

5.0

7440-41-7

Beryllium

3.0 U

ugIL

3.0

7440-43-9

Cadmium

5.0 U

ugh..

5.0

7440-70-2

Calcium

250 U

ugIL

250

7440-47-3

Chromium

5.0 U

ug/L

5.0

7440-48-4

Cobalt

5.0 U

ug/L

5.0

7440-50-8

Copper

10 U

ug/L

10

7439-89-6

Iron

100 U

ugfL

100

7439-92-I

Lead

20 U

ug/L

20

7439-95-4

Magnesium

250 U

ug/L

250

7439-96-5

Manganese

5.0 U

ugfL

5.0

7439-98-7

Molybdenum

10 U

ug/L

10

7440-02-0

Nickel

10 U

ugfL

10

7440-09-7

Potassium

1000 1.]

ugj’L

1000

7782-49-2

Selenium

45 U

ughL

7440-22-4

Silver

5.0 U

ug/L

5.0

7440-23-5

Sodium

1000 U

ug/L

1000

7440-24-6

Strontium

5.0 U

ugfL

5.0

7440-28-0

Thallium

30

U

ugIL

30

7440-32-6

Titanium

5.0 U

ug/L

7440-62-2

Vanadium

5.0 U

7440-65-5

Yttrium

7440-66-6

Zinc

PageS of 34

Results Qualifiers

E104009 TCLPM TMTL FINAL

Prepured

11:07 12/03/lU

lnavzed Method

11:07

3:47

12/03/tO 11:07 12103/10 ll:07 12/03/10 11:07 12/03/lU 11:07 12/03/lO 11:07 2 0310 11:07 12/03/10 11:07 l2/03:l0 11:07 12/03/10 11:07 12/03/10 11:07 12/03/10 11:07 12/03/b 11:07 12/03/10 11:07

12/20/10

12/03110

11:07 12/03/10 11:07 l2J03/I0 11:07 12/03/10 11:07 I2/03/lO

13:47 12/20/10 13:47 12/20/10 13:47 2/20/10 13:47 12/20/10 13:47 12/20:10 l3:47 12/20/10 13:47 I2v20/I0 13:47 12/20/10 13:47 12/20/10 13:47 12/20/10 13:47 12/20/10 13:47 12/2W10 13:47 12/20/10 13:47 12)20/10 13:47 12/20/10 13:47 12/20/10 13:47

EPA6OIO EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 60I0

EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010

EPA 6010 EPA

6010

EPA 6010

11:07

I2/20/bo 13:47

EPA 6010

12/03/10 11:07

12/20/10 13:47

EPA 6010

5.0

12/03/lO

11’20/bO

11:07

13:47

ug/L

5.0

12/03/Ia

12/20/la

3.0 U

ug’L

3.0

10 U

ug/L

10

11:07 12103/lU 1:07 12/03/10 11:07

13:47 12/20/10

13:47 12/20/10 13:47

EPA

6010

EPA 6010 EPA 6010 EPA 6010

1/4/lI 10:55

0

D I

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700



-,

L

0

DART. Id: 10-0629

Project: 10-0629 Hercules Inc Repoed by Jenny Scifres

o’

-

TCLP Metals

Project: 10-0629, Hercules Inc Lab ID:

Sample ID: ERBOI

E104009-O1

Matrix: Equipment Rinse Blank

Station ID: Date Collected: 9/23/10 13:30 C4S

Number

4na!yte

7440-38-2

Arsenic:

Results Qualifiers

NA-5

Units

4IRL

Prepared

1.0

12/29/10 10-38

12/2910 1041

EPA 6010

12/29/10

12/29/10

1038 12/2910 10-38

0:41 12/29/10 10-41 12/29/ID

EPA 6010

7440-39-3

Barium:

XA-5

010

7440-43-9

Cadmium:

NA-5

0.10

7440-47-3

Chromium:

NA-5

0.10

7439-92-1

Lead:

NA-5

0.40

7782-49-2

Selenium:

NA-5

0.90

7440-22-4

Silver:

NA-5

0.10

Page 6 of 34

E104009 TCLPM TMTL FINAL

12/29/10 10-38 12/29/10 10-38 12/29/10 10-38 12/29/10 l0

.4nalyed

10:41 12/29/10 10:41 12/29/10 10:41 12/29/10 041

lkthad

EPA6OIO EPA 6010 EPA6OIO EPA 6010 EPA6OIO

1/4/I 1 10:55

0

0

UNETED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

Total Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: PBO1 Station ID:

E104009-02

Matrix: Preservative Blank

Date Collected: 9/23/10 13:30 C.4S

Number

.4nalyte

7429-90-5

Aluminum

7440-36-0

Antimony

40 U

ugfL

7440-38-2

Arsenic

50 U

ug/L

Re.s’idis Qualifiers

100 U

Units

‘tIRL

Prepared

ugL

100

12120/10 14:08

EPA 6010

40

2/03/10 11:07 12/03/10 11:07

12/20/10 14:08

EPA 6010

50

12/03110 11:07

12/20/10 14:00

EPA 6010

12/20110

EPA 6010

.tnaly:ed Method

7440-39-3

Barium

5.0 U

ugfL

5.0

12103/10

11:07

14:08

7440-41-7

Beryllium

3.0 U

ugfL

3.0

12/03/10

2120/10

Cadmium

5.0 U

ugIL

5.0

250 U

ug/L

250

5.0 C

ug/L

5.0

11:07 12/03/10 11:07 12103/10 1107 12/03/10 11:07

14.08 12/20/10 14:08 12/20/10 1408 12/20/10 14:08 12/20/10

7440-43-9 740-7Q-2

7440-47-3

Calcium Chromium

7440-48-4

Cobalt

5.0 U

ug/L

5.0

12/03/10 11:07

7440-50-8

Copper

10 U

ugfL

10

12/03/10 11:07

14:08

7439-89-6

Iron

100 U

ug/L

100

7439-92-1

Lead

20 U

ug/L

20

2/OYIO 1107 12/03/10 11:07

12/20/10 14:08 12/20/10 14:08

7439-95-4

Magnesium

250 U

ug/L

250

12/03/10

12/20/10

7439-96-5

Manganese

5.0 U

ug/L

5.0

11:07 12/03/10 11:07

14:08 12/20/10 14:08

7439-98-7

Molybdenum

JO U

uWL

10

12/03/10 11:07

12/20/10

7440-02-0

Nickel

7440-09-7

Potassium

7782-49-2 7440-22-4

12/03/10 11:07 12/03/10 11:07 12/03/10 11:07 12/03/10 11:07 12/23/10 11:07 12/03/10 11:07 12/03/10

10 U

ug/L

10

1000 U

ug/L

1000

Selenium

45 U

ugfL

Silver

5.0 U

ug/L

5.0 1000

7440-23-5

Sodium

1000 U

ug/L

7440-24-6

Strontium

5.0 U

ug/L

5.0

7440-28-0

Thallium

30 U

ug/L

30

7440-32-6

Titanium

5.0 U

ug!L

7440-62-2

Vanadium

5.0 U

ug/L

5.0

7440-65-5

Yttrium

3.0 U

ug/L

3.0

7440-66-6

Zinc

10 U

ug/L

10

Page 7 of 34

E104009 TCLPM TMTL FINAL

4.08 12/20/10

14:08 12/20/10 14:08 12/20/10 14:08 12)20/10 14:08 12/20/10 14:08 12/20/10 14:08 12120/10

14:08 12/20/10

11:07

14:08

12/03/10 11.07 12/03/10 11:07 12/03/10 11:07 12/03/10

12120/10 14:08 12120/10 14:08 12/20/10 14:08 12/20/10

11:07

14:08

EPA 6010 EPA 6010 EPA 6010 EPA

6010

EPA 6010

EPA 6010 EPA 6010 EPA 6010 EPA 6010

EPA 6010 EPA 6010

EPA 6010 EPA 6010

EPA 6010 EPA 6010 EPA 6010

EPA 6010 EPA 6010 EPA 6010

EPA 6010 EPA 6010 EPA

6010

1/4/11 10:55

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

TCLP Metals Project: 10-0629, Hercules Inc Lab 1D

Sample ID: PBO1

E104009-02

Matrix: Preservative Blank

Station ID: Date Collected: 9/23/10 13:30 C4S u,nher

dnalyte

7440-38-2

Arsenic:

7440-39-3 7440-43-9 7440-47-3 7439-92-I 7782-49-2 7440-22-4

Page 8 of34

Results Qualifiers

NA-5

Barium:

NA-5 NA-5

Cadmium: Chromium:

NA-5

Lead:

NA-5

Selenium:

NA-5

Silver:

NA-5

E104009 TCLPM TMTL FINAL

Units

MRL

1.0 0.10 0.10 0.10 0.40 0.90 0.10

Prepared

1nu1ved Method

12/29/10

EPA 6010

12/0

12129)10

EPA 6010

22910

12/2910

EPA 6010

12/29/10

92:/i10

EPA 6010

12/2910

12910

EPA 6010

12/29/10 12/29iW

EPA 6010 12,29/10

EPA6OIO

1/4/11 10:55

0

0

UNTTED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700

Z

D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Repoed by Jenny Scifres -

Total Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO1-A Station ID: HERCO1

E104009-03

Matrix: Waste

Date Collected: 9/28/10 10:10 ClS ,Vurnher

.4.al;’re

7429-90-5

Aluminum

7440-36-0

Antimony

7440-38-2

Arsenic

7440-39-3

Barium

7440-41-7

Results Qualifiers

Units

7tIRL

Prepared

.4nidwzed

12/09/10

14:01 12109/10

ii:oi

12/20/10 15:10 12120/10 15:10 12/20110 1510

licEhod

mg/kg

9.3

3.7 U

mg/kg

37

4.7 U

mg/kg

4.7

12109/10 41)1

18

mg/kg

0.47

Beryllium

0.28 Ii

mg/kg

0.28

7440-43-9

Cadmium

0.47 U

mg/kg

0.47

7440-70-2

Calcium

75 J, QM-2, Qvl-3

mg/kg

23

7440-47-3

Chromium

24

mg/kg

0.47

7440-48-4

Cobalt

7.9

mg/kg

0.47

7440-50-8

Copper

69 J, QM-2, QM-3

mg/kg

0.93

7439-89-6

Iron

7439-92-1

Lead

23

mg/lcg

1.9

7439-95-4

Magnesium

65

mg/kg

23

7439-96-5

Manganese

4.6

mg/kg

0.47

7439-98-7

Molybdenum

8.0

mg/kg

0.93

7440-02-0

Nickel

71 J, QM-2, QM-3

mg/kg

0.93

7440-09-7

Potassiuns

93 U

mg/kg

93

7782-49-2

Selenium

4.2 U

mg/kg

4.2

7440-22-4

Silver

0.47 U

mg/kg

0.47

7440-23-5

Sodium

170 3, QR-2

mg/kg

12/09/10 14:01 12109/10 14:01 12/09/10 14:01 12./09/10 1401 12/09/10 14:0! 12/0910 1401 12/09/10 14:01 12109/10 14:01 12/09/10 14:01 1209/10 1401 12/09/10 14:01 12109/10 14:01 12/09/10 14:01 12/09/lU 1401 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01

12/20/10 15:10 12120/10 15:10 12/20/10 15:10 12/20/10 15:10 12/20/10 15:10 12/20/10 15:10 12/20/10 15:10 12/20/tO 15:10 12/20/10 15:10 12:20/10 1510 12/20/10 15:10 12/20/10 15:10 12/20/10 15:10 12/20/10 15:10 12120/10 15:10 12/20/10 15:10 12/20/10 15:10

7440-24-6

Strontium

2.1

mg/kg

0.47

12.09,10

12i20/l0

7440-28-0

Thallium

2.8 U, J, QM-1

mg/kg

2.8

14:01 12109/10 14:01

15:10 12120/10 15:10

EPA

12/20:10 15:10

EPA 6010 EPA 6010

7440-32-6

Titanium

7440-62-2

Vanadium

7440-65-5

Yttrium

7440-66-6

Zinc

Page 9 of 34

6600

1200 J. QM-2

E104009 TCLPM TMTL FINAL

mg/kg

32

mg/kg

0.47

12/09:10 14.01

4.3

mg/kg

0.47

12/09/10

12120/10

0.58

mg/kg

0.28

270 J, QM-2, QM-3

mg/kg

1401 12J09/l0 14:01 12/09/10 14:01

15:10 12/20/10 15:10 12/20/10 15:10

.

1.9

EPA 6010

EPA 6010 EPA

6010

EPA 6010 EPA 6010

EPA 6010 [P\

6010

EPA 6010 EPA6OIO EPA 6010 EPA

6010

EPA

6010

EPA 6010 EPA

6010

EPA 6010

EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA6OIO

6010

EPA 6010 EPA

6010

1/4/11 10:55

0

C)

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

TCLP Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: IIERCOI-A

E104009-03

Matrix: Waste

Station ID: IIERCOI Date Collected: 9/28/10 10:10 C4S her

7440-38-2

.dnalyfr

ResuIt Quali:/ier.s

Arsenic:

NA-5

Unjs

MRL

1.0

7440-39-3

Barium:

NA-5

0.10

7440-43-9

Cadmium:

NA5

0.10

7440-47-3

Chromium:

NA-5

0.10

7439-92-1

Lead:

NA-5

0.40

7782-49-2

Selenium:

NA-5

0.90

7440-22-4

Silver:

NA-5

0.10

Page 10 of34

E104009 TCLPM TMTL FINAL

Prepared 12129/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 0:38

.1navzed iltethod 12129/10 10:41

12/29/10 10:41 12129/10 10:41 12/29/10 10:41 12/29/10 10:41 12/29/10 10:41 12/29/10 10:41

EPA

6010

EPA 6010 EPA 6010

EPA6O1O EPA6OIO

EPA 6010 EPA6OIO

1/4/11 10:55

0

0 ST

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700

I

D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Jenny Scifres

P9O

-

Total Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO2-B Station ID: HERCO2

E104009-04

Matrix: Waste

Date Collected: 9/28/10 10:55 (‘AS Vumber

.4na!yte

7429-90-5

Aluminum

7440-36-0

Antimony

7440-38-2

Arsenic

7440-39-3

Barium

7440-41-7

7440-43-9

7440-47-3

Results Qualifiers

4900

Units

mg/kg

3.9 U

mg/kg

4.9 U

mg/kg

MRL

9.8

Prepared

.4navzed

12/09/tO 14:01 12109)10 14:01

12/20/10 15:33 12)20/10 15:33 12/20110 5:33 12/20/10 15:33 2r20/Io 15:33 12/20/10 15:33 2/20/10 15:33

18

mg/kg

0.49

Beryllium

0.29 U

mg/kg

0.29

Cadmium

0.49 U

mg/kg

0.49

Calcium

58

mg/kg

25

14:01 12109/10 14:01 12/09/10 l4:01 12/09/10 14:01 12/09/tO 1401

Chromium

11

mg/kg

0.49

12/09/10 14:01

12/20/10 15:33

Cobalt

14

mg/kg

0.49

12/09/10 14:01 12/09/10 14:01 2,09:10 14:01 12/09/10 14:01 12/09/10 14:01

12/20/10 15:33 12/20/to 15:33 220/10 15:33 12/20/10 15:33 12/20/10 15:33

12/09/10

12/20/10 15:33 12/20/10 5:33

7440-50-8

Copper

4-89-6

Iron

7439-92-1 7439-95-4

44

mg/kg

0.98

1600

mg/kg

9.8

Lead

60

mg/kg

2.0

Magnesium

45

mg/kg

25

7439-96-5

Manganese

3.8

mg/kg

7439-98-7

Molybdenum

3.1

mg/kg

0.98

14:01 12109/10 14:01

7440-02-0

Nickel

120

mg/lcg

0.98

12/09/10 14:01

12/20/10

7440-09-7

Potassium

98 U

mg/kg

98

7782-49-2

Selenium

4.4 U

mg/kg

12/20/10

7440-22-4

Silver

0.49 U

mg/kg

12/09/tO 14:01 12/09/10 14:01 12/09/tO 1401

7440-23-5

Sodium

12109/10

12/20/10

7440-24-6

0.49

0.49

150 J, QR-2

mg/kg

98

Strontium

1.6

mg/kg

0,49

7440-28-0

Thallium

2.9 U

mg/kg

2.9

7440-32-6

Titanium

17

mg/kg

0.49

7440-62-2

Vanadium

2.1

mg/kg

0.49

7440-65-5

Yttrium

0.57

mg/kg

0.29

7440-66-6

Zinc

120

mg/kg

2.0

Page 11 of34

E104009 TCLPM TMTL FINAL

14:0] 12109/tO 14:01 12/09/10 14:01 120910 14:01 12/09/10 14:01 12/09/tO 14:01 12/09/tO 14.01

15:33 12/20/tO 15:33 15:33 12/20/10 15:33 15:33 12/20/10 15:33 12120/tO 15:33 12/20:10 15:33 12/20/10 5:33 12/20/10 15:33 12120/10 15:33

Method

EPA 6010

EPA

6010

EPA 6010

EPA 6010 EPA 6010 EPA 6010 EPA 6010

EPA 6010 EPA 6010 EPA 6010 EPA 6010

EPA 6010 EPA 6010

EPA 6010 EPA 6010

EPA 6010 EPA 6010 EPA 6010 EPA 6010

EPA 6010 EPA6OIO EPA 6010 EPA 6010 EPA6OIO EPA 6010 EPA 6010

1/4/Il 10:55

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, HercuIs Inc Reported by Jenny Scifres -

TCLP Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO2-B

E104009-04

Matrix: Waste

Station ID: HERCO2 Date Collected: 9/28/10 10:55 C4S Nninber

.4nalyte

7440-38-2

Arsenic:

7440-39-3 7440-43-9 7440-47-3 7439-92-1 7782-49-2

7440-22-4

Page 12of34

,IIRL

Prepured

NA-5

1.0

Barium:

NA-5

0.10

12129/10 038 12/29/10

12129,10 1041 12/29/JO

Cadmium:

NA5

0.10

10:38 12129/10 0:38

041 12,29/10

12/29/10

12/29/10

Results Qualifiers

Chromium:

A-5

Lead:

NA-5

Selenium:

NA-5

Silver:

NA-5

E104009 TCLPM TMTL FINAL

Units

0.10 0.40

10:38 I2/29/l0 038

0.90

12/29/10 IO’38

0.10

!2/29I0 1039

.4nu1zed ,lfethod

1041

EPA 6010 EPA6OIO EPA 6010

1041

EPA 6010

12/29/10 1041 12/29/10

EPA 60l0

1O4l

EPA 6010

12/2910 041

EPA 6010

1/4/11 10:55

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

Total Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO3-B Station ID: HERCO3

E104009-05

Matrix: Waste

Date Collected: 9/28/10 13:15 C ES ,\umher

.4na!te

7429-90-5

Aluminum

RexulI Qualifiers

5700

Units

MRL

mg/kg

.

Prepared

12109/10

-

.4nalyzed Method

12120/10 1541 12)20/10 15:41

EPA 6010

7440-36-0

Antimony

3.7 U

mg/kg

7440-38-2

Arsenic

4.6 U

rng:kg

4.6

1109/10 1401

7440-39-3

Barium

21

mg/kg

0.46

7440-41-7

Beryllium

0.27 U

mg/kg

0.27

7440-43-9

Cadmium

0.46 U

mg/kg

0.46

12/09/10 1401 I20910 (401 12/09/10 1401

7440-70-2

Calcium

210

mg/kg

12109/10 14:01

744b47-3

Chromium

7.7

mg/kg

7440-48-4

Cobalt

2.9

mg/kg

0.46

12)09/10 1401 12/09/10 140I

15:41

EPA 6010

7440-50-8

Copper

29

mg/kg

0.92

12/09/10 1401

12/20/10 15:41

EPA 6010

7439-89-6

Iron

4300

mg/kg

9.2

Lead

9.1

mg/kg

1.8

7439-95-4

Magnesium

230

mg/kg

23

7439-96-5

Manganese

31

mg/kg

0.46

7439-98-7

Molybdenum

0.92 U

mg/kg

0.92

7440-02-0

Nickel

7440-09-7

Potassium

7782-49-2

Selenium

7440-22-4

Silver

7440-23-5

Sodium

7440-24-6

I2/20/I0 15:41 12/20/10 15:41 2/20/b 15:41 12/20/10 15:41 12/20/10 15:41 12/20/10 (5:41 12/20/10 15:41 12/20/10 15:41 2/20/10 (5:41 (2/20/10 15:41 12/20/10 15:41 12/20/10 15.41 12/20/10 15:41 12120/10 15:41 12/20/10 15:41 12/20/10 1541

EPA 6010

7439-92-1

12/09/10 1401 12109/10 14:01 l2/09/Io 14:01 12/09/10 1401 12/09/10 1401 12/09/10 1401 2109/10 1401 12/09/10 14:01 12/09/10 (401 12/09/10 14:01 12/09/10 1401 12/09/10 1401 12/09/10 1401 12/09/10 1401 12/09/10 1401 12/09/10 14:0!

-,

0.46

80

mg/kg

0.92

180

mg/kg

92

4.1 15

mg/kg

4.1

0.46 U

mg/kg

0.46

92 15

mg/kg

Strontium

2.1

mg/kg

0.46

7440-28-0

Thallium

2.7 U

mg/kg

2.7

7440-32-6

Titanium

62

mg/kg

0.46

7440-62-2

Vanadium

8.7

mg/kg

0.46

7440-65-5

Yttrium

1.2

mg/kg

0.27

7440-66-6

Zinc

68

mg/kg

l.oo

Page 13 of34

E104009 TCLPM TMTL FINAL

12/09/10 14:01

EPA

6010

ll’20l0

15:41 15:41 2120/10 5:41 12/20/10 15:41 12/20/10 15:41

12/20/10 15:41 I2’20/I0

EPA 6010 EPA 6010

EPA 6010 EPA 6010 EPA

6010

EPA 6010 EPA 6010 EPA 6010 EPA 6010

EPA 6010 EPA6OIO EPA 6010 EPA

6010

EPA

6010

EPA 6010

EPA 6010 EPA 6010

EPA 6010 EPA6OIO EPA 6010

1/4/11 10:55

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 I).A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

TCLP Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO3-B

E104009-05

Matrix: Waste

Station ID: HERCO3 Date Collected: 9/28/JO 13:15 (ZIS .Vumher

.4nalyte

7440-38-2

Arsenic:

7440-39-3 7440-43-9 744047-3

7439-92-1 7782-49-2 7440-22-4

Page I4of34

Results Qualifiers

NA-5

barium:

NA-5

Cadmium:

NA-S

Chromium:

NA-S

Lead:

NA-5

Selenium:

NA-5

Silver:

NA-5

E104009 TCLPM TMTL FiNAl.

Units

MRL

1naly.ed

12/29/10

12/29/10

12/29/10

1229,I0

EPA 6010

‘°

12129/10

EPA 6010

EPA 6010

1.0 0.10 0.10 0.10

0.40 0,90 0.10

lh’thod

Prepared

I229/i0

EPA 6010

‘° 1229/i0

EPA 6010

EPA 6010 I229/IO

EPA 6010

1/4/11 10:55

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

Total Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO4-B Station ID: HERCO4

E104009-06

Matrix: Waste

Date Collected: 9/28/10 13:50 C.4S Number

.4nalyw

Rc,,lIy Qualifiers

Units

31RL

Prepared

.4nulyzed

12/20/10 15:49 ll’20:l0 5:49 12/20/10 15:49 12120/10 15:49 12/20/10 15:49 12/20/10 15:49 12/20/10 15:49 12/20/10 15:49 12120/10 15:49

7429-90-5

Aluminum

7440-36-0

Antimony

3.6 U

mg/kg

7440-38-2

Arsenic

6.4

mg/kg

4.6

7440-39-3

Barium

27

mg/kg

0.46

7440-41-7

Beryllium

0.27 U

mg/kg

0.27

7440-43-9

Cadmium

0.46

mg/kg

0.46

7440-70-2

Calcium

400

mg/kg

23

7440-47-3

Chromium

29

mg/kg

0.46

7440-48-4

Cobalt

14

mg/kg

0.46

7440-50-8

Copper

100

mg/kg

0.91

12109/10 14:01 12/09/10 14:01 1209/10 14:01 12/09/10 14:01 12/09/10 14:01 12J09/10 14:01 12/09/10 4:01 12/09/10 14:01 12/09/10 14:01 12109/10 14:01

7439-89-6

Iron

3400

mg/kg

9.1

2/09/10 14:01

7439-92-1

Lead

26

mg/kg

1.8

7439-95-4

Magnesium

76

mg/kg

23

7439-96-5

Manganese

0.46

7439-98-7

Molybdenum

7440-02-0

Nickel

7440-09-7

Potassium

7782-49-2

Selenium

7440-22-4

Silver

7440-23-5

Sodium

7440-24-6

Strontium

7440-28-0

Thallium

7440-32-6

Titanium

7440-62-2

Vanadium

7440-65-5 7440-66-6

12/09/10 14:01 12’09/I0 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12109/10 I40l 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 1401 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01

Page 15 of34

5200

mg/kg

9.1 3.6

14

mg/kg

4.0

mg/kg

0.91

200

mgllcg

0.91

96

mg/kg

91

4.1 U

mg/kg

4.1

0.46 U

mg/kg

0.46

mg/kg

91

6.1

mg/kg

0.46

2.7 U

mg/kg

2.7

42

mg/kg

0.46

5.6

mg/kg

0.46

Yttrium

0.99

mg/kg

0.27

Zinc

510

mg/kg

1.8

130 J, QR-2

E104009 TCLPM TMTL FINAL

12/20/10 15:49

12i20/I0

I5:49 12/20/10 15:49 12/20/10 15:49 12/20/10 15:49 12/20/10 15:49 12/20/10 15:49 12/20/10 15:49 12/20/10 15:49 12120/10 15:49 12/20/10 15:49 12/20/10 5:49 12/20/10 15:49 12/20/10 15:49 12/20/10 15:49 12/20/10 15:49 12/20/10 15:49

lh’thod

EPA 6010 EPA

6010

EPA 6010 EPA 6010 EPA 6010 EPA

6010

EPA 6010

EPA 6010 EPA 6010 EPA

6010

EPA 6010

EPA 6010 EPA 6010

EPA 6010 EPA6OIO

EPA6OIO EPA 6010

EPA6OIO EPA 6010 EPA 6010 EPA 6010

EPA 6010 EPA 6010 EPA

6010

EPA 6010 EPA6OIO

1/4/11 10:55

0

CD

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

TCLP Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO4-B

E104009-06

Matrix: Waste

Station 1D: HERCO4 Date Collected: 9/28/10 13:50 C4S Number

.4nalyte

7440-38-2

Arsenic:

7440-39-3

Results Qualifiers

NA-S

Barium:

XA-5

Units

MRL

1.0 0.10

7440-43-9

Cadmium:

NA-5

0.10

7440-47-3

Chromium:

NA-S

0.10

7439-92-I

Lead:

NA-5

0.40

7782-49-2

Selenium:

NA5

0.90

7440-22-4

Page 16of34

Silver:

NA-S

E104009 TCLPM TMTL FINAL

0.10

Prepared 32)29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:30 12/29!I0 030

.4nusvzed Slethod 2)29/10

10:4 I 32/29/10

10:41 12)29/10 I0:41 1229/10 10:43 12/29/30 10:41 12/29/10 30:43 2/29/Il/

EPA 6010

EPA

6010

EPA 6010 EPA6OIO

EPA 6010 EPA

6010

EPA 6010

1/4/11 10:55

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

Total Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCOS-A

E104009-07

Matrix: Waste

Station ID: HERCO5 Date Collected: 9/28/10 14:05 C4S

Number

4nalyte

7429-90-5

Aluminum

Results Qual:jiers

5100

Units

mg/kg

tIIRL

9.7

7440-36-0

Antimony

3.9 U

mg/kg

7440-38-2

Arsenic

5.6

mg/kg

7440-39-3

Barium

35

mg/kg

0.49

7440-41-7

Beryllium

0.29 U

mg/kg

0.29

7440-43-9

Cadmium

0.49

mg/kg

0.49

7440-70-2

Calcium

2000

mg/kg

24

7440-47-3

Chromium

45

mg/kg

0.49 0.49 0.97

7440-48-4

Cobalt

17

mg/kg

7440-50-8

Copper

84

mg/kg

7439-89-6

Iron

7439-92-1

Lead

7439-95-4

kIagnesium

7439-96-5

Manganese

7439-98-7

Molybdenum

4600

mg/kg

34

mg/kg

1.9

1556 12/20/10 15:56 1120/lU 15:56 12/20/10 15:56

EPA 6010 EPA 6010

0.49

mg/kg

0.97 0.97 97

2/0910 140I

12/20/10 15:56

12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12109/10 14:01 12/09/10 14:01 1309/10 14:01 12/09/10 14:01 12/09/10 401 12/09/10

12/20/10 15.56 12/20/10 5:56 12/20/10 15:56 l2120l0 15:56

210 110

mg/kg

7782-49-2

Selenium

4.4 U

mg/kg

7440-22-4

Silver

0.49 U

mg/kg

7440-23-5

Sodium

460 3, QR-2

mg/kg

97

7440-24-6

Strontium

8.9

mg/kg

0.49

7440-28-0

Thallium

2.9 U

mg/kg

2.9

7440-32-6

Titanium

51

mg/kg

0.49

7440-62-2

Vanadium

6.6

mg/kg

0.49

1.1

mg/kg

0.29

690

mg/kg

1.9

E104009 TCLPM TMTL FINAL

12.2010

32

Potassium

Page 17 of34

l209 10

4.8

Nickel

Yttrium

l5:56 12/20/10 15:56 12/20/10 l5:56 12/20/10 15:56 12/20/10 15:56 12/20/10 15:56 1220110 15:56 /2(2/10 15:56

12/20/b

1401 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01

24

0.49

EPA 6010

12/09/10 14:01 2/09/10 1401 12/09/10 14:01 12/09/b 14:01 12/09/10 14:01 12/09/tO I4Ol 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/lO 4:01 12/09/10 14:01

mg/kg

7440-09-7

Zinc

12120/10 15:56 12/20/10 15:56 12/20/10 l556 12/20/10 15:56

mg/kg

7440-02-0

7440-66-6

2/09/10

Analyzed Method

170

mg/kg

7440-65-5

Prepared

14:01

12/20/10

1556 1220/10 15:56 12/20/10 15:56 12/20/10 1556 12/20/10 15:56

EPA

6010

EPA 6010

EPA 6010 EPA

6010

EPA 6010 EPA 6010 EPA

6010

EPA 6010 EPA 6010 EPA 6010

EPA6OIO EPA

6010

EPA 6010 EPA 6010

EPA

6010

EPA 6010 EPA

6010

EPA 6010 EPA

6010

EPA6OIO EPA

6010

EPA6OIO

EPA6OIO

1/4/11 10:55

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 1 0-0629, Hercules Inc Reported by Jenny Scifres -

TCLP Metals Project: 10-0629, Flercules Inc Lab ID:

Sample ID: HERCO5-A

E104009-07

Matrix: Waste

Station ID: HERCO5 Date Collected: 9/28/10 14:05 CAS Nunber

.4naiyte

7440-38-2

Arsenic:

7440-39-3

Results

Qualifiers

NA-5

Barium:

>A-5

Units

MRL

1.0 0.10

7440-43-9

Cadmium:

NA5

0.10

7440-47-3

Chromium:

NA-5

0.10

7439-92-1

Lead:

NA-5

0.40

7782-49-2

Selenium:

NA-5

0.90

7440-22-4

Silver:

NA-5

0.10

Page 18 of34

E104009 TCLPM TMTL FINAL

Prepared

•trwly:ed lfethod

12/29/10 10:38

12/29/10

12/29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:38

12/29/10

10:41

10:41 12/29/10

10:41 12129/10 10:41 12/29/10 10:41 12/29/10 10:41 12/29/10 10:41

EPA 6010 EPA6O1O EPA 6010

EPA 6010 EPA 6010

EPA 6010 EPA6OIO

1/4/11 10:55

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Jenny Scifres

ZLpRo1”

-

Total Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO6-B Station 1D: HERCO6

E104009-08

Matrix: Waste

Date Collected: 9/28/10 14:55 ( IS N,u,zhs’r

.4nulyre

7429-90-5

Aluminum

7440-36-0

Antimony

3.9 U, I, QM-1

mg/kg

7440-38-2

Arsenic

4.9 U

mg/kg

7440-39-3

Barium

100 J, QM-2

mg/kg

0.49

7440-41-7

Beryllium

0.30 U

mg/kg

0.30

7440-43-9

Cadmium

0.49 U

mg/kg

0.49

7440-70-2

Calcium

5000

mg/kg

25

7440-47-3

Chromium

mg/kg

0.49

7440-48-4

Cobalt

mg/kg

0.49

7440-50-8

Copper

27 J, QM-1, QM-3

mg/kg

0.99

7439-89-6

Iron

4000 J, QM-2. QM-3

mg/kg

Results Qualifiers

5800

20 J, QM-1

7.2

Units

1fRL

12109/10 14:01 12/09)10

mg/kg

14:01

7439-92-1

Lead

7439-95-4

Magnesium

440 J, QM-2

mg/kg

25

7439-96-5

Manganese

200 J, QM-2, QM-3

mg/kg

0.49

7439-98-7

Molybdenum

21 J, Q\1-l

mg/kg

0.99

7440-02-0

Nickel

54 J, QM-2

mg/kg

0.99

7440-09-7

Potassium

160

mg/kg

7782-49-2

Selenium

4.4 U

mg/kg

22

mg/kg

2.0

EPA 6010 EPA 6010

12/20/10

6:04 12/20/10 16:04 12/20/10 16:04 12/20/10 16:04 12/20/10 16:04 12/20/tO 16:04 12/20/10 604 12/20/10 16:04 12/20/10

1401

1604

12/20/10 16:04 12120/10 16:04

99

34 J, QM-2

mg/kg

0.49

12/09/10 4:0!

12/20/10

mg/lcg

3.0

12/09/10

12/20/10

mg/kg

0.49

14:0! 12/09/10 14:01 12/09/10 14:01 12/09/10

16:04 12/20/10 1604 12/20/tO 16:04 12/20/10

7440-24-6

Strontium

7440-28-0

Thallium

7440-32-6

Titanium

7440-62-2

Vanadium

3.9

mg/kg

0.49

7440-65-5

Yttrium

1.9

mg/kg

0.30

0.49 U

3.0 U, 3, QM-1

56 3, QM-2

500 .1, QM-1, QM-3

El 04009 TCLPM TMTL FINAL

16:04

12/09)10 14:0! 1209/10 4:0!

mg/kg

mg/kg

0.49

2.0

EPA 6010

EPA 6010

12,20/10 16:04

mg/kg

Sodium

Page 19 of 34

14:01

12/09/10 14:01 12/09/tO 14:01 12/OWlS

12/20/10 16:04 12/20/10 04 12120/10

180 J, QR.-2

Silver

7440-23-5

Zinc

14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10

.dnalyzed Method

12109/10 14:01 12/09/10 140! 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01

7440-22-4

7440-66-6

Prepared

12/20/tO 16:04 12/20/10 16:04 12/20/10 16:04 12120:10 16:04 12/20/10 16:04 1604

EPA 6010

EPA 6010 EPA 6010 EPA 6010 EPA 6010

EPA 6010 EPA 6010

EPA 6010 EPA 6010 EPA 6010

EPA 6010 EPA 6010 EPA 6010

EPA 6010 EPA 6010 EPA 6010

EPA 6010

EPA 6010 EPA 6010 EPA 6010

14:01

16:04

EPA 6010

12109/10 14:01

12/20/tO 16:04

EPA 6010

1/4/11 10:55

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

TCLP Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERC06-B

E104009-08

Matrix: Waste

Station 1D: HERCO6 Date Collected: 9/28/10 14:55 C4S Niunber

.4nalyte

7440-38-2

Arsenic:

Results Qualifiers

NA-5

Units

MRL

1.0

7440-39-3

Barium:

NA-5

0.10

7440-43-9

Cadmium:

NA-5

0.10

7440-47-3

Chromium:

NA5

0.10

7439-92-I

Lead:

NA-5

0.40

7782-49-2

Selenium:

XA-5

0.90

7440-22-4

Silver:

NA-5

0.10

Page 20 of34

E104009 TCL.PM TMTL FINAL

Prepared

.4nalvzed

12J291l0 1038 12/29/10 10:38 12/29/10 1038 12/29/10 10:38 12/29/10 1038 12/29/10 10:38 12/29/10 1038

12129/10 10:41 12/29/10 0:41 12129/10 10:41 12/29/10 10:41 1129/10 10:41 12/29/10 10:41 12/29/10 10:41

‘81ethod

EPA 6010 EPA 6010 EPA 60(0 EPA 6010 EPA6OIO

EPA 6010 EPA6OIO

1/4/lI 10:55

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700

-

D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

Total Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO7-B Station ID: HERCO7

E104009-09

Matrix: Waste

Date Collected: 9/28/10 15:25 ClS .Vu,,ther

.4nulvle

Results Qualifiers

7429-90-5

Aluminum

7440-36-0

Antimony

3.8 U

7440-38-2

Arsenic

7440-39-3

Barium

7440-41-7 7440-43-9

Units

MRL

Prepared

lnalvzed

9.5

12/09/10

12/20/10 704

mg/kg

3.8

12109/10

12/20/10

4.8 U

mg/kg

4.8

23

mg/lcg

0.48

Beryllium

0.29 U

mg/kg

0.29

Cadmium

0.48

mg/kg

0.48

710

mg/kg

24

32

mg/kg

0.48

Cobalt

9.5

mg/kg

0.48

12109/10

14:01

17:04 12/20/10 17:04 12/20/10 17:04 12/20/10 17:04 12/20/10 (704

7440-50-8

Copper

26

mg/kg

0.95

12109/10

12/20/10

14:01

7439-89-6

Iron

5200

mg/kg

7439-92-1

Lead

23

mg/kg

7439-95-4

Magnesium

62

mg/kg

24

7439-96-5

Manganese

37

mgllcg

0.48

17:04 12125/10 7:04 12/20/10 17:04 12/20/10 17:04 12/20/10 17:04

6700

Calcium

7440-47-3

Chromium

mg/kg

12109/10 14:01 12/09/10 4:01 12/09/10 14:01 12/09/10

14:01 12109/10 14:01

12/09/10

1.9

7439-98-7

Molybdenum

40

mg/kg

0.95

7440-02-0

Nickel

44

mg/kg

0.95

7440-09-7

Potassium

95 U

mg/kg

95

7782-49-2

Selenium

4.3 U-

mg/lcg

7440-22-4

Silver

7440-23-5

Sodium

7440-24-6

0.48 U

14:01 12109110

14:01 12/09/10 14:01 12/0910

1401 12109/10 14:01

1704 12120/10

12/20/10 17:114 2120/10

12/09/10

1220/10

14:01 12/09/10 14:01 12/09/10

7:04 12120/10 17:04 2/20/10

tfethod

EPA 6010

EPA 6010 EPA 6010 EPA 6010 EPA6OIO

EPA 6010 EPA 60(0 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 60(0 EPA 6010 EPA 6010

14:01

1704

12/09/10 14:01 12/09/10 14:01

12/20/10 17:04 12/20/10

EPA 6010

EPA6OIO

mg/kg

0.48

130 J, QR-2

mg/kg

95

12/09/10

Strontium

8.9

mg/kg

0.48

7440-28-0

Thallium

2.9 U

mg/kg

2.9

7440-32-6

Titanium

22

mg/kg

0.48

7440-62-2

Vanadium

2.8

mg/kg

0.48

12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01

12/20/10 17:04 12-20,10 17:04 2/20)10 17:04 12120/10 17:04 2/20/10 17:04

7440-65-5

Yttrium

1.7

mg/kg

0.29

2091(0 1401

1220:10 7-04

EPA6OIO

7440-66-6

Zinc

1.9

12/09/10 14:01

12/20/10 17:04

EPA 60(0

Page 21 of 34

650

E104009 TCLPM TMTL FINAL

mg/kg

.

7:04

EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010

1/4/11 10:55

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART, Id: 10-0629

Prolect: 10-0629, Hercules Inc Reported by Jenny Scifres -

TCLP Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO7-B

E104009-09

Matrix: Waste

Station ID: HERCO7 Date Collected: 9/28/10 15:25 C4S Number

lna!yte

7440-38-2

Arsenic:

NA-S

1.0

7440-39-3

Barium:

NA-5

0.10

Results Qualijiers

Units

MRL

7440-43-9

Cadmium:

NA-S

0.10

7440-47-3

Chromium:

NA-S

0.10

7439-92-1

7782-49-2 7440-22-3

Page 22 of 34

NA-5

Lead:

NA-S

Selenium:

NA-S

Silver:

E104009 TCLPM TMTL FINAL

0.40

0.90

0.10

Prepared

.lnalrzed ,Olethod

12/29/10 038 12)29110 10:38

12/29/10 10:41 12/29/10 10:41

1129/10 10:30 12/29/10 10:38

12/29/10 10:41 12/29/10 10:41

12/29/10

12/29/10

EPA 6010 EPA 6010 6010

EPA6O1O

0:38

1041

EPA 6010

12/29/10

12/29/10

EPA 6010

10:38

1041

1229 0 039

112910

1041

EPA 6010

1/4/11 10:55

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

Total Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO8 Station ID: HERCO8

E104009-10

Matrix: Waste

Date Collected: 9/29/10 8:50 C IS lnalvte

Results Qualifiers

Units

MRL

Prepared 12/09/10 1401 12/09/10 14:01 1209/10

7429-90-5

Aluminum

7440-36-0

Antimony

3.9 U

mg/kg

7440-38-2

Arsenic

4.8 U

mg/kg

4.8

7440-39-3

Barium

61

mg/kg

0.48

12/09/10

744041-7

Beryllium

0.29 u

mg/kg

0.29

12/09/10

7440-43-9

Cadmium

0.48 U

mg/kg

0.48

7440-70-2

Calcium

250

mg/kg

24

7440-47-3

Chromium

20

mg/kg

0.48

7440-48-4

Cobalt

2.7

mg/kg

0.48

7440-50-8

Copper

7439-89-6

Iron

7439-92-1

Lead

7439-95-4

Magnesium

7439-96-5

Manganese

7439-98-7

Molybdenum

7440-02-0

Nickel

7440-09-7

7900

mg/kg

9.6

17

mg/kg

8300

mg/kg

9.6

24

mg/kg

1.9

240

mg/kg

24

350

mg/lcg

0.48

37

mg/lcg

0.96

8.2

mg/kg

0.96

Potassium

210

mg/kg

96

7782-49-2

Selenium

4.3 U

mg/kg

7440-22-4

Silver

7440-23-5

Sodium

7440-24-6

Strontium

7440-28-0

Thallium

7440-32-6

Titanium

7440-62-2

Vanadium

18

mg/kg

7440-65-5

Yttrium

2.7

mg/kg

7440-66-6

Zinc

130

mg/kg

1.9

Page 23 of 34

0.48 U

mg/kg

96 U

mg/kg

2.6

mg/kg

2.9 U

mg/kg

2.9

mg/kg

0.48

98

El 04009 TCLPM TMTL FTNAL

0.96

0.48

14:01

14:01

14:01 12/09/10 14:01 12109,10 1401 12/09/10 14:01 1209’lO

.4nutyzed Method 12/20/10 17:1 12/20/10 17:11 12/20/10 17:11

12/20/10 17:11 12/20/10 1711 12/20/10 17:11 12/20/10 17:11 12/20/10 17:11 122010

EPA 6010

EPA 6010 EPA 6010 EPA 6010

EPA 60W EPA 6010 EPA6OIO EPA 6010

14:01

17:11

EPA 6010

12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01

12/20/10 17:11

EPA6OIO

12/09/to

4:01 12/09/10 14:01 t109!O

12/20/10

7:!! 12/20/10 17:11 2120/10 17:11 12/20/10 17:11 12/20/10

17:11 12/20/10 17:11 12/20/10 17:11 12/20/tO 17:11 2/20/to

1401

17:11

96

12/09/10 14:01

12/20/10

0.48

2/09.10

1Z’20110

14:0! 12/09/10 14:01 12/09/10

14:01

17:11 12/20/to 17:11 12/20/tO 17:1!

0.48

12/09/10

12/20/10

14:01

17:1!

0.29

12/09/10

12/20/10

14:01 12/09/10 14:01

17:11 12/20/10 17:11

17:11

EPA 6010 EPA 6010

EPA 6010 EPA 6010 EPA

6010

EPA

6010

EPA 6010 EPA 6010 EPA 6010

EPA 6010 EPA6OIO EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010

1/4/11 10:55

C

CD

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 L).A.RT. Id: 10-0629

Project: 10-0629, Hercu?es Inc Reported by Jenny Scifres -

TCLP Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO8

E104009—10

Matrix: Waste

Station ID: HERCOS Date Collected: 9/29/10 8:50 ( IS Niuither

lnu4’re

Results Qua/fliers

7440-38-2

Arsenic:

NA-5

7440-39-3

Barium:

\A-5

7440-43-9 7440-47-3 7439-92-I 7782-49-2

7440-22-4

Page 24 of 34

Cadmium:

NA-5

NA-5

Chromium:

NA-5

Lead: Selenium:

NA-S

Silver:

NA-5

E104009 TCLPM TMTL FINAL

Units

MRL

Prepared

inulvzed

12/29110

0.10 0.10 0.10

0.40 0.90 0.10

Ofethod

EPA6OIO

EPA 6010

‘‘(° 122910

l2::0

EPA6OIO

12/29/10

1.0

EPA 6010

12/29/10 12/29110

EPA 6010 12129/10

EPA 6010

12//10

EPA 6010

1/4/11 10:55

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

Total Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO9-B Station ID: HERCO9

E104009-11

Matrix: Waste

Date Collected: 9/29/10 14:20 C IS .Vu,nhr

4na1fr

7429-90-5

Aluminum

Results QualifIers

7100

Units

mg/kg

MRL

9.6

7440-36-0

Antimony

3.8 U

mg/kg

7440-38-2

Arsenic

4.8 U

mg/kg

4.8

7440-39-3

Barium

23

mg/kg

0.48

7440-41-7

Beryllium

0.29 U

mg/kg

0.29

7440-43-9

Cadmium

0.48 U

mg/kg

0.48

7440-70-2

530

mg/kg

24

7440-47-3

Chromium

20

mg/kg

0.48

7440-48-4

Cobalt

10

mg/kg

0.48

7440-50-8

Copper

110

mg/kg

0.96

7439-89-6

Iron

3500

mg/kg

9.6

7439-92-1

Lead

25

mg/Icg

1.9

7439-95-4

Magnesium

160

mg/kg

24

7439-96-5

Manganese

39

mg/kg

0.48

7439-98-7

Molybdenum

13

mg/kg

0.96

7440-02-0

Nickel

150

mg/leg

0.96

7440-09-7

Potassium

160

mg/kg

96

7782-49-2

Selenium

4.3 U

mg/kg

7440-22-4

Silver

1.0

mg/kg

0.48

,

Calcium

3.8

7440-23-5

Sodium

150 J, QR-2

mg/kg

96

7440-24-6

Strontium

4.6

mg/kg

0.48

7440-28-0

Thallium

2.9 U

mg/kg

2.9

7440-32-6

Titanium

46

mg/kg

0.48

7440-62-2

Vanadium

5.9

mg/kg

0.48

7440-65-5

Yttrium

2.0

mg/kg

0.29

7440-66-6

Zinc

220

mg/kg

1.9

Page 25 of34

E104009 TCLPM TMTL FINAL

Prepared

lnalv:ed .lfethod

lZ’09’IO

12)20/10

14:01 12109110 14:01

l212o/lo

I2’09/IO

12120i10

14:01 12/09/lu l4:01 12/09/10 14:01 12)09/10 14:01 12/09/10 1401

17:19 12/20/10 17:19 2/20/10 7:19 12/20/10 17:19 2/20/10 7:19

12/09/10

12/20/10

14:01 12/09/10 14.01 12/09/10 14:01 12109/10 140I 12/09/10 14:01 12/09/10 4:01 12/09/10 14:01 12109/10 l4:0I 12/09/10 14:01 12/04/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 4:01 12/09/10 14:01 12/09/10 4:01 12/09/10 14:01 I2/09/I0 14:01 2/09/10 14:01

17:19 12/20/10 17:I9 12120/10 17:19 2/20/10 I7I9 12/20/10 17:19 12/20/tO 7:19 12/20/10 17:19 12/20/tO l7:I9 12/20/10 17:19 12)20/10 17:19 12120/10 7:19 12/20/IS 17:19 12)20/10 7:19 12/2010 17:19 12/20/10 7:19 12)20/b 17:19 2/20/10 17:19 12)20/10 17:19 2/20/ID 17:19

17:19 17:19

EPA6OIO EPA 6010 EPA 6010

EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010

EPA 6010

EPA 6010 EPA 6010

EPA6OIO EPA

60I0

EPA 6010 EPA 6010 EPA6OIO EPA6OIO EPA

6010

EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA

6010

EPA6OIO EPA 6010 EPA6OIO

1/4/11 10:55

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

TCLP Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERCO9-B

E104009-I1

Matrix: Waste

Station ID: HERCO9 Date Collected: 9/29/10 14:20 C4S Number

.4na!yte

7440-38-2

Arsenic:

7440-39-3

7440-43-9 7440-47-3 7439-92-1

7782-49-2 7440-22-4

Page 26 of 34

Results Qualifiers

V

Barium:

NA-5 NA-5

Cadmium:

NA-5

NA-S

Chromium: Lead:

NA-5

Selenium:

NA-S

Silver:

NA-5

E104009 TCLPM TMTL FINAL

Units

9IRL

1.0 0.10

0.10 0.10

0.40 0.90

0.10

Prepared 1212

.4nalyzed ;Otethod 120

12/0 12129,10

EPA 6010

EPA 6010 12129r10

12/29/10

EPA

6010

EPA 6010

‘°

1229/10

EPA 6010

‘°

12/29/10

EPA 6010

1229/10

1229,10

EPA 6010

1/4/11

10:55

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules nc- Reported by Jenny Scifres

Total Metals Project: 10-0629, Hercules Inc Lab 1D:

Sample ID: HERCIO-B Station ID: HERCIO

E104009-12

Matrix: Waste

Date Collected: 9/29/10 14:15 C4S Number

(nalyte

7429-90-5

Aluminum

Results Qualifiers

6400

Units

mg/kg

MRL

9.6

Prepared 12/09/10

.1nwy;ed iltethod 2/20/10

14:01

17:27

12/20/10

14:01

17:27 12/20/10 17:27 12/20/10 17:27

EPA 6010

7440-36-0

Antimony

3.9U

mg/kg

12/09/10

7440-38-2

Arsenic

5.0

mg/kg

4.8

12/09/10

7440-39-3

Barium

33

mg/lcg

0.48

7440-41-7

Beryllium

0.29 U

mg/kg

029

7440-43-9

Cadmium

0.48 U

mg/kg

0.48

7440-70-2

Calcium

2800

mg/kg

24

7440-47-3

Chromium

26

mg/kg

0.48

7440-48-4

Cobalt

14

mg/kg

0.48

7440-50-8

Copper

210

mg/kg

0.96

12109/10

17:27

EPA 6010

7439-89-6

Iron

3200

mg/kg

9.6

12/09/10 14:01

1120:10 17:27

EPA6OIO

12)20/10

7439-92-1

Lead

7439-95-4

Magnesium

7439-96-5

Manganese

7439-98-7

Molybdenum

7440-02-0

Nickel

7440-09-7

Potassium

7782-49-2

Selenium

7440-22-4

,

14:01 12)09/10 14:01 2/09/10

14:01 12/09/10 14:01 12/09/10 1401 12)09/10 14:01 12/09/10 14:01

14:01

12/20/10

17:27 12/20/10 17:27 12/20/10

17:27 12/20/10

17:27 12/20/10 17:27 12/20/10

EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010

23

mg/kg

1.9

14:01

17:27

200

rngkg

24

120910 14:1)1

12.20.10 17:27

EPA 6010

12/09/10 14:0!

12/20110 17:27

EPA 6010

12r09’IO

12/2010

14:01 12/09/10 14:01

17:27 12/20/10

36

mg/kg

0.48

mg/kg

0.96

340

mg/kg

0.96

220

mg/kg

4.3 C

mg/kg

Silver

0.48 U

mg/kg

0.48

7440-23-5

Sodium

210 J, QR-2

mg/kg

7440-24-6

Strontium

7.3

7440-28-0

Thallium

2.9 U

96

12/09/10

17:27 12/20/10

EPA6OIO EPA 6010 EPA 6010

1401

17:27 12)20)10

14:01 1109:10 14:01

12/20:10 17:27

EPA 6010

96

12/09/10

12)20/10

14:01

17:27

EPA 6010

mg/kg

0.48

12,09/10

1220/10

mg/kg

2.9

17:27

1401

‘27

12)09)10

12)20/10

EPA 6010 EPA

6010

17:27 12/2010 17:27

EPA 6010

12/20/10

EPA 6010

7440-32-6

Titanium

61

mg/kg

0.48

Vanadium

7.6

mg/kg

0.48

12)09/10

14:01

17:27

7440-65-5

Yttrium

1.2

mg/kg

0.29

12/09/10

12/20/10

14:01

17:27

7440-66-6

Zinc

1.9

12109/10

12/20/10

14:01

17:27

mg/kg

EPA 6010

14:01

7440-62-2

570

EPA6O1O

12/09/10

120910 l4 0!

El 04009 TCLPM TMTL FINAL

EPA 6010 EPA 6010

12109/10

6.4

Page 27 of 34

EPA 6010

EPA

6010

EPA 6010

1/4/11 10:55

C

0

UNITED STATES ENVIRONMENTAL PROTECTiON AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 DART. Id: 10-0629

Project: 10-0629, Hercules nc- Reported by Jenny Scifres

TCLP Metals Project: 10-0629, Hercules Inc Lab

Sample ID: HERC1O-B

m:

E104009-12

Matrix: Waste

Station ID: HERC1O Date Collected: 9/29/10 14:15 C.4S Number

.4nalyre

7440-38-2

Arsenic:

7440-39-3

7440439 7440-47-3 7439 92 1 7782-49-2 7440 22-4

Page 28 of 34

Results Qualijidrs

Units

NA-5

Banum:

NA-5

Cadmium

NA 5

Chromium:

\A-5

Lead

NA 5

Selenium:

NA-5

Silver

NA 5

E104009 TCLPM TMTL FINAL

MRL

Prepared

1.0

‘‘),°

0.10

-4l

010 0.10 0 40 0.90 0 10

2

Analyzed Method

EPA 6010 10

EPA 6010

12129110

l’’IO

1/10

12/0

12/29/10

12/29/10

hA 6010

12/29/10

2/29/10

EPA 6010

12/29/10

12’9/I0

EPA 6010

EPA 6010 EPA6O1O

1/4/11 10:55

0

0 **t

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700

t\

\

D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

Total Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERC1I-B

E104009-13

Matrix: Waste

Station ID: HERC1I Date Collected: 9/29/10 14:30 CIS N,,mhor

.4nalyte

7429-90-5

Aluminum

Results Qualifiers

7000

Units

mg/kg

7440-36-0

Antimony

3.9 U

mg/kg

7440-38-2

Arsenic

4.9 U

mg/kg

MRL

Prepared

9.8

12109fl0 14:01

1220110

4.9

12/09/10 14:0! 12/09/tO 14:01

12/20/10 17:34 2/20/10 1734 12/20/10 17:34 12/20/10

7440-39-3

Barium

23

mg/kg

0.49

12/09/10 14:01

7440-41-7

Beryllium

0.29 Ii

mg/kg

0.29

12)09/b l4:01

7440-43-9

Cadmium

0.49 U

mg/kg

0.49

7440-70-2

Calcium

350

mg/kg

25

12/09/10 14:01 12/09/10 14:01

Chromium

25

mg/kg

0.49

7440-47-3

-

7440-48-4

Cobalt

10

mg/kg

0.49

7440-50-8

Copper

93

mg/kg

0.98

7439-89-6

Iron

1900

mg/kg

9.8

7439-92-1

Lead

23

mg/kg

2.0

7439-95-4

Magnesium

170

mg/kg

25

7439-96-5

Manganese

7439-98-7

Molybdenum

14

mg/kg

0.49

4.0

mg/kg

0.98

7440-02-0

Nickel

140

mg/lcg

7440-09-7

Potassium

160

mg/kg

7782-49-2

Selenium

4.4 U

mg/kg

7440-22-4

Silver

0.49 U

mg/lcg

0.49

7440-23-5

Sodium

180 J, QR-2

mg/kg

98

7440-24-6

Strontium

4.2

mg/kg

0.49

7440-28-0

Thallium

2.9 U

mg/kg

2.9

7440-32-6

Titanium

52

mg/kg

0.49

7440-62-2

Vanadium

7.2

mg/lcg

0.49

7440-65-5

Yttrium

1.2

mg/kg

0.29

7440-66-6

Zinc

270

mg/kg

2.0

Page 29 of 34

E104009 TCLPM TMTL FINAL

Analyzed Method

0.98 98

12)09/10 14:01 12/09/10 14:0! 12/09/10 14:0! 2/09/TO

14:01 12)09/10 14:01 12:09/ID

401

1734

17:34 12/20/10 17:34 12/20/10 17:34

12/20/10 17:34 12/20/10 17:34 12/20/10 17:34 12/20/10 17:34 12/20/10 17:34 12/20/10

14:01 12)09/10 14:01

17:34 12/20/1(1 17:34 12/20/10 l7:34

12/09/10

12/20/10

12/09/10

14:01 2/09/10 14:01 12)09/10 14:01 12/09/10 14:01 12/09/10 14:01 2/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12)09/10 14:01 12/09/10 14:01 12/09/10 14:01

EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA6OIO EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010

EPA 6010 EPA 6010

17:34

EPA 6010

12/20/10

EPA 6010

17:34 12/20/10 17:34 12/20/10 17:34 12/20/10 17:34 12/20/10 17:34 12/20/10 17:34 12/20/10 17:34 12)20/10 17:34 12/20/10 17:34 12/20/10 17:34

EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010

1/4/11 10:55

0

. 9 i:

C

UNiTED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700

cJ

D.A.R.T. Ed: 10-0629 Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

TCLP Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERC1I-B

E104009-13

Matrix: Waste

Station ID: HERC1I Date Collected: 9/29/10 14:30 ( IS .Vu,nhcr

.4nalyte

7440-38-2

Arsenic:

Resulis Qualifiers

NA-5

Units

MRL

1.0

7440-39-3

Barium:

NA5

0.10

7440-43-9

Cadmium:

NA-S

0.10

7440-47-3

Chromium:

NA-5

0.10

7439-92-1

Lead:

NA-5

0.40

7782-49-2

Selenium:

NA-S

0.90

7440-22-4

Siher:

NAS

0.10

Page 30

of34

B 104009 TCLPM TMTL FINAL

Prepared 2129110 0:38

12/29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:38 12/29/10 10:38

Analyzed 12/29/10 10:41 12/29/10 10:41 12/29/10 10:41 12/29/10 10:41 12/29/10 10:41 12/29/10 10:41 12129/10 10:41

llethod

EPA6OIO EPA 6010 EPA6OIO EPA6OIO EPA 6010

EPA 6010 EPA 6010

1/4/11 10:55

0

0 t’aO ST 61

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Suppo Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Jenny Scifres

PR

-

Total Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERC12-B Station ID: HERCI2

E104009-14

Matrix: Waste

Date Collected: 9/29/10 14:50 .‘V,,,nher

4nolyte

7429-90-5

Aluminum

7440-36-0

Antimony

3.7 U

mg/kg

7440-38-2

Arsenic

4.6 U

mg/kg

Results Qualifiers

6700

Units

mg/kg

1IRL

9.1

4.6

7440-39-3

Barium

30

mg/kg

0.46

7440-41-7

Beryllium

0.27 U

mg/kg

0.27

7440-43-9

Cadmium

0.46 U

mg/kg

0.46

7440-70-2

Calcium

1200

mg/kg

23

7440-47-3

Chromium

18

mg/kg

0.46

13

mg/kg

0.46

110

mg/kg

0.91

4700

mg/kg

9.1

7440-48-4

Cobalt

7440-50-8

Copper

7439-89-6

Iron

7439-92-1

Lead

7439-95-4

Magnesium

7439-96-5

Manganese

7439-98-7

Molybdenum

7440-02-0

Nickel

7440-09-7

Potassium

7782-49-2

Selenium

7440-22-4

Silver

7440-23-5

Sodium

7440-24-6

Strontium

7440-28-0

Thallium

18

mg/kg

1.8

210

mg/kg

23

36

mg/lcg

0.46

2.8

mg/kg

0.91

270

mg/leg

0.91

170

mg/kg

91

4.1 U

mg/kg

4.1

0.46 U

mg/kg

0.46

mg/kg

91

8.5

mg/kg

0.46

2.7 U

mg/kg

2.7

240 3, QR-2

7440-32-6

Titanium

54

mg/kg

0.46

7440-62-2

Vanadium

7.5

mg/kg

0.46

7440-65-5

Yttrium

1.6

mg/kg

0.27

7440-66-6

Zinc

370

mg/kg

1.8

Page 31 of 34

El 04009 TCLPM TMTL FINAL

Prepared

.lnatyzed Method

12/09/10

12/20/10

14:01 12/09/10 14:01 12/09/10

17:42 12120/10 17:42 12/20)10

14:01

17:42

12/09/10 14:01 12/09/10

12/20/10 17:42 12/20/tO

14:01

17:42

12/09/10 14:01 12/09/10

12/20/10 17:42 12/20/10

14:01

17:42

12/09/10 14:01 12109/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01

12/20/10 17:42 12/20/10 17:42 12/20/10 17:42 7:42 12/20/10 17:42 12/20/10 17:42 12/20/10 17:42

12109/tO

12/20/10

14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12109/10 14:01

17:42 12/20/10 17:42 12/20/10 17:42 12/20/10 17:42 12/20/10 17:42

12)09/10

12/20/10

14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 14:01 12/09/10 1401 12/09/10 14:01

17:42 12120/10 17:42 12/20/10 17:42 12/20/10 17:42 12/20/10 17:42 12/20/10 17:42 12120/10 17:42

12/20/10

EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010

EPA 6010 EPA 6010

EPA 6010 EPA 6010 EPA 6010

EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA6OIO EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010

EPA 6010 EPA 6010 EPA 6010

EPA 6010 EPA 6010

1/4/11 10:55

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

TCLP Metals Project: 1OO629, Hercules Inc Lab ID:

Sample ID: HERCI2-B

E104009-14

Matrix: Waste

Station ID: UERCI2 Date Collected: 9/29/10 14:50

c.is Results Qualifiers

Units

MRL

,Vu,uber

.4nalvre

7440-38-2

Arsenic:

7440-39-3

Barium:

NA-5

0.10

7440-43-9

Cadmium:

NA5

0.10

7440-47-3

Chromium:

A-5

0.10

7439-92-1

Lead:

NA-5

0.40

7782-49-2

Selenium:

NA5

0.90

7440-22-4

Silver:

NA-5

0.10

Page 32 of34

NA-5

E104009 TCLPM TMTL FINAL

1.0

Prepared 12/29/10 1038 12/29/10 0:38 12/29/10 10:38 12129/10 10:30 12/29/10 10:38 12/29/10 10:38 12/29/10 1038

.lnatr;ed llethod 12129/10 0:41 12/29/10 10:41 12/29/tO 10:41 12/29/10 10:41 12/29/10 10:41 12/29/10 10:41 12/29/10 10:41

EPA 6010 EPA6O1O EPA 6010

EPA 6010 EPA 6010 EPA 6010 EPA6OIO

1/4/11 10:55

0

0

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629 Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

Total Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: HERC13-B Station ID: HERCI3

E104009-15

Matrix: Waste

Date Collected: 9/29/10 15:10 C4S Niunher

4nalyte

7429-90-5

Aluminum

7440-36-0

Antimony

3.7 U

mg/kg

7440-3t1-2

Arsenic

5.6

mg/kg

4.6

7440-39-3

Barium

45

mg/kg

0.46

7440-41-7

Beryllium

0.27 U

mg/kg

0.27

7440-43-9

Cadmium

0.46 U

mg/kg

0.46

7440-70-2

Calcium

1700

mg/kg

23

7440-47-3

Chromium

36

mg/kg

0.46

7440-48-4

Cobalt

21

mg/kg

0.46

7440-50-8

Copper

7439-89-6

Iron

7439-92-1

Lead

7439-95-4

Magnesium

7439-96-5

Manganese

7439-98-7

Molybdenum

7440-02-0

Results Qualifiers

6800

Units mg/kg

MRL

9.1

12109/10

12/20/10

14:01 12)09/10 14:01 12109/10 1401 12)09/10 14:01 2/09/10

1750 12/20/10 17:50 12120/10 750 12120/10 17:50

12120/10 17:50 12/20/10 1750 12/20/10

14:01 12/09/10

17:50 1120/10

l750 12)20/10 17:50

EPA 6010 EPA6OIO

0.91

mg/kg

9.1

l2Jo9lO 14:01

12120’IO 7:50

12)09)10 14:01 12/09/10

12)20/10 17:50 12/20/10

mg/kg

1.8

mg/kg

23

mg/kg mg/kg

0.91

Nickel

490

mg/kg

0.91

7440-09-7

Potassium

190

mg/kg

91

7782-49-2

Selenium

4.1 U

mg/kg

4.1

7340-22-4

Silver

0.46 U

mg/kg

0.46

7440-23-5

Sodium

230 1, QR-2

mg/kg

91

7440-24-6

Strontium

8.9

mg/kg

0.46

7440-28-0

Thallium

2.7 U

mg/kg

2.7

7440-32-6

Titanium

76

mg/kg

0.46

7440-62-2

Vanadium

9.0

mg/kg

0.46

7440-65-5

Yttrium

1.2

mg/kg

0.27

7440-66-6

Zinc

480

mg/kg

1.8

0.46

[P\ 6010 EPA 6010

12)09/10 14:01 12109/10 14:01 12/09/10

mg/kg

36

EPA 6010

EPA 6010

12120/10 17:50

210

150

llethad

14:01

3100

15

El 04009 TCLPM TMTL FINAL

tnalvzed

12)09/10 14:01

5.6

Page 33 of 34

Prepared

1401

1750

12)09/10 14:01 12/09/10 14:01 12)09/10 1401 12100/10

12/20/10 17:50 12/20/10 17:50 12/20/10 17:50 12/20/10

14:01

750

12/09/10 14:01 12:09/10

12/20/10 17:50 12/20/10

14:01

17:50

12)09/10 14:01 12109/10

12/20/10 17:50 12/20/10

14:01

17:50

12109/10 14:01 12/09/10 14:01

12)20/10 17:50 12/20/10 17:50

12/09/10

12/20/10

14:01 12109/10 14:01 12/09/10 14:01

17:50 12/20/10 17:50 12/20/10 17:50

EPA 6010

EPA 6010 EPA 6010 EPA 6010 EPA 6010

EPA 6010

EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010 EPA 6010

EPA 6010 EPA 6010 EPA 6010

1/4/11 10:55

0

0

UN[TED STATES ENVIRONMENTAL PROTECTION AGENCY Region 4 Science and Ecosystem Support Division 980 College Station Road, Athens, Georgia 30605-2700 D.A.R.T. Id: 10-0629

Project: 10-0629, Hercules Inc Reported by Jenny Scifres -

TCLP Metals Project: 10-0629, Hercules Inc Lab ID:

Sample ID: I{ERC13-B

E104009-15

Matrix: Waste

Station ID: HERC13 Date Collected: 9/29/10 15:10 C4S Number

.4ntilvte

7440-38-2

Arsenic:

Results

Qualifiers

NA-S

Units

11RL

1.0

7440-39-3

Barium:

NA-5

0.10

7440-439

Cadmium:

NA-S

0.10

7440-47-3 7439-92-1

Chromium:

NA-S

NA-S

Lead:

0.10 0.40

7782-49-2

Selenium:

NA-S

0.90

7440-22-4

Silver:

NA-S

0.10

Prepured

.4 nO! ‘zed Ofethod

‘°

EPA 6010

j’’°

EPA 6010

I2)2910

122910

EPA 6010

12/29/10

12/2900

EPA 6010

I2r29I0

0

EPA 6010

12)29/10

12/290

EPA 6010

21010

12,29/10

IPA 6010

End of Report

Page 34 of 34

E104009 TCLPM TMTL FiNAL

1/4/11 10:55